scholarly journals The impact of the water-to-cement ratio on the surface morphology of cementitious materials

2020 ◽  
Vol 32 ◽  
pp. 101716
Author(s):  
Edgar Chuta ◽  
Johan Colin ◽  
Jena Jeong
2021 ◽  
Vol 888 ◽  
pp. 67-75
Author(s):  
Ariel Verzosa Melendres ◽  
Napoleon Solo Dela Cruz ◽  
Araceli Magsino Monsada ◽  
Rolan Pepito Vera Cruz

Chloride ingress into concrete from the surrounding environment can result in the corrosion of the embedded steel reinforcement and cause damage to the concrete. Superabsorbent polymer (SAP) with fine particle size was incorporated into the structure of concrete for controlling the chloride ingress and improving its compressive strength via promotion of internal curing. The SAP used in this study was evaluated for its absorbency property when exposed to cementitious environment such as aqueous solution of Ca (OH)2 and cement slurry. The results were compared to that in sodium chloride solution, the environment where absorbency of most of the SAP found in the market are well studied. Results showed that although SAP absorbency decreased with increasing concentration of Ca (OH)2 and cement, the results suggest that water containing cementitious materials are able to be absorbed by SAP. Chloride ingress into 28-day cured concrete specimens were determined using Rapid Chloride Penetration Test (RCPT) method employing 60V DC driving force. Concrete samples with size of 50 mm height x 100 mm diameter were prepared using a M25 mix design with 0.4 and 0.45 water to cement ratios and different percentages of SAP such as 0.05%, 0.1% and 0.15% with respect to cement mass. Results showed that concrete with 0.15% SAP gave the best result with 14% less chloride permeability than concrete with no SAP for a 0.4 water to cement ratio. Concrete samples for compressive strength tests with size of 200 mm height x 100 mm diameter were prepared using the same mix design and percentages of SAP and cured for 28 days. Results showed that the best results for compressive strength was found at 0.1% SAP at a 0.4 water to cement ratio which can be attributed to internal curing provided by SAP.


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4583
Author(s):  
Martyna Nieświec ◽  
Łukasz Sadowski

Recently, the surfaces of concrete structures are impregnated to protect them against the environment in order to increase their durability. It is still not known how the use of these agents affects the near-surface hardness of concrete. This is especially important for experts who use the near-surface hardness of concrete for estimating its compressive strength. The impregnation agents are colorless and, thus, without knowledge of their use, mistakes can be made when testing the surface hardness of concrete. This paper presents the results of investigations concerning the impact of impregnation on the subsurface hardness concrete measured using a Schmidt hammer. For this research, samples of cement paste with a water–cement ratio of 0.4 and 0.5 were used. The samples were impregnated with one, two, and three layers of two different agents. The first agent has been made based on silanes and siloxanes and the second agent has been made based on based on polymers. The obtained research results allow for the conclusion that impregnation affects the near-surface hardness of concrete. This research highlights the fact that a lack of knowledge about the applied impregnation of concrete when testing its near-surface hardness, which is then translated into its compressive strength, can lead to serious mistakes.


Carbonation is one of the imperative properties that affect the durability of concrete especially in case of reinforced structures. In this present study, an attempt has been taken to study the effect of M sand and other supplementary cementitious materials like silica fume, fly ash and steel slag as a partial replacement to cement. Different combinations with M sand, river sand and combinations of M sand and river sand with supplementary cementitious materials at water to cement ratio varying from 0.45 to 0.5 was studied. Results revealed that the complete replacement of river sand by M sand reduced the rate of carbonation but addition of supplementary cementitious along with either river sand or M sand resulted in increase over the rate of carbonation compared to conventional concrete.


2021 ◽  
Author(s):  
Ahmed Mohammed ◽  
Kawan Ghafor ◽  
Wael Mahmood ◽  
Warzer Sarwar ◽  
Lajan Burhan

