scholarly journals Hybrid green organic/inorganic filler polypropylene composites: Morphological study and mechanical performance investigations

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 710-721
Author(s):  
Mohammed T. Hayajneh ◽  
Faris M. AL-Oqla ◽  
Mu’ayyad M. Al-Shrida
Keyword(s):  
Mechanical Performance ◽  
Hybrid Composites ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Inorganic Filler ◽  
Hybrid Filler ◽  
Polypropylene Composites ◽  
Polypropylene Matrix ◽  
Mechanical Performances ◽  
Flexural Tests

Abstract In this study, the morphological and mechanical performances of hybrid green organic and inorganic filler composites were investigated. Various hybrid reinforcements using natural waste fillers including lemon leaves and eggshells were utilized for the study. The tensile strength, tensile modulus, elongation to break, flexural strength, and flexural modulus were investigated for the composites with polypropylene matrix. The results revealed that eggshells composites had the best values for both tensile and flexural tests while lemon leaves composites had the lowest values. However, the hybrid filler (lemon leaves-eggshells) had intermediate values. The poor properties of lemon leaves were attributed to the agglomeration and weak bonding presented by the morphological analysis of the hybrid composites.

scholarly journals Effect of Stacking Sequences on Mechanical Properties of Kenaf Hybrid Composites

2020 ◽  
Vol 1010 ◽  
pp. 459-464
Author(s):  
Ikhwan Yusuff ◽  
Norshahida Sariffudin ◽  
Afifah Mohd Ali ◽  
Hanafi Ismail ◽  
S. Norbahiyah
Keyword(s):  
Volume Fraction ◽  
Hybrid Composites ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Optical Microscope ◽  
Kenaf Fiber ◽  
Hybrid Sample ◽  
Flexural Tests ◽  
Infusion Technique ◽  
Scanning Electron

In the current project, Kenaf fiber (K) and carbon fiber (C) with epoxy resin were utilized to form carbon-kenaf hybrid composites using a vacuum infusion technique. The volume fraction of fiber and thickness of a hybrid composite was fixed at 40 vol.% and 3mm, respectively. Four different sequences were introduced in the current project including CCCCC, KKKKK, KCKCK, and CKCKC. Mechanical testing such as tensile and flexural tests were performed according to ASTM D3039 and ASTM D790, respectively. Scanning Electron Microscope (SEM) and Optical Microscope (OM) were used to identify modes of failures in both tensile and flexural tests of carbon/kenaf hybrid composites. The hybrid CKCKC sample displayed a higher value in tensile strength (264.23 MPa), tensile modulus (11.06 GPa), flexural strength (438.51 MPa) and flexural modulus (25.13 GPa) as compared than KCKCK hybrid sample.

Polypropylene composites reinforced with hybrid inorganic fillers: Morphological, mechanical, and rheological properties

2018 ◽  
Vol 32 (6) ◽  
pp. 848-864 ◽  
Author(s):  
Prakhar Mittal ◽  
Shiva Naresh ◽  
Priyanka Luthra ◽  
Amardeep Singh ◽  
Jatinder Singh Dhaliwal ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Hybrid Composites ◽  
Flexural Modulus ◽  
Filler Particle ◽  
Tensile Modulus ◽  
Filler Loading ◽  
Polypropylene Composites ◽  
Filler Particle Size ◽  
Size Type ◽  
Mineral Fillers

Mineral fillers like talc and mica are commonly used in the plastic industry because of their tendency to alter the properties of thermoplastic materials. Polypropylene (PP)-talc (PTC), PP-mica (PMC), and PP-talc/mica hybrid composites (PHC) were prepared. Results indicated that filler particle size, type, and content greatly influence the mechanical and rheological properties of the composites. Shear viscosity decreased with the increase in shear rate. At 40°C, an increase of approximately 120% in storage modulus ( E′) was observed in PMC composites. C parameter increased, whereas reinforcing efficiency ( r) decreased with the increase in filler loading. Percent elongation of each type of composites decreased with the increase in filler loading. Tensile modulus of PTC composite increased significantly by 103% (571 MPa) at 20% loading of talc, whereas for PHC and PMC composites, increase of 93% (543 MPa) and 81% (511 MPa) was observed. Flexural modulus also increased considerably by 88% (2413 MPa), 80% (2313 MPa), and 62% (2084 MPa) of PTC, PHC, and PMC composites at 20% filler loading.

scholarly journals Improving the mechanical properties of polypropylene composites with coconut shell particles

