scholarly journals Development of low-cost iron mixed porous pellet adsorbent by mixture design approach and its application for arsenate and arsenite adsorption from water

2017 ◽  
Vol 36 (1-2) ◽  
pp. 372-392 ◽  
Author(s):  
Borano Te ◽  
Boonchai Wichitsathian ◽  
Chatpet Yossapol ◽  
Watcharapol Wonglertarak
Keyword(s):  
Low Cost ◽  
Mixture Design ◽  
Alkaline Condition ◽  
P Value ◽  
Maximum Adsorption Capacity ◽  
Natural Clay ◽  
Optimum Proportion ◽  
Negative Effect ◽  
Pseudo Second Order ◽  
Arsenite Removal

In this study, natural clay, iron oxide, and iron powder were combined to develop low-cost iron mixed porous pellet adsorbent for arsenate and arsenite removal from aqueous solution in batch experiments. The augmented simplex centroid mixture design was applied to obtain the optimum proportion of each constituent. Higher correlation coefficient of the models (R2 > 0.95), good distribution of residuals, and lower values of p value (<0.05) indicated that the method is suitable for determining the optimum mixture proportion. Extensive decrease of both arsenate and arsenite adsorption occurred in the alkaline condition (pH > 9). Kinetic and isotherm experimental data of both arsenate and arsenite were well described by the pseudo-second order and Sips models, respectively. The maximum adsorption capacity of arsenate and arsenite derived from Sips model were 13.33 and 19.06 mg/g, respectively. The separation and heterogeneity factors showed that both arsenate and arsenite were favorably adsorbed. Among coexisting anions, phosphate significantly showed negative effect on the adsorption of either arsenate or arsenite. The adsorbent could be effectively reused for several times after its regeneration and was considered as non-hazardous material after adsorption.

Preparation of bio-based magnetic adsorbent and application for efficient removal of Cd(II) from water

2018 ◽  
Vol 77 (5) ◽  
pp. 1313-1323 ◽  
Author(s):  
Jianjun Zhou ◽  
Xionghui Ji ◽  
Xiaohui Zhou ◽  
Jialin Ren ◽  
Yaochi Liu
Keyword(s):  
Aqueous Solution ◽  
Adsorption Process ◽  
Low Cost ◽  
Maximum Adsorption Capacity ◽  
Magnetic Adsorbent ◽  
Order Model ◽  
Efficient Removal ◽  
Adsorption Ability ◽  
Adsorption Sites ◽  
Pseudo Second Order

Abstract A novel magnetic bio-adsorbent (MCIA) was developed, characterized and tested for its Cd(II) removal from aqueous solution. MCIA could be easily separated from the solution after equilibrium adsorption due to its super-paramagnetic property. The functional and magnetic bio-material was an attractive adsorbent for the removal of Cd(II) from aqueous solution owing to the abundant adsorption sites, amino-group and oxygen-containing groups on the surface of Cyclosorus interruptus. The experimental results indicated that the MCIA exhibited excellent adsorption ability and the adsorption process was spontaneous and endothermic. The adsorption isotherm was consistent with the Langmuir model. The adsorption kinetic fitted the pseudo-second-order model very well. The maximum adsorption capacity of Cd(II) onto MCIA was 40.8, 49.4, 54.6 and 56.6 mg/g at 293, 303, 313 and 323 K, respectively. And the MCIA exhibited an excellent reusability and impressive regeneration. Therefore, MCIA could serve as a sustainable, efficient and low-cost magnetic adsorbent for Cd(II) removal from aqueous solution.

scholarly journals Simultaneous Adsorption of Cr(VI) and Phenol from Binary Mixture Using Iron Incorporated Rice Husk: Insight to Multicomponent Equilibrium Isotherm

2016 ◽  
Vol 2016 ◽  
pp. 1-11 ◽  
Author(s):  
Ankur Gupta ◽  
Chandrajit Balomajumder
Keyword(s):  
Experimental Data ◽  
Rice Husk ◽  
Low Cost ◽  
Binary Solution ◽  
Multicomponent System ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Order Model ◽  
Adsorption Isotherm Models ◽  
Pseudo Second Order