Abstract In this study, the effect of two water reducer polymers with smooth and rough surfaces on the compression strength of Ordinary Portland cement (OPC) was investigated. Three different initial ratios between water and cement (w/c) 0.5, 0.6, and 1 were used in this study. The amount of polymer contents varied from 0 to 0.06 % (%wt) for the cement paste with initial w/c of 0.5 and the polymer contents ranged between 0 to 0.16% (%wt) for the cement paste with initial w/c of 0.6 and 1 were investigated. SEM test was conducted to identify the impact of polymers on the behavior of cement paste. The compression strength of OPC cement was increased significantly with increasing the polymer contents. Because of a fiber net (netting) around cement paste particle was developed when the polymers were added to the cement paste which leads to decrease the void between the particles, binding the cement particles, therefore, increased the viscosity and compression strength of the cement rapidly. In this analysis, the hardness of cement paste with polymer contents has been evaluated and modeled using four different model technics. More environmentally sustainable construction, and lower cost than conventional building materials and early age strengths of the cement. To overcome the mentioned matter, this study aims to establish systematic multiscale models to predict the compression strength of cement paste containing polymers and to be used by the construction industry with no theoretical restrictions. For that purpose, a wide data a total of 280 tested cement paste modified with polymers, has been conducted, analyzed, and modeled. Linear, Nonlinear regression, M5P-tree, and Artificial Neural Network (ANN) technical approaches were used for the qualifications. In the modeling process, the most relevant parameters affecting the strength of cement paste, i.e. polymer incorporation ratio (0-0.16% of cement's mass), water-to-cement ratio (0.5-1), and curing ages (1 to 28 days). According to the correlation coefficient (R), mean absolute error and the root means a square error, the compression strength of cement paste can be well predicted in terms of w/c, polymer content, and curing time using four various simulation techniques. Among the used approaches and based on the training data set, the model made based on the Non-linear regression, ANN, and M5P-tree models seem to be the most reliable models. The sensitivity investigation concludes that the polymer content is the most dominating parameter for the prediction of the compression strength of cement paste with this data set.


Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 240
Author(s):  
Jianlan Chen ◽  
Jiandong Wang ◽  
Rui He ◽  
Huaizhu Shu ◽  
Chuanqing Fu

This study investigated the effective chloride diffusion coefficient of cement mortar with different water-to-cement ratio (w/c) under electrical accelerated migration measurement. The cumulative chloride concentration in anode cell solution and the cumulative chloride concentration drop in the cathode cell solution was measured by RCT measurement and the results were further used to calculate the chloride diffusion coefficient by Nordtest Build 355 method and Truc method. The influence of w/c on cement mortar’s chloride coefficient was investigated and the chloride diffusion coefficient under different determination methods were compared with other researchers’ work, a good consistency between this work’s results and literatures’ results was obtained. The results indicated that the increased w/c of cement mortar samples will have a higher chloride diffusion coefficient. The cumulative chloride concentration drop in the cathode cell solution will have deviation in early stage measurement (before 60 h) which will result in overestimation of the effective chloride diffusion coefficient.


2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Haoliang Huang ◽  
Guang Ye

In this research, self-healing due to further hydration of unhydrated cement particles is taken as an example for investigating the effects of capsules on the self-healing efficiency and mechanical properties of cementitious materials. The efficiency of supply of water by using capsules as a function of capsule dosages and sizes was determined numerically. By knowing the amount of water supplied via capsules, the efficiency of self-healing due to further hydration of unhydrated cement was quantified. In addition, the impact of capsules on mechanical properties was investigated numerically. The amount of released water increases with the dosage of capsules at different slops as the size of capsules varies. Concerning the best efficiency of self-healing, the optimizing size of capsules is 6.5 mm for capsule dosages of 3%, 5%, and 7%, respectively. Both elastic modulus and tensile strength of cementitious materials decrease with the increase of capsule. The decreasing tendency of tensile strength is larger than that of elastic modulus. However, it was found that the increase of positive effect (the capacity of inducing self-healing) of capsules is larger than that of negative effects (decreasing mechanical properties) when the dosage of capsules increases.


2012 ◽  
Vol 730-732 ◽  
pp. 271-276
Author(s):  
H.R. Pakravan ◽  
M. Jamshidi ◽  
M. Latifi ◽  
F. Pacheco-Torgal

This paper compares the adhesion strength between three polymeric fibres (polypropylene (PP), nylon66 (N66) and polyacrylonitrile (PAN)) embedded in a cement paste. The specimens were prepared at a water to cement ratio (w/c) of 0.5 and tested after 7, 14 and 28 curing days. It was found that although the adhesion between the polymeric fibres to the cement matrix is an important factor, the energy absorption capacity or energy dissipation ability of the fibres, plays a more important role in the improvement of the cementitious composites fracture toughness. Scanning electron micrographs were used to characterize the fibres surface before and after the Pull-out tests.


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