scholarly journals Experimental Study on High Pressure Combustion of Decomposed Ammonia: How Can Ammonia Be Best Used in a Gas Turbine?

2021 ◽  
Author(s):  
Mario Ditaranto ◽  
Inge Saanum ◽  
Jenny Larfeldt
Keyword(s):  
Experimental Study ◽  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Favourable Effect ◽  
Small Scale ◽  
Nox Formation ◽  
Fuel Blends ◽  
Combustion Properties ◽  
Fuel Mixtures

Abstract Hydrogen, a carbon-free fuel, is a challenging gas to transport and store, but that can be solved by producing ammonia, a worldwide commonly distributed chemical. Ideally, ammonia should be used directly on site as a fuel, but it has many combustion shortcomings, with a very low reactivity and a high propensity to generate NOx. Alternatively, ammonia could be decomposed back to a mixture of hydrogen and nitrogen which has better combustion properties, but at the expense of an endothermal reaction. Between these two options, a trade off could be a partial decomposition where the end use fuel is a mixture of ammonia, hydrogen, and nitrogen. We present an experimental study aiming at finding optimal NH3-H2-N2 fuel blends to be used in gas turbines and provide manufacturers with guidelines for their use in retrofit and new combustion applications. The industrial burner considered in this study is a small-scale Siemens burner used in the SGT-750 gas turbine, tested in the SINTEF high pressure combustion facility. The overall behaviour of the burner in terms of stability and emissions is characterized as a function of fuel mixtures corresponding to partial and full decomposition of ammonia. It is found that when ammonia is present in the fuel, the NOx emissions although high can be limited if the primary flame zone is operated fuel rich. Increasing pressure has shown to have a strong and favourable effect on NOx formation. When ammonia is fully decomposed to 75% H2 and 25% N2, the opposite behaviour is observed. In conclusion, either low rate or full decomposition are found to be the better options.

A Reactor Model for the NOx Formation in a Reacting Jet in Hot Cross Flow Under Atmospheric and High Pressure Conditions

2014 ◽  
Author(s):  
Vera Hoferichter ◽  
Denise Ahrens ◽  
Michael Kolb ◽  
Thomas Sattelmayer
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Nox Reduction ◽  
Cross Flow ◽  
Nox Emission ◽  
Emission Characteristics ◽  
Ignition Process ◽  
Reactor Model ◽  
Nox Formation

Staged combustion is a promising technology for gas turbines to achieve load flexibility and low NOx emission levels at the same time. Therefore, a large scale atmospheric test rig has been set up at the Institute of Thermodynamics, Technical University of Munich to study NOx emission characteristics of a reacting jet in hot cross flow. The premixed primary combustion stage is operated at ϕ = 0.5 and provides the hot cross flow. In the second stage a premixed jet at ϕ = 0.77 is injected perpendicular to the first stage. In both stages natural gas is used as fuel and air as oxidant. This paper presents a reactor model approach for the computation of the resulting NOx concentrations. The mixing and ignition process along the jet streamline of maximum NOx formation is simulated using a perfectly stirred reactor with Cantera 1.8. The reactor model is validated for the ambient pressure case using experimental data. Afterwards, a high pressure simulation is performed in order to investigate the NOx emission characteristics under gas turbine conditions. The NOx formation is divided into flame NOx and post flame NOx. The reactor model reveals that the formation of post flame NOx in the second combustion stage can be efficiently suppressed due to fast mixing with cross flow material and the corresponding temperature reduction. Compared to single stage combustion with the same power output, no NOx reduction was observed in the experiment. However, the results from the reactor model suggest a NOx reduction potential at gas turbine conditions caused by the increased influence of post flame NOx production at high pressure.

