scholarly journals Effect of Pyrolysis Temperature and Residence Time on Bio-char Obtained from Pyrolysis of Shredded Cotton Stalk

2020 ◽  
pp. 10-28
Author(s):  
J. M. Makavana ◽  
P. N. Sarsavadia ◽  
P. M. Chauhan
Keyword(s):  
Residence Time ◽  
Pyrolysis Temperature ◽  
Calorific Value ◽  
Volatile Matter ◽  
Quality Parameters ◽  
Ash Content ◽  
Cotton Stalk ◽  
Fixed Carbon ◽  
Heating Value

Bio-char is carbon-rich product generated from biomass through batch type slow pyrolysis. In this study, the effects of pyrolysis temperature and residence time on the yield and properties of bio-chars obtained from shredded cotton stalks were investigated. Safely said that the quality of bio-char of shredded cotton stalk obtained at 500°C temperature and 240 min is best out of the all experimental levels of variables of temperature and residence time. At this temperature and residence time, the quality of bio-char in terms higher heating value (8101.3cal /g or 33.89 MJ/kg), nitrogen (1.56%), Carbon (79.30%), and C/N ratio (50.83) respectively. The quality of bio-char for various applications is discussed along with different quality parameters. The bio-char could be used for the production of activated carbon, in fuel applications, and water purification processes. Average bulk density of whole cotton stalk and shredded cotton stalk was found as 29.90 kg/m3 and 147.02 kg/m3 respectively. Thus density was increased by 3.91 times. The value of pH, EC and CEC of shredded cotton stalk biomass was found as 5.59, 0.03 dS/m and 38.84 cmol/kg respectively. Minimum and maximum values pH, EC and CEC of its bio-char was found as 5.85 to9.86, 0.04 to 0.10 dS/m and 38.02 to 24.39 cmol/kg at 200°C and 60 min and; 500°C and 240 min temperature and residence time respectively. Moisture content, ash content, volatile matter and fixed carbon of shredded cotton stalk biomass were found as, 12.5, 5.27, 80.22, and 14.51 (%, d.b) respectively. The minimum and maximum value of bio-char in terms of ash content, volatile matter and fixed carbon of bio-char were found as 5.5 to 15.56, 48.02 to 79.48 and 15.02 to 36.40 (%, d.b) respectively. Calorific value of cotton stalk biomass was found as 3685.3 cal /g. The minimum and maximum higher heating value of its bio-char was found as 4622.0 cal/ g and 8101.3 cal/g at 200°C and 60 min and; 500˚C and 240 min temperature and residence time.

scholarly journals PENGARUH SUHU DAN KONSENTRASI PEREKAT TERHADAP KARAKTERISTIK BRIKET BIOARANG BERBAHAN BAKU TANDAN KOSONG KELAPA SAWIT DENGAN PROSES PIROLISIS

Konversi ◽  
2015 ◽  
Vol 4 (2) ◽  
pp. 16
Author(s):  
Yuli Ristianingsih ◽  
Ayuning Ulfa ◽  
Rachmi Syafitri K.S
Keyword(s):  
Solid Waste ◽  
Palm Oil ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Crude Palm Oil ◽  
Fixed Carbon ◽  
Heating Value ◽  
Empty Fruit Bunches ◽  
Rate Of Combustion

