Carboniferous volcanic rocks of the Magdalen Islands, Gulf of St. Lawrence

1985 ◽  
Vol 22 (11) ◽  
pp. 1679-1688 ◽  
Author(s):  
Sandra M. Barr ◽  
Daniel Brisebois ◽  
Alan S. Macdonald

Volcanic rocks of Mississippian age occur on the Magdalen Islands as cap rocks and within collapse breccias above salt diapirs that have formed the islands. They consist of coarse volcaniclastic deposits and basaltic flows, intruded by minor mafic dykes and plugs. Petrologic studies of the basaltic rocks show that they are extensively altered. Original plagioclase, clinopyroxene, olivine, and interstitial glass are partially to entirely replaced by mixtures of chlorite, sericite, smectite, sphene, carbonate, epidote, albite, potassium feldspar, and iron oxides, and the samples display a relatively wide range in chemical compositions. Especially mobile were K, Na, and Ca, and most samples are classified as potash spilites (poenites). Using standard discriminant diagrams for mafic igneous rocks, it can be seen that the basalts appear to range from continental tholeiitic to continental alkalic. However, relict clinopyroxene compositions and the presence of kaersutitic amphibole and titaniferous biotite in some samples imply that the suite may originally have been more alkalic than tholeiitic.

2006 ◽  
Vol 11 ◽  
pp. 145-162 ◽  
Author(s):  
Kai Sørensen ◽  
John A. Korstgård ◽  
William E. Glassley ◽  
Bo Møller Stensgaard

The Nordre Strømfjord shear zone in the fjord Arfersiorfik, central West Greenland, consists of alternating panels of supracrustal rocks and orthogneisses which together form a vertical zone up to 7 km wide with sinistral transcurrent, ductile deformation, which occurred under middle amphibolite facies conditions. The pelitic and metavolcanic schists and paragneisses are all highly deformed, while the orthogneisses appear more variably deformed, with increasing deformation evident towards the supracrustal units. The c. 1.92 Ga Arfersiorfik quartz diorite is traceable for a distance of at least 35 km from the Inland Ice towards the west-south-west. Towards its northern contact with an intensely deformed schist unit it shows a similar pattern of increasing strain, which is accompanied by chemical and mineralogical changes. The metasomatic changes associated with the shear zone deformation are superimposed on a wide range of original chemical compositions, which reflect magmatic olivine and/ or pyroxene as well as hornblende fractionation trends. The chemistry of the Arfersiorfik quartz diorite suite as a whole is comparable to that of Phanerozoic plutonic and volcanic rocks of calc-alkaline affinity.


2016 ◽  
Vol 43 (4) ◽  
pp. 251 ◽  
Author(s):  
J. Gregory Shellnutt

The Early Permian (290 Ma) Panjal Traps are the largest contiguous outcropping of volcanic rocks associated with the Himalayan Magmatic Province (HMP). The eruptions of HMP-related lava were contemporaneous with the initial break-up of Pangea. The Panjal Traps are primarily basalt but volumetrically minor intermediate and felsic volcanic rocks also occur. The basaltic rocks range in composition from continental tholeiite to ocean-floor basalt and nearly all have experienced, to varying extent, crustal contamination. Uncontaminated basaltic rocks have Sr–Nd isotopes similar to a chondritic source (ISr = 0.7043 to 0.7073; eNd(t) = 0 ± 1), whereas the remaining basaltic rocks have a wide range of Nd (eNd(t) = –6.1 to +4.3) and Sr (ISr = 0.7051 to 0.7185) isotopic values. The calculated primary melt compositions of basalt are picritic and their mantle potential temperatures (TP ≤ 1450°C) are similar to ambient mantle rather than anomalously hot mantle. The silicic volcanic rocks were likely derived by partial melting of the crust whereas the andesitic rocks were derived by mixing between crustal and mantle melts. The Traps erupted within a continental rift setting that developed into a shallow sea. Sustained rifting created a nascent ocean basin that led to sea-floor spreading and the rifting of microcontinents from Gondwana to form the ribbon-like continent Cimmeria and the Neotethys Ocean.RÉSUMÉLes Panjal Traps du début Permien (290 Ma) constituent le plus grand affleurement contigu de roches volcaniques associées à la province magmatique de himalayienne (HMP). Les éruptions de lave de type HMP étaient contemporaines de la rupture initiale de la Pangée. Les Panjal Traps sont essentiellement des basaltes, mais on y trouve aussi des roches volcaniques intermédiaires et felsiques en quantités mineures. La composition de ces roches basaltiques varie de tholéiite continentale à basalte de plancher océanique, et presque toutes ont subi, à des degrés divers, une contamination de matériaux crustaux. Les roches basaltiques non contaminées ont des contenus isotopiques Sr–Nd similaires à une source chondritique (Isr = 0,7043 à 0,7073; eNd (t) = 0 ± 1), alors que les roches basaltiques autres montrent une large gamme de valeurs isotopiques en Nd (eNd (t) = –6,1 à +4,3) et Sr (Isr = de 0,7051 à 0,7185). Les compositions de fusion primaire calculées des basaltes sont picritiques et leurs températures potentielles mantelliques (TP de ≤ 1450°C) sont similaires à la température ambiante du manteau plutôt que celle d’un manteau anormalement chaud. Les roches volcaniques siliciques dérivent probablement de la fusion partielle de la croûte alors que les roches andésitiques proviennent du mélange entre des matériaux de fusion crustaux et mantelliques. Les Traps ont fait irruption dans un contexte de rift continental qui s’est développé dans une mer peu profonde. Un rifting soutenu a créé un début de bassin océanique lequel conduit à une expansion du fond océanique et au rifting de microcontinents tirés du Gondwana pour former le continent rubané de Cimméria et l'océan Néotéthys.


