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Nanomaterials ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 200
Author(s):  
Christian Scheurer ◽  
Rafael E. Hincapie ◽  
Elisabeth Neubauer ◽  
Astrid Metz ◽  
Daniel Ness

We investigated the interaction of silica nanostructured particles and sandstone rock using various experimental approaches, such as fluid compatibility, batch sorption and single-phase core-floods. Diol and polyethylenglycol (PEG) surface-modified nanostructured silica materials were tested using two brines differing in ionic strength and with the addition of sodium carbonate (Na2CO3). Berea and Keuper outcrop materials (core plug and crushed samples) were used. Core-flood effluents were analysed to define changes in concentration and a rock’s retention compared to a tracer. Field Flow Fractionation (FFF) and Dynamic Light Scattering (DLS) were performed to investigate changes in the effluent’s size distribution. Adsorption was evaluated using UV–visible spectroscopy and scanning electron microscopy (SEM). The highest adsorption was observed in brine with high ionic strength, whereas the use of alkali reduced the adsorption. The crushed material from Berea rock showed slightly higher adsorption compared to Keuper rock, whereas temperature had a minor effect on adsorption behaviour. In core-flood experiments, no effects on permeability have been observed. The used particles showed a delayed breakthrough compared to the tracer, and bigger particles passed the rock core faster. Nanoparticle recovery was significantly lower for PEG-modified nanomaterials in Berea compared to diol-modified nanomaterials, suggesting high adsorption. SEM images indicate that adsorption spots are defined via surface roughness rather than mineral type. Despite an excess of nanomaterials in the porous medium, monolayer adsorption was the prevailing type observed.


2021 ◽  
Author(s):  
Tormod Skauge ◽  
Kenneth Sorbie ◽  
Ali Al-Sumaiti ◽  
Shehadeh Masalmeh ◽  
Arne Skauge

Abstract A large, untapped EOR potential may be extracted by extending polymer flooding to carbonate reservoirs. However, several challenges are encountered in carbonates due to generally more heterogeneous rock and lower permeability. In addition, high salinity may lead to high polymer retention. Here we show how in-situ viscosity varies with permeability and heterogeneity in carbonate rock from analysis of core flood results and combined with review of data available in literature. In-situ rheology experiments were performed on both carbonate outcrop and reservoir cores with a range in permeabilities. The polymer used was a high ATBS content polyacrylamide (SAV10) which tolerates high temperature and high salinity. Some cores were aged with crude oil to generate non-water-wet, reservoir representative wettability conditions. These results are compared to a compilation of literature data on in-situ rheology for predominantly synthetic polymers in various carbonate rock. A systematic approach was utilized to derive correlations for resistance factor, permeability reduction and in-situ viscosity as a function of rock and polymer properties. Polymer flooding is applied to improve sweep efficiency that may occur due to reservoir heterogeneities (large permeability contrasts, anisotropy, thief zones) or adverse mobility ratio (high mobility contrast oil-brine). In flooding design, the viscosity of the polymer solution in the reservoir, the in-situ viscosity, is an essential parameter as this is tuned to correct the mobility difference and to improve sweep. The viscosity is estimated from rheometer/viscometer measurements or, better, measured in laboratory core flood experiments. However, upscaling core flood experiments to field is challenging. Core flood experiments measure differential pressure, which is the basis for the resistance factor, RF, that describes the increased resistance to flow for polymer relative to brine. However, the pressure is also influenced by several other factors such as the permeability reduction caused by adsorption and retention of polymer in the rock, the tortuosity of the rock and the viscosity of the flowing polymer solution. Deduction of in-situ viscosity is straight forward using Darcy's law but the capillary bundle model that is the basis for applying this law fails for non-Newtonian fluids. This is particularly evident in carbonate rock. Interpretation of in-situ rheology experiments can therefore be misleading if the wrong assumptions are made. Polymer flooding in carbonate reservoirs has a large potential for increased utilization of petroleum reserves at a reduced CO2 footprint. In this paper we apply learnings from an extensive core flood program for a polymer flood project in the UAE and combine this with reported literature data to generate a basis for interpretation of in-situ rheology experiments in carbonates. Most importantly, we suggest a methodology to screen experiments and select data to be used as basis for modelling polymer flooding. This improves polymer flood design, optimize the polymer consumption, and thereby improve project economy and energy efficiency.