Abstrak-Tandan Kosong Kelapa Sawit merupakan limbah padat hasil produksi Crude Palm Oil (CPO). Setiap 1(satu) ton tandan buah segar dihasilkan 23% limbah padat. Limbah padat ini dapat di konversi menjadi bahan bakar pengganti minyak yaitu briket. Briket bioarang adalah bahan bakar padat yang dapat digunakan sebagai bahan bakar alternatif pengganti bahan bakar yang berasal dari fosil seperti minyak dan gas. Penelitian ini bertujuan untuk mengetahui pengaruh suhu pirolisis terhadap yield bioarang yang dihasilkan dan mengetahui pengaruh konsentrasi perekat kanji (5% w/w, 10% w/w, 15% w/w) terhadap karakteristik briket hasil penelitian (kadar air, volatile matter, kadar abu, fixed carbon, nilai kalor dan laju pembakaran). Penelitian dilakukan dengan metode pirolisis yaitu proses pembakaran bahan baku dalam reaktor pirolisis dengan menggunakan suhu yang tinggi dan tanpa atau dengan sedikit oksigen. Pirolisis dilakukan selama 2,5 jam dengan variasi suhu yaitu 350°C, 400°C, 450°C dan 500°C. Arang yang dihasilkan dicampur dengan perekat sesuai variasi dan dicetak menjadi briket. Briket kemudian dianalisa kadar air, kadar abu, kadar karbon, kadar zat terbang, nilai kalor dan laju pembakaran. Briket dengan yield tertinggi terdapat pada suhu 350°C sebesar 51,53% dan yield terendah pada suhu 500°C sebesar 26,03%. Briket hasil penelitian ini telah memenuhi standar mutu briket sebagai bahan bakar dilihat dari nilai kalor. Komposisi optimal antara perekat kanji dan arang TKKS hasil pirolisis yaitu pada 5%:95% yang menghasilkan nilai kalor terbesar yaitu 6748,15kal/g.  Kata kunci : Briket Bioarang, Pirolisis, Tandan Kosong Kelapa Sawit                Abstract-Palm Oil Empty Fruit Bunches are solid waste from Crude Palm Oil (CPO industry). For 1 ton of fresh fruit bunches produced 23% of solid waste. This solid waste can be converted into alternative energy that called briquettes. Briquettes are solid fuel that can be used as an alternative fuel replacement for fossil fuels such as oil and gas. This study aims to determine the effect of temperature on the yield generated briquettes and the effect of stach adhesive concentration (5, 10 and 15% wt) to briquettes characteristics (moisture content, volatile matter, ash content, fixed carbon, calorific value and the rate of combustion). In this reseacrh, two kilograms of palm oil empty fruit bunches was burned using pyrolisis reactor at different temperatur (350, 400, 450 and 5000C) for 2.5 hour. Charcoal produced was mixed with an adhesive in accordance variations and molded into briquettes. Briquettes then analyzed the water content, ash content, carbon content, volatile matter content, heating value and rate of combustion. The maximum yield of briquettes which was obtained in this research is 51.53% at temperature 3500C and the lowest yield at temperature of 500 ° C by 26.03%. Briquettes results of this study have met the quality standards of fuel briquettes as seen from the heating value. Optimal adhesive composition between starch and charcoal TKKS is 5%: 95% that generates highest calorific value about 6748.15kal/ g. Keywords: Briquette Bioarang, Pyrolysis, oil palm empty bunches

scholarly journals Physiochemical Properties of Cotton Stalk Biomass from Aricultural Residues

2015 ◽  
Vol 10 (1) ◽  
pp. 343-349 ◽  
Author(s):  
Dobariya Umesh ◽  
P Sarsavadiya ◽  
Krishna Vaja ◽  
Khardiwar Mahadeo
Keyword(s):  
Calorific Value ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Agricultural Residues ◽  
Ash Content ◽  
Cotton Stalk ◽  
Fixed Carbon ◽  
Physiochemical Properties ◽  
Feed Stock ◽  
Energy Conversion Process

The study was undertaken to investigate the properties of cotton stalk fuel from the agricultural residues. The whole cotton stalk plant is converted into shredded material with the help of cotton stalk shredder. The capacity of cotton stalk shredder machine is 218 kg/h. The proximate analysis of the shredded cotton stalk in terms of bulk density 34.92 kg / m3 moisture content 13.63 %, volatile matter 74.52 %, ash content (4.95 %, fixed carbon 20.53 % and calorific value of cotton stalk biomass (3827 cal/g) respectively. were showed that agricultural residues are the most potential and their quantitative availability, Since the aim by using shredded cotton stalk as feed stock for energy conversion process of the developed gasifier.

scholarly journals Quality Improvement on Briquettes Made of Oil Palm Empty Fruit Bunches (EFB) Using of Brown Algae Adhesive

2020 ◽  
Vol 15 (1) ◽  
pp. 38-44
Author(s):  
Ana Dewita ◽  
M. Faisal ◽  
Asri Gani
Keyword(s):  
Oil Palm ◽  
Brown Algae ◽  
Thermal Characteristics ◽  
Calorific Value ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Ash Content ◽  
Fixed Carbon ◽  
Empty Fruit Bunches

