Production of Biodiesel Via Catalytic Processes: A Brief Review

2018 ◽  
Vol 16 (5) ◽  
Author(s):  
Eugênia Leandro Almeida ◽  
Cid Marcos Gonçalves Andrade ◽  
Onélia Andreo dos Santos
Keyword(s):  
Heterogeneous Catalysts ◽  
Raw Materials ◽  
Enzymatic Catalysis ◽  
Combustion Process ◽  
Fats And Oils ◽  
Diesel Oil ◽  
Animal Fats ◽  
Environmental Damages ◽  
Catalytic Processes ◽  
Materials Used

Abstract Currently, there is a worldwide concern, not only with the exhaustion of diesel oil, but also with the environmental damages caused by this fuel, from the process of extracting oil to consumption. The emission of the gases from the combustion process of this fuel are harmful to the health of living beings and contribute directly to the worsening of the greenhouse effect. Biodiesel appears in this context as a possible substitute for diesel. Thus, the main objective of this work was to carry out a bibliographical review of the main catalytic processes available in the literature for the production of biodiesel, respectively, the main chemical reactions involved in these processes, being: the esterification and transesterification reaction. Among the catalytic processes, the alkaline, acid and enzymatic catalysis was highlighted. And, among the main raw materials used in the production process are: vegetable oils, animal fats and oils and fats; as economically and environmentally viable alternatives. Still referring to the raw materials, there are the alcohols: methanol and ethanol, which are frequently used. In this way, the most varied catalytic methods present in the literature were presented. For each catalytic process, the work was presented, which developed methodologies for: homogeneous, heterogeneous catalysts, dispersed or immobilized, with the most diverse raw materials, which are currently used or that may be used in the process of obtaining biodiesel in the future. Industrial scale.

scholarly journals Developments in Improving Biodiesel Production from Animal Fats

2020 ◽  
Author(s):  
Fidel Toldrá ◽  
Leticia Mora ◽  
Fidel Toldra Reig
Keyword(s):  
Heterogeneous Catalysts ◽  
Raw Materials ◽  
Oxidation Stability ◽  
Process Intensification ◽  
Biodiesel Production ◽  
Animal Fats ◽  
Costly Treatment ◽  
Recent Developments ◽  
Materials Used ◽  
The Cost

Animal fats, usually found as waste from slaughterhouses, meat processing industry, and cooking facilities, constitute some of the most relevant waste with costly treatment because environmental regulations are quite strict. Part of such costs may be reduced through the generation of biodiesel that constitutes a valid renewable source of energy because it is biodegradable, non-toxic and has a good combustion emission profile. Furthermore, biodiesel can be blended up to 20% with fossil diesel for its use in many countries. Up to 70% of the total cost of biodiesel majorly depends on the cost of the raw materials used, which can be reduced using animal fat waste because they are cheaper than vegetable oil waste. Transesterification with alkaline catalysis is still preferred at industrial plants producing biodiesel. However, recent developments in technologies for process intensification like ultrasound, microwave, and different types of reactors have been successfully applied in transesterification and improved biodiesel production. Better efficiency has been achieved with new heterogeneous catalysts and nanocatalysts that can be easily recovered, regenerated and reused, and immobilized lipases with increased stability and resistance to alcohol denaturation. Also new adsorbents for increased oxidation stability of biodiesel. All these developments are promising for industrial use in near future.

Production of Biodiesel from Desert Date Seed Oil Using Heterogeneous Catalysts

2021 ◽  
Vol 53 ◽  
pp. 180-189
Author(s):  
Saidat Olanipekun Giwa ◽  
Maku Barbanas Haggai ◽  
Abdulwahab Giwa
Keyword(s):  
Reaction Time ◽  
Alternative Fuels ◽  
Heterogeneous Catalysts ◽  
Raw Materials ◽  
Biodiesel Production ◽  
Local Market ◽  
Flat Bottom ◽  
Optimum Yield ◽  
Animal Fats ◽  
Date Seed

