Elemental analysis of residual ash generated during plasma incineration of cellulosic, rubber and plastic waste

2021 ◽  
pp. 0734242X2110382
Author(s):  
Keyur C Pancholi ◽  
Param Jeet Singh ◽  
Kaustava Bhattacharyya ◽  
Mahesh Tiwari ◽  
Sanjay Kumar Sahu ◽  
...  
Keyword(s):  
Elemental Analysis ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Reduction Factor ◽  
Volume Reduction ◽  
Enrichment Ratio ◽  
Composition Analysis ◽  
Feed Composition ◽  
Cellulosic Waste ◽  
Residual Ash

Management of plastic, rubber and cellulosic waste from various industries is a challenging task. An engineering scale plasma pyrolysis based incinerator has been commissioned for incineration of combustible waste, including plastic, rubber and cellulose. Operational trials of wastes with simulated composition show a weight reduction factor of more than 18 and volume reduction factor of more than 30. The volume reduction factor is tenfold higher than the compaction process currently practised for rubber and plastic wastes. Representative residual ash samples derived from these runs are subjected to their elemental analysis using EDXRF technique and results are comparable with the published literature. Relative variation of individual elements is attributed to the type of waste and feed composition. Analysis is aided with the calculation of index of geoaccumulation, enrichment factor (EF), contamination factor (CF) and pollution load index (PLI). From this study, it is evident that S, Cr, Zn, As, Se, Hg and Pb are of concern for environment in residual ash from plasma incineration of combustible waste. The efficacy of the incineration process is evaluated; C, H and O reduction achieved is more than 98% and overall enrichment ratio (ER) for the inorganic elements is more than 4.5. This study highlights the importance of elemental composition for the performance analysis of the plasma based incineration as well as hazards evaluation of constituents in residual ash for its further management.

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals The content of copper and heavy metals in the multilayer soil mud from the Buchim lake under the Buchim mine's waste dump, Republic North Macedonia

Tehnika ◽  
2020 ◽  
Vol 75 (4) ◽  
pp. 297-304
Author(s):  
Todor Serafimovski ◽  
Goran Tasev ◽  
Trajce Stafilov
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Porphyry Copper ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Mining Areas ◽  
Target Value ◽  
Standard Values ◽  
Almost All

The intense mineral extraction in mining areas during the last several decades has produced a large amount of waste material and tailings, which release toxic elements to the environment. The aim of the study was to determine in two vertical profiles/sections (1 and 2) the heavy metal contents of samples derived from six samples, three from each section located in the porphyry copper mine Buchim area, Republic North Macedonia. The results have been compared to new Dutchlist (DL) and Kabata-Pendias (KP) standards and the following was concluded: As values ranged 14.985÷60.131 mg kg-1 with 4 samples above the target value of the DL (29 mg kg-1 As) and 6 above standard values given in KP value (5 mg kg-1 As), in that context Co values ranged 11 ÷57 mg kg-1 with 6 values above the target value of the DL (9 mg kg-1 Co) and 5 above standard values given in KP value (12 mg kg-1 Co), Cr with range 29.32÷75.76 mg kg-1 with 6 over KP value (10 mg kg-1 Cr) and none above the target value of the DL (100 mg kg-1 Cr), Cu with range 2694÷6749 mg kg-1 with 6 samples above the target value of the DL (36 mg kg-1 Cu) and 6 above standard values given in KP value (20 mg kg-1 Cu), Ni with range 59.57÷105.98 mg kg-1 with 6 samples above the target value of the DL (35 mg kg-1 Ni) and 6 above standard values given in KP value (20 mg kg-1 Ni), Pb with range 27.06 ÷96.08 mg kg-1 with 1 sample above the target value of the DL (85 mg kg-1Pb) and 6 above standard values given in KP value (25 mg kg-1Pb), Zn with range 147÷273 mg kg-1 with 6 over target value of the DL (140 mg kg-1 Zn) and 6 above standard KP value (64 mg kg-1 Zn), V with range 34.44÷92.57 mg kg-1 with 5 over target value of the DL (42 mg kg-1 V) and one above KP value (90 mg kg-1 V).In order to compare the level of contamination, the contamination factor (𝐶𝑓 𝑖 ), degree of contamination (Cd), and pollution load index (PLI) were computed. Serious numbers were found for Cu, as, Zn, Co and Ni, which exceeded standard values at almost all samples from both vertical sections. Compared from section 1 and section 2, pollution load index increased by 13.43%, which in almost all samples was classified as heavily polluted to extremely polluted. The fact that mining activities at the Buchim Mine last for almost 40 years, the presence of heavy metals in soils at a serious level is understandable. The high level of contamination is a result of heavy metal persistence and non-biodegradability.