2021 ◽  
Vol 30 ◽  
pp. 263498332110074
Author(s):  
Henry C Obasi ◽  
Uchechi C Mark ◽  
Udochukwu Mark
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Flexural Modulus ◽  
Filler Particle ◽  
Tensile Modulus ◽  
Coconut Shell ◽  
Polypropylene Composites ◽  
Increase With Increase ◽  
Pp Composites ◽  
Shell Particles

Conventional inorganic fillers are widely used as fillers for polymer-based composites. Though, their processing difficulties and cost have demanded the quest for credible alternatives of organic origin like coconut shell fillers. Dried shells of coconut were burnt, ground, and sifted to sizes of 63, 150, 300, and 425 µm. The ground coconut shell particles (CSP) were used as a filler to prepare polypropylene (PP) composites at filler contents of 0% to 40% via injection melt blending process to produce PP composite sheets. The effect of the filler particle size on the mechanical properties was investigated. The decrease in the size of filler (CSP) was found to improve the yield strength, tensile strength, tensile modulus, flexural strength, flexural modulus, and hardness of PP by 8.5 MPa, 15.75 MPa, 1.72 GPa, 7.5 MPa, 100 MPa, and 10.5 HR for 63 µm at 40%, respectively. However, the elongation at break and modulus of resilience of the PP composites were seen to increase with increase in the filler size. Scanning electron microscope analysis showed that fillers with 63 µm particle size had the best distribution and interaction with the PP matrix resulting in enhanced properties.

EFFECT OF CELLULOSE FIBER SURFACE TREATMENT TO REPLACE CARBON BLACK IN NATURAL RUBBER HYBRID COMPOSITES

2021 ◽  
Author(s):  
Hossein Kazemi ◽  
Frej Mighri ◽  
Keun Wan Park ◽  
Slim Frikha ◽  
Denis Rodrigue
Keyword(s):  
Carbon Black ◽  
Natural Rubber ◽  
Surface Treatment ◽  
Hybrid Composites ◽  
Tensile Modulus ◽  
Fiber Surface ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Infrared Spectrometry ◽  
Hybrid Filler

ABSTRACT In recent years, cellulose fibers have attracted considerable attention as biofillers for natural rubber (NR) composites. However, neat cellulose cannot be used as a substitute for conventional fillers due to its poor compatibility with NR. Therefore, a new surface treatment via maleic anhydride grafted to polyisoprene (MAPI) in solution was developed to improve the filler–matrix interaction. Different contents of carbon black (CB) and cellulose fibers (before and after modification) were used as a hybrid filler system to investigate the possibility of CB substitution in NR composites. First, contact angle, Fourier transformed infrared spectrometry (FTIR), and scanning electron microscopy (SEM) techniques were used to confirm the successful cellulose surface treatment. Second, morphological analysis, Payne effect, and swelling behavior of the rubber compounds in toluene confirmed the effect of cellulose treatment on improving the interfacial filler–matrix adhesion. Finally, the results showed that the composite filled with 20 phr modified cellulose and 20 phr CB (50% replacement of CB) exhibited even better results than the composite filled with 40 phr of CB, since the tensile strength was only 7% lower, but the elongation at break, tensile modulus at 100%, and storage modulus at 25 °C were respectively 35%, 24%, and 22% higher.

A CASE STUDY OF BIOCOMPOSITE MATERIAL USE IN AUTOMOTIVE APPLICATIONS

2021 ◽  
Author(s):  
DANIEL WALCZYK ◽  
RONALD BUCINELL ◽  
STEVEN FLEISHMAN ◽  
SHARMAD JOSHI
Keyword(s):  
High Performance ◽  
Mechanical Performance ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Maximum Tensile Stress ◽  
High Viscosity ◽  
Flexural Stress ◽  
Fiber Volume ◽  
Low Viscosity ◽  
Biocomposite Material

Interest in biocomposites is growing worldwide as companies that manufacture high-performance products seek out more sustainable material options. Although there is significant research on biocomposite material options and processing found in the literature from at least the last two decades, there are few experimentally based case studies published to help guide product designers and engineers when considering these materials. This paper discusses the use of biocomposites in the seat of an electric bus. Although it is clear that biocomposite material options are quite limited, the authors eventually settled on three natural reinforcements (cellulose, hemp, flax), two epoxies (one low and the other high viscosity) with high biobased carbon content, and one flax precoated with bioepoxy for consideration. Laminate plates with a 4mm nominal thickness are manufactured using VARTM (low viscosity epoxy only), hand layup as a surrogate for prepregging (high viscosity epoxy only), compression molding, and an out-of-autoclave process called the Pressure Focusing Layer (PFL) method. Permeability of the three reinforcements infused with the high viscosity epoxy and fiber volume fractions are determined experimentally to provide insight into VARTM processing and mechanical performance. The tensile modulus, maximum tensile stress, flexural modulus, and maximum flexural stress are measured for all combinations of reinforcement, resin, and processing using tension testing and three-point bending based on ASTM standards. Basic conclusions are drawn about the specific application and more generally about the process of using biocomposites in commercial products.

