scholarly journals Coagulation of waste water from the point of view of physic-chemical interactions

2021 ◽  
Vol 263 ◽  
pp. 04011
Author(s):  
Evgeny Alekseev ◽  
Svetlana Shambina

The widespread use of reagent coagulation in the technology of purification of natural and waste waters is due to the complexity of the chemical composition and phase-dispersed state of the aqua systems of these waters, on the one hand, and the multifactorial action of coagulants on them, on the other. The mechanisms of interaction between coagulants and pollutants of wastewater which are in different phase-dispersed states include the physicochemical phenomena of coagulation, heterocoagulation, adagulation and sorption. The physicochemical concept “coagulation” reflects only one mechanism of coagulants’ action on pollutants. This leads to the appearing of the problem in terminological description of the physicochemical processes’ combined action when adding coagulants to the water being cleaned. The purpose of the study is to justify the use of universal indicators characterizing the multifactorial nature of the coagulation process, its formalization and quantitative assessment. The solution of the problem is to use the concept of “coasorption”, which determines the multifactorial nature of the interaction between coagulants and pollutants, and to use the technological indicator “specific coasorption”, which establishes a quantitative relationship between the pollutants’ indicators and the dose of coagulant. The test coagulation’s results of two different types of synthetic dyes’ solutions using aluminum salts reflect the difference in the mechanisms of their interaction with the coagulant. The formula for coasorption isotherm can be used to determine the required doses of reagents for coagulation of water basing on the initial and residual content of pollutants in the purified waters.

Dreyfus argues that there is a basic methodological difference between the natural sciences and the social sciences, a difference that derives from the different goals and practices of each. He goes on to argue that being a realist about natural entities is compatible with pluralism or, as he calls it, “plural realism.” If intelligibility is always grounded in our practices, Dreyfus points out, then there is no point of view from which one can ask about or provide an answer to the one true nature of ultimate reality. But that is consistent with believing that the natural sciences can still reveal the way the world is independent of our theories and practices.


Author(s):  
Е.В. Алексеев

Широкое распространение реагентного коагулирования в технологии очистки природных и промышленных сточных вод обусловлено, с одной стороны, сложностью химического состава и фазово-дисперсного состояния их аквасистем, с другой – многофакторностью действия на них коагулянтов. Рассмотрены основные механизмы взаимодействия коагулянтов и загрязняющих веществ на примере очистки промышленных сточных вод, содержащих органические вещества (поверхностно-активные вещества и синтетические красители). Физико-химическое понятие «коагуляция» отражает только один из механизмов действия коагулянтов на загрязнители. Принятые в настоящее время технологические показатели «доза коагулянта» и «удельная доза коагулянта» также не отражают многообразие взаимодействий загрязняющих веществ с солями коагулянтов и не привязаны к результату коагулирования. Это обусловливает трудность описания совокупного действия физико-химических процессов при добавлении коагулянтов в очищаемые воды и его количественной оценки. Решение проблемы возможно введением понятия «коасорбция», определяющего многофакторность взаимодействия коагулянтов с загрязняющими веществами в процессах очистки сточных вод коагулированием, и технологического показателя «удельная коасорбция», устанавливающего количественную взаимосвязь между величинами загрязняющих веществ в исходной и очищенной воде с дозой коагулянта. Графически представлены функции удельной коасорбции в форме изотерм коасорбции для двух типов поверхностно-активных веществ и синтетических красителей. На основании результатов анализа особенностей изотерм показано, что они отражают разные механизмы взаимодействия коагулянтов и загрязняющих веществ. Использование коасорбции как технологического понятия способствует выявлению механизмов взаимодействия загрязняющих веществ с коагулянтом и созданию наилучших условий для осуществления процесса коагулирования. Функциональное описание изотерм коасорбции позволяет экстраполировать результаты пробного коагулирования в широком интервале концентраций загрязняющих веществ. Практическое значение изотерм удельной коасорбции состоит в возможности определения доз реагентов при коагулировании воды по начальному содержанию загрязняющих веществ и требуемому в очищенных водах. The widespread use of chemical coagulation in purification of natural water and industrial wastewater is due, on the one hand, to the complex chemical composition and phase-disperse state of their aqua systems, and on the other hand, to the multifactorial effect of coagulants on them. The main mechanisms of interaction between coagulants and pollutants are considered through the example of industrial wastewater treatment containing organic substances (surfactants and synthetic dyes). The physicochemical term «coagulation» reflects only one of the mechanisms of the effect of coagulants on pollutants. The currently accepted process parameters «dose of coagulant» and «specific dose of coagulant» do not reflect the variety of interactions of pollutants with coagulant salts either, and are not linked to the result of coagulation. This makes it difficult to describe the collective effect of physicochemical processes while adding coagulants to the treated water and to quantify it. The solution to the problem is possible introducing the concept of «coasorption» that determines the multifactorial origin of the interaction of coagulants and pollutants in the processes of wastewater treatment by coagulation; and the process parameter «specific coasorption» that establishes a quantitative relationship between the concentrations of pollutants in raw wastewater and effluent with a dose of coagulant. The specific coasorption functions are graphically presented in the form of coasorption isotherms for two types of surfactants and synthetic dyes. Based on the results of the analysis of the features of the isotherms, it is shown that they reflect different mechanisms of interaction between coagulants and pollutants. The use of coasorption as a technological concept provides for identifying the mechanisms of interaction of pollutants with a coagulant and establishing the best conditions for the coagulation process. The functional description of the coasorption isotherms allows extrapolating the results of trial coagulation in a wide range of pollutant concentrations. The practical importance of specific coasorption isotherms provides for determining the dosages of chemicals during coagulation of water based on the initial concentration of pollutants and effluent standard.


