scholarly journals Effect of Silica Nanoparticles on Activation Energy of Phenol Novolac Epoxy Resin/Unsaturated Polyester at Various Temperatures

2019 ◽  
pp. 1-9
Author(s):  
Seyyed Mojtaba Mousavi ◽  
Seyyed Alireza Hashemi ◽  
Ali Mohammad Amani ◽  
Amir Savar Dashtaki ◽  
Mohammad Reza Jamshidi ◽  
...  
Keyword(s):  
Activation Energy ◽  
Silica Nanoparticles ◽  
Unsaturated Polyester ◽  
Silica Nanoparticle ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Ultrasonic Equipment ◽  
The Matrix ◽  
Tetraethylene Pentamine ◽  
Novolac Epoxy

In the current study, the activation energy of modified phenol novolac epoxy (PNE) resin with unsaturated polyester (UPS) and silica nanoparticle (SN) at different filler loadings was investigated. In this case, effect of silica nanoparticles as a nano-size filler on the activation energy of PNE/UPS blend was evaluated. For this matter, tetraethylene pentamine (HA-11) which is an amine hardener was used as curing agent. SNs were dispersed in the mixture using ultrasonic equipment to prevent their agglomeration. The curing reaction of epoxy-based resins is exothermic. In this regard, the dynamic curing process was studied using differential scanning calorimetry (DSC) in four different heating rates, including 2, 5, 10 and 15 °C/min. Besides, various methods, including Ozawa, Flynn-Wall, Friedman and Butchart-Denilez were used to determine whether the activation energy of PNE/UPS blend or the best method for calculation of activation energy. Achieved results showed that the addition of SNs to the matrix can increase the activation energy and thus increase the curing time.

scholarly journals Formation of metal oxide-based hydroxysodalite by alkali-activation of kaolinite

Chemija ◽  
2020 ◽  
Vol 31 (3) ◽  
Author(s):  
Ehab AlShamaileh ◽  
Muayad Esaifan ◽  
Qusay Abu-Afifeh
Keyword(s):  
Activation Energy ◽  
Metal Oxide ◽  
Alkali Activation ◽  
Dsc Analysis ◽  
X Ray Diffraction ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Xrd Study ◽  
Dsc Curves

The formation of metal oxide-based hydroxysodalite by alkali-activation of kaolinite is studied using X-ray diffraction (XRD) study and differential scanning calorimetry (DSC) analysis. Different metal oxides (CoO, MgO, FeO and SiO2) were used to form the metal oxide-based hydroxysodalite. The transformation from kaolinite into hydroxysodalite is confirmed by XRD. In the thermodynamic study, the maximum peak temperatures for DSC curves at various heating rates were used to determine the activation energy (Ea) of the hydroxysodalite formation. With magnesium oxide and cobalt oxide, the formation process was found to be exothermic while it was endothermic with iron oxide.

Thermo Mechanical behaviour of Phenol Novolac Resin and Unsaturated Polyester Toughened Epoxy using nano Bentonite and Silica Nanoparticles

2020 ◽  
Vol 1 (3) ◽  
pp. 77-83
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Silica Nanoparticles ◽  
Moisture Absorption ◽  
Unsaturated Polyester ◽  
Physical And Mechanical Properties ◽  
Bending Test ◽  
Mechanical And Thermal Properties ◽  
Novolac Epoxy ◽  
Industrial Needs

Phenol novolac epoxy resin is a polymer matter which its properties can be modified for industrial needs. In this research, nanocomposites of phenol novolac epoxy resin and unsaturated polyester are made nano Bentonite and silica nanoparticles as filler. For this purpose, effect of nanoparticles percent on nanocomposite formation is studied and their physical, mechanical and thermal properties are obtained. The presence of unsaturated polyester in this process forms a cross-link capable of improving the physical and mechanical properties of epoxy resin. Fracture behavior was determined by a SEM device. Moreover, TGA, DSC, impact tests and bending test were applied for data analysis. When process ability is growing, moisture absorption decreases. Fracture toughness was also evaluated in a stoichiometric network. Physical and mechanical properties improve significantly with increasing nanoparticles. The most important reason for using this nanocomposite is its high resistance to corrosion.