Analysis of Water–Fuel Ratio Variation in a Gas Turbine With a Wet-Compressor System by Change in Fuel Composition

2017 ◽  
Vol 140 (5) ◽  
Author(s):  
Yonatan Cadavid ◽  
Andres Amell ◽  
Juan Alzate ◽  
Gerjan Bermejo ◽  
Gustavo A. Ebratt
Keyword(s):  
Gas Turbine ◽  
Burning Velocity ◽  
Thermal Power ◽  
Flame Temperature ◽  
Fuel Composition ◽  
Nox Formation ◽  
Gaseous Hydrocarbon ◽  
Power Generators ◽  
Fuel Ratio ◽  
Combustion Properties

The wet compressor (WC) has become a reliable way to reduce gas emissions and increase gas turbine efficiency. However, fuel source diversification in the short and medium terms presents a challenge for gas turbine operators to know how the WC will respond to changes in fuel composition. For this study, we assessed the operational data of two thermal power generators, with outputs of 610 MW and 300 MW, in Colombia. The purpose was to determine the maximum amount of water that can be added into a gas turbine with a WC system, as well as how the NOx/CO emissions vary due to changes in fuel composition. The combustion properties of different gaseous hydrocarbon mixtures at wet conditions did not vary significantly from each other—except for the laminar burning velocity. It was found that the fuel/air equivalence ratio in the turbine reduced with lower CH4 content in the fuel. Less water can be added to the turbine with leaner combustion; the water/fuel ratio was decreased over the range of 1.4–0.4 for the studied case. The limit is mainly due to a reduction in flame temperature and major risk of lean blowout (LBO) or dynamic instabilities. A hybrid reaction mechanism was created from GRI-MECH 3.0 and NGIII to model hydrocarbons up to C5 with NOx formation. The model was validated with experimental results published previously in literature. Finally, the effect of atmospheric water in the premixed combustion was analyzed and explained.

Hydrogen Blending Into Ansaldo Energia AE94.3A Gas Turbine: High Pressure Tests, Field Experience and Modelling Considerations

2021 ◽  
Author(s):  
A. Ciani ◽  
L. Tay-Wo-Chong ◽  
A. Amato ◽  
E. Bertolotto ◽  
G. Spataro
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Power Plants ◽  
Flame Structure ◽  
Flux Ratio ◽  
Fuel Blends ◽  
Pressure Tests ◽  
Fuel Staging ◽  
Combustion Tests ◽  
The Impact

Abstract Fuel flexibility in gas turbine development has become increasingly important and modern engines need to cope with a broad variety of fuels. The target to operate power plants with hydrogen-based fuels and low emissions will be of paramount importance in a future focusing on electric power decarbonization. Ansaldo Energia AE94.3A engine acquired broad experience with operation of various natural gas and hydrogen fuel blends, starting in 2006 in the Brindisi (Italy) power plant. Based on the exhaustive experience acquired in the field, this paper describes the latest advancements characterizing the operation of the AE94.3A burner with high pressure combustion tests adding hydrogen blends ranging from 0 to 40% in volume. The interpretation of the test results is supported by reactive and non-reactive simulations describing the effects of varying fuel reactivity on the flame structure as well as the impact of fuel / air momentum flux ratio on the fuel / air interaction and fuel distribution in the combustion chamber. As expected, increasing amounts of hydrogen in the fuel are also associated with higher amounts of NOx production, however this effect could be countered by optimization of the fuel staging strategy, based on the mentioned CFD considerations and feedback from high pressure tests.

Three Spool High Efficiency Small Scale Gas Turbine Concept

2017 ◽  
Author(s):  
Matti Malkamäki ◽  
Ahti Jaatinen-Värri ◽  
Antti Uusitalo ◽  
Aki Grönman ◽  
Juha Honkatukia ◽  
...  
Keyword(s):  
Power Generation ◽  
Gas Turbine ◽  
Gas Turbines ◽  
High Efficiency ◽  
Small Scale ◽  
Inlet Temperature ◽  
Substantial Impact ◽  
Electrical Efficiency ◽  
Partial Load ◽  
Reciprocating Engines