Fe modified rice husk was prepared as a low cost biosorbent for the removal of Cr(VI) and phenol both singly and in combination from single and binary simulated synthetic waste water. Rice husk was modified by treating with FeSO4·7H2O. The results showed that impregnation of iron onto the surface of rice husk improved the adsorption capability of both Cr(VI) and phenol. The effects of process parameters for multicomponent system such as pH, adsorbent dose, and contact time onto the percentage removal of both Cr(VI) and phenol were investigated. The experimental data for the adsorption of both Cr(VI) and phenol onto the surface of Fe modified rice husk applied to various kinetic and adsorption isotherm models. Multicomponent isotherm models such as Nonmodified Langmuir, Modified Langmuir, Extended Langmuir, Extended Freundlich, Competitive Nonmodified Redlich Peterson, Competitive Modified Redlich Peterson were applied. The results show that Extended Freundlich model best described the experimental data for both Cr(VI) and phenol from binary solution. Pseudo second-order model agreed well with Cr(VI) while pseudo first-order model agreed well with phenol. Maximum adsorption capacity in synthetic binary solution of Cr(VI) and phenol was found to be 36.3817 mg g−1for Cr(VI) and 6.569 mg g−1for phenol, respectively.

Equilibrium, kinetic and thermodynamic studies of mercury adsorption on almond shell

2012 ◽  
Vol 65 (8) ◽  
pp. 1341-1349 ◽  
Author(s):  
Shokooh Sadat Khaloo ◽  
Amir Hossein Matin ◽  
Sahar Sharifi ◽  
Masoumeh Fadaeinia ◽  
Narges Kazempour ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Low Cost ◽  
Second Order ◽  
Ion Concentration ◽  
Physical Parameters ◽  
Maximum Adsorption Capacity ◽  
Almond Shell ◽  
Pseudo Second Order ◽  
Uptake Process ◽  
Reaction Equations

The application of almond shell as a low cost natural adsorbent to remove Hg2+ from aqueous solution was investigated. Batch experiments were carried out to evaluate the adsorption capacity of the material. The chemical and physical parameters such as pH, sorbent amount, initial ion concentration, and contact time were optimized for the maximum uptake of mercury onto the solid surface. Adsorption isotherms were expressed by Langmuir and Freundlich adsorption models, and the experimental data were found to fit the Langmuir model rather than the Freundlich. The maximum adsorption capacity obtained from the Langmuir isotherm was 135.13 mg/g. A kinetic study was carried out with pseudo-first-order and pseudo-second-order reaction equations and it was found that the Hg2+ uptake process followed the pseudo-second-order rate expression. The thermodynamic values, ΔG0, ΔH0 and ΔS0, indicated that adsorption was an endothermic and spontaneous process. The potential of this material for mercury elimination was demonstrated by efficient Hg2+ removal from a synthetic effluent.

scholarly journals Treatment of effluent from fertilizer industry by adsorption on willow sawdust-removal of Ni(II) and Cd(II) from the effluent

2021 ◽  
pp. 1-12
Author(s):  
Raafia Najam ◽  
Syed Muzaffar Ali Andrabi
Keyword(s):  
Aqueous Solution ◽  
Adsorption Process ◽  
Low Cost ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Solution Ph ◽  
The World ◽  
Pseudo Second Order ◽  
Almost All ◽  
Willow Tree

Sawdust of willow has been investigated as an adsorbent for the removal of Ni(II), and Cd(II) ions from aqueous solution. Since willow tree is widely grown in almost all parts of Kashmir, it can be a common most easily available, sustainable, low cost adsorbent for the treatment of wastewaters in this part of the world where growing industrialization is affecting water quality like elsewhere in the world. Therefore, it is worthwhile to investigate the potential of sawdust of willow tree as an adsorbent for the removal of Ni(II) and Cd(II) ions from aqueous solution as a first step. Batch experiments were conducted to study the effect of some parameters such as contact time, initial concentration of metal ions, solution pH and temperature. Langmuir and Freundlich models were employed for the mechanistic analysis of experimental data obtained. Results reveal that in our system adsorption follows the Langmuir isotherm. The maximum adsorption capacity of Ni(II) and Cd(II) were found to be 7.98 and 7.11 mg/g respectively at optimum conditions. The pseudo-first-order and pseudo-second-order models were employed for kinetic analysis of adsorption process. The adsorption process follows pseudo-second-order kinetics. The efficacy of the adsorbent in the treatment of effluent from fertilizer factory has been investigated and the results have been found encouraging.

scholarly journals Highly Effective Covalently Crosslinked Composite Alginate Cryogels for Cationic Dye Removal

Gels ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 178
Author(s):  
Serap Sezen ◽  
Vijay Kumar Thakur ◽  
Mehmet Murat Ozmen
Keyword(s):  
Adsorption Capacity ◽  
Dye Removal ◽  
Low Cost ◽  
Dye Adsorption ◽  
Maximum Adsorption Capacity ◽  
High Porosity ◽  
Order Model ◽  
Removal Capacity ◽  
Pseudo Second Order ◽  
The One