scholarly journals Non-Isothermal Sublimation Kinetics of 2,4,6-Trinitrotoluene (TNT) Nanofilms

Molecules ◽  
2019 ◽  
Vol 24 (6) ◽  
pp. 1163 ◽  
Author(s):  
Walid Hikal ◽  
Brandon Weeks
Keyword(s):  
Activation Energy ◽  
Analytical Techniques ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Absorbance Spectroscopy ◽  
Calculated Activation Energy ◽  
Sublimation Kinetics ◽  
Sublimation Rates ◽  
First Time ◽  
Kinetics Of

Non-isothermal sublimation kinetics of low-volatile materials is more favorable over isothermal data when time is a crucial factor to be considered, especially in the subject of detecting explosives. In this article, we report on the in-situ measurements of the sublimation activation energy for 2,4,6-trinitrotoluene (TNT) continuous nanofilms in air using rising-temperature UV-Vis absorbance spectroscopy at different heating rates. The TNT films were prepared by the spin coating deposition technique. For the first time, the most widely used procedure to determine sublimation rates using thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) was followed in this work using UV-Vis absorbance spectroscopy. The sublimation kinetics were analyzed using three well-established calculating techniques. The non-isothermal based activation energy values using the Ozawa, Flynn–Wall, and Kissinger models were 105.9 ± 1.4 kJ mol−1, 102.1 ± 2.7 kJ mol−1, and 105.8 ± 1.6 kJ mol−1, respectively. The calculated activation energy agreed well with our previously reported isothermally-measured value for TNT nanofilms using UV-Vis absorbance spectroscopy. The results show that the well-established non-isothermal analytical techniques can be successfully applied at a nanoscale to determine sublimation kinetics using absorbance spectroscopy.

scholarly journals Hydrothermal Synthesis of Hematite Nanoparticles Decorated on Carbon Mesospheres and Their Synergetic Action on the Thermal Decomposition of Nitrocellulose

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 968 ◽  
Author(s):  
Abdenacer Benhammada ◽  
Djalal Trache ◽  
Mohamed Kesraoui ◽  
Salim Chelouche
Keyword(s):  
Activation Energy ◽  
Thermal Decomposition ◽  
Analytical Techniques ◽  
Decomposition Reaction ◽  
Decomposition Temperature ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Nano Catalyst ◽  
Average Size ◽  
A Minor

In this study, carbon mesospheres (CMS) and iron oxide nanoparticles decorated on carbon mesospheres (Fe2O3-CMS) were effectively synthesized by a direct and simple hydrothermal approach. α-Fe2O3 nanoparticles have been successfully dispersed in situ on a CMS surface. The nanoparticles obtained have been characterized by employing different analytical techniques encompassing Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM). The produced carbon mesospheres, mostly spherical in shape, exhibited an average size of 334.5 nm, whereas that of Fe2O3 supported on CMS is at around 80 nm. The catalytic effect of the nanocatalyst on the thermal behavior of cellulose nitrate (NC) was investigated by utilizing differential scanning calorimetry (DSC). The determination of kinetic parameters has been carried out using four isoconversional kinetic methods based on DSC data obtained at various heating rates. It is demonstrated that Fe2O3-CMS have a minor influence on the decomposition temperature of NC, while a noticeable diminution of the activation energy is acquired. In contrast, pure CMS have a slight stabilizing effect with an increase of apparent activation energy. Furthermore, the decomposition reaction mechanism of NC is affected by the introduction of the nano-catalyst. Lastly, we can infer that Fe2O3-CMS may be securely employed as an effective catalyst for the thermal decomposition of NC.

scholarly journals Thermal Analysis On The Kinetics Of Magnesium-Aluminum Layered Double Hydroxides In Different Heating Rates