scholarly journals Seasonal Variation of Metallic Contamination of Water and Sediments in Navigation Canal and Industrial Zone South Port Said, Egypt

2018 ◽  
pp. 1-12
Author(s):  
Nabil, A. E. Azzaz ◽  
Mokhtar, S. Beheary ◽  
Mohamed, N. Raslan ◽  
Hazem T. Abd El Hamid
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Winter Season ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Industrial Zone ◽  
Sediment Samples ◽  
Accumulation Index ◽  
Port Said ◽  
Mean Concentration

In the present study, water and sediment samples were collected from Navigation Canal and from Industrial Zone South Port Said to assess heavy metals contamination. It was shown that, the highest mean concentration of heavy metals in water samples was observed in summer, and the lowest mean was observed in winter. It has been made evident that the industrialization in Industrial Zone South Port Said was responsible for the present deteriorating conditions. However, it was shown that, the highest mean concentration of heavy metals in sediment samples was observed in winter, and the lowest mean was observed in summer. Pollution status was evaluated using some indices: geo-accumulation index (Igeo), contamination factor (CF), pollution load index (PLI) and ecological risk index (RI). Based on Igeo, all metal values were unpolluted. On the basis of the values of CF, sediments are high in winter and low in summer. Metals concentrations were in the following order: Ni > Fe > Mn > Pb > Cu > Zn > Co > Cd. According to CF classification, Ni contamination was considerable. RI of winter season can be classified as moderate pollution. No pollution was classified for PLI in all seasons. The decrease in PLI and RI values were indicated dilution and dispersion of metal content with increasing distance from source areas. It is suggested that PLI can give an indication about the trend spatially and temporarily. In addition, it also provides significant data and advice to the policy and decision makers on the contamination degree of the area.

scholarly journals Distribution of Heavy Metals in Surface Sediments of the Bay of Bengal Coast

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
M. Z. H. Khan ◽  
M. R. Hasan ◽  
M. Khan ◽  
S. Aktar ◽  
K. Fatema
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Gas Production ◽  
Production Plant ◽  
Marine Sediment Quality ◽  
Bay Of Bengal Coast ◽  
The Impact

The concentrations of major (Si, Al, Ca, Fe, and K) and minor (Cd, Mn, Ni, Pb, U, Zn, Co, Cr, As, Cu, Rb, Sr, and Zr,) elements in the surficial sediments were studied in an attempt to establish their concentration in the Bengal coast. It was revealed that the majority of the trace elements have been introduced into the Bengal marine from the riverine inflows that are also affected by the impact of industrial, ship breaking yard, gas production plant, and urban wastes. The concentration of heavy metals was measured using Atomic Absorption Spectroscopy and Energy Dispersive X-ray fluorescence instruments. The highest concentrations for several trace elements were thus recorded which generally decrease with distance from the coast. It was observed that the heavy metal concentrations in the sediments generally met the criteria of international marine sediment quality. However, both the contamination factor and pollution load index values suggested the elevation of some metals’ concentrations in the region. Constant monitoring of the Bengal coast water quality needs to be recorded with a view to minimizing the risk of health of the population and the detrimental impacts on the aquatic ecosystem.