2021 ◽  
Author(s):  
Rezki Oughanem ◽  
Thomas Gumpenberger ◽  
Jean Grégoire Boero-Rollo ◽  
Scherwan Suleiman ◽  
Jalel Ochi ◽  
...  

Abstract A water treatment pilot skid called WaOω has been developed by TotalEnergies to test the efficiency of the centrifugation technology in treating the produced water containing back produced polymer. In case of success, this technology would be implemented on field and the water quality targeted by the technology must allow re-injecting the treated produced water in matrix flow regime for pressure maintain and sweep efficiency. The same interest was expressed by OMV and a partnership project has been built. It was also agreed that OMV builds a second pilot skid called PRT that allows carrying out core flood tests onsite to assess the formation damage and related permeability decline that could be induced by the treated produced water. Both pilot skids have been implemented, connected to each other, and tested during more than one year on the OMV's Matzen oil field nearby Vienna where degraded polymer is already back produced by wells and present in the produced water. More than seventy core flooding tests have been performed in different centrifugation conditions in terms of speed and water qualities, some of them on high permeable sand packs representing the field targeted by TotalEnergies and some others on consolidated sandstone samples of lower permeability representing OMV reservoirs. The effect of adding fresh polymer to the treated produced water for EOR purposes has also been investigated. Some complementary core flood tests have also been performed in TotalEnergies labs using reconstituted sand packs and produced waters with and without polymer to understand the contribution of the degraded polymer alone, the produced water quality alone and both to understand the formation damage and some uncommon results observed with the PRT pilot skid. Core flood tests data often obtained on long injection periods revealed of a high quality, reliable and reproducible. They also showed that even if centrifugation seems to be a good technology, the very clean and transparent water that it delivered induced surprisingly some core permeability declines the origin of which would be discussed in this paper. However, it was clearly established that the presence of degraded polymer has a cleaning effect and limits the formation damage induced by the produced water injected on cores if the Total Suspended Solids in the treated water remains at an acceptable level. Adding fresh polymers limited even more the formation damage because their cleaning effect is more pronounced than with degraded polymer.


2021 ◽  
Author(s):  
Max Olsen ◽  
Ragni Hatlebakk ◽  
Chris Holcroft ◽  
Roar Egil Flatebø ◽  
Asif Hoq ◽  
...  

Abstract This paper reports the development and testing, of a Phosphate controlled dissolution glass composition used to strengthen the matrix of chalk whilst retaining the permeability of the rock, facilitating improved hydrocarbon recovery in unstable wells. Multiple versions of the glass solutions and different types of colloidal silica were extensively tested in the laboratory to determine injectability and reactivity with calcium carbonate rocks. The goal of the testing was to determine the best performing solution for use in a field trial in the Norwegian North Sea. The laboratory testing included filtration and core flood tests to determine the injectability of the solutions and post treatment permeability, and Brazilian strength tests to determine the tensile strength of the treated chalk cores. The filterability was tested through filter screen sizes ranging from 5 to 0.6 µm. Core flood testing was performed on 10 cm long chalk cores with 1.5 mD permeability. The glass solutions showed the best results in the filtration and core flood testing, achieving significantly greater invasion depth than any of the colloidal silica samples. The phosphate glass treated chalk cores maintained 70 to 100% of the original permeability while delivering a 3 to 5 fold tensile strength increase. The lab tests demonstrated the potential of a glass based treatment to strengthen chalk formations without impeding permeability.Based on the promising results from the lab tests, it was decided to trial the selected glass solution in a mature vertical proppant fractured well. The test confirmed that the glass solution could be pumped into the well, but the test failed pre-maturely after two months of varied production, and the trial will not be covered in this paper.However, due to the high value in being able to stabilize chalk in the field, the Operator is evaluating a new trial in a horizontal well, and learnings from the first trial will be used to inform further lab tests in the next phase. The glass solution used in this trial is being further developed to be used in other formation types, such as sand and non-calcium containing reservoirs.