2015 ◽  
Vol 60 (2) ◽  
pp. 1357-1359 ◽  
Author(s):  
Y. Hongbo ◽  
C. Meiling ◽  
W. Xu ◽  
G. Hong
Keyword(s):  
Activation Energy ◽  
Thermal Analysis ◽  
Layered Double Hydroxides ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Exponential Factor ◽  
Thermal Kinetic Parameters ◽  
Double Hydroxides ◽  
Kinetics Of ◽  
Dsc Curves

Abstract The thermal decomposition of magnesium-aluminum layered double hydroxides (LDHs) was investigated by thermogravimetry analysis and differential scanning calorimetry (DSC) methods in argon environment. The influence of heating rates (including 2.5, 5, 10, 15 and 20K/min) on the thermal behavior of LDHs was revealed. By the methods of Kissinger and Flynn-Wall-Ozawa, the thermal kinetic parameters of activation energy and pre-exponential factor for the exothermic processes under non-isothermal conditions were calculated using the analysis of corresponding DSC curves.

Kinetics Study on Non-Isothermal Crystallization of Amorphous Alloy Mg65Cu15Ag10Y10

2011 ◽  
Vol 413 ◽  
pp. 432-438
Author(s):  
Xiao Jun Wang ◽  
Tian Dong Xia ◽  
Xue Ding Chen
Keyword(s):  
Activation Energy ◽  
Amorphous Alloy ◽  
Heating Rate ◽  
Volume Fraction ◽  
Strong Dependence ◽  
Continuous Heating ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Local Activation ◽  
Local Activation Energy

The crystallization kinetics of amorphous alloy Mg65Cu15Ag10Y10has been studied by differential scanning calorimetry in the mode of continuous heating annealing. It is found that both DSC curves and activation energy show a strong dependence on the heating rate. The activation energy for crystallization are determined as 186.1 and 184.4 KJ mol−1for the heating rates β=5-20 Kmin−1, and 107.5 and 110.0 KJmol−1for the heating rates β=20-80Kmin−1, when using the Kissinger equation and the Ozawa equation, respectively. Local activation energy at any volume fraction crystallized was obtained by the general Ozawa's isoconversional method. The average value of local activation energy for heating rates ranging from 5 to 20Kmin−1is 180.9 KJ mol−1and for heating rates ranging between 20 and 80Kmin−1is 110.2 KJ mol−1. Using the Suriñach curve fitting procedure, the kinetics mode was specified. The JMA kinetics is manifested as a rule in the early stages of the crystallization. The JMA exponent,n, initially being larger than 4 and continuously decreases to about 2 along with the development of crystallization. The NGG-like mode dominates in the advanced stages of the transformation. These two modes are mutually independent. The proportion between the JMA-like and the NGG-like modes is related to the heating rate.

Crystallization Kinetics in Cu64.5Zr35.5 Binary Metallic Glass

2017 ◽  
Vol 727 ◽  
pp. 233-238 ◽  
Author(s):  
Qian Gao ◽  
Zeng Yun Jian ◽  
Jun Feng Xu ◽  
Man Zhu
Keyword(s):  
Activation Energy ◽  
Grain Growth ◽  
Crystallization Kinetics ◽  
Crystallization Process ◽  
Crystallization Kinetic ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Growth Activation ◽  
Local Activation Energy ◽  
Kinetics Of

The crystallization kinetics of melt-spun Cu64.5Zr35.5 amorphous alloy ribbons was investigated using differential scanning calorimetry (DSC) at different heating rates. Besides, the Kissinger and isoconversional approaches were used to obtain the crystallization kinetic parameters. As shown in the results, the activation energies for glass transition and crystallization process at the onset, peak and end crystallization temperatures were obtained by means of Kissinger equation to be 577.65 ± 34, 539.86 ± 54, 518.25 ± 20 and 224.84 ± 2 kJ/mol, respectively. The nucleation activation energy Enucleation is greater than grain growth activation energy Egrowth, indicating that the nucleation process is harder than grain growth. The local activation energy Eα decreases in the whole crystallization process, which suggests that crystallization process is increasingly easy.