Author(s):  
M. Mohammadzadeh Moghaddam ◽  
S. Mirzaei ◽  
M. Abedi

Abstract —New insights in the aeromagnetic data over the Central Iranian Microcontinent (CIM) have revealed interesting results for future studies and exploration. This work presents the interpretation of different magnetic analyses and the calculated 3D inversion model to provide important insights into the distribution of igneous rocks in the area that may be traced under significant cover. By analyzing several hundred magnetic susceptibility data points and aeromagnetic anomalies of known igneous rocks over the area, it was determined that mafic–ultramafic intrusive rocks generally have a high magnetic susceptibility and produce a strong magnetic response. Intermediate–felsic intrusive rocks have a low magnetic susceptibility and show a smooth gradient variation and commonly regular shape. Volcanic rocks show a wide range of magnetic susceptibility; therefore, the aeromagnetic anomalies are often random or show strong amplitude with high frequency signals and are rapidly eliminated when an upward continuation is applied. Based on the results of analysis of different magnetic maps and 3D inversion of data, and combining this information with known outcropped of igneous rocks, we revealed 1215 concealed intrusive rocks and 528 volcanic rocks in the area. We also renewed the boundaries of tens outcropped igneous rocks. The known and new mapped igneous rocks can be identified as 12 regions (or zones) for intrusive rocks and 4 regions for volcanic rocks. The results indicate that the mafic–ultramafic rocks are mainly located in the Sistan suture zone of eastern Iran along the Nehbandan fault zone. They also show that the many parts of the Lut block as the main structure of CIM have been under magmatic events, so that most of concealed igneous rocks are distributed in the middle and southern part of the Lut block. Volcanic rocks are widespread in the southeastern and northern parts of the area such as the Urumieh-Dokhtar Magmatic Arc, North Lut, and Bam region.


2021 ◽  
Vol 48 (1) ◽  
pp. e104451
Author(s):  
Patricia Lopes DESCOVI ◽  
Marcus Vinícius Berao ADE ◽  
Gabriela De Oliveira AVELLAR ◽  
Silvia Lorena Bejarano BERMÚDEZ ◽  
Fábio Pinto VIEIRA

Within the oil and gas industry, igneous rocks are still seen as exploration and production challenges, due to their diverse petrogenesis and the wide range of values of some important petrophysical properties. This petrophysical variability depends on both primary and secondary processes. These facts made these rocks unattractive for decades. This condition is still observed in many fields around the world. This article has as main objective to make a historical review of studies developed globally with a focus on igneous rocks that act as a reservoir in petroleum systems. The review covered in this article was developed from a compilation of global data, thus allowing an overview of the countries that produce hydrocarbons in volcanic rocks, what types of rocks, geological age, and size of the reserve. Countries such as China and Indonesia stand out with higher daily production, exceeding orders of quantities of 108 cubic meters of gas and 104 tons of barrels of oil. In these countries, geological patterns are already being noticed in volcanic reservoirs, such as more recent geological ages and typical lithologies. Also, this work seeks to emphasize the importance of studying this type of reservoir, as its knowledge can lead to the solution of real problems within the world oil and gas industry.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


Author(s):  
Henrik Stendal ◽  
Wulf Mueller ◽  
Nicolai Birkedal ◽  
Esben I. Hansen ◽  
Claus Østergaard