The charcoal produced from oil palm empty fruit bunches pyrolysis can be utilized as environmentally friendly alternative fuel briquettes. This research aimed at improving the quality of these EFB briquettes using brown algae adhesive (alginate). The adhesive was added at 2.5%, 5%, 7.5%, and 10%. Proximate analysis was then performed on EFB and the brown algae. The best quality briquettes were obtained by adding brown algae adhesive at 2.5% concentrate, which resulted in a calorific value of 21,405 J/g. Other characteristics such as moisture content, ash content, volatile matter, and fixed carbon were found to be 7.4%, 4.9%, 79%, and 8.7%, respectively. In addition, the thermal characteristics such as density, flash point, and burning time were found at 0.96 g/cm3, 5.1 second, and 300 minutes, respectively.

scholarly journals MUTU BRIKET ARANG KULIT BUAH KAKAO DENGAN MENGGUNAKAN KANJI SEBAGAI PEREKAT

PERENNIAL ◽  
2007 ◽  
Vol 3 (2) ◽  
pp. 55
Author(s):  
M. Natsir Usman
Keyword(s):  
Energy Source ◽  
Particle Size ◽  
Alternative Energy ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Fixed Carbon ◽  
Natural Energy ◽  
Charcoal Particle

The development of an alternative energy is now becoming important due to the decrease of natural energy source, The current research was conducted to observe the quality of making charcoal briquette from cocoa pod shell with the particle size of 30 mesh, 50 mesh, 70 mesh and 7 % starch as adhesive. The result showed that charcoal particle size of 70 mesh gave the best charcoal briquette quality having characteristics: moisture 10.67 %, density of 1.15 g/cm3, 18.98% ash content, 49.93 % fixed carbon, 24.99% volatile matter and the calorific value of 4372.54 cal/g. Charcoal briquette from cocoa pod shell was utilized as alternative energy. Key words: Cocoa pod shell, charcoal briquette, starch as adhesive. References

scholarly journals PEMBUATAN BIOPELET DARI KAYU PUTIH DENGAN PENAMBAHAN GONDORUKEM SEBAGAI BAHAN BAKAR ALTERNATIF

2018 ◽  
Vol 2 (1) ◽  
pp. 91-100
Author(s):  
Sofia Mustamu ◽  
Gysberth Pattiruhu
Keyword(s):  
Renewable Energy ◽  
Moisture Content ◽  
Energy Content ◽  
Raw Materials ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Fixed Carbon

Biopelet is one of the renewable energy alternatives that have uniformity of size, shape, density, and energy content. The purpose of this study was to examine the characteristics of biopelet consisting of a mixture of cajeput and gondorukem, and to determine the composition of the raw materials that can produce a biopelet with the best quality. The compositions of a mixture in this research are as follow 95%:5%, 90%:10%, 80%:20%, 70%:30%, 60%:40%, 50%:50%, cajeput 100% and gondorukem 100%. The manufacture of biopelet used a 20 mesh of dust with the pressure of 526.4 kg/cm2  at a temperature of 200 ◦C for 15 minutes. Types of tests performed on biopelet include density, moisture content, volatile matter, ash content, carbon bonded, and calorific value. The results of the best quality of biopelet was in the percentage of cajeput and gondorukem was 70%:30%,  tests showed densities of biopelet 0,84 g/cm3, moisture content5,89%, ash content 2,42%, volatile matter 73,99%, fixed carbon 18,96%, and calorific value 5152 kkal/kg.

Evaluation of the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using near infrared spectroscopy

2017 ◽  
Vol 25 (5) ◽  
pp. 301-310 ◽  
Author(s):  
Jetsada Posom ◽  
Panmanas Sirisomboon
Keyword(s):  
Infrared Spectroscopy ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Model Development ◽  
Volatile Matter ◽  
Ash Content ◽  
Least Squares Regression ◽  
Fixed Carbon ◽  
Bomb Calorimetry ◽  
Heating Value

