scholarly journals Effect of boron oxide addition on fibre drawing, mechanical properties and dissolution behaviour of phosphate-based glass fibres with fixed 40, 45 and 50 mol% P2O5

2014 ◽  
Vol 29 (5) ◽  
pp. 639-653 ◽  
Author(s):  
Nusrat Sharmin ◽  
Andrew J Parsons ◽  
Chris D Rudd ◽  
Ifty Ahmed

Previous studies investigating manufacture of phosphate-based glass fibres from glasses fixed with P2O5 content less than 50 mol% showed that continuous manufacture without breakage was very difficult. In this study, nine phosphate-based glass formulations from the system P2O5-CaO-Na2O-MgO-B2O3 were prepared with P2O5 contents fixed at 40, 45 and 50 mol%, where Na2O was replaced by 5 and 10 mol% B2O3 and MgO and CaO were fixed to 24 and 16 mol%, respectively. The effect of B2O3 addition on the fibre drawing, fibre mechanical properties and dissolution behaviour was investigated. It was found that addition of 5 and 10 mol% B2O3 enabled successful drawing of continuous fibres from glasses with phosphate (P2O5) contents fixed at 40, 45 and 50 mol%. The mechanical properties of the fibres were found to significantly increase with increasing B2O3 content. The highest tensile strength (1200 ± 130 MPa) was recorded for 45P2O5-16CaO-5Na2O-24MgO-10B2O3 glass fibres. The fibres were annealed, and a comparison of the mechanical properties and mode of degradation of annealed and non-annealed fibres were investigated. A decrease in tensile strength and an increase in tensile modulus were observed for the annealed fibres. An assessment of the change in mechanical properties of both the annealed and non-annealed fibres was performed in phosphate-buffered saline (PBS) at 37℃ for 28 and 60 days, respectively. Initial loss of mechanical properties due to annealing was found to be recovered with degradation. The B2O3-containing glass fibres were found to degrade at a much slower rate as compared to the non-B2O3-containing fibres. Both annealed and non-annealed fibres exhibited a peeling effect of the fibre's outer layer during degradation.

2014 ◽  
Vol 1025-1026 ◽  
pp. 215-220 ◽  
Author(s):  
Sasirada Weerasunthorn ◽  
Pranut Potiyaraj

Fumed silica particles (SiO2) were directly added into poly (butylene succinate) (PBS) by melt mixing process. The effects of amount of fumed silica particles on mechanical properties of PBS/fumed silica composites, those are tensile strength, tensile modulus, impact strength as well as flexural strength, were investigated. It was found that the mechanical properties decreased with increasing fumed silica loading (0-3 wt%). In order to increase polymer-filler interaction, fumed silica was treated with 3-glycidyloxypropyl trimethoxysilane (GPMS), and its structure was analyzed by FT-IR spectrophotometry. The PBS/modified was found to possess better tensile strength, tensile modulus, impact strength and flexural strength that those of PBS/fumed silica composites.


2020 ◽  
Vol 35 (1) ◽  
pp. 61-70
Author(s):  
Na Young Park ◽  
Young Chan Ko ◽  
Lili Melani ◽  
Hyoung Jin Kim

AbstractFor the mechanical properties of paper, tensile testing has been widely used. Among the tensile properties, the tensile stiffness has been used to determine the softness of low-density paper. The lower tensile stiffness, the greater softness of paper. Because the elastic region may not be clearly defined in a load-elongation curve, it is suggested to use the tensile modulus which is defined as the slope between the two points in the curve. The two points which provide the best correlation with subjective softness evaluation should be selected. Low-density paper has a much lower tensile strength, but much larger elongation at the break. It undergoes a continuous structural change during mechanical testing. The degree of the structural change should depend on tensile conditions such as the sample size, the gauge length, and the rate of elongation. For low-density paper, the tensile modulus and the tensile strength should be independent of each other. The structure efficiency factor (SEF) is defined as a ratio of the tensile strength to the tensile modulus and it may be used a guideline in developing superior low-density paper products.