In the recent time, there is increasing research in the area of alternative fuels as the exhausts of presently used petroleum-based fuels have been identified to have negative effects on the environment. Fuels produced from plant oils and animal fats have the tendencies of replacing petro fuels since they are renewable in nature. One of these renewable fuels is biodiesel. However, the homogenous catalyst used in biodiesel production has some drawbacks such as difficulty in separation from the fuel, soap formation and corrosiveness of the product mixture. In this work, the use of heterogeneous catalyst sourced from local raw materials (kaolin and eggshell) for the production of biodiesel from oil of desert date seed has been investigated. The kaolin obtained from Alkaleri Mining Site, Bauchi, was calcined in an oven at 800 °C for 3 h. The calcined kaolin was then chemically activated. Also, the eggshell-based catalyst was produced from raw eggshells after washing, drying, grinding, sieving using 0.3 mm sieve size and calcining at 900 °C for 3 h. Furthermore, the oil content of the desert date seed, which was acquired from a local market in Bauchi, was extracted via solvent extraction in a laboratory with a yield of 42%. Then, the biodiesel was subsequently prepared by mixing the oil, methanol and catalyst in a flat bottom flask and heating the mixture for a specified period. The catalyst concentration, methanol to oil ratio and time of reaction were subsequently varied to obtain the best yield. The results obtained revealed that an optimum yield of 29% could be obtained at methanol to oil ratio of 6:1 and a reaction time of 60 min using 1.5 g of eggshell-based catalyst while an optimum yield of 22% was obtained with 0.6 g for kaolin-based catalyst at a reaction time of 60 min and methanol to oil ratio of 4:1. It is recommended that further work should be carried out to improve on the yield of the biodiesel obtained using the heterogeneous catalysts.

scholarly journals Trends in Biodiesel Production from Animal Fat Waste

2020 ◽  
Vol 10 (10) ◽  
pp. 3644 ◽  
Author(s):  
Fidel Toldrá-Reig ◽  
Leticia Mora ◽  
Fidel Toldrá
Keyword(s):  
Heterogeneous Catalysts ◽  
Raw Materials ◽  
Biodiesel Production ◽  
Industrial Plants ◽  
Animal Fat ◽  
Recent Developments ◽  
Combustion Emission ◽  
Materials Used ◽  
The Cost ◽  
Alkaline Catalysis

The agro-food industry generates large amounts of waste that contribute to environmental contamination. Animal fat waste constitutes some of the most relevant waste and the treatment of such waste is quite costly because environmental regulations are quite strict. Part of such costs might be reduced through the generation of bioenergy. Biodiesel constitutes a valid renewable source of energy because it is biodegradable, non-toxic and has a good combustion emission profile and can be blended up to 20% with fossil diesel for its use in many countries. Furthermore, up to 70% of the total cost of biodiesel majorly depends on the cost of the raw materials used, which can be reduced using animal fat waste because they are cheaper than vegetable oil waste. In fact, 6% of total feedstock corresponded to animal fat in 2019. Transesterification with alkaline catalysis is still preferred at industrial plants producing biodiesel. Recent developments in heterogeneous catalysts that can be easily recovered, regenerated and reused, as well as immobilized lipases with increased stability and resistance to alcohol denaturation, are promising for future industrial use. This manuscript reviews the available processes and recent advances for biodiesel generation from animal fat waste.

scholarly journals Thermal Treatment of Biomass: A Bibliometric Analysis—The Torrefaction Case

Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 162
Author(s):  
Adrian Knapczyk ◽  
Sławomir Francik ◽  
Marcin Jewiarz ◽  
Agnieszka Zawiślak ◽  
Renata Francik
Keyword(s):  
Thermal Treatment ◽  
Chemical Engineering ◽  
Environmental Science ◽  
Raw Materials ◽  
Combustion Process ◽  
Hydrothermal Carbonization ◽  
Subject Area ◽  
Research Topics ◽  
Materials Used ◽  
Number Of Publications