This research aimed to determine the higher heating value, volatile matter, fixed carbon and ash content of ground bamboo using Fourier transform near infrared spectroscopy as an alternative to bomb calorimetry and thermogravimetry. Bamboo culms used in this study had circumferences ranging from 16 to 40 cm. Model development was performed using partial least squares regression. The higher heating value, volatile matter, fixed carbon and ash content were predicted with coefficients of determination (r2) of 0.92, 0.82, 0.85 and 0.51; root mean square error of prediction (RMSEP) of 122 J g−1, 1.15%, 1.00% and 0.77%; ratio of the standard deviation to standard error of validation (RPD) of 3.66, 2.55, 2.62 and 1.44; and bias of 14.4 J g−1, −0.43%, 0.03% and −0.11%, respectively. This report shows that near infrared spectroscopy is quite successful in predicting the higher heating value, and is usable with screening for the determination of fixed carbon and volatile matter. For ash content, the method is not recommended. The models should be able to predict the properties of bamboo samples which are suitable for achieving higher efficiency for the biomass conversion process.

scholarly journals Valorization of briquettes fuel using Pinus spp. sawdust from five regions of Mexico

BioResources ◽  
2021 ◽  
Vol 16 (2) ◽  
pp. 2249-2263
Author(s):  
María Alejandra Ramírez-Ramírez ◽  
Artemio Carrillo-Parra ◽  
Faustino Ruíz-Aquino ◽  
Luis Fernando Pintor-Ibarra ◽  
Nicolás González-Ortega ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Impact Resistance ◽  
Resistance Index ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Fixed Carbon ◽  
Volumetric Expansion ◽  
Pinus Spp ◽  
The Impact

This research characterized briquettes made with Pinus spp. sawdust without the use of additives. For this purpose, 19 samples of sawdust from different wood industries located in five states of the Mexican Republic were used. The densification process was carried out in a vertical hydraulic piston laboratory briquette machine. The briquettes were made with 40 g of sawdust, at 50 °C, 20 kPa and pressing for 5 min. The results obtained varied as follows: moisture content (4.1% to 7.2%), density (813.9 to 1,014.4 kg/m3), volumetric expansion (7.4% to 37.3%), compressive strength (4.9 to 40.8 N/mm), impact resistance index (46.7% to 200%), ash (0.1% to 1.1%), volatile matter (82.9% to 90.7%), fixed carbon (8.9% to 16.4%), and calorific value (20.5 to 22.8 MJ/kg). The density of the briquettes was within the “acceptable” classification (800 to 1,200 kg/m3). It was observed that, the higher the density, the lower the volumetric expansion, the higher the compressive strength, and the higher the impact resistance index. According to the ash content, the briquettes could achieve international quality. Due to high volatile matter values, rapid combustion of the briquettes with little generation of toxic smoke would be expected. Fixed carbon and calorific value results were acceptable.

scholarly journals Analysis of the Quality of Mixed Coconut Shell Waste Briquettes with Various Biomass Additives as Alternative Fuels

2021 ◽  
Vol 4 (2) ◽  
Author(s):  
Yusraida Khairani Dalimunthe ◽  
Sugiatmo Kasmungin ◽  
Listiana Satiawati ◽  
Thariq Madani ◽  
Teuku Ananda Rizky
Keyword(s):  
Moisture Content ◽  
Calorific Value ◽  
Volatile Matter ◽  
Matter Content ◽  
Ash Content ◽  
Coconut Shell ◽  
Bamboo Charcoal ◽  
A Value ◽  
Shell Waste

The purpose of this study was to see the best quality of briquettes from the main ingredient of coconut shell waste<br />with various biomass additives to see the calorific value, moisture content, ash content, and volatile matter<br />content of the biomass mixture. Furthermore, further research will be carried out specifically to see the quality of<br />briquettes from a mixture of coconut shell waste and sawdust. The method used in this research is to conduct a<br />literature study of various literature related to briquettes from coconut shell waste mixed with various additives<br />specifically and then look at the best quality briquettes produced from these various pieces of literature. As for<br />what is determined as the control variable of this study is coconut shell waste and as an independent variable,<br />namely coffee skin waste, rice husks, water hyacinth, Bintaro fruit, segon wood sawdust, coconut husk, durian<br />skin, bamboo charcoal, areca nut skin, and leather waste. sago with a certain composition. Furthermore, this<br />paper also describes the stages of making briquettes from coconut shell waste and sawdust for further testing of<br />the calorific value, moisture content, ash content, volatile matter content on a laboratory scale for further<br />research. From various literatures, it was found that the highest calorific value was obtained from a mixture of<br />coconut shell waste and bamboo charcoal with a value of 7110.7288 cal / gr and the lowest calorific value was<br />obtained from a mixture of coconut shell waste and sago shell waste with a value of 114 cal / gr, then for the value<br />The highest water content was obtained from a mixture of coconut shell waste and rice husk with a value of<br />37.70% and the lowest water content value was obtained from a mixture of coconut shell waste 3.80%, then for the<br />highest ash content value was obtained from a mixture of coconut shell waste and coffee skin with a value of<br />20.862% and for the lowest ash content value obtained from a mixture of coconut shell and Bintaro fruit waste,<br />namely 2%, and for the highest volatile matter content value obtained from a mixture of coconut shell and coconut<br />husk waste with a value of 33.45% and for the value of volatile matter levels The lowest was obtained from a<br />mixture of coconut shell waste and sago skin waste with a value of 33 , 45%.