2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
J. Sahari ◽  
M. A. Maleque

The mechanical properties of oil palm shell (OPS) composites were investigated with different volume fraction of OPS such as 0%, 10%, 20%, and 30% using unsaturated polyester (UPE) as a matrix. The results presented that the tensile strength and tensile modulus of the UPE/OPS composites increased as the OPS loading increased. The highest tensile modulus of UPE/OPS was obtained at 30 vol% of OPS with the value of 8.50 GPa. The tensile strength of the composites was 1.15, 1.17, and 1.18 times higher than the pure UPE matrix for 10, 20, and 30 vol% of OPS, respectively. The FTIR spectra showed the change of functional group of composites with different volume fractions of OPS. SEM analysis shows the filler pull-out present in the composites which proved the poor filler-matrix interfacial bonding.


Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2650
Author(s):  
Jae-Won Choi ◽  
Woo-Youl Maeng ◽  
Young-Hag Koh ◽  
Hyun Lee ◽  
Hyoun-Ee Kim

This study demonstrates the utility of camphene as the pore-regulating agent for phase separation-based 3D plotting to produce hierarchical macro/micro-porous poly(ε-caprolactone) (PCL)–calcium phosphate (CaP) composite scaffolds, specifically featuring highly microporous surfaces. Unlike conventional particulate porogens, camphene is highly soluble in acetone, the solvent for PCL polymer, but insoluble in coagulation medium (water). In this study, this unique characteristic supported the creation of numerous micropores both within and at the surfaces of PCL and PCL–CaP composite filaments when using high camphene contents (40 and 50 wt%). In addition, the incorporation of the CaP particles into PCL solutions did not deteriorate the formation of microporous structures, and thus hierarchical macro/micro-porous PCL–CaP composite scaffolds could be successfully produced. As the CaP content increased, the in vitro biocompatibility, apatite-forming ability, and mechanical properties (tensile strength, tensile modulus, and compressive modulus) of the PCL–CaP composite scaffolds were substantially improved.


Holzforschung ◽  
2015 ◽  
Vol 69 (2) ◽  
pp. 215-221 ◽  
Author(s):  
Haitao Cheng ◽  
Jie Gao ◽  
Ge Wang ◽  
Sheldon Q. Shi ◽  
Shuangbao Zhang ◽  
...  

Abstract The work aimed at the improvement of the mechanical properties of bamboo fiber-polypropylene composites (BaFPPC) by treatment of the fibers with CaCO3 at various concentrations of the solution (0.05, 0.1, 0.2, and 0.3 mol l-1). CaCO3 particles were successfully deposited in situ to bamboo fibers by means of ionic reaction of Na2 CO3 and CaCl2 aqueous solution at various temperatures. Then BaFPPC were produced, and various tests on single fibers and the composites were performed. The compatibility between BaF and PP matrix was improved by the treatments. The crystallinity of inorganic materials was significantly affected by the reagent’s concentration. A 10.4% increase in tensile strength and a 16.7% increase in tensile modulus were observed after fiber treatment with CaCO3 at a concentration of 0.2 mol l-1.


2017 ◽  
Vol 756 ◽  
pp. 35-43
Author(s):  
Martin Bednarik ◽  
Adam Skrobak ◽  
Vaclav Janostik

This study deals with the effect of high doses of ionizing beta radiation (132, 165 and 198 kGy) on mechanical properties (tensile strength, tensile modulus and elongation) of low and high density polyethylene under thermal loading. The measurement results of this study indicate that with an increasing dose of radiation grows tensile strength and modulus of low and high density polyethylene. For all examined materials were also observed changes in elongation.


Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 18 ◽  
Author(s):  
Anna Kufel ◽  
Stanisław Kuciel

The aim of the research was to study the effects of adding natural fillers to a polypropylene (PP) matrix on mechanical and physical properties of hybrid composites. The 10%, 15%, and 20% by weight basalt fibers (BF) and ground hazelnut shells (HS) were added to the PP matrix. Composites were produced by making use of an injection molding method. Tensile strength, tensile modulus, strain at break, Charpy impact strength, and the coefficient of thermal expansion were determined. The influence of temperature, thermal aging, and water absorption on mechanical properties was also investigated. In addition, short-time creep tests were carried out. To characterize the morphology and the filler distribution within the matrix, a scanning electron microscope (SEM) was used. The results showed that the addition of the two types of filler enhanced mechanical properties. Furthermore, improvements in thermal stability were monitored. After water absorption, the changes in the tensile properties of the tested composites were moderate. However, thermal aging caused a decrease in tensile strength and tensile modulus.