2021 ◽  
Author(s):  
Ifeanyi Seteyeobot ◽  
Mahmoud Jamiolahmady ◽  
Philip Jaeger ◽  
Abdulelah Nasieef

Abstract The application of non-hydrocarbon gas injection for enhanced gas and condensate recovery (EGCR) is still in a developmental stage as the mixing/interaction between the injected gas and resident reservoir fluid is yet to be extensively understood and the inability to optimize the recovery process has led to limited pilot trials. Carbon dioxide (CO2) injection into gas-condensate reservoirs for improved recovery and CO2 storage provides additional and favorable changes in phase and fluid flow behaviour making it economically more attractive compared to other injection gases. However, to make an informed decision, adequate phase and flow behaviour analysis are required to better forecast the reservoir performance under CO2 injection. In this research, appropriate experimental phase behaviour, EOS modeling, and unsteady-state flow tests have been conducted to determine the level of CO2/gas-condensate interaction including condensing/vaporizing mechanisms during CO2 Huff-n-Puff (HnP) injection. A CO2 HnP injection technique was followed to identify the best CO2 flooding conditions. A total of four HnP injection cycles with incremental CO2 volumes of 20, 40, 60, and 80 % of the initial resident fluid volume prior to depletion was considered. CO2 injection pressure and volume are optimized below the saturation pressure. The analysis is based on evaluating the level of interaction between CO2 and resident fluid at the maximum condensate saturation of the corresponding CO2-gas-condensate fluid mixture as determined in a phase equilibria cell. Appropriate experimental phase behaviour and core flood data were generated and analyzed to identify and quantify the level of condensing/vaporizing mechanisms which are vital for adequate optimization of the injection pressure and amount of injected CO2 for both enhanced gas and condensate recovery and CO2 storage purposes. The amount of gas, condensate, and CO2 produced at each core flood stage was recorded. These data allow bridging the gap between conflicting reports on the trend and level of CO2/gas-condensate fluid interactions at pressures below the dew point pressure (Pdew). They also provide a better knowledge of the governing mechanisms during CO2 flooding, which are required for designing appropriate CO2 HnP injection for reservoir engineering applications.


2021 ◽  
Author(s):  
Zach Quintanilla ◽  
Rod Russell ◽  
Mukul Sharma

Abstract Improved Oil Recovery, IOR, in shales is a topic of growing interest due to the low oil recovery observed in shales. Evaluating different IOR chemicals at the lab scale has proved difficult and time consuming due to their ultra-low permeability and low porosity. Conventional core procedures (such as core floods) are often not practical to use with such samples since they take too long. In this study, we introduce a new laboratory method for measuring the oil recovery in a huff-and-puff IOR process in shales. In huff-and-puff IOR, a treatment additive and a gas are typically injected in combination into the reservoir. Oil production is initiated after a shut-in period. Our experimental protocol starts by saturating preserved shales with oil by exposing them to the reservoir oil under pressure for an extended time. To speed up this process the preserved shale sample is crushed and sieved to 5-10 mesh. The pressure vessels are then loaded with these oil-saturated 5-10 mesh shale particles and the desired IOR fluid is injected into the pressure vessel. The vessel is rotated to ensure full contact with the shale. The samples are heated to ensure that the fluid is at reservoir pressure and temperature. Several tests were done to ensure that the fluid temperature and pressure inside the vessels were at the desired conditions throughout the 72-hour test period. T2 NMR scans were carried out before and after treatment to determine the amount of incremental oil recovery from the treatment. In tests where the two fluid phases were indistinguishable, deuterium was used in the treatment fluid in lieu of water. Excellent reproducible results were obtained with this method. This new method has been used to test a number of different treatment fluids, gases and solvents under a variety of conditions. The test can be completed in a matter of a few days as compared to several weeks that would be required for a core flood. Several tests can be run simultaneously, further speeding up the process. The results of the laboratory tests can be scaled to the field by using suitable surface-to-volume ratios in the lab and comparing them to the field. With this new method we have a fast and robust method for conducting these huff-and-puff experiments in a repeatable, and precise manner. This allows us to quickly evaluate different IOR fluids for a particular shale-fluid system at reservoir conditions.