Currently, macroporous hydrogels have been receiving attention in wastewater treatment due to their unique structures. As a natural polymer, alginate is used to remove cationic dyes due to its sustainable features such as abundance, low cost, processability, and being environmentally friendly. Herein, alginate/montmorillonite composite macroporous hydrogels (cryogels) with high porosity, mechanical elasticity, and high adsorption yield for methylene blue (MB) were generated by the one-step cryogelation technique. These cryogels were synthesized by adding montmorillonite into gel precursor, followed by chemical cross-linking employing carbodiimide chemistry in a frozen state. The as-prepared adsorbents were analyzed by FT-IR, SEM, gel fraction, swelling, uniaxial compression, and MB adsorption tests. The results indicated that alginate/montmorillonite cryogels exhibited high gelation yield (up to 80%), colossal water uptake capacity, elasticity, and effective dye adsorption capacity (93.7%). Maximum adsorption capacity against MB was 559.94 mg g−1 by linear regression of Langmuir model onto experimental data. The Pseudo-Second-Order model was fitted better onto kinetic data compared to the Pseudo-First-Order model. Improved porosity and mechanical elasticity yielding enhanced dye removal capacity make them highly potential alternative adsorbents compared to available alginate/montmorillonite materials for MB removal.

scholarly journals Sugarcane Bagasse as an Efficient Biosorbent for Methylene Blue Removal: Kinetics, Isotherms and Thermodynamics

2020 ◽  
Vol 17 (2) ◽  
pp. 526 ◽  
Author(s):  
Thaisa Caroline Andrade Siqueira ◽  
Isabella Zanette da Silva ◽  
Andressa Jenifer Rubio ◽  
Rosângela Bergamasco ◽  
Francielli Gasparotto ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Sugarcane Bagasse ◽  
Adsorption Isotherms ◽  
Low Cost ◽  
Cost Effective ◽  
Blue Dye ◽  
Maximum Adsorption Capacity ◽  
Effective Option ◽  
Pseudo Second Order ◽  
Isotherms And Thermodynamics

Adsorption in biomass has proven to be a cost-effective option for treatment of wastewater containing dyes and other pollutants, as it is a simple and low cost technique and does not require high initial investments. The present work aimed to study the adsorption of methylene blue dye (MB) using sugarcane bagasse (SCB). The biomass was characterized by scanning electron microscopy (SEM). Adsorption studies were conducted batchwise. Kinetics, adsorption isotherms, and thermodynamics were studied. The results showed that SCB presented a maximum adsorption capacity of 9.41 mg g−1 at 45 °C after 24 h of contact time. Adsorption kinetics data better fitted the pseudo-second order model, indicating a chemical process was involved. The Sips’s three-parameter isotherm model was better for adjusting the data obtained for the adsorption isotherms, indicating a heterogeneous adsorption process. The process showed to be endothermic, spontaneous, and feasible. Therefore, it was concluded that SCB presented as a potential biosorbent material for the treatment of MB-contaminated waters.

scholarly journals Adsorption of Hexavalent Chromium Using Banana Pseudostem Biochar and Its Mechanism

2018 ◽  
Vol 10 (11) ◽  
pp. 4250 ◽  
Author(s):  
Shuang Xu ◽  
Weiguang Yu ◽  
Sen Liu ◽  
Congying Xu ◽  
Jihui Li ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Pyrolysis Temperature ◽  
Low Cost ◽  
Surface Adsorption ◽  
Maximum Adsorption Capacity ◽  
X Ray ◽  
Adsorption Processes ◽  
Different Temperatures ◽  
Pseudo Second Order ◽  
Porosity Analysis

A low-cost biochar was prepared through slow pyrolysis of banana pseudostem biowaste at different temperatures, and characterized by surface area and porosity analysis, scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). It was shown that the biochar prepared at low pyrolysis temperature was rich in oxygen-containing groups on the surface. Adsorption experiments revealed that the biochar prepared at 300 °C (BB300) was the best adsorbent for Cr(VI) with 125.44 mg/g maximum adsorption capacity at pH 2 and 25 °C. All the adsorption processes were well described by pseudo-second-order and Langmuir models, indicating a monolayer chemiadsorption. Furthermore, it was demonstrated that adsorption of Cr(VI) was mainly attributed to reduction of Cr(VI) to Cr(III) followed by ion exchange and complexation with the biochar.

scholarly journals Syringa vulgaris leaves powder a novel low-cost adsorbent for methylene blue removal: isotherms, kinetics, thermodynamic and optimization by Taguchi method