Environmental Susceptibility: Soil Contamination of Heavy Metals in the Territory of E-Waste Recycling Area

2017 ◽  
Vol 3 (01) ◽  
pp. 25-31 ◽  
Author(s):  
Charu Gangwar ◽  
Aprajita Singh ◽  
Raina Pal ◽  
Atul Kumar ◽  
Saloni Sharma ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Negative Impact ◽  
Contamination Factor ◽  
Industrial Area ◽  
Waste Recycling ◽  
Pollution Load Index ◽  
Physiological Analysis

E-waste is a popular name given to those electronic products nearing the end of their useful life which has become a major source of heavy metal contamination in soil and hence, became the global concern. Various samples of soil were collected from different sites and were determined for heavy metal analysis by the ICP-AAS after the digestion process. The main source of contamination is illegal e-waste recycling activities such as burning of PCB's acid baths etc. Different soil indices like contamination factor, I-geo, pollution load index, were calculated to determine the quality of the soil. Results indicate that e-waste recycling and industrial area are strongly contaminated by the heavy metals. Physiological analysis of soil revealed that e-waste processing and industrial activities decrease the soil pH and organic matter while enhancing the electrical conductivity of soil. The exceedance of metal contamination imposed negative impact to the soil environment and human health.

scholarly journals Lead and Cadmium Levels in Residential Soils of Lagos and Ibadan, Nigeria

2017 ◽  
Vol 7 (13) ◽  
pp. 42-55 ◽  
Author(s):  
Adebola A. Adeyi ◽  
Babafemi A. Babalola
Keyword(s):  
Low Income ◽  
Residential Buildings ◽  
Control Sample ◽  
Contamination Factor ◽  
The United States ◽  
Pollution Load Index ◽  
Vulnerable Groups ◽  
Pollution Load ◽  
Residential Areas ◽  
Lead And Cadmium

Background. Lead and cadmium are components of paints sold in Nigeria. These heavy metals are associated with adverse neurological, cardiovascular and other human health effects. Objectives. This study assesses the levels of lead and cadmium in topsoil of residential areas in Lagos and Ibadan potentially resulting from painting of buildings. Methods. Samples were pre-treated prior to metal determination using atomic absorption spectrophotometry. Metal speciation was determined using modified Tessier sequential extraction. Soil characteristics were determined by standard methods. Soil contamination was assessed using contamination factor, geo-accumulation and pollution load indices. The United States Environmental Protection Agency integrated exposure uptake biokinetic (IEUBK) model was used to estimate and predict children's blood lead levels (BLL). Results. Lead and cadmium concentrations in residential areas in Lagos and Ibadan ranged from 1.56–419 mg/kg and not detected–2.8 mg/kg, respectively. Metal contamination factor and pollution load index were highest at the Lagos low income settlement. Results of IEUBK modelling showed that the Lagos low income settlement had the highest probability density for children between 1–7 years of age with an estimated BLL of >10 μg/dL. This population made up less than 0.01% of those within this age range. Conclusions. Lead and cadmium concentrations in soil around the residential buildings were higher than those in the control sample. Contamination factor and pollution load index showed significant contamination in average and low income settlements. These results suggested that there was accumulation of the metals in the soil, which can persist in the environment. This may pose serious health risks, especially to vulnerable groups such as children. Competing Interests. The authors declare no competing financial interests.

scholarly journals Applying Some Indices for Soil Pollution Assessment in Northern Industrial Area from Erbil Governorate

2021 ◽  
Vol 26 (4) ◽  
pp. 45-58
Author(s):  
Nashmeel Khudhur ◽  
Sidra Qubad Yassin ◽  
Ahmed Saman Hassan ◽  
Mortatha Nawzad Omar
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Surface Soil ◽  
Contamination Factor ◽  
Pollution Assessment ◽  
Industrial Area ◽  
Pollution Load Index ◽  
Growth Effect ◽  
Lepidium Sativum ◽  
Soil Site

