scholarly journals The Importance of Nutrients Concentration Monitoring In Coastal Area

2019 ◽  
Vol 24 (2) ◽  
pp. 69
Author(s):  
Wisnu Arya Gemilang ◽  
Ulung Jantama Wisha ◽  
Ruzana Dhiauddin

Land utilization changes of the natural resources conservation area of Pangandaran coastal area, that have been utilized as a marine tourism area, which affect many kinds of environmental degradation threats. Updating the condition of Pangandaran waters is essential due to its condition impacted by anthropogenic activities. Water condition monitoring was done by measuring nutrients as an indicator to assess the water fertility and pollution. Fourty five observation points were selected and divided into three locations, representing the condition of river, estuary/mangrove area, and open sea. Nutrients were analyzed by employing Standard Methods for The Examination of Water and Wastewater 22nd Edition 2012 (SMEWW). Currents and tides were measured for 15 days, used as the basis input of hydrodynamic model. The results showed that the highest of average value of nitrate was found in the estuary/mangrove forest which reached 0.998 mg.L-1. While, the highest phosphate content was observed in the river which reached 0.928 mg.L-1. The highest ammonia concentration was observed in the sea which reached 0.027 mg.L-1. N:P ratios in the study area are categorized <16, which showed that Pangandaran waters are in the condition of N-limitation. These conditions trigger blooming of phytoplankton due to the high concentration of nitrate. The higher nutrient concentration indicates that anthropogenic activities take place. Tidal current has an important role transporting nutrient in the estuary, triggering nutrient deposition and blooming tendency. Restrictions on residential areas and the utilization of coastal areas are an appropriate step to reduce the pollution level in Pangandaran waters.

2019 ◽  
Vol 6 (2) ◽  
pp. 207
Author(s):  
Baskara Adam Saleh, Boedi Setya Rahardja, Muhammad Arief

Abstract Oil drilling and industrial effluent that wasted through the Bengawan Solo River estuary is a source of environmental pollution in the Sidayu and Banyu Urip district, Gresik as one that produces the blood shellfish (Anadara granosa). One of the most dangerous contaminants of heavy metals is mercury. However shellfish can accumulate more heavy metals than other aquatic animals because it settle and filter their food (filter feeder) and slow to be able to avoid the effects of pollution The Aim of this study are to determine the levels of mercury and methyl mercury predictions on blood shellfish (Anadara granosa). The process of sampling was done at coastal area of Sidayu and Banyu Urip district, Gresik then performed using Atomic Absorbance readings Spectrophotometric (AAS). This is a descriptive study and the data obtained, and then continued with stoichiometric calculations to predict the content of methyl mercury. Based on the analysis of mercury and prediction of methyl mercury in the blood shellfish (Anadara granosa) organs in coastal area of Sidayu and Banyu Urip district, Gresik, has not exceeded the threshold of SNI, the value is 0.5 ppm. Mercury contamination was high in blood clam shell with the average value of 0.273 ppm and 0.293 ppm, followed by the stomach and intestines shell with an average value of 0.226 ppm and 0.281 ppm. Lowest contamination is on the organ gill, liver, and kidneys with the average value of 0.150 ppm and 0.133 ppm.


2020 ◽  
Vol 4 (1) ◽  
pp. 14-28
Author(s):  
S. K. Gaikwad ◽  
N. D. Pathan ◽  
N. S. Bansode ◽  
S. P. Gaikwad ◽  
Y. P. Badhe ◽  
...  

To study the chemistry of major ion in groundwater from Vel (Velu) River basin, sixty (60) samples of dug wells and bore wells were collected and analyzed using standard techniques given by APHA. It shows order of dominance for cations, Na+ > Ca2+ > Mg2+ > K+ and in anionic concentration as HCO3- > Cl- > SO42- in groundwater. The pH of groundwater is slightly alkaline (range: pH 7.0 - 8.1), while average values of Electrical Conductivity (EC) is about 2641 µS/cm indicating high mineralization of groundwater. In general, the cationic concentration (Na+, K+, Ca2+ and Mg2+) of the groundwater increase in the downstream side (from Northwest to South east), suggesting geological control on the composition of groundwater while highest concentration is in lower part of the basin are generally associated with the high salinity. In the major anions, bicarbonate (HCO3-) is higher due to rock-water interaction. Average value of chloride is about of 235 mg/L due to discharge zones along with anthropogenic activities. The geochemical data plotted on Piper Trilinear Diagram is showing dominant hydro-chemical facies: Ca2++Mg2+, Na++ K+, Cl-+ SO42- -HCO3- found in 83.3 % samples indicating the alkaline earth exceeding the alkalis and the strong acids exceeds the weak acids. The pH, Total Hardness (TH) and Magnesium (Mg2+) of the samples show more proportion of samples falling above desirable limit. Otherwise the quality of groundwater is good for drinking. The irrigation indices like SAR, KR and SSP were considered to evaluate groundwater suitability for irrigation. Comparing with SAR parameter all samples are excellent to good for irrigation. In SSP, 33.3 % samples are within permissible, while 66.6% samples are doubtful for irrigation purpose. In KR almost all samples (excluding 04 samples in lower side of basin) are suitable for irrigation. So, variations in climate, geology with anthropogenic activities are modifying the groundwater geochemistry of Vel River Basin.


1993 ◽  
Vol 28 (1) ◽  
pp. 83-110 ◽  
Author(s):  
Richard E. Farrell ◽  
Jae E. Yang ◽  
P. Ming Huang ◽  
Wen K. Liaw

Abstract Porewater samples from the upper Qu’Appelle River basin in Saskatchewan, Canada, were analyzed to obtain metal, inorganic ligand and amino add profiles. These data were used to compute the aqueous speciation of the metals in each porewater using the computer program GEOCHEM-PC. The porewaters were classified as slightly to moderately saline. Metal concentrations reflected both the geology of the drainage basin and the impact of anthropogenic activities. Whereas K and Na were present almost entirely as the free aquo ions, carbonate equilibria dominated the speciation of Ca. Mg and Mn (the predominant metal ligand species were of the type MCO3 (s). MCO30. and MHCO3+). Trace metal concentrations were generally within the ranges reported for non-polluted freshwater systems. Whereas the speciation of the trace metals Cr(III) and Co(II) was dominated by carbonate equilibria, Hg(II)-, Zn(II)- and Fe(II)-speciation was dominated by hydroxy-metal complexes of the type M(OH)+ and M(OH)2°. The speciation of Fe(III) was dominated by Fe(OH)3 (s). In porewaters with high chloride concentrations (&gt; 2 mM), however, significant amounts of Hg(II) were bound as HgCl20 and HgClOH0. The aqueous speciation of Al was dominated by Al(OH)4− and Al2Si2O4(OH)6 (s). Total concentrations of dissolved free amino acids varied from 15.21 to 25.17 umole L−1. The most important metal scavenging amino acids were histidine (due to high stability constants for the metal-histidine complexes) and tryptophan (due to its relatively high concentration in the porewaters. i.e., 5.96 to 7.73 umole L−1). Secondary concentrations of various trace metal-amino add complexes were computed for all the porewaters, but metal-amino acid complexes dominated the speciation of Cu(II) in all the porewaters and Ni(II) in two of the porewaters.


Antioxidants ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 13
Author(s):  
Elena Forte ◽  
Sergey A. Siletsky ◽  
Vitaliy B. Borisov

Interaction of two redox enzymes of Escherichia coli, cytochrome bo3 and cytochrome bd-I, with ammonium sulfate/ammonia at pH 7.0 and 8.3 was studied using high-resolution respirometry and absorption spectroscopy. At pH 7.0, the oxygen reductase activity of none of the enzymes is affected by the ligand. At pH 8.3, cytochrome bo3 is inhibited by the ligand, with 40% maximum inhibition at 100 mM (NH4)2SO4. In contrast, the activity of cytochrome bd-I at pH 8.3 increases with increasing the ligand concentration, the largest increase (140%) is observed at 100 mM (NH4)2SO4. In both cases, the effector molecule is apparently not NH4+ but NH3. The ligand induces changes in absorption spectra of both oxidized cytochromes at pH 8.3. The magnitude of these changes increases as ammonia concentration is increased, yielding apparent dissociation constants Kdapp of 24.3 ± 2.7 mM (NH4)2SO4 (4.9 ± 0.5 mM NH3) for the Soret region in cytochrome bo3, and 35.9 ± 7.1 and 24.6 ± 12.4 mM (NH4)2SO4 (7.2 ± 1.4 and 4.9 ± 2.5 mM NH3) for the Soret and visible regions, respectively, in cytochrome bd-I. Consistently, addition of (NH4)2SO4 to cells of the E. coli mutant containing cytochrome bd-I as the only terminal oxidase at pH 8.3 accelerates the O2 consumption rate, the highest one (140%) being at 27 mM (NH4)2SO4. We discuss possible molecular mechanisms and physiological significance of modulation of the enzymatic activities by ammonia present at high concentration in the intestines, a niche occupied by E. coli.


2020 ◽  
Vol 12 (1) ◽  
pp. 203-219
Author(s):  
Wei Li ◽  
Xiaohong Chen ◽  
Linshen Xie ◽  
Gong Cheng ◽  
Zhao Liu ◽  
...  