2020 ◽  
Vol 12 (2) ◽  
pp. 244-248
Author(s):  
Yiwen Xu ◽  
Shengcai Qi ◽  
Yuanzhi Xu

The objective of this study is to enhance the thermal and mechanical properties of the photosensitive resin for RP (Rapid Prototyping) modifying with TiO2 nanoparticles NPs. The coupling agent KH570 was chosen for treating the surface of TiO2 NPs. The influence of the TiO2 content on the viscosity and the curing depth of photosensitive resin were analyzed in this study. We also tested the mechanical properties such as tensile modulus, tensile strength, hardness and flexural strength. Using differential scanning calorimetry, we tested the thermal stability of the modified photosensitive resin. Modified photosensitive resin's comprehensive performance was really good when the content of TiO2 was at 0.25%, the increase in tensile strength from 24.3 to 46.9 MPa was noticed to be 89%, the increase in tensile modulus from 1990 to 2251 MPa was noticed to be 18%, the increase in hardness and flexural strength was noticed to be 5 and 6%, respectively. Moreover, the heat stability and plasticity of the modified photosensitive resin are also enhanced. This paper gives a cost-efficient method of improving the functioning of photosensitive resin for RP.


2011 ◽  
Vol 393-395 ◽  
pp. 76-79 ◽  
Author(s):  
Hai Bing Huang ◽  
Hu Hu Du ◽  
Wei Hong Wang ◽  
Hai Gang Wang

In this article, wood-plastic composites(WPCs) were manufactured with wood flour(80~120mesh、40~80mesh、20~40mesh、10~20mesh) combing with high density polyethylene(HDPE). Effects of the size of wood flour on mechanical properies and density of composites were investigated. Results showed that particle size of wood flour had an important effect on properitiesof WPCs. Change of mesh number had a outstanding effect on flexural modulus, tensile modulus and impact strength, howere, little effect on flexural strength and tensile strength. When mesh number of wood flour changed from 80~120mesh to 10~20mesh,flexural modulus and tensile modulus were respectively enhanced by 42.4% and 28.4%, respectively, and impact strength was decreased by 35.5%.Size of wood flour basically had no effect on density of composite within 10~120mesh. The use of wood flour or fiber as fillers and reinforcements in thermoplastics has been gaining acceptance in commodity plastics applications in the past few years. WPCs are currently experiencing a dramatic increase in use. Most of them are used to produce window/door profiles,decking,railing,ang siding. Wood thermoplastic composites are manufactured by dispering wood fiber or wood flour(WF) into molten plastics to form composite materials by processing techniques such as extrusion,themoforming, and compression or injection molding[1]. WPCs have such advantages[2]:(1)With wood as filler can improve heat resistance and strength of plastic, and wood has a low cost, comparing with inorganic filler, wood has a low density. Wood as strengthen material has a great potential in improving tensile strength and flexural modulus[3];(2) For composite of same volume, composites with wood as filler have a little abrasion for equipment and can be regenerated;(3)They have a low water absorption and low hygroscopic property, They are not in need of protective waterproof paint, at the same time, composite can be dyed and painted for them own needs;(4)They are superior to wood in resistantnce to crack、leaf mold and termite aspects, composites are the same biodegradation as wood;(5)They can be processed or connected like wood;(6)They can be processed into a lots of complicated shape product by means of extrusion or molding and so on, meanwhile, they have high-efficiency raw material conversion and itself recycle utilization[4]. While there are many sucesses to report in WPCs, there are still some issues that need to be addressed before this technology will reach its full potential. This technology involves two different types of materials: one hygroscopic(biomass) and one hydrophobic(plastic), so there are issues of phase separation and compatibilization[5]. In this paper, Effects of the size of wood powder on mechanical properties of WPCs were studied.


Kevlar fibres are para aramid fibres rather than Meta-Aramid structure of Nomex. These fibres have high tensile strength, tensile modulus and heat resistance .Kevlar is about five times lighter than steel in terms of the same tensile strength. In fact, it is the strongest textile fibre available today. It is therefore used in Radial tyres, Conveyor belts, Aircraft parts and mainly used in Ballistics and Frictional products. The aim of this investigation is to increase the mechanical properties of composite material of Kevlar fibre. The Kevlar fibre is reinforced with the banana fibre,which is a Natural Fibre and Aluminium Mesh using Epoxy resin. The Mechanical Properties of Newly formed Composite material using Kevlar Fibre is improved and find its application in a higher position while comparing to the Kevlar Fibre


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