Decentralized electricity and heat production is a rising trend in small-scale industry. There is a tendency towards more distributed power generation. The decentralized power generation is also pushed forward by the policymakers. Reciprocating engines and gas turbines have an essential role in the global decentralized energy markets and improvements in their electrical efficiency have a substantial impact from the environmental and economic viewpoints. This paper introduces an intercooled and recuperated three stage, three-shaft gas turbine concept in 850 kW electric output range. The gas turbine is optimized for a realistic combination of the turbomachinery efficiencies, the turbine inlet temperature, the compressor specific speeds, the recuperation rate and the pressure ratio. The new gas turbine design is a natural development of the earlier two-spool gas turbine construction and it competes with the efficiencies achieved both with similar size reciprocating engines and large industrial gas turbines used in heat and power generation all over the world and manufactured in large production series. This paper presents a small-scale gas turbine process, which has a simulated electrical efficiency of 48% as well as thermal efficiency of 51% and can compete with reciprocating engines in terms of electrical efficiency at nominal and partial load conditions.

Measurement and Analysis of Flame Transfer Function in a Sector Combustor Under High Pressure Conditions

2003 ◽  
Author(s):  
W. S. Cheung ◽  
G. J. M. Sims ◽  
R. W. Copplestone ◽  
J. R. Tilston ◽  
C. W. Wilson ◽  
...  
Keyword(s):  
High Pressure ◽  
Transfer Function ◽  
Heat Release ◽  
Gas Turbine ◽  
Mass Flow ◽  
Atmospheric Pressure ◽  
Acoustic Waves ◽  
Gas Turbines ◽  
Transfer Functions ◽  
Unsteady Pressure

Lean premixed prevaporised (LPP) combustion can reduce NOx emissions from gas turbines, but often leads to combustion instability. A flame transfer function describes the change in the rate of heat release in response to perturbations in the inlet flow as a function of frequency. It is a quantitative assessment of the susceptibility of combustion to disturbances. The resulting fluctuations will in turn generate more acoustic waves and in some situations self-sustained oscillations can result. Flame transfer functions for LPP combustion are poorly understood at present but are crucial for predicting combustion oscillations. This paper describes an experiment designed to measure the flame transfer function of a simple combustor incorporating realistic components. Tests were conducted initially on this combustor at atmospheric pressure (1.2 bar and 550 K) to make an early demonstration of the combustion system. The test rig consisted of a plenum chamber with an inline siren, followed by a single LPP premixer/duct and a combustion chamber with a silencer to prevent natural instabilities. The siren was used to induce variable frequency pressure/acoustic signals into the air approaching the combustor. Both unsteady pressure and heat release measurements were undertaken. There was good coherence between the pressure and heat release signals. At each test frequency, two unsteady pressure measurements in the plenum were used to calculate the acoustic waves in this chamber and hence estimate the mass-flow perturbation at the fuel injection point inside the LPP duct. The flame transfer function relating the heat release perturbation to this mass flow was found as a function of frequency. The same combustor hardware and associated instrumentation were then used for the high pressure (15 bar and 800 K) tests. Flame transfer function measurements were taken at three combustion conditions that simulated the staging point conditions (Idle, Approach and Take-off) of a large turbofan gas turbine. There was good coherence between pressure and heat release signals at Idle, indicating a close relationship between acoustic and heat release processes. Problems were encountered at high frequencies for the Approach and Take-off conditions, but the flame transfer function for the Idle case had very good qualitative agreement with the atmospheric-pressure tests. The flame transfer functions calculated here could be used directly for predicting combustion oscillations in gas turbine using the same LPP duct at the same operating conditions. More importantly they can guide work to produce a general analytical model.