The Effects of Oil Palm Fruit Bunch (OPFB) Fiber and Coupling Agent Loadings on the Performance of Hybrid Composites

2012 ◽  
Vol 535-537 ◽  
pp. 154-160 ◽  
Author(s):  
Anizah Kalam ◽  
M.N. Berhan ◽  
Hanafi Ismail
Keyword(s):  
Thermal Stability ◽  
Tensile Strength ◽  
Oil Palm ◽  
Hybrid Composites ◽  
Tensile Modulus ◽  
Palm Fruit ◽  
Degradation Tests ◽  
Mechanical Performances ◽  
The Impact ◽  
Thermal Stability Of

Hybrid composites were prepared by incorporating oil palm fruit bunch (OPFB) fibre in the mixture of clay and polypropylene as secondary filler. OPFB and MAPP loadings were varied to investigate it effects on the performance. Tensile and impact tests were performed on the hybrid composites to evaluate their mechanical performances. Water absorption and thermal degradation tests were also conducted on the hybrid composites. Results indicated that the incorporation of OPFB in PP/PPnanoclay has decreased the thermal stability of hybrid composites. Tensile modulus of hybrid composites increased as the OPFB loading increases and further increased with the increasing of MAPP loading. Generally the tensile strength has decreased with the addition of OPFB, however slight increased was observed when the MAPP loading was increased. The impact strength has also increased with the increasing of OPFB for higher MAPP loading.

Experimental study on the effect of stitch arrangement on mechanical performance of GFRP laminates manufactured on a basis of stitched preforms

2011 ◽  
Vol 46 (9) ◽  
pp. 1067-1078 ◽  
Author(s):  
Mateusz Koziol
Keyword(s):  
Shear Strength ◽  
Composite Laminates ◽  
Mechanical Performance ◽  
Flexural Modulus ◽  
Interlaminar Shear Strength ◽  
Direction Parallel ◽  
Stitch Density ◽  
Stitch Length ◽  
Interlaminar Shear ◽  
Flexural Tests

This article presents the results of interlaminar shear and flexural tests of stitched polyester glass fiber laminates in dependence on stitch density and main geometric stitching parameters: stitch length and stitch spacing. Purpose of the study is to work out guidelines and indications for manufacturers of composite laminates who use or who plan to use stitching technique. It was found that stitching significantly improves interlaminar shear strength which increases with stitch density. However, stitching causes deterioration of in-plane flexural properties – the deterioration progresses when stitch density increases. Obtained results indicate that it is better to achieve increase in stitch density (resulting in improvement of interlaminar shear strength) by reduction of stitch length than by reduction of stitch spacing. Stitched laminate shows higher flexural strength and flexural modulus when bent into direction parallel to the stitch lines than when bent into the transverse direction. The results obtained within the study and their approximation constants may be a base for a new theoretical model simulating behavior of stitched laminate during static bending and enabling prediction of its mechanical performance.

scholarly journals Hybrid Composites from Wheat Straw, Inorganic Filler, and Recycled Polypropylene: Morphology and Mechanical and Thermal Expansion Performance

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Min Yu ◽  
Runzhou Huang ◽  
Chunxia He ◽  
Qinglin Wu ◽  
Xueni Zhao
Keyword(s):  
Thermal Expansion ◽  
Fly Ash ◽  
Calcium Carbonate ◽  
Water Absorption ◽  
Wheat Straw ◽  
Hybrid Composites ◽  
Flexural Modulus ◽  
Inorganic Filler ◽  
Recycled Polypropylene ◽  
Inorganic Fillers

Reinforcing effect of hybrid filler including wheat straw (WS) and inorganic filler (heavy calcium carbonate, silicon dioxide, and fly ash) in recycled polypropylene (R-PP) has been investigated. The effects of individual filler (WS) and combined fillers (WS and inorganic filler) on morphological, mechanical, and thermal expansion and water absorption properties of hybrid composites were investigated. The flexural modulus and flexural strength were both reduced when reinforced with three kinds of inorganic fillers, respectively, which was possibly due to the poor interphase adhesion as observed in SEM. The high surface energy of heavy calcium carbonate due to its high acidic character provides an opportunity of better PP-heavy calcium carbonate interfacial interactions compared to PP-straw, PP-fly ash, and PP-SiO2interface. The water absorption at saturation increased markedly by introduction of WS in it. The hybrid composites from WS and inorganic fillers showed better water absorption compared to those WS/PP composites. The thermal expansion of composites decreased with the increase of WS loading. Heavy calcium and SiO2can obviously reduce the LCTE value of composite. At the 25% inorganic filler content, composites had the smallest LCTE values.