2021 ◽  
Author(s):  
Ibi-Ada Itotoi ◽  
Taju Gbadamosi ◽  
Christian Ihwiwhu ◽  
Udeme John ◽  
Anita Odiete ◽  
...  

Abstract Low oil price and increased environmental regulations presents a new frontier for many indigenous oil and gas companies in Nigeria. In mature fields with significant water production, produced water treatment and handling could easily account for up to a third of OPEX. Underground produced water disposal is a tested approach that has been used worldwide with mixed results. Studies have been published on the subject; however, it was observed that there were no Niger Delta case studies. This paper presents SEPLAT's subsurface approach to in-field water disposal, drawing upon geological and petroleum engineering analysis coupled with learnings from over 6 years of produced water re-injection experience. Some of the areas that will be discussed include reservoir selection/screening methodology, water quality impact on permeability, produced water disposal well selection/completion, operating philosophy, general surveillance, and basic separation requirements. Thirteen reservoirs located within 2 proximal fields were screened for suitability and ranked as possible candidates for water disposal based on 8 criteria. The best 2 were then high-graded and detailed studies carried out, spanning detailed geological characterization for reservoir quality and connectivity (including quantitative interpretation), to dynamic simulation, injection well location optimization and performance prediction (for clean water). The results of core flood tests were incorporated. It is recommended that total suspended solids should not exceed 5 mg/L, with a maximum of 5 microns particle size, under matrix injection conditions while oil content should be limited to below 30-50 ppm. Tolerance for TSS can be relaxed to 10ppm – 50ppm at fracturing conditions, depending on the reservoir parameters and process systems. The knowledge of these parameters should drive the technology selection for optimum water treatment and injection.


Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1946
Author(s):  
Bashirul Haq

Green enhanced oil recovery is an oil recovery process involving the injection of specific environmentally friendly fluids (liquid chemicals and gases) that effectively displace oil due to their ability to alter the properties of enhanced oil recovery. In the microbial enhanced oil recovery (MEOR) process, microbes produce products such as surfactants, polymers, ketones, alcohols, and gases. These products reduce interfacial tension and capillary force, increase viscosity and mobility, alter wettability, and boost oil production. The influence of ketones in green surfactant-polymer (SP) formulations is not yet well understood and requires further analysis. The work aims to examine acetone and butanone’s effectiveness in green SP formulations used in a sandstone reservoir. The manuscript consists of both laboratory experiments and simulations. The two microbial ketones examined in this work are acetone and butanone. A spinning drop tensiometer was utilized to determine the interfacial tension (IFT) values for the selected formulations. Viscosity and shear rate across a wide range of temperatures were measured via a Discovery hybrid rheometer. Two core flood experiments were then conducted using sandstone cores at reservoir temperature and pressure. The two formulations selected were an acetone and SP blend and a butanone and SP mixture. These were chosen based on their IFT reduction and viscosity enhancement capabilities for core flooding, both important in assessing a sandstone core’s oil recovery potential. In the first formulation, acetone was mixed with alkyl polyglucoside (APG), a non-ionic green surfactant, and the biopolymer Xanthan gum (XG). This formulation produced 32% tertiary oil in the sandstone core. In addition, the acetone and SP formulation was effective at recovering residual oil from the core. In the second formulation, butanone was blended with APG and XG; the formulation recovered about 25% residual oil from the sandstone core. A modified Eclipse simulator was utilized to simulate the acetone and SP core-flood experiment and examine the effects of surfactant adsorption on oil recovery. The simulated oil recovery curve matched well with the laboratory values. In the sensitivity analysis, it was found that oil recovery decreased as the adsorption values increased.