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Giannin Mosoarca ◽  
Cosmin Vancea ◽  
Simona Popa ◽  
Marius Gheju ◽  
Sorina Boran
Keyword(s):  
Methylene Blue ◽  
Low Cost ◽  
Dye Adsorption ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Adsorbent Surface ◽  
Order Kinetic Model ◽  
Endothermic Process ◽  
Pseudo Second Order ◽  
Better Than

Abstract In this study, the potential of a new low-cost adsorbent, Syringa vulgaris leaves powder, for methylene blue adsorption from aqueous solution was investigated. The adsorbent surface was examined using SEM and FTIR techniques. The experiments were conducted, in batch system, to find out the effect of pH, contact time, adsorbent dose, initial dye concentration, temperature and ionic strength on dye adsorption. The process is best described by Langmuir isotherm and the pseudo second order kinetic model. Maximum adsorption capacity, 188.2 (mg g−1), is better than other similar adsorbent materials. Thermodynamic parameters revealed a spontaneous and endothermic process, suggesting a physisorption mechanism. A Taguchi orthogonal array (L27) experimental design was used to determine the optimum conditions for the removal of dye. Various desorbing agents were used to investigate the regeneration possibility of used adsorbent. Results suggest that the adsorbent material is very effective for removal of methylene blue from aqueous solutions.

Adsorption of the Blue Dye Reactive Remazol RN in Cellulosic Materials

2014 ◽  
Vol 775-776 ◽  
pp. 749-754
Author(s):  
Mirna Sales Loiola Rosa ◽  
Marcos Pereira Silva ◽  
Alan Icaro Morais ◽  
Maria Rita de Morais Chaves Santos ◽  
Edson Cavalcanti Silva Filho ◽  
...  
Keyword(s):  
Low Cost ◽  
Langmuir Model ◽  
Blue Dye ◽  
Maximum Adsorption Capacity ◽  
Order Model ◽  
Textile Waste ◽  
Pseudo Second Order ◽  
Filter Papers ◽  
Best Fit ◽  
The Ideal

The disposal of textile waste in water bodies is exacerbating environmental problems, which led scientists to seek natural materials to develop more sustainable ways. Searching for low cost materials was used to remove the dye in two cellulosic sources (filter papers of different brands). The papers were characterized by XRD which confirmed crystallographic profile similar to cellulose. With the aim of optimizing the best conditions, various tests were performed, where the ideal time was 180 minutes for the paper 1 and 240 minutes for the second paper, both by adjusting the pseudo second-order model. The other parameters studied was the pH, adsorbate-adsorbent systems which have maximum adsorption capacity of 2.76 mg / g at pH 2.02 and 2 mg / g at pH 11 for the paper 1 and 10.57 mg / g pH 4 and 2 mg / g at pH 11 for the paper 2. Both adsorbents had the best fit to the Langmuir model in pHs 2 and 11 at the temperature of 298 K.

scholarly journals Valorization of Agroindustrial Wastes as Biosorbent for the Removal of Textile Dyes from Aqueous Solutions

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Elsa Contreras ◽  
Luisa Sepúlveda ◽  
Carolyn Palma
Keyword(s):  
Low Cost ◽  
Orange Peel ◽  
Maximum Adsorption Capacity ◽  
Reactive Black 5 ◽  
Positive Effects ◽  
Spent Grains ◽  
Constant Rate ◽  
Pseudo Second Order ◽  
Equilibrium Concentrations ◽  
Agroindustrial Wastes

The goal is to determinate the technical feasibility of using agroindustrial wastes for adsorption of dyes. The pHpzcof Brewer’s spent grains and Orange peel is 5.3 and 3.5, respectively. The equilibrium isotherms of Basic Blue 41, Reactiive Black 5, and Acid Black 1 were carried out without pHs control which ranging between 4 and 5.5. The equilibrium concentrations for both adsorbents were fitted by the Freundlich and Langmuir models. The maximum adsorption capacity measured for Basic Blue 41, Reactive Black 5, and Acid Black 1 was 32.4, 22.3, and 19.8 mg g-1for Brewer’s spent grains; and 157, 62.6, and 45.5 for orange peel, respectively. The kinetic of process was fitted by the model of pseudo-second order. The constant rate for orange peel decreased to extend the initial concentration of dye increased, obtaining 4.08 * 10−3−0.6 * 10−3(Basic Blue 41), 2.98 * 10−3−0.36 * 10−3(Acid Black 1), and 3.40 * 10−3−0.46 * 10−3 g mg−1 min−1(Reactive Black 5). The best removal efficiency was obtained in orange peel with values started from 63% to 20%. Consequently, according the results obtained there are two positive effects, the reuse of agricultural wastes and its use as low-cost adsorbent of the dyes.

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