Effect of Cooling Rate on Boron Removal and Solidification Behavior of Al-Si Alloy

2015 ◽  
Vol 34 (1) ◽  
Author(s):  
Yanlei Li ◽  
Jian Chen ◽  
Boyuan Ban ◽  
Taotao Zhang ◽  
Songyuan Dai
Keyword(s):  
Cooling Rate ◽  
Removal Rate ◽  
Solidification Process ◽  
Alloy System ◽  
Primary Silicon ◽  
Boron Removal ◽  
Segregation Coefficient ◽  
Solidification Behavior ◽  
Solidification Temperature ◽  
Average Width

AbstractThe effect of cooling rate on boron removal and solidification behavior of Al-Si alloy with different silicon contents were studied during solar grade silicon purification. It is found that the boron removal rate is controlled by kinetic factor. A method is proposed to calculate apparent segregation coefficient of solidification process that spans over a temperature range. This apparent segregation coefficient is used to evaluate purification effect in alloy system with changing segregation coefficients. When average solidification temperature decreases, the apparent segregation coefficient of boron decreases. The average width and mass of primary silicon flakes decrease with increasing cooling rate. Impurity elements form intermetallic compound phases such as α-Al

Study of the Boron Distribution and Microstructure of Solidified Al-Si Alloy During the Process of Silicon Purification

2018 ◽  
Vol 37 (1) ◽  
pp. 69-73 ◽  
Author(s):  
Yanlei Li ◽  
Jian Chen ◽  
Songyuan Dai
Keyword(s):  
Cooling Rate ◽  
Transition Layer ◽  
Boron Content ◽  
Eutectic Silicon ◽  
Primary Silicon ◽  
Silicon Phase ◽  
Cooling Rates ◽  
Average Width ◽  
Boron Distribution ◽  
Silicon Purification

AbstractThe Al-Si melts that contain different silicon contents were solidified with a series of cooling rates, and the boron contents in primary silicon phases and eutectic silicon phases were measured and discussed. The results indicate that the boron content in the eutectic silicon phases is higher than that in the primary silicon phases when the cooling rate is constant. When the cooling rate decreases, the boron content in the primary silicon phases decreases, but the boron content in the eutectic silicon phases increases. The microstructure observations of solidified ingots show that there is an interface transition layer beside the primary silicon phase, and the average width of the interface transition layer increases with decreasing cooling rate.

Thermal Profile and Microstructure of Wrought Aluminium 7075 for Semisolid Metal Processing

2020 ◽  
Vol 17 (2) ◽  
pp. 7842-7850
Author(s):  
N. A. Razak ◽  
A. H. Ahmad ◽  
M. R. Maarof
Keyword(s):  
Cooling Rate ◽  
Solidus Temperature ◽  
Solidification Process ◽  
Graphite Crucible ◽  
Cooling Curve ◽  
Data Logger ◽  
Quick Method ◽  
Solidification Temperature ◽  
Open Atmosphere ◽  
Significant Difference

Thermal analysis (TA) is a non-damaging and quick method to check the molten metal’s condition preceding to casting. This paper aims to present the relationship between fraction solid and temperature by utilising cooling curve analysis (CCA), to acquire correct processing parameters for wrought aluminium 7075 in semisolid condition. An induction furnace was used to heat a graphite crucible containing wrought aluminium 7075 alloy up to the temperature of 750 °C. A calibrated Chromel-Alumel K-type thermocouple was placed at the centre of the crucible and was submerged to 15 mm in the melt. The solidification temperature and time were measured by Data Logger GL-220. Normal, intermediate, and high cooling rate conditions were achieved when the crucible was left in an open atmosphere, in an open atmosphere with additional minimum airflow, and in an open atmosphere with the maximum airflow, respectively. It was found that the normal cooling rate was estimated at 2.23 °C/s, the intermediate cooling rate was calculated at 2.88 °C/s while the high cooling rate was recorded at 3.20 °C/s. The increase in cooling rate conditions has a significant effect on the changes of phases during solidification process where it leads to the decreased in liquidus, eutectic and solidus temperature. The microstructure feature was found to have a significant difference with the variation of cooling rates where higher cooling rate led to smaller primary grain size.