2021 ◽  
Author(s):  
Alla Packevich

The monograph, on the one hand, examines the period of development of the descending cycle of evolution and the associated progressive changes that show the irreversibility of the processes of formation of the planetary system. The end of one cycle and the beginning of another leads to the transformation of the system of life and the expansion of consciousness at a new energy level. On the other hand, the questions of potential opportunities for the development of the ascending phase of evolution, which goes both along the path of complexity of the organization and along the path of diversity, are considered. In the ascending evolutionary stream, what has been differentiated into the corresponding levels in the descending cycle is brought together and thus prepared to enter into new, more perfect forms of unity. It is shown that the development of humanity along its entire path depends on the interaction of energies of various forms and potentials. Understanding the relationships between different types of energy and their use provides insight into many important issues in the evolution of society. The material introduces the modern features of the existence of the male and female sexes from the energy point of view. The idea of a way out of the current conflict situation that has arisen between the sexes at the present stage of evolution is proposed. It will be useful for those interested in the problems of scientific knowledge, architects, philosophers,historians, physicists and methodologists of science, students and students of secondary schools.


2020 ◽  
Vol 12 (9) ◽  
pp. 3858 ◽  
Author(s):  
Magda Sibley ◽  
Antonio Peña-García

This paper presents the first comparative study of its type of the performance of light pipes with different types of apertures: a flat glass versus a bohemian crystal dome. Measurements were taken at 20-minute intervals over a period of one year in the bathrooms of two newly built identical houses of the same orientation located in Manchester, UK. The comparative analysis of the data collected for both light pipes types reveals that the crystal domed aperture consistently outperforms the flat glass one. Furthermore, the difference in the recorded horizontal illuminance is most marked during the winter months and at the end of the one-year experiment, indicating that the crystal dome has better performance for low incident winter light and higher resistance for the long term effect of weathering and pollution. This study provides strong evidence based on long term real measurements. Such evidence informs architects’ decisions when weighing up the aesthetic considerations of a flat glass aperture versus the higher illumination levels afforded by a crystal dome aperture with higher resistance to weathering and pollution.


1999 ◽  
Vol 15 (4) ◽  
pp. 701-709 ◽  
Author(s):  
Dina Czeresnia

In this article the author presents a point of view which she considers central to understanding the difference between prevention - associated with the traditional discourse of public health - and health promotion, an idea in connection with which proposals are now being presented for rethinking and redirecting public health practices. This perspective relates to the limits of the health and disease concepts in relation to the concrete experiences of health and illness. On the one hand, practical awareness of this limit implies far-reaching changes in the way scientific knowledge is related to (and used in) the formulation and organization of health practices; on the other, health promotion projects also avail themselves of the concepts guiding the discourse of prevention. This leads to certain difficulties that appear as inconsistencies or gray areas in the operationalization of promotion projects, which do not always succeed in asserting their nature as distinct from traditional preventive practices.


1981 ◽  
Vol 11 (1) ◽  
pp. 44-46 ◽  
Author(s):  
D.P. Fourie

It is increasingly realized that hypnosis may be seen from an interpersonal point of view, meaning that it forms part of the relationship between the hypnotist and the subject. From this premise it follows that what goes on in the relationship prior to hypnosis probably has an influence on the hypnosis. Certain of these prior occurences can then be seen as waking suggestionns (however implicitly given) that the subject should behave in a certain way with regard to the subsequent hypnosis. A study was conducted to test the hypothesis that waking suggestions regarding post-hypnotic amnesia are effective. Eighteen female subjects were randomly divided into two groups. The groups listened to a tape-recorded talk on hypnosis in which for the one group amnesia for the subsequent hypnotic experience and for the other group no such amnesia was suggested. Thereafter the Stanford Hypnotic Susceptibility Scale was administered to all subjects. Only the interrogation part of the amnesia item of the scale was administered. The subjects to whom post-hypnotic amnesia was suggested tended to score lower on the amnesia item than the other subjects, as was expected, but the difference between the mean amnesia scores of the two groups was not significant.


2020 ◽  
Vol 12 (10) ◽  
pp. 4232
Author(s):  
Khaled Shaaban ◽  
Hassan Hamad

A critical gap value of a roundabout is mainly affected by the interactions between the circulating vehicles and vehicles entering the roundabout. These interactions are impacted by many factors, including the number of circulating lanes, the aggressiveness of local drivers, vehicle types, and the number of approaching lanes. Therefore, it is essential to locally investigate critical gap values before conducting any studies to improve capacity and delay at roundabouts. The purpose of this study is to measure and compare the critical gap values for different types of roundabouts in Qatar. More than 10,000 measurements were collected. The results showed that the critical gap values were 2.24 s, 2.55 s, and 2.40 s for the one-, two-, and three-lane roundabouts, respectively. These values are also quite low when compared to values calculated in other countries, which can be an indication of driver aggressiveness and risky behavior. The study is one of the first efforts to compare three types of roundabouts and to understand the difference in operation between them in this region. The results of this study can help engineers, planners, and public agencies to plan, study, and design similar facilities.