The aim of the paper was to summarize and discuss current research trends in biomass thermal treatment (torrefaction process). Quantitative analyses were carried out, in which the main countries, research units and scientists were indicated. The analysis showed a clear upward trend in number of publications after 2010. Most scientists on selected topics come from China, USA, Canada, South Korea, Republic of China, Poland (Web od Science—Core Collection (WoS-CC) and Scopus databases). Quantitative analysis also showed that the most relevant WoS-CC categories in the summary are: Energy Fuels, Engineering Chemical, Agricultural Engineering, Biotechnology Applied Microbiology and Thermodynamics and Scopus Subject area: Energy, Chemical Engineering, Environmental Science, Engineering and Chemistry. Thematic analysis included research topics, process parameters and raw materials used. Thematic groups were separated: torrefaction process (temp.: 150–400 °C), hydrothermal carbonization process (HTC) (temp: 120–500 °C), pyrolysis process (temp.: 200–650 °C) and gasification and co-combustion process (temp.: 350–1600 °C). In the years 2015–2019, current research topics were: new torrefaction technologies (e.g., HTC), improvement of the physico-mechanical, chemical and energetic properties of produced fuel as well as the use of torrefied biomass in the process of pyrolysis, gasification and co-combustion. The raw materials used in all types of biomass thermal treatment were: energy crops, wood from fast-growing and exotic trees, waste from the agri-food industry, sewage sludge and microalgae.

SIFAT MEKANIK PAPAN GYPSUM DARI SERBUK LIMBAH KAYU NON KOMERSIAL

2014 ◽  
Vol 6 (2) ◽  
pp. 1
Author(s):  
Saibatul Hamdi
Keyword(s):  
Raw Materials ◽  
Wood Particle ◽  
Quality Standards ◽  
Gypsum Board ◽  
Average Value ◽  
Wood Particles ◽  
Sawn Timber ◽  
Materials Used ◽  
Artocarpus Elasticus ◽  
Ficus Glomerata

The purpose of this research is to know the mechanical strength of gypsum board by utilizing waste sawn wood. Raw materials used consist of flour, gypsum,wood particles, boraks and kambang (Goniothalamus sp), wood tarap (Artocarpus elasticus REINW) and lua (Ficus glomerata ROXB). Wood particle 40 mesh and 60 mesh, concentrations boraks of 1 and 2 and the percentage particles of gypsum sawn timber is 300, 400 and 500%. The results showed that the average value Modulus of Rufture (MoR) in lua wood ranges from 12.55 – 14,47 kgcm2, wood kambang 25.10-31,11 kgcm2 and wood tarap 19.20- 24,18 kgcm2. As for Modulus of Elasticity (MoE) on the lua 1129,80- 2092,70 kgcm2, wood kambang 2512,37-3971,32 kgcm2 and tarap 2050,63-2691,09 kgcm2. Gypsum board are mechanical properties do not meet quality standards created SNI 03-6434-2000.Keywords: sawdust, lua, kambang, tarap, gypsum, mechanical

COMPARATIVE ANALYSIS OF BIOACTIVE SUBSTANCES CONTENT IN THE LEAVES AND FRUITS OF A ROWAN-TREE (SORBUS AUCUPARIA FRUCTUS) AND ASSESSMENT OF PROSPECTS IN MEDICINE AND PHARMACY

2020 ◽  
pp. 58-62
Author(s):  
Chernichkina A.D.
Keyword(s):  
Raw Materials ◽  
Wide Distribution ◽  
Biologically Active ◽  
Bioactive Substances ◽  
Plant Raw Materials ◽  
Mountain Ash ◽  
The Russian Federation ◽  
Materials Used ◽  
Active Substances ◽  
Pectin Substances

A large number of biologically active substances, organic acids, tannins, and pectin substances were detected during the study of fruits, leaves, and pulp of the fruits of mountain Ash. The content of these substances in leaves and pulp will significantly expand the arsenal of medicinal plant raw materials used. Given the wide distribution of mountain Ash in the territory of the Russian Federation, harvesting leaves from the same plants after harvesting the fruit and using pulp will make it possible to obtain new phytopreparations.