Effects of the Size of Wood Flour on Mechanical Properties of Wood-Plastic Composites

2011 ◽  
Vol 393-395 ◽  
pp. 76-79 ◽  
Author(s):  
Hai Bing Huang ◽  
Hu Hu Du ◽  
Wei Hong Wang ◽  
Hai Gang Wang
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Impact Strength ◽  
Wood Flour ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Inorganic Filler ◽  
Full Potential ◽  
Wood Plastic Composites ◽  
Plastic Composites

In this article, wood-plastic composites(WPCs) were manufactured with wood flour(80～120mesh、40～80mesh、20～40mesh、10～20mesh) combing with high density polyethylene(HDPE). Effects of the size of wood flour on mechanical properies and density of composites were investigated. Results showed that particle size of wood flour had an important effect on properitiesof WPCs. Change of mesh number had a outstanding effect on flexural modulus, tensile modulus and impact strength, howere, little effect on flexural strength and tensile strength. When mesh number of wood flour changed from 80～120mesh to 10～20mesh,flexural modulus and tensile modulus were respectively enhanced by 42.4% and 28.4%, respectively, and impact strength was decreased by 35.5%.Size of wood flour basically had no effect on density of composite within 10～120mesh. The use of wood flour or fiber as fillers and reinforcements in thermoplastics has been gaining acceptance in commodity plastics applications in the past few years. WPCs are currently experiencing a dramatic increase in use. Most of them are used to produce window/door profiles,decking,railing,ang siding. Wood thermoplastic composites are manufactured by dispering wood fiber or wood flour(WF) into molten plastics to form composite materials by processing techniques such as extrusion,themoforming, and compression or injection molding[1]. WPCs have such advantages[2]：(1)With wood as filler can improve heat resistance and strength of plastic, and wood has a low cost, comparing with inorganic filler, wood has a low density. Wood as strengthen material has a great potential in improving tensile strength and flexural modulus[3]；(2) For composite of same volume, composites with wood as filler have a little abrasion for equipment and can be regenerated；(3)They have a low water absorption and low hygroscopic property, They are not in need of protective waterproof paint, at the same time, composite can be dyed and painted for them own needs；(4)They are superior to wood in resistantnce to crack、leaf mold and termite aspects, composites are the same biodegradation as wood；(5)They can be processed or connected like wood；（6）They can be processed into a lots of complicated shape product by means of extrusion or molding and so on, meanwhile, they have high-efficiency raw material conversion and itself recycle utilization[4]. While there are many sucesses to report in WPCs, there are still some issues that need to be addressed before this technology will reach its full potential. This technology involves two different types of materials: one hygroscopic(biomass) and one hydrophobic(plastic), so there are issues of phase separation and compatibilization[5]. In this paper, Effects of the size of wood powder on mechanical properties of WPCs were studied.

Influence of Alkali Treatment and Nanoclay Content on the Properties of Rice Husk Filled Polyester Composites

2017 ◽  
Vol 882 ◽  
pp. 89-100 ◽  
Author(s):  
Omid Nabinejad ◽  
Sujan Debnath ◽  
Teh J. Ying ◽  
Willey Y.H. Liew ◽  
Ian J. Davies
Keyword(s):  
Water Absorption ◽  
Rice Husk ◽  
Moisture Absorption ◽  
Mechanical Performance ◽  
Alkali Treatment ◽  
Unsaturated Polyester ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Scanning Electron Micrographs ◽  
Nanoclay Content

The effect of alkali treatment and nanoclay addition on the mechanical properties and water absorption behavior of rice husk particle (RHP) reinforced unsaturated polyester (UP) composites was investigated. Thermogravimetric analysis (TGA) indicated that the alkali treatment removed most of the hemicellulose and impurities from the RHP with the tensile strength, tensile modulus, flexural strength and flexural modulus of the resulting composites being improved by alkali treatment. The results indicated that the 5% sodium hydroxide concentration had the optimum performance on mechanical strength and water absorption resistance. Furthermore, the influence of nanoclay addition (1, 3 and 5 wt%) on the properties of optimum alkali treated RHP-UP composites was investigated with the lowest content (1 wt%) of nanoclay showing the highest mechanical performance. However, further addition of nanoclay improved the moisture absorption resistance of the composites. Good interface bonding between the filler and matrix was observed from scanning electron micrographs for the optimum RHP alkali treated and nanoclay dispersed RHP-UP composites.

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