2021 ◽  
Author(s):  
Albert Bokkers ◽  
Piter Brandenburg ◽  
Coert Van Lare ◽  
Cees Kooijman ◽  
Arjan Schutte

Abstract This work presents a matrix acidizing formulation which comprises a salt of monochloroacetic acid giving a delayed acidification and a chelating agent to prevent precipitation of a calcium salt. Results of dissolution capacity, core flood test and corrosion inhibition are presented and are compared to performance of 15 wt% emulsified HCl. Dissolution capacity tests were performed in a stirred reactor at atmospheric pressure using equimolar amounts of the crushed limestone and dolomites. Four different chelating agents were added to test the calcium ion sequestering power. Corrosion tests were executed using an autoclave reactor under nitrogen atmosphere at 10 barg. Core flood tests were performed to simulate carbonate matrix stimulation using limestone cores. It was found that the half-life time of the hydrolysis reaction is 77 min at a temperature of 100 °C. Sodium gluconate and the sodium salt of D-glucoheptonic acid were identified to successfully prevent the precipitation of the reaction product calcium glycolate at a temperature of 40 °C. Computed Tomography (CT) scans of the treated cores at optimum injection rate showed a single wormhole formed. At 150 °C an optimum injection rate of 1 ml/min was found which corresponds to a minimum PVBT of 6. In addition, no face dissolution was observed after coreflooding. Furthermore, the corrosion rates of different metallurgies (L80 and J55) were measured which are significantly less than data reported in literature for 15wt% emulsified HCl. The novelty of this formulation is that it slowly releases an organic acid in the well allowing deeper penetration in the formation and sodium gluconate prevents precipitation of the reaction product. The corrosivity of this formulation is relatively low saving maintenance costs to installations and pipe work. The active ingredient in the formulation is a solid, allowing onsite preparation of the acidizing fluid.


2021 ◽  
Vol 13 (5) ◽  
pp. 2744
Author(s):  
Chia-Wei Kuo ◽  
Sally M. Benson

New guidelines and suggestions for taking reliable effective relative permeability measurements in heterogeneous rocks are presented. The results are based on a combination of high resolution of 3D core-flooding simulations and semi-analytical solutions for the heterogeneous cores. Synthetic “data sets” are generated using TOUGH2 and are subsequently used to calculate effective relative permeability curves. A comparison between the input relative permeability curves and “calculated” relative permeability is used to assess the accuracy of the “measured” values. The results show that, for a capillary number (Ncv = kLpc × A/H2μCO2qt) smaller than a critical value, flows are viscous dominated. Under these conditions, saturation depends only on the fractional flow as well as capillary heterogeneity, and is independent of flow rate, gravity, permeability, core length, and interfacial tension. Accurate whole-core effective relative permeability measurements can be obtained regardless of the orientation of the core and for a high degree of heterogeneity under a range of relevant and practical conditions. Importantly, the transition from the viscous to gravity/capillary dominated flow regimes occurs at much higher flow rates for heterogeneous rocks. For the capillary numbers larger than the critical value, saturation gradients develop along the length of the core and accurate relative permeability measurements are not obtained using traditional steady-state methods. However, if capillary pressure measurements at the end of the core are available or can be estimated from independently measured capillary pressure curves and the measured saturation at the inlet and outlet of the core, accurate effective relative permeability measurements can be obtained even when there is a small saturation gradient across the core.


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