Microstructural and Micromechanical Characteristics of Tin-Based Solders Under Self-Propagating Exothermic Reaction Heating

2020 ◽  
Vol 49 (10) ◽  
pp. 6214-6222
Author(s):  
Zheng Zhou ◽  
Anna Zhang ◽  
Xu Guan ◽  
Hui Liu ◽  
Changqing Liu ◽  
...  
Keyword(s):  
Exothermic Reaction ◽  
Micromechanical Characteristics

Nuclear Reactions in Deuterium Titanium

1990 ◽  
Vol 48 (2) ◽  
pp. 134-135
Author(s):  
D.M. Vanderwalker
Keyword(s):  
Nuclear Reactions ◽  
Ion Beam ◽  
Exothermic Reaction ◽  
Pure Titanium ◽  
Fundamental Interest ◽  
Transmission Electron ◽  
Iodide Titanium ◽  
A Cell ◽  
After Hours ◽  
Quantity Of Heat

There is a fundamental interest in electrochemical fusion of deuterium in palladium and titanium since its supposed discovery by Fleischmann and Pons. Their calorimetric experiments reveal that a large quantity of heat is released by Pd after hours in a cell, suggesting fusion occurs. They cannot explain fusion by force arguments, nor can it be an exothermic reaction on the formation of deuterides because a smaller quantity of heat is released. This study examines reactions of deuterium in titanium.Both iodide titanium and 99% pure titanium samples were encapsulated in vacuum tubes, annealed for 2h at 800 °C. The Ti foils were charged with deuterium in a D2SO4 D2O solution at a potential of .45V with respect to a calomel reference junction. Samples were ion beam thinned for transmission electron microscopy. The TEM was performed on the JEOL 200CX.The structure of D charged titanium is α-Ti with hexagonal and fee deuterides.

A simulation apparatus for the experimental study of batch reactor control methods

1986 ◽  
Vol 51 (6) ◽  
pp. 1259-1267
Author(s):  
Josef Horák ◽  
Petr Beránek
Keyword(s):  
Experimental Study ◽  
Closed Loop ◽  
Dynamic Properties ◽  
Batch Reactor ◽  
Exothermic Reaction ◽  
Electric Heating ◽  
Batch Reactors ◽  
Exchange Area ◽  
The Stability ◽  
Methods Of Control

A simulation apparatus for the experimental study of the methods of control of batch reactors is devised. In this apparatus, the production of heat by an exothermic reaction is replaced by electric heating controlled by a computer in a closed loop; the reactor is cooled with an external cooler whose dynamic properties can be varied while keeping the heat exchange area constant. The effect of the cooler geometry on its dynamic properties is investigated and the effect of the cooler inertia on the stability and safety of the on-off temperature control in the unstable pseudostationary state is examined.

Intensification of cooling in a batch reactor with an exothermic reaction by nonisothermal control in stable pseudostationary states

1984 ◽  
Vol 49 (11) ◽  
pp. 2566-2578 ◽  
Author(s):  
Josef Horák ◽  
Petr Beránek ◽  
Dagmar Maršálková
Keyword(s):  
Batch Reactor ◽  
Exothermic Reaction ◽  
Reaction Model ◽  
Order Reaction ◽  
Zero Order ◽  
Coolant Temperature ◽  
Inlet Temperature ◽  
Adaptive Parameter ◽  
Zero Order Reaction ◽  
Set Up

An algorithm is set up and tested for the temperature control of a batch reactor consisting in jump changes in the inlet temperature of entering coolant. This temperature is so chosen that its difference from the temperature of the reaction mixture is near the highest difference at which the stable pseudostationary state of the system still exists. For the prediction of the new coolant inlet temperature, a zero-order reaction model is used with an adaptive parameter estimated from the experimentally established value of the maximum of the reaction mixture overheating at the previous coolant temperature.

A simplified method of temperature control maximizing productivity of the batch reactor; The effect of inertia of the cooling system

1982 ◽  
Vol 47 (2) ◽  
pp. 454-464 ◽  
Author(s):  
František Jiráček ◽  
Josef Horák
Keyword(s):  
Mathematical Model ◽  
Temperature Control ◽  
Cooling System ◽  
Batch Reactor ◽  
Exothermic Reaction ◽  
Cooling Capacity ◽  
Variable Activity ◽  
Simplified Method ◽  
Opening And Closing ◽  
Time Of Operation

The effect has been studied of the inertia of the cooling system on the reliability of control of the temperature of the reaction mixture. The study has been made using a mathematical model of the batch reactor with an exothermic reaction. The temperature has been controlled by a two-level controller opening and closing the flow of the coolant. The aim of the control has been to maintain a constant value of the degree of utilization of the cooling capacity of the reactor. The instantaneous value of the degree of utilization has been assessed from the ratio of times for which the cooling system is idle to the time of operation. The reliability of control has been studied for variable activity of the catalyst.

Temperature control in a chemical reactor through variable area of the heat transfer surface. Experimental verification

1982 ◽  
Vol 47 (2) ◽  
pp. 446-453
Author(s):  
Josef Horák ◽  
František Jiráček ◽  
Libuše Ježová
Keyword(s):  
Batch Reactor ◽  
Exothermic Reaction ◽  
Chemical Reactor ◽  
Open Loop ◽  
Heat Transfer Surface ◽  
Laboratory Reactor ◽  
Hysteresis Control ◽  
Relay With Hysteresis ◽  
Rate Of Response ◽  
The Ideal

A possibility has been tested in the paper of the feed back control of temperature of the reaction mixture in a batch reactor with an exothermic reaction through the variable area of the cooling surface. The measurement were carried out in a laboratory reactor with a retractable cooler which was being immersed into the reaction mixture. The speed of motion of the cooler was sufficiently high permitting the process of immersion to be regarded as practically instantaneous. The aim of the control was to stabilize the set point temperature of the reaction mixture by a two-point controler. In dependence on the rate of response of the system to a change of the section variable either the ideal relay or the relay with hysteresis control algorithmus were used. The results of measurements showed that with the aid of a retractable cooler the temperature could be controlled safely even in those cases, in which the control by the variable flow rate of the coolant was unfeasible. The verification was carried out in the open-loop instable operating point of the reactor.