Mutual Influence Study of Food Acids and Polysaccharides of Different Nature on the Sensory Perception of Low-Calorie Sweet Dishes

Food Industry ◽  
2020 ◽  
Vol 5 (2) ◽  
pp. 71-78
Author(s):  
Ekaterina Minnikhanova ◽  
Nataliya Zavorokhina ◽  
Anna Gilina
Keyword(s):  
Mutual Influence ◽  
Raw Materials ◽  
Sucrose Solution ◽  
Complex Mixture ◽  
The Body ◽  
Sensory Characteristics ◽  
Apple Pectin ◽  
Low Calorie ◽  
Functional Reserves ◽  
Materials Used

Abstract The inclusion of polysaccharide thickeners in the recipes of sweet dishes increases the functional reserves of the body, contributes to the preservation of health and the prevention of diseases. The purpose of the research is to study the sensory characteristics of polysaccharides of various nature when combined with food acids, to develop a recipe for a basic mixture of low-calorie meals for public catering. The authors analyzed citric, lactic and succinic acids in combinations with polysaccharides of various nature. Organoleptic tests were evaluated by a touch panel. The organization of the tasting analysis corresponded to GOST ISO 6658-2016; the consistency was determined according to GOST 31986-2012, GOST ISO 11036-2017, GOST ISO 8588-2011. The optimal organoleptic combinations of the presented food acids and complex additives of sweeteners (CDP) were identified, which included aspartame, sodium saccharinate, Sucralose, sweetness coefficient – 340: the mixture with citric acid had a long pleasant aftertaste without foreign tastes and the best taste characteristics. Using the “A-not A” method, we found that the sample with the addition of CDP is identical to the sucrose solution. In the second part of the study, polysaccharides were added to model samples of acids with complex sweeteners; the best sensory characteristics were obtained by model samples consisting of a mixture of low-esterified Apple pectin with lactic acid and KDP. The technology of obtaining a stable elastic jelly using low-esterified Apple pectin has been developed, since the complex mixture of sweeteners and food acids does not have a dehydrating effect. Developed a dry mix recipe that can serve as a basic development, low-calorie sweet products for catering and has a variance of use of lactic and succinic acids, depending on the flavor characteristics of the raw materials used and its corrective ability.

DAMPAK SUBSITUSI IMPORT TERHADAP DEFISIT NERACA PERDAGANGAN: STUDI KASUS IMPOR KULIT INDONESIA

2020 ◽  
Vol 4 (2) ◽  
Author(s):  
Ivan Yulianto ◽  
Ario Seno Nugroho
Keyword(s):  
General Equilibrium ◽  
Foreign Exchange ◽  
Computable General Equilibrium ◽  
Trade Balance ◽  
Raw Materials ◽  
Import Substitution ◽  
Leather Industry ◽  
Materials Used ◽  
Net Export ◽  
Balance Deficit

An alternative strategy to reduce the trade balance deficit simultaneously to increase the net foreign exchange is the import-substitution for raw materials used to produce an export goods. This paper proposes an import substitution study on footwear products that have a dependency on imported raw materials by 70 percent, with the largest composition being leather raw materials by 67 percent. This paper analyzes the relationship between subsidies on the leather industry to leather import-substitution, multiplier effect to footwear sector, and Indonesia trade balance. Author make use of simulation the on Input-Output 2010 table and Computable General Equilibrium (CGE) Model. The simulation shows 100 billion subsidies on the leather sector, lead for the substitution-import of leather by 7,94 million rupiah, increase the net export foreign exchange by 1.1 billion rupiah of the footwear sector, and for overall, increase Indonesia trade balance deficit by 68 billion rupiah. Keywords: Computable General Equilibrium, footwear, leather, net foreign exchange, subsidy.ABSTRAK: Salah satu terobosan untuk mengurangi defisit neraca perdagangan dan meningkatkan nilai neto devisa ekspor adalah dengan substitusi impor bahan baku yang digunakan untuk memproduksi barang ekspor. Paper ini mengusulkan kajian substitusi impor pada produk alas kaki yang mempunyai ketergantungan bahan baku impornya sebesar 70 persen, dengan komposisi terbesar adalah bahan baku kulit sebesar 67 persