scholarly journals Polymer Architectures for Optical and Photonic Applications

2021 ◽  
Author(s):  
Ana-Maria Albu ◽  
Vlad Marian Târpă
Keyword(s):  
High Performance ◽  
Organic Materials ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Optical Nonlinearity ◽  
Fundamental Relationship ◽  
Polymer Architectures ◽  
Materials Used ◽  
Molecule Interactions ◽  
Relationship Of

The last decade of the last century is marked by a revolution in the synthesis of materials for optical and photonic applications, against the background of the growing need for new high-performance materials to increase the efficiency, reliability and speed of response linked to environmental aspects. The diversity of requirements and the optimization of the responses has led to a major dispute over the structure and composition of these materials: Inorganic or Organic, Natural or Synthetic, Hybrid or Pure, which has stimulated interest in the development of various architectures. Special attention shall be paid to establishing a fundamental relationship to correlate the non-linear optical response and chemical structure, especially for the category of organic materials- particularly polymers- distinguished by structural/compositional versatility and suitable for processing by simple technique which allows serial production. In fact, optical nonlinearity (NLO) is not an exotic phenomenon. Indeed, all materials are optically nonlinear if light is sufficiently intense. The synthesis of functional photonic organic materials is a major challenge of contemporary community of material scientists to imagine new functional materials based of” collective” phenomena by virtue of the “engineered” molecule- molecule interactions and spatial relationships. In this context, this paper aims to highlight the most important features concerning the structural - compositional relationship of polymeric materials used in optoelectronic and photonic applications.

Molecular materials for micro-electronics

2000 ◽  
Vol 78 (3) ◽  
pp. 231-241 ◽  
Author(s):  
M D'Iorio
Keyword(s):  
High Performance ◽  
Organic Materials ◽  
Coming Of Age ◽  
Polymeric Materials ◽  
Organic Light Emitting Diodes ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Plastic Electronics ◽  
Organic Light ◽  
Recent Developments

Molecular organic materials have had an illustrious past but the ability to deposit these as homogeneous thin films has rejuvenated the field and led to organic light-emitting diodes (OLEDs) and the development of an increasing number of high-performance polymers for nonlinear and electronic applications. Whereas the use of organic materials in micro-electronics was restricted to photoresists for patterning purposes, polymeric materials are coming of age as metallic interconnects, flexible substrates, insulators, and semiconductors in all-plastic electronics. The focus of this topical review will be on organic light-emitting devices with a discussion of the most recent developments in electronic devices.PACS Nos.: 85.60Jb, 78.60Fi, 78.55Kz, 78.66Qn, 73.61Ph, 72.80Le

High-performance polymer composites with enhanced mechanical and thermal properties from cyanate ester/benzoxazine resin and short Kevlar/glass hybrid fibers

2018 ◽  
Vol 31 (6) ◽  
pp. 719-732 ◽  
Author(s):  
Abdeldjalil Zegaoui ◽  
Mehdi Derradji ◽  
Abdul Qadeer Dayo ◽  
Aboubakr Medjahed ◽  
Hui-yan Zhang ◽  
...  
Keyword(s):  
Thermal Properties ◽  
High Performance ◽  
Hybrid Composites ◽  
Glass Fibers ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Cyanate Ester ◽  
Resin Matrix ◽  
Mechanical And Thermal Properties ◽  
Hybrid Fibers

The investigation and design of new polymeric materials with an astonishing combination of properties are nowadays of great importance to facilitate the manufacturing process of high-quality products intended to be utilized in different applications and technical fields. For this intent, novel high-performance blend composites composed of the cyanate ester/benzoxazine resin blend reinforced by different proportions of silane-surface modified Kevlar and glass fibers were successfully fabricated by a compression molding technique and characterized by different experimental tests. The mechanical test results revealed that the bending and impact strength properties were considerably improved when increasing the amount of the hybrid fibers. The studied materials also presented excellent thermal stabilities as compared to the unfilled blend’s properties. With respect to the properties of the reinforcing systems, these improvements seen in either the mechanical or thermal properties could be due to the good dispersion as well as excellent adhesion of the reinforcing fibers inside the resin matrix, which were further evidenced by the Fourier transform infrared spectroscopy and scanning electron microscopy results. Consequently, the improved mechanical and thermal properties promote the use of the fabricated hybrid composites in domestic and industrial applications requiring functional materials with advanced properties for aerospace and military applications.

Pyridyl disulfide-based thiol–disulfide exchange reaction: shaping the design of redox-responsive polymeric materials

2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal
Keyword(s):  
Exchange Reaction ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Disulfide Exchange ◽  
Redox Responsive ◽  
Synthetic Approaches

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

High-Performance Polymeric Materials

1987 ◽  
Author(s):  
J. E. Mark
Keyword(s):  
High Performance ◽  
Polymeric Materials

scholarly journals Research and application progress of lignin-based composite membrane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Youjing Li ◽  
Fen Li ◽  
Ying Yang ◽  
Baocai Ge ◽  
Fanzhu Meng
Keyword(s):  
Environmental Pollution ◽  
Raw Materials ◽  
Waste Product ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Composite Membranes ◽  
Organic Polymer ◽  
Future Research ◽  
Sustainable Resources ◽  
New Perspective

Abstract In view of the serious environmental pollution, which is the greatest problem the world is facing, and the continuous consumption of raw materials, it is imminent to search for green and sustainable resources. Lignin is an organic polymer that exists widely in nature, and if it can be transformed from traditional low-value waste product with low range of applications to functional materials with high application prospects, it can be of great significance to alleviate environmental pollution and shortage of fossil resources. One of the functional applications of lignin involves its use to fabricate composite with other polymeric materials, which can then be used to prepare membrane materials. This review summarizes the recent research and application progress of combining lignin with polypropylene, polyvinyl alcohol, starch, cellulose, chitosan, and other polymeric materials to prepare composite membranes; and summarizes the future development direction of lignin-based composite membranes. We hope this review may provide a new perspective to the understanding of lignin-based composite membranes and a useful reference for future research.

scholarly journals Elucidation of the Crystal Growth Characteristics of SnO2 Nanoaggregates Formed by Sequential Low-Temperature Sol-Gel Reaction and Freeze Drying

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1738
Author(s):  
Saeid Vafaei ◽  
Alexander Wolosz ◽  
Catlin Ethridge ◽  
Udo Schnupf ◽  
Nagisa Hattori ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Low Temperature ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
Freeze Drying ◽  
Sno2 Nanoparticles ◽  
Sol Gel ◽  
Functional Materials ◽  
Cost Effective ◽  
High Concentration

SnO2 nanoparticles are regarded as attractive, functional materials because of their versatile applications. SnO2 nanoaggregates with single-nanometer-scale lumpy surfaces provide opportunities to enhance hetero-material interfacial areas, leading to the performance improvement of materials and devices. For the first time, we demonstrate that SnO2 nanoaggregates with oxygen vacancies can be produced by a simple, low-temperature sol-gel approach combined with freeze-drying. We characterize the initiation of the low-temperature crystal growth of the obtained SnO2 nanoaggregates using high-resolution transmission electron microscopy (HRTEM). The results indicate that Sn (II) hydroxide precursors are converted into submicrometer-scale nanoaggregates consisting of uniform SnO2 spherical nanocrystals (2~5 nm in size). As the sol-gel reaction time increases, further crystallization is observed through the neighboring particles in a confined part of the aggregates, while the specific surface areas of the SnO2 samples increase concomitantly. In addition, X-ray photoelectron spectroscopy (XPS) measurements suggest that Sn (II) ions exist in the SnO2 samples when the reactions are stopped after a short time or when a relatively high concentration of Sn (II) is involved in the corresponding sol-gel reactions. Understanding this low-temperature growth of 3D SnO2 will provide new avenues for developing and producing high-performance, photofunctional nanomaterials via a cost-effective and scalable method.

Evaluation of Abrasive Wear of Polymeric Materials Using Single-Pass Pendulum Scratching

2002 ◽  
Author(s):  
Marcelo Torres Piza Paes ◽  
Antonio Marcos Rego Motta ◽  
Lauro Lemos Lontra Filho ◽  
Juliano Ose´ias de Morais ◽  
Sine´sio Domingues Franco
Keyword(s):  
Deep Water ◽  
Wear Mechanisms ◽  
Degradation Mechanism ◽  
Single Point ◽  
Polymeric Materials ◽  
Scratch Resistance ◽  
Wear Behaviour ◽  
Sediment Layer ◽  
Materials Used ◽  
Energy Dissipated

Scratching abrasion due to rubbing against the sediment layer is an important degradation mechanism of flexible cable in deep water oil and natural gas exploitation. The present study was initiated to gain relevant data on the wear behaviour of some commercial materials used to externally protect these cables. So, Comparison tests were carried out using the single-point scratching technique, which consists of a sharp point mounted at the extremity of a pendulum. The energy dissipated during the scratching is used to evaluate the relative scratch resistance. The results showed, that the contact geometry strongly affects the specific scratching energy. Using SEM imaging, it was found, that these changes were related to the operating wear mechanisms. The observed wear mechanisms are also compared with those observed on some cables in deep water operations.

scholarly journals Environmentally Friendly, High-Performance Fire Retardant Made from Cellulose and Graphite

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2400
Author(s):  
Leandra P. Santos ◽  
Douglas S. da Silva ◽  
Thais H. Morari ◽  
Fernando Galembeck
Keyword(s):  
High Performance ◽  
Raw Materials ◽  
Fire Retardant ◽  
Visual Observation ◽  
Flame Resistance ◽  
New Developments ◽  
New Class ◽  
New Material ◽  
Accredited Laboratory ◽  
Materials Used

Many materials and additives perform well as fire retardants and suppressants, but there is an ever-growing list of unfulfilled demands requiring new developments. This work explores the outstanding dispersant and adhesive performances of cellulose to create a new effective fire-retardant: exfoliated and reassembled graphite (ERG). This is a new 2D polyfunctional material formed by drying aqueous dispersions of graphite and cellulose on wood, canvas, and other lignocellulosic materials, thus producing adherent layers that reduce the damage caused by a flame to the substrates. Visual observation, thermal images and surface temperature measurements reveal fast heat transfer away from the flamed spots, suppressing flare formation. Pinewood coated with ERG underwent standard flame resistance tests in an accredited laboratory, reaching the highest possible class for combustible substrates. The fire-retardant performance of ERG derives from its thermal stability in air and from its ability to transfer heat to the environment, by conduction and radiation. This new material may thus lead a new class of flame-retardant coatings based on a hitherto unexplored mechanism for fire retardation and showing several technical advantages: the precursor dispersions are water-based, the raw materials used are commodities, and the production process can be performed on commonly used equipment with minimal waste.

Sign in / Sign up

Export Citation Format

Share Document