Application of Ultra-Low NOx Combustor to the MHPS Existing Gas Turbine

2021 ◽  
Author(s):  
Takashi Nishiumi ◽  
Hirofumi Ohara ◽  
Kotaro Miyauchi ◽  
Sosuke Nakamura ◽  
Toshishige Ai ◽  
...  
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Combined Cycle ◽  
Inlet Temperature ◽  
Operational Experience ◽  
Emission Rates ◽  
Gas Temperature ◽  
Design Development ◽  
And Control

Abstract In recent years, MHPS achieved a NET M501J gas turbine combined cycle (GTCC) efficiency in excess of 62% operating at 1,600°C, while maintaining NOx under 25ppm. Taking advantage of our gas turbine combustion design, development and operational experience, retrofits of earlier generation gas turbines have been successfully applied and will be described in this paper. One example of the latest J-Series technologies, a conventional pilot nozzle was changed to a premix type pilot nozzle for low emission. The technology was retrofitted to the existing F-Series gas turbines, which resulted in emission rates of lower than 9ppm NOx(15%O2) while maintaining the same Turbine Inlet Temperature (TIT: Average Gas Temperature at the exit of the transition piece). After performing retrofitting design, high pressure rig tests, the field test prior to commercial operation was conducted on January 2019. This paper describes the Ultra-Low NOx combustor design features, retrofit design, high pressure rig test and verification test results of the upgraded M501F gas turbine. In addition, it describes another upgrade of turbine to improve efficiency and of combustion control system to achieve low emissions. Furthermore it describes the trouble-free upgrade of seven (7) units, which was completed by utilizing MHPS integration capabilities, including handling all the design, construction and service work of the main equipment, plant and control systems.

Toward Decarbonized Power Generation With Gas Turbines by Using Sequential Combustion for Burning Hydrogen

2019 ◽  
Vol 141 (12) ◽  
Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Tuning Parameter ◽  
Stable Combustion ◽  
Second Stage ◽  
Fuel Flexibility ◽  
Mild Reduction ◽  
In Series ◽  
Exit Temperature

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas (NG) will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia's gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e., the temperature between the first and the second stage. The standard constant pressure sequential combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of NG and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e., without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.

Design Study of an Advanced Concept Simple Gas Turbine for Possible Use in Low Emission Automobiles

1972 ◽  
Author(s):  
H. C. Eatock ◽  
M. D. Stoten
Keyword(s):  
High Pressure ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Pressure Ratio ◽  
Simple Cycle ◽  
Turbine Engines ◽  
Nox Emissions ◽  
Preliminary Design ◽  
Gas Turbine Engines ◽  
High Pressure Ratio

United Aircraft Corporation studied the potential costs of various possible gas turbine engines which might be used to reduce automobile exhaust emissions. As part of that study, United Aircraft of Canada undertook the preliminary design and performance analysis of high-pressure-ratio nonregenerated (simple cycle) gas turbine engines. For the first time, high levels of single-stage component efficiency are available extending from a pressure ratio less than 4 up to 10 or 12 to 1. As a result, the study showed that the simple-cycle engine may provide satisfactory running costs with significantly lower manufacturing costs and NOx emissions than a regenerated engine. In this paper some features of the preliminary design of both single-shaft and a free power turbine version of this engine are examined. The major component technology assumptions, in particular the high pressure ratio centrifugal compressor, employed for performance extrapolation are explained and compared with current technology. The potential low NOx emissions of the simple-cycle gas turbine compared to regenerative or recuperative gas turbines is discussed. Finally, some of the problems which might be encountered in using this totally different power plant for the conventional automobile are identified.

Development and Testing of a FuelFlex Dry-Low-NOx Micromix Combustor for Industrial Gas Turbine Applications With Variable Hydrogen Methane Mixtures

2019 ◽  
Author(s):  
H. H.-W. Funke ◽  
N. Beckmann ◽  
S. Abanteriba
Keyword(s):  
Gas Turbine ◽  
Experimental Studies ◽  
Fuel Mixture ◽  
Combustion Efficiency ◽  
Pollutant Emission ◽  
Pure Hydrogen ◽  
Negative Effects ◽  
Low Emission ◽  
Combustion Properties ◽  
Fuel Mixtures