AbstractGroundwater chemical evolution is the key to ensuring the sustainability of local society and economy development. In this study, four river sections and 59 groundwater wells are investigated in the Longgang River (L.R.) basin in South China. Comprehensive hydrochemical analysis methods are adopted to determine the dominant factors controlling the chemical evolution of the local phreatic groundwater and the potential impact of human activities on groundwater quality. The results indicate that the ionic composition of the local phreatic groundwater is dominated by Ca2+ (0.9–144.0 mg/L), HCO3− (4.4–280.0 mg/L), and SO42− (1.0–199.0 mg/L). Ca–Mg–HCO3, Ca–Na–HCO3, and Na–Ca–HCO3 are the major groundwater hydrochemical facies. Water–rock interactions, such as the dissolution of calcite and dolomite, are the primary source of the major ions in the local groundwater. Cation-exchange reaction has its effects on the contents of Ca2+, Mg2+, and Na+. Ammonia concentration of the sampling sections in the L.R. increases from 0.03 to 2.01 mg/L along the flow direction. Groundwater nitrate in the regions of the farmland is attributed to the lowest level of the groundwater quality standards of China, while the same test results are obtained for heavy metals in the industrial park and landfill, suggesting a negative impact of the anthropogenic activities on the local phreatic groundwater quality.


Water ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1321 ◽  
Author(s):  
Muhammad Aleem ◽  
Cao Shun ◽  
Chao Li ◽  
Arslan Aslam ◽  
Wu Yang ◽  
...  

The industrial augmentation and unguided anthropogenic activities contaminate water sources in most parts of the world especially in developing countries like Pakistan. High concentration of pollutants in groundwater affects human, soil, and crop health badly. The present study was conducted to investigate groundwater quality for drinking and irrigation purposes in an industrial zone of Pakistan. A GIS tool was used to investigate the spatial distribution of different physico-chemical parameters. In this study, the average results exceeding World Health Organization (WHO) and National Environmental Quality Standards (NEQS) were found for pH 7.84, total dissolved solids (TDS) 1492 mg/L, phosphate 0.51 mg/L, dissolved oxygen (DO) 9.92% saturation, F-coli 6.48 colonies/100 mL, Na+ 366 mg/L, HCO3− 771 mg/L, sulfate 251 mg/L, chlorides 427 mg/L, total hardness (as CaCO3) 292 mg/L, electrical conductivity (EC) 2408 μS/cm, iron (Fe) 0.48 mg/L, chrome (Cr) 0.50 mg/L, arsenic (As) 0.04 mg/L, total phosphorus (TP) 0.17 mg/L, sodium adsorption ratio (SAR) 9.76 (in meq/L), residual sodium carbonate (RSC) 9.28 meq/L, % ion balance 14.4 (in meq/L), percentage sodium ion (% Na+) concentration 58.9 meq/L, and water quality index (WQI) 69.0. The trend of cations and anions were (in meq/L) Na > Mg > Ca > K and HCO3 > Cl > CO3 > SO4 respectively. Although the results of the present study showed poor conditions of the groundwater for drinking as WQI but and irrigation purposes as SAR, it needs to improve some more conditions for the provision of safe drinking water and irrigation water quality.


Author(s):  
Mazlin Mokhtar ◽  
Minhaz Farid Ahmed ◽  
Khai Ern Lee ◽  
Lubna Alam ◽  
Choo Ta Goh ◽  
...  

Despite many good policies and institutions, the coastal environment of Langkawi continues to deteriorate. This could be due to lack of effective governance as well as unregulated waste discharge. Evidences collected from the literature during 1996 to 2013 also revealed a significant increase in the concentrations of Zn (R2 = 0.78) and Pb (R2 = 0.12) in the sediment. This appears to be the result of large volume of terrestrial runoff that brings these metals originating from extensive anthropogenic activities. It is a vital indicator of coastal pollution. It is a matter of concern that in many cases Pb concentration in the sediment exceeded the world average value 20 μg/g as well as Canadian Interim Sediment Quality Standard of 35 μg/g for the coastal areas. Similarly, the metal pollution index (MPI) measured over a period of 2007 to 2009 in fish also indicated an increasing trend of pollution in Langkawi. The maximum MPI value (4.87) was recorded in Spanish mackerel. Since pollution of coastal environment has serious implications for marine biodiversity and health of seafood consumers, measures are required to address this problem. Use of constructed wetland might be effective in reducing the coastal pollution as this will filter the effluent and waste before their mixing with the coastal water. Furthermore, enabling the stakeholders to play the environmental stewardship role will ensure better governance of coastal ecosystem and effective implementation of policies, envisaging an improved monitoring of waste/effluent discharge into the coastal marine environment. These measures are among the actions necessary for achieving a sustainable coastal environment of Langkawi.