2014 ◽  
Vol 8 (2) ◽  
Author(s):  
Simone Elisabeth Lang

AbstractIn describing the position of the narrator, research in literary studies generally follows Gérard Genette’s pioneering theory of narrative in distinguishing between the homo- and heterodiegetic type of narrator. This categorization is not sufficient to allow the position of the narrator to be described properly. The different ways in which the terms are used in literary studies reveal a shortcoming in the distinction behind them. Even in Genette’s work, there is a contradiction between the definition and the names of the two categories: Genette defines homo- and heterodiegesis with reference to the narrator’s presence in the narrated story, whereas he elsewhere states that the diegesis (in the sense of FrenchThe present article aims to do just that, starting from a theoretical standpoint. Thus, the different types of narrator that are possible are sketched in outline, and then explained with the help of examples.I begin by exposing the problems that result from using the terms in Genette’s manner (1), in order then to develop a list of possible narratorial standpoints based on the one hand on the involvement of the narratorial instance in the narrated world and on the other on its involvement in the story. By establishing separation of the two aspects as a ground rule in this way, a number of misunderstandings that are due to the varied ways in which the terminology has been used to date can be overcome.There follows a description of those cases that are unambiguously hetero- and homodiegetic (2), after which the problematic cases are considered (3), yielding the different types of homodiegetic narration that are possible. This latter set of distinctions will, like the others, shed light on the contours of the different narratorial positions and thus be capable of being put profitably into practice in textual interpretation. Accordingly, what is suggested is a way of using the terms that is first unambiguous and second beneficial to the interpretation of works, thus doing justice to the heuristic importance of narratology (see Kindt/Müller 2003; Stanzel 2002, 19).Thus, whereas the concept of diegesis provides the foundation for a distinction based on an ontological criterion that divides homo- and heterodiegesis from each other, the relationship between story and narrator is used to describe various types of homodiegetic narration. In the process, there come to light two types that are distinguished from each other by involvement in events (›homodiegetic, in the story‹ and ›homodiegetic, not in the story‹ narrators). If the narrator is not involved in events, the question arises of whether it would in principle have been possible for him to be involved in events, which is the norm with ›homodiegetic, not in the story‹ narrators, or whether a physical impossibility is the reason for his lack of involvement in the story. A special case of the ›homodiegetic, not in the story‹ narrator can be derived from this: peridiegetic narration: whereas narratorial instances of the ›homodiegetic, in the story‹ and ›homodiegetic, not in the story‹ types could in principle have been involved in the action and those of the ›homodiegetic, in the story‹ type actually were, peridiegetic narrators are marked by the fact that they cannot have been involved in the events.In summary, it will be shown that the concept of homodiegesis – in particular in the form in which it has previously been used, where links with the action and appearance in the story were not kept distinct – is in effect an umbrella term that brings together a number of possible forms. There is a prominent distinction between the ›homodiegetic, in the story‹ and the ›homodiegetic, not in the story‹ types of narrator (these types are represented in the present article by the old lawyer in Leo Perutz’s »The Beaming Moon« and the narrator who is a friend of Nathanael in E. T. A. Hoffmann’s »Sandman« respectively). The different degrees of homodiegetic narrator, which have often been mentioned in previous research and are defined by the strength of the character’s presence in the narrated world (from an uninvolved witness to an autodiegetic protagonist), are also to be situated between these two poles.It will also be shown in the process that the case of the narrator who is, for reasons of physical difference, not involved in events (the peridiegetic narrator) should be treated as a form of homodiegesis (for instance the schoolmaster in Theodor Storm’s


2021 ◽  
Vol 66 (Special Issue) ◽  
pp. 89-89
Author(s):  
Sabine Hauser ◽  
◽  
Rouven Porz ◽  
Maria Aluaș ◽  
◽  
...  

"In March 2020, many countries in commissions and medical societies moved very quickly to draft fair and transparent triage guidelines; this in order to plan ahead for possible resource bottlenecks in the treatment of COVID-19 patients in intensive care units. There are a lot of consciously chosen (but also less reflected) ethical values in these guidelines. Our presentation compares the values of eight of such guidelines, but first shows how to read such values in the first place. Many health professionals are hardly aware of the explicit presentation of ethical-philosophical values. From a methodological point of view, this presentation is based on a hermeneutic-ethical approach. The guidelines are interpreted, an interpretation aid is developed, and the values of the guidelines are reconsidered in comparison. On a meta-level, we could identify different types of values, besides medical and ethical values, the guidelines were also filled with procedural, structural and legal-political values. On a content level, the unreflective handling of the value of autonomy, which often competes with the value of public health, is particularly evident. This competition is little reflected. Another point of divergence between the guidelines is the degree of precision or the difference between long-term and short-term medical prognosis. We believe that with our analysis we can contribute to making value discussions in health care more open and explicit. We would like to present these conclusions for discussion at this year’s EACME conference in Cluj. "


Author(s):  
Hilary B. Moore

There are two types of ground at Port Erin, differing widely in the general environmental conditions, and each with a characteristic type of urchin on it. The difference is sufficiently well marked for the local fishermen, who collect the urchins for sale to summer visitors, to distinguish them as different types. The littoral urchins from the Breakwater are larger and thicker shelled than those from the Breast. Their gonads reach a greater maximum size, and, in fact, never fall as low even as the maximum volume for the Breast urchin gonads. This difference is probably correlated with the much greater food supply on the Breakwater, since the gonad is the one organ of the body in which the animal can store reserve food material. Spawning commences in March or April and lasts for about two months, but is slightly earlier on the Breakwater than on the Breast. Ripening also takes place considerably earlier in both sexes on the littoral ground. Spawning seems to set in at a temperature of about 7° C., and the colder winter of 1931, compared with 1932, was associated with a later ripening and spawning, i n the former year. Similarly it is suggested that the slightly later spawning on the Breast than on the Breakwater is correlated with the slightly later rise in the temperature of the water on the deeper water ground in the spring.


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