Investigation on the Primary Si Phase Solidification and the Properties of SiCw/Al-18Si Composites

2007 ◽  
Vol 353-358 ◽  
pp. 1275-1278
Author(s):  
Lin Geng ◽  
Hong Mei Wei ◽  
Xue Xi Zhang
Keyword(s):  
Squeeze Casting ◽  
Volume Fraction ◽  
Primary Silicon ◽  
Solidification Behavior ◽  
Scanning Calorimetry ◽  
Solidification Temperature ◽  
Casting Technique ◽  
Microstructure Observation ◽  
Primary Si ◽  
Average Size

SiCw/Al-18Si composites were prepared by squeeze casting technique. SiCw/Al-18Si composites were remelted before solidification. The effects of volume fraction of SiC whisker on solidification behavior of SiCw/Al-18Si composites were investigated by means of differential scanning calorimetry (DSC) technique and microstructure observation. DSC results indicated that the start solidification temperature and primary silicon peak temperature decreased gradually and the degree of supercooling increased with the increasing of SiC whisker content. SiC whisker and Sr decreased the average size of Si phases and improved the mechanical properties of the composites.

scholarly journals Study on the Solidification Behavior of Inconel617 Electron Beam Cladding NiCoCrAlY: Numerical and Experimental Simulation

Coatings ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 58
Author(s):  
Jian Chen ◽  
Hailang Liu ◽  
Zhiguo Peng ◽  
Jie Tang
Keyword(s):  
Electron Beam ◽  
Temperature Gradient ◽  
Cooling Rate ◽  
Molten Pool ◽  
Solidification Rate ◽  
Solidification Process ◽  
The Self ◽  
Cooling Effect ◽  
Tissue Structure ◽  
Solidification Behavior

To better control the Inconel617 electron beam cladding solidification process, a three-dimensional temperature field model was built to simulate the temperature gradient, cooling rate, and solidification rate in the solidification process and take a deep dive into the solidification behavior, as well as the calculation of the solidification characteristic parameters at the edge of the molten pool and then predict the solidification tissue structure. The study shows that the largest temperature gradient occurred in the material thickness direction. The self-cooling effect of the material dominated the solidification of the alloy layer; the cooling rate depended on the high-temperature thermal conductivity of the material and the self-cooling effect of the matrix, and the maximum cooling rate in the bonding zone was 1380 °C/s. The steady-state solidification rate was equal to the moving speed of the heat source; the solidification characteristics of the solidification process at the edge of the molten pool increased with the distance from the surface: the cooling rate decreased from 1421.61 to 623 °C/s, the temperature gradient increased from 0.0723 × 106 to 0.417 × 106, and the solidification rate decreased from 0.01 to 0 m/s. The prediction was made that the small and thin equiaxed crystals are on the top, a thin and short dendritic transition structure in the middle, and relatively coarse dendrites at the bottom. Experiments confirmed that the solidification tissue structure is basically consistent with the simulation law.

scholarly journals Comparison of Phase Characteristics and Residual Stresses in Ti-6Al-4V Alloy Manufactured by Laser Powder Bed Fusion (L-PBF) and Electron Beam Powder Bed Fusion (EB-PBF) Techniques

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 796
Author(s):  
Aya Takase ◽  
Takuya Ishimoto ◽  
Naotaka Morita ◽  
Naoko Ikeo ◽  
Takayoshi Nakano
Keyword(s):  
Electron Beam ◽  
Residual Stresses ◽  
Cooling Rate ◽  
Process Parameters ◽  
Phase Evolution ◽  
Powder Bed Fusion ◽  
Laser Powder Bed Fusion ◽  
Solidification Temperature ◽  
Powder Bed ◽  
Β Phase

Ti-6Al-4V alloy fabricated by laser powder bed fusion (L-PBF) and electron beam powder bed fusion (EB-PBF) techniques have been studied for applications ranging from medicine to aviation. The fabrication technique is often selected based on the part size and fabrication speed, while less attention is paid to the differences in the physicochemical properties. Especially, the relationship between the evolution of α, α’, and β phases in as-grown parts and the fabrication techniques is unclear. This work systematically and quantitatively investigates how L-PBF and EB-PBF and their process parameters affect the phase evolution of Ti-6Al-4V and residual stresses in the final parts. This is the first report demonstrating the correlations among measured parameters, indicating the lattice strain reduces, and c/a increases, shifting from an α’ to α+β or α structure as the crystallite size of the α or α’ phase increases. The experimental results combined with heat-transfer simulation indicate the cooling rate near the β transus temperature dictates the resulting phase characteristics, whereas the residual stress depends on the cooling rate immediately below the solidification temperature. This study provides new insights into the previously unknown differences in the α, α’, and β phase evolution between L-PBF and EB-PBF and their process parameters.

scholarly journals Nucleation Behavior of a Single Al-20Si Particle Rapidly Solidified in a Fast Scanning Calorimeter

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2920
Author(s):  
Qin Peng ◽  
Bin Yang ◽  
Benjamin Milkereit ◽  
Dongmei Liu ◽  
Armin Springer ◽  
...  
Keyword(s):  
Cooling Rate ◽  
Rapid Solidification ◽  
Heterogeneous Nucleation ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Solidification Behavior ◽  
Nucleation Kinetics ◽  
Nucleation Behavior ◽  
Nucleation Undercooling ◽  
Primary Si