Preparation, Morphology and Thermal Properties of Rubber-Modified Polyester Resins

e-Polymers ◽  
2007 ◽  
Vol 7 (1) ◽  
Author(s):  
M O Munyati ◽  
P A Lovell
Keyword(s):  
Thermal Properties ◽  
Polyester Resin ◽  
Unsaturated Polyester ◽  
Matrix Material ◽  
Good Control ◽  
Resin Matrix ◽  
Scanning Calorimetry ◽  
Polyester Resins ◽  
The Matrix ◽  
Size And Morphology

AbstractThe preparation of polyester resin blends consisting of an unsaturated polyester resin matrix and rubbery particles comprising three radially-alternating glassy and rubbery layers is described. The morphology of the resin blends was examined by transmission electron microscopy (TEM) while thermal properties were investigated by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA). The results show that the particles were prepared with good control of particle size and morphology. DMTA results showed no reduction in the Tg of the matrix whilst the shear modulus of modified materials was found to be lower than that of the matrix material.

scholarly journals A Comparative Study of Dispersion Techniques for Nanocomposite Made with Nanoclays and an Unsaturated Polyester Resin

2011 ◽  
Vol 2011 ◽  
pp. 1-12 ◽  
Author(s):  
Farida Bensadoun ◽  
Nadir Kchit ◽  
Catherine Billotte ◽  
François Trochu ◽  
Edu Ruiz
Keyword(s):  
Rheological Behavior ◽  
Polyester Resin ◽  
Unsaturated Polyester ◽  
Unsaturated Polyester Resin ◽  
Liquid Composite Molding ◽  
Scanning Calorimetry ◽  
Polymer Resin ◽  
The Matrix ◽  
Shear Mixing ◽  
Mixing Method

Over the last few years, polymer/clay nanocomposites have been an area of intensive research due to their capacity to improve the properties of the polymer resin. These nanocharged polymers exhibit a complex rheological behavior due to their dispersed structure in the matrix. Thus, to gain fundamental understanding of nanocomposite dispersion, characterization of their internal structure and their rheological behavior is crucial. Such understanding is also key to determine the manufacturing conditions to produce these nanomaterials by liquid composite molding (LCM) process. This paper investigates the mix of nanoclays particles in an unsaturated polyester resin using three different dispersion techniques: manual mixing, sonication, and high shear mixing (HSM). This paper shows that the mixing method has a significant effect on the sample morphology. Rheology, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC) characterization techniques were used to analyze the blends morphology and evaluate the nanoclays stacks/polymer matrix interaction. Several phenomena, such as shear thinning and premature polymer gelification, were notably observed.

scholarly journals Evaluation the Effect of Amine Type on the Non-isothermally Derived Activation Energy for the Interaction of 3 Antidepressant Drugs with Lactose

2019 ◽  
Vol 9 (2) ◽  
pp. 289-293 ◽  
Author(s):  
Faranak Ghaderi ◽  
Mahboob Nemati ◽  
Mohammad Reza siahi-shadbad ◽  
Hadi valizadeh ◽  
Farnaz Monajjemzadeh
Keyword(s):  
Activation Energy ◽  
Antidepressant Drugs ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Thermal Methods ◽  
Kinetic Evaluation ◽  
Pka Value ◽  
Preformulation Studies ◽  
State Kinetic ◽  
Calculated Activation

Purpose: Evaluation of drug-excipients compatibility is an important stage during preformulation studies. In the present research, differential scanning calorimetry (DSC) at different heating rates (2.5, 10, 15°C/min) was applied for the kinetic evaluation of fluvoxamine (FLM), sertraline (SER) and doxepin (DOX) binary mixtures with lactose. Methods: Solid state kinetic parameters of the mixtures were calculated using two different thermal methods including ASTM E698 and Starink and the effect of amine type (pKa value) was investigated based on the calculated activation energies. Results: Based on obtained results mean activation energy calculated for FLM, SER and DOX with lactose using ASTM E698 and Starink methods are equal to 335.23, 132.02 and 270.99 kJ/ mol respectively. Conclusion: Results showed that the probability of drug-lactose interaction is higher in the SERlactose mixture in comparison with other two antidepressant drugs which is consistent with their pKa values.

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