Abstract The negative effects on the earth’s climate make the reduction of the potent greenhouse gases carbon-dioxide (CO2) and nitrogen oxides (NOx) an imperative of the combustion research. Hydrogen based gas turbine systems are in the focus of the energy producing industry, due to their potential to eliminate CO2 emissions completely as combustion product, if the fuel is produced from renewable and sustainable energy sources. Due to the difference in the physical properties of hydrogen-rich fuel mixtures compared to common gas turbine fuels, well established combustion systems cannot be directly applied for Dry Low NOx (DLN) hydrogen combustion. The paper presents initial test data of a recently designed low emission Micromix combustor adapted to flexible fuel operation with variable fuel mixtures of hydrogen and methane. Based on previous studies, targeting low emission combustion of pure hydrogen and dual fuel operation with hydrogen and syngas (H2/CO 90/10 vol.%), a FuelFlex Micromix combustor for variable hydrogen methane mixtures has been developed. For facilitating the experimental low pressure testing the combustion chamber test rig is adapted for flexible fuel operation. A computer-controlled gas mixing facility is designed and installed to continuously provide accurate and homogeneous hydrogen methane fuel mixtures to the combustor. An evaluation of all major error sources has been conducted. In the presented experimental studies, the integration-optimized FuelFlex Micromix combustor geometry is tested at atmospheric pressure with hydrogen methane fuel mixtures ranging from 57 vol.% to 100 vol.% hydrogen in the fuel. For evaluating the combustion characteristics, the results of experimental exhaust gas analyses are applied. Despite the design compromise, that takes into account the significantly different fuel and combustion properties of the applied fuels, the initial results confirm promising operating behaviour, combustion efficiency and pollutant emission levels for flexible fuel operation. The investigated combustor module exceeds 99.4% combustion efficiency for hydrogen contents of 80–100% in the fuel mixture and shows NOx emissions less than 4 ppm corrected to 15 vol.% O2 at the design point.

Sequential Combustion in Gas Turbines: The Key Technology for Burning High Hydrogen Contents With Low Emissions

2019 ◽  
Author(s):  
Mirko R. Bothien ◽  
Andrea Ciani ◽  
John P. Wood ◽  
Gerhard Fruechtel
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Gas Turbine ◽  
Gas Turbines ◽  
Tuning Parameter ◽  
High Hydrogen ◽  
Stable Combustion ◽  
Second Stage ◽  
In Series ◽  
Exit Temperature

Abstract Excess energy generation from renewables can be conveniently stored as hydrogen for later use as a gas turbine fuel. Also, the strategy to sequestrate CO2 from natural gas will require gas turbines to run with hydrogen-based fuels. In such scenarios, high temperature low emission combustion of hydrogen is a key requirement for the future gas turbine market. Ansaldo Energia’s gas turbines featuring sequential combustion have an intrinsic advantage when it comes to fuel flexibility and in particular hydrogen-based fuels. The sequential combustion system is composed of two complementary combustion stages in series: one premix stage followed by an auto-ignited second stage overcoming the limits of traditional premix combustion systems through a highly effective extra tuning parameter, i.e. the temperature between the first and the second stage. The standard Constant Pressure Sequential Combustion (CPSC) system as applied in the GT36 engine is tested, at high pressure, demonstrating that a modified operation concept allows stable combustion with no changes in combustor hardware for the whole range of natural gas and hydrogen blends. It is shown that in the range from 0% to 70% (vol.) hydrogen, stable combustion is achieved at full nominal exit temperature, i.e. without any derating and thus clearly outperforming other available conventional premixed combustors. Operation between 70% and 100% is possible as well and only requires a mild reduction of the combustor exit temperature. By proving the transferability of the single-can high pressure results to the engine, this paper demonstrates the practicality of operating the Ansaldo Energia GT36 H-Class gas turbine on fuels containing unprecedented concentrations of hydrogen while maintaining excellent performance and low emissions both in terms of NOx and CO2.

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