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Stendal, H., Mueller, W., Birkedal, N., Hansen, E. I., & Østergaard, C. (1997). Mafic igneous rocks and mineralisation in the Palaeoproterozoic Ketilidian orogen, South-East Greenland: project SUPRASYD 1996. Geology of Greenland Survey Bulletin, 176, 66-74. https://doi.org/10.34194/ggub.v176.5064 _______________ The multidisciplinary SUPRASYD project (1992–96) focused on a regional investigation of the Palaeoproterozoic Ketilidian orogenic belt which crosses the southern tip of Greenland. Apart from a broad range of geological and structural studies (Nielsen et al., 1993; Garde & Schønwandt, 1994, 1995; Garde et al., 1997), the project included a mineral resource evaluation of the supracrustal sequences associated with the Ketilidian orogen (e.g. Mosher, 1995). The Ketilidian orogen of southern Greenland can be divided from north-west to south-east into: (1) a border zone in which the crystalline rocks of the Archaean craton are unconformably overlain by Ketilidian supracrustal rocks; (2) a major polyphase pluton, referred to as the Julianehåb batholith; and (3) extensive areas of Ketilidian supracrustal rocks, divided into psammitic and pelitic rocks with subordinate interstratified mafic volcanic rocks (Fig. 1). The Julianehåb batholith is viewed as emplaced in a magmatic arc setting; the supracrustal sequences south of the batholith have been interpreted as either (1) deposited in an intra-arc and fore-arc basin (Chadwick & Garde, 1996), or (2) deposited in a back-arc or intra-arc setting (Stendal & Swager, 1995; Swager, 1995). Both possibilities are plausible and infer subduction-related processes. Regional compilations of geological, geochemical and geophysical data for southern Greenland have been presented by Thorning et al. (1994). Mosher (1995) has recently reviewed the mineral exploration potential of the region. The commercial company Nunaoil A/S has been engaged in gold prospecting in South Greenland since 1990 (e.g. Gowen et al., 1993). A principal goal of the SUPRASYD project was to test the mineral potential of the Ketilidian supracrustal sequences and define the gold potential in the shear zones in the Julianehåb batholith. Previous work has substantiated a gold potential in amphibolitic rocks in the south-west coastal areas (Gowen et al., 1993.), and in the amphibolitic rocks of the Kutseq area (Swager et al., 1995). Field work in 1996 was focused on prospective gold-bearing sites in mafic rocks in South-East Greenland. Three M.Sc. students mapped showings under the supervision of the H. S., while an area on the south side of Kangerluluk fjord was mapped by H. S. and W. M. (Fig. 4).


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3357
Author(s):  
Péter Nagy ◽  
Nadia Rohbeck ◽  
Zoltán Hegedűs ◽  
Johann Michler ◽  
László Pethö ◽  
...  

A nanocrystalline Co-Cr-Ni-Fe compositional complex alloy (CCA) film with a thickness of about 1 micron was produced by a multiple-beam-sputtering physical vapor deposition (PVD) technique. The main advantage of this novel method is that it does not require alloy targets, but rather uses commercially pure metal sources. Another benefit of the application of this technique is that it produces compositional gradient samples on a disk surface with a wide range of elemental concentrations, enabling combinatorial analysis of CCA films. In this study, the variation of the phase composition, the microstructure (crystallite size and defect density), and the mechanical performance (hardness and elastic modulus) as a function of the chemical composition was studied in a combinatorial Co-Cr-Ni-Fe thin film sample that was produced on a surface of a disk with a diameter of about 10 cm. The spatial variation of the crystallite size and the density of lattice defects (e.g., dislocations and twin faults) were investigated by X-ray diffraction line profile analysis performed on the patterns taken by synchrotron radiation. The hardness and the elastic modulus were measured by the nanoindentation technique. It was found that a single-phase face-centered cubic (fcc) structure was formed for a wide range of chemical compositions. The microstructure was nanocrystalline with a crystallite size of 10–27 nm and contained a high lattice defect density. The hardness and the elastic modulus values measured for very different compositions were in the ranges of 8.4–11.8 and 182–239 GPa, respectively.


2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.


2021 ◽  
Vol 62 (10) ◽  
pp. 1175-1187
Author(s):  
A.D. Nozhkin ◽  
O.M. Turkina ◽  
K.A. Savko

Abstract —The paper presents results of a petrogeochemical and isotope–geochronological study of the granite–leucogranite association of the Pavlov massif and felsic volcanics from the Elash graben (Biryusa block, southwest of the Siberian craton). A characteristic feature of the granite–leucogranites is their spatial and temporal association with vein aplites and pegmatites of the East Sayan rare-metal province. The U–Pb age of zircon from granites of the Pavlov massif (1852 ± 5 Ma) is close to the age of the pegmatites of the Vishnyakovskoe rare-metal deposit (1838 ± 3 Ma). The predominant biotite porphyritic granites and leucogranites of the Pavlov massif show variable alkali ratios (K2O/Na2O = 1.1–2.3) and ferroan (Fe*) index and a peraluminous composition; they are comparable with S-granites. The studied rhyolites of the Tagul River (SiO2 = 71–76%) show a low ferroan index, a high K2O/Na2O ratio (1.6–4.0), low (La/Yb)n values (4.3–10.5), and a clear Eu minimum (Eu/Eu* = 0.3–0.5); they are similar to highly fractionated I-granites. All coeval late Paleoproterozoic (1.88–1.85 Ga) granites and felsic volcanics of the Elash graben have distinct differences in composition, especially in the ferroan index and HREE contents, owing to variations in the source composition and melting conditions during their formation at postcollisions extension. The wide range of the isotope parameters of granites and felsic volcanic rocks (εNd from +2.0 to –3.7) and zircons (εHf from +3.0 to +0.8, granites of the Toporok massif) indicates the heterogeneity of the crustal basement of the Elash graben, which formed both in the Archean and in the Paleoproterozoic.


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