scholarly journals Analysis of the efficiency of a solid fuel boiler depending on the choice of combusted fuel

2020 ◽  
Vol 154 ◽  
pp. 02003
Author(s):  
Grzegorz Pełka ◽  
Wojciech Luboń ◽  
Przemysław Pachytel
Keyword(s):  
Energy Efficiency ◽  
Solid Fuel ◽  
Combustion Process ◽  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Solid Fuels ◽  
The Real ◽  
Residential Sector

In the municipal and residential sector in Poland, as many as 50% of households are heated by solid fuel boilers. Most often these are, unfortunately, inefficient boilers, fired with low-quality coal. This study characterizes the market of boilers for solid fuels in Poland, and also presents the main apportionment of these devices, due to the different criteria that characterize them. The current legal changes in the scope of energy and emission requirements for solid fuel boilers are also discussed. The main purpose of this work is to analyze the real efficiency of the solid fuel over-fired boiler used, depending on the fuel burned in it. The process of burning selected fuels (seasoned wood, coal and pea coal) in the boiler was preceded by tests of these fuels to determine their energy parameters, such as moisture, ash content, the share of volatile matter and calorific value. In the next step, the energy efficiency obtained by the tested solid fuel boiler during the combustion of selected solid fuels was compared. The highest efficiency was achieved during the combustion of pea coal, and the lowest was achieved during the combustion of wood. In any case, the nominal efficiency value was achieved. Solutions that could improve the quality of the combustion process in this type of boiler were proposed.

ANALISIS KUALITAS PEMBAKARAN BRIKET BATUBARA DENGAN METODE KARBONISASI BERDASARKAN PARAMETER KUALITAS BRIKET, UKURAN PARTIKEL DAN KOMPOSISI

2018 ◽  
Vol 4 (01) ◽  
Author(s):  
Didi Kasi Setiawan ◽  
Agus Triantoro ◽  
Annisa Annisa
Keyword(s):  
Calorific Value ◽  
Volatile Matter ◽  
Ash Content ◽  
Fixed Carbon ◽  
American Society

Briket batubara merupakan bahan bakar padat yang mempunyai kelayakan teknis dan ketersedian batubara cukup banyak di Indonesia. Permasalahan yang sering di jumpai dalam penggunaan briket batubara sebagai bahan bakar energi adalah lamanya penyalaan, aroma yang tidak sedap pada saat dibakar, dan daya rekat briket yang tidak bagus sehingga briket mudah pecah. Untuk mengatasi masalah tersebut perlu mengetahui pengaruh komposisi dan ukuran partikel briket batubara terhadap kualitas pembakaran serta kualitas briket batubara. Dalam hal ini, diperlukan analisis laboratorium yang hasilnya dapat digunakan untuk mengklasifikasikan tingkatan kualitas briket batubara.Metode analisis yang digunakan untuk kualitas briket yaitu American Society for Testing and Materials (ASTM) meliputi pengujian moisture, ash content, volatile matter, calorific value, fixed carbon dan karbonisasi untuk peningkatan kualitas, meliputi moisture, volatile matter serta calorific value. Berdasarkan hasil pengujian yang telah dilakukan dapat disimpulkan bahwa proses karbonisasi batubara dapat menurunkan kandungan kualitas batubara inherent moisture adb (17,1 % - 6,38%) dan meningkatkan nilai calorific value cal/g adb (5462 - 6261), waktu nyala api (0:23:14 – 0:47:06), waktu nyala bara (0:44:56 – 1:23:10) serta durasi pembakaran (1:08:10 – 2:10:16). Kata-kata kunci: Briket, Batubara, Karbonisasi, Kualitas Batubara.

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