Rapid Epitaxial Growth of Si and SiGe Mono-Crystalline Films on Silicon-on-Glass Substrates by Reactive CVD Using SiH4, GeH4, and F2

2012 ◽  
Vol 1426 ◽  
pp. 331-337
Author(s):  
Hiroshi Noge ◽  
Akira Okada ◽  
Ta-Ko Chuang ◽  
J. Greg Couillard ◽  
Michio Kondo
Keyword(s):  
Epitaxial Growth ◽  
Heating Temperature ◽  
Exothermic Reaction ◽  
Epitaxial Films ◽  
Si Substrates ◽  
Glass Substrates ◽  
Good Crystallinity ◽  
Crystalline Films ◽  
Si Films ◽  
First Time

ABSTRACTWe have succeeded in the rapid epitaxial growth of Si, Ge, and SiGe films on Si substrates below 670 ºC by reactive CVD utilizing the spontaneous exothermic reaction between SiH4, GeH4, and F2. Mono-crystalline SiGe epitaxial films with Ge composition ranging from 0.1 to 1.0 have been successfully grown by reactive CVD for the first time.This technique has also been successfully applied to the growth of these films on silicon-on-glass substrates by a 20 - 50 ºC increase of the heating temperature. Over 10 μm thick epitaxial films at 3 nm/s growth rate are obtained. The etch pit density of the 5.2 μm-thick Si0.5Ge0.5 film is as low as 5 x 106 cm-2 on top. Mobilities of the undoped SiGe and Si films are 180 to 550 cm2/Vs, confirming the good crystallinity of the epitaxial films.

scholarly journals Acid red G dye removal from aqueous solutions by porous ceramsite produced from solid wastes: Batch and fixed-bed studies

2020 ◽  
Vol 9 (1) ◽  
pp. 770-782
Author(s):  
Tianpeng Li ◽  
Jing Fan ◽  
Tingting Sun
Keyword(s):  
Aqueous Solutions ◽  
Dye Removal ◽  
Coal Fly Ash ◽  
Exothermic Reaction ◽  
Fixed Bed ◽  
Column Experiment ◽  
Solid Wastes ◽  
Order Kinetic ◽  
Cost Effective Treatment ◽  
Acid Red G

AbstractA novel porous ceramsite was made of municipal sludge, coal fly ash, and river sediment by sintering process, and the performance of batch and fixed-bed column systems containing this material in the removal of acid red G (ARG) dye from aqueous solutions was assessed in this study. The results of orthogonal test showed that sintering temperature was the most important determinant in the preparation of porous ceramsite, and it possesses developed pore structure and high specific surface area. Batch experiment results indicated that the adsorption process of ARG dye toward porous ceramsite was a spontaneous exothermic reaction, which could be better described with Freundlich–Langmuir isotherm model (R2 > 0.992) and basically followed the pseudo-first-order kinetic equation (R2 > 0.993). Column experiment results showed that when the porous ceramsite was used as packing material, its adsorption capacity was roughly improved by 3.5 times compared with that in batch system, and the breakthrough behavior was simulated well with Yoon–Nelson model, with R2 > 0.954. This study suggested that the novelty man-made porous ceramsite obtained from solid wastes might be processed as a certain cost-effective treatment material fit for the dye removal in aqueous solutions.

scholarly journals Energetic-Materials-Driven Synthesis of Graphene-Encapsulated Tin Oxide Nanoparticles for Sodium-Ion Batteries

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2550
Author(s):  
Yingchun Wang ◽  
Jinxu Liu ◽  
Min Yang ◽  
Lijuan Hou ◽  
Tingting Xu ◽  
...  
Keyword(s):  
Tin Oxide ◽  
Energetic Materials ◽  
High Speed ◽  
Coulombic Efficiency ◽  
Sno2 Nanoparticles ◽  
Direct Synthesis ◽  
Exothermic Reaction ◽  
Rate Capability ◽  
Rapid Expansion ◽  
Core Shell

By evenly mixing polytetrafluoroethylene-silicon energetic materials (PTFE-Si EMs) with tin oxide (SnO2) particles, we demonstrate a direct synthesis of graphene-encapsulated SnO2 (Gr-SnO2) nanoparticles through the self-propagated exothermic reaction of the EMs. The highly exothermic reaction of the PTFE-Si EMs released a huge amount of heat that induced an instantaneous temperature rise at the reaction zone, and the rapid expansion of the gaseous SiF4 product provided a high-speed gas flow for dispersing the molten particles into finer nanoscale particles. Furthermore, the reaction of the PTFE-NPs with Si resulted in a simultaneous synthesis of graphene that encapsulated the SnO2 nanoparticles in order to form the core-shell nanostructure. As sodium storage material, the graphene-encapsulated SnO2 nanoparticles exhibit a good cycling performance, superior rate capability, and a high initial Coulombic efficiency of 85.3%. This proves the effectiveness of our approach for the scalable synthesis of core-shell-structured graphene-encapsulated nanomaterials.

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