Soil pollution by some heavy metals including: Cr, Mn, Fe, Ni, Cu, Zn, As, Mo, Cd and Pb from northern industrial area of Erbil City was assessed. The contamination indices including: geoaccumulation (Igeo), contamination factor (CF), enrichment factor (EF), degree of contamination (Cdeg), pollution load index (PLI) and element contamination index (ECI) were applied to assess soil pollution in Erbil North Industrial area at three sites (for both surface and sub-surface soils). Maximum Fe value 34243.6 ppm was recorded in sub-surface soil (site 2). Maximum values 265.4, 248.8, 98.23 and 397.45 ppm were recorded for Cr, Ni, Cu and Zn at sub-surface soil (site 3). Whereas, maximum values of 22.52, 5.36, 23.9, 6.12 and 65.67 ppm were recorded for As, Mo, Ag, Cd and Pb at surface soil (site 3). Results of analysed heavy metals for soil Cr, Mn, Fe, Ni, Cu, Zn, As, Mo, Ag, Cd and Pb have shown that the studied sites were severely contaminated with Cd, so the maximum detected Cd concentration was 6.12 ppm in surface soil (300 meters away from the industrial area). The soil pollution in the studied area was classified as moderate to strong surface and sub-surface soil contamination. Behavioral toxicity experiment showed slight growth effect on Lepidium sativum L.

scholarly journals Assessment of Anions and Heavy Metals in Sediments from River Sio, Busia County, Kenya

2019 ◽  
pp. 1-18
Author(s):  
K. O. Ondoo ◽  
J. K. Kiptoo ◽  
A. O. Onditi ◽  
S. M. Shivaji ◽  
J. K. Ogilo
Keyword(s):  
Heavy Metals ◽  
Surface Runoff ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Water Source ◽  
Pollution Load Index ◽  
Dry Season ◽  
Wet Season ◽  
Flame Atomic Absorption ◽  
Flame Atomic Absorption Spectrophotometer

Agricultural activities, discharge of raw sewage into farms and the rise in urbanization have greatly contributed to soil pollution. During the rainy season, surface runoff from farms find their way into water bodies and deposits these contaminants into Rivers and Lakes which poses a threat to both aquatic and terrestrial organisms that depend on that water source. The objective of this research was to determine the level of anions and heavy metals from sediments in River Sio, Busia County, Kenya. Five sediment samples were taken from five sampling points and the levels of anions and heavy metals in them determined. Anions were determined using Shimadzu 1800 UV/visible spectrophotometer while heavy metals were determined using Shimadzu 6200 flame atomic absorption spectrophotometer (AAS). Copper, lead and nickel were above the allowed WHO limits while cadmium was below detection limit. The levels of nitrates, phosphates and chlorides were higher during the wet season due to surface runoff that carried these nutrients from the farms and deposited them on the bottom of the River. The levels of heavy metals were high during the dry season due to evaporation of water from the River, leading to an increase in the analyte concentration during the dry season. High levels of copper and nickel in the sediments points to the use of herbicides and pesticides in farming and washing of vehicles and motorcycles on the banks of the River. According to Igeo nickel showed moderate pollution during the dry season. The contamination factor for lead was very high during the dry season, while pollution load index confirmed pollution due to anthropogenic activities in sampling sites 1 – 4 during the dry season and no pollution due to anthropogenic activities during the wet season.  The study recommends reduced use of inorganic fertilizers in order to save the River from the danger of eutrophication. Excessive use of agrochemicals such as herbicides and pesticides should be discouraged. In addition, pesticide leaching and the level of microbes in soil and sediments should be considered for further research

scholarly journals Evaluation of Some Trace Elements Pollution in Sediments of the Tigris River in Wasit Governorate, Iraq