Author(s):  
Durdana Rais Hashmi ◽  
Akhtar Shareef ◽  
Talha Rehan Qadri ◽  
Muhammad Azam

Present study was carried out to analyze the concentration of the pollutants due to air born particulate matter (PM10) and infectious trace gases and their effects on human health at ten different locations along busy intersections in the commercial, residential and industrial areas of Karachi city. At each selected location, the study was carried out to determine the level of particulate matter and trace gases for a period of 8 h twice in a month during the year 2015. Samples were collected at ten selected locations i.e. Karimabad(C-1), Tibet Centre(C-2), and Liaquatabad(C-3) in commercial areas; PIB Colony(R-1), Nazimabad(R-2) and Gulshan-e-Iqbal(R-3) in residential areas; Siemens G. Belt(I-E1), Naurus G Belt (I-E2), Singer Chowrangi(I-W3) and Chamra Chowrangi(I-W4) in industrial areas of the city. Resultsreceived from different air quality categories were calculated according to National Environmental Quality Standard (NEQS) at selected locations, as in commercial areas showing poor pollution level for trace gases and PM10 due to high traffic density. In Residential areas PIB Colony (R-1) and Gulshan-e-Iqbal (R-3), found under good category with respect to the trace gases and moderate pollution level for the PM10 pollution, having low traffic density whereas Nazimabad(R-2) presents moderate category for trace gases and unhealthy category for PM10 pollution with high traffic density. In industrial areas Singer Chowrangi (I-W3) and Chamra Chowrangi(I-W4) found under moderate pollution level with moderate traffic density, whereas, Siemens G. Belt(I-E1) and Naurus G. Belt(I-E2) locations are represented by moderate pollution values for trace gases and found under poor pollution level for PM10 pollution, may be due to industrial emissions and heavy vehicular emission. Level of PM10 and trace gases at all the selected sites excluding residential areas, exceeds the permissible limits as specified by NEQS.


2021 ◽  
Vol 325 ◽  
pp. 01023
Author(s):  
Rizki Adriadi Ghiffari ◽  
Haryo Dwito Armono

Coastal erosion is the process of land erosion in coastal areas due to waves and ocean currents which reduce land and can adversely affect socio-economic activities in coastal areas. Coastal erosion risk assessment in the estuary is a development of previous research, because the erosion and accretion processes do not only occur along the shoreline, but also on the side facing river water bodies, due to the confluence of fluvial and marine processes. The landward shift of the shoreline in the Muara Asam Asam coastal area has reached 90 meters in the last 28 years, and has been detrimental because the area is a densely populated area with major economic activities in the fisheries and agriculture sectors. This study aims to determine the coastal erosion risk level zones based on the relationship among vulnerability and consequence parameters, through distance decay weighted based method. The results indicate that Muara Asam Asam has high risk zones of coastal erosion, especially in densely populated residential areas and dry land agriculture on the west side of the estuary, due to the lack of implementation of preventive measures through hard coastal structure and coastal zoning policy to protect socio-economic activities and coastal ecological environments.


2021 ◽  
Vol 46 (2) ◽  
Author(s):  
O.A. Oguntade ◽  
V.I. I Fesiokwu ◽  
O. S. Sule

High concentration of contaminants in drinking water can affect human health. This study assessed quality of groundwater at industrial and residential areas of Sango Ota, Ogun State. Water samples were collected in triplicates from 8 wells at industrial and residential areas and analyzed for its physicochemical properties. The pH, electrical conductivity, total dissolved solid (TDS), nitrate, sulphate, total suspended solid (TSS), total hardness (TH), iron, zinc, copper, lead, nickel, chromium and cadmium concentrations in the water samples were determined following American Public Health Association (APHA) procedure. Results showed that pH of 50 % of the wells were lower than minimum limit of 6.5 recommended by WHO. Sulphate, TH and iron in the water were significantly (p < 0.05) higher at residential area than industrial area. Electrical conductivity exhibited significant (p < 0.01) correlation with TDS (r = 0.701**) and NO32- (r = 0.922**) at residential area. At the industrial area however, concentration of salts in water samples was highly associated with SO42- (r = 0.864**) and Cd (r = 0.587**). Across locations of groundwater, iron and lead were above allowable WHO limits in drinking water. Cadmium was also above drinking limit at location T4 of the residential area. Consumers of groundwater in the study area are prone to health related challenges of heavy metal toxicity.


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