Understanding the rapid solidification behavior characteristics, nucleation undercooling, and nucleation mechanism is important for modifying the microstructures and properties of metal alloys. In order to investigate the rapid solidification behavior in-situ, accurate measurements of nucleation undercooling and cooling rate are required in most rapid solidification processes, e.g., in additive manufacturing (AM). In this study, differential fast scanning calorimetry (DFSC) was applied to investigate the nucleation kinetics in a single micro-sized Al-20Si (mass%) particle under a controlled cooling rate of 5000 K/s. The nucleation rates of primary Si and secondary α-Al phases were calculated by a statistical analysis of 300 identical melting/solidification experiments. Applying a model based on the classical nucleation theory (CNT) together with available thermodynamic data, two different heterogeneous nucleation mechanisms of primary Si and secondary α-Al were proposed, i.e., surface heterogeneous nucleation for primary Si and interface heterogenous nucleation for secondary α-Al. The present study introduces a practical method for a detailed investigation of rapid solidification behavior of metal particles to distinguish surface and interface nucleation.

scholarly journals Study of the Effect of Carbon on the Contraction of Hypo-Peritectic Steels during Initial Solidification by Surface Roughness

Metals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 982 ◽  
Author(s):  
Dazhi Pu ◽  
Guanghua Wen ◽  
Dachao Fu ◽  
Ping Tang ◽  
Junli Guo
Keyword(s):  
Surface Roughness ◽  
Cooling Rate ◽  
Solidification Process ◽  
Casting Process ◽  
Continuous Casting Process ◽  
Peritectic Steel ◽  
Laser Confocal Microscope ◽  
Initial Solidification

In the continuous casting process, the shrinkage of the peritectic phase transition during the initial solidification process has an important influence on the surface quality of peritectic steel. The initial solidification process of 0.10C%, 0.14C%, and 0.16C% peritectic steels was observed in situ by a high temperature laser confocal microscope, and the contraction degree during initial solidification was characterized by surface roughness. The results showed that under the cooling rate of 20 °C/s, the surface roughness value Ra(δ/γ) of 0.10C% peritectic steel was 32 μm, the Ra(δ/γ) value of 0.14C% peritectic steel was 25 μm, and the Ra(δ/γ) value of 0.16C% peritectic steel was 17 μm. With increasing carbon content, the contraction degree of the δ→γ transformation decreased, and the value of the surface roughness Ra(δ/γ) declined. Therefore, surface roughness can characterize the contraction degree of the δ→γ transformation in the initial solidification process of peritectic steel under the condition of a large cooling rate.

Cooling rate dependence of solidification for liquid aluminium: a large-scale molecular dynamics simulation study

2016 ◽  
Vol 18 (26) ◽  
pp. 17461-17469 ◽  
Author(s):  
Z. Y. Hou ◽  
K. J. Dong ◽  
Z. A. Tian ◽  
R. S. Liu ◽  
Z. Wang ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulation ◽  
Cooling Rate ◽  
Simulation Study ◽  
Large Scale ◽  
Solidification Process ◽  
Molecular Dynamics Method ◽  
Dynamics Simulation ◽  
Liquid Aluminium ◽  
Dynamics Method

The effect of the cooling rate on the solidification process of liquid aluminium is studied using a large-scale molecular dynamics method.

Conjugate Heat Transfer and Effects of Interfacial Heat Flux During the Solidification Process of Continuous Castings

2003 ◽  
Vol 125 (2) ◽  
pp. 339-348 ◽  
Author(s):  
M. Ruhul Amin ◽  
Nikhil L. Gawas
Keyword(s):  
Heat Transfer ◽  
Continuous Casting ◽  
Cooling Rate ◽  
Solidification Process ◽  
Air Gap ◽  
Gap Formation ◽  
Continuous Casting Mold ◽  
Withdrawal Velocity ◽  
Multiphase Fluid Flow ◽  
Multiphase Fluid

Multiphase fluid flow involving solidification is common in many industrial processes such as extrusion, continuous casting, drawing, etc. The present study concentrates on the study of air gap formation due to metal shrinkage on the interfacial heat transfer of a continuous casting mold. Enthalpy method was employed to model the solidification of continuously moving metal. The effect of basic process parameters mainly superheat, withdrawal velocity, mold cooling rate and the post mold cooling rate on the heat transfer was studied. The results of cases run with air gap formation were also compared with those without air gap formation to understand the phenomenon comprehensively. The current study shows that there exists a limiting value of Pe above which the effect of air gap formation on the overall heat transfer is negligible.

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