2020 ◽  
Vol 17 (1) ◽  
pp. 0009 ◽  
Author(s):  
Issa Et al.
Keyword(s):  
Trace Elements ◽  
Metal Pollution ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Sediment Samples ◽  
Tigris River ◽  
Drainage Canals ◽  
Concentration Levels ◽  
Geo Accumulation

The main objectives of present study are to evaluate the trace elements pollution in the sediment of the Tigris River and drainage canals in Wasit Governorate, Iraq. Assessment of trace elements pollutants were conducted for 18 sediment samples collected in March 2017. Trace elements were analyzed in sediment Tigris River samples in Wasit Governorate. This metal pollution was evaluated using geo-accumulation (I-geo) index, Contamination Factor (CF) and Pollution Load Index (PLI). According to  these statistical indices, the sediments collected from Tigris River in the study area are highly polluted with Titanium (71.9 ppm), Nickel (226.6 ppm) Chromium (425.2 ppm), Cadmium (2ppm) and Molybdenum (15.8 ppm) while  the sediments  were moderately polluted with Cobalt (25.1 ppm), Strontium (839.3 ppm), Copper (56.2), Manganese (106.1ppm), Vanadium (135 ppm), Niobium (9.79 ppm). However, the sediments of the Tigris River is not polluted by Lead, Barium, Gallium, Rubidium and, Zinc.  Metals concentration levels in the sediments of the drainage canals that discharged into the Tigris River showed higher concentrations  than  the Tigris sediments in Ta, V, Ni, Cu, Ga, Br, Sr and Mo.

scholarly journals POLLUTION HAZARDS OF HEAVY METALS IN SEWAGE SLUDGE ASH FROM THE WASTEWATER TREATMENT PLANTS IN CAMBERENE, SENEGAL

2021 ◽  
Vol 9 (11) ◽  
pp. 946-953
Author(s):  
Mamoudou Sall ◽  
◽  
Prince Momar Gueye ◽  
Abdou Ciss Wade ◽  
Alassane Traore ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Fly Ash ◽  
Heavy Metal Contamination ◽  
Wastewater Treatment Plants ◽  
Bottom Ash ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Contamination Rate ◽  
Metal Contents ◽  
Sludge Ash

Solid wastes and their by-products are gaining interest worldwide given their high environmental impact. Fly ash and Bottom ash from Camberene sludge waste center (Senegal) were characterized to assess the heavy metal contamination (using XRF and the Toxicological Risk) that is very important in type 1 unlike in type 2. The Index of geo-accumulation (Igeo), the Pollution load index (PLI), the Enrichment factor (EF) and Contamination factor (CF) have been computed to evaluate the contamination rate. These show that the fly ash has aIgeo value of 3.57 for Pb and 3.04 for As which means they are very polluted. For Cu we have an Igeo value of 4.23 and for Zn it is 4.67 so these ashes are strongly to extremely polluted by Cu and Zn but unpolluted to moderately polluted by Cr. For the bottom ashes we have Igeo values of 3.03 for Cu and 3.02 for Zn, to say they are also strongly polluted. However, they are not polluted by Cr and are only moderately polluted by Pb and As results confirmed by the EF calculation. Fine and dirty ashes have significantly been enriched by the metal As with an EF of 13.71 while for Pb its EF is 19.10 for the fine ash. As for the bottom ash we have respectively 7.26 and 5.19 for the EF of As and Pb. From the values of PLI these ashes are very highly polluted. Their possible dangerousness depends essentially on their heavy metal contents (criterion H14 of Directive 91 / 689 / EEC). In this Directive the material is toxic if its content in heavy metal is higher to some thresholds (see Annex III, Table 6). Most of their heavy metal contents are below the threshold in Annex III, indicating their harmlessness. This analysis highlighted the principal characteristics to be taken into account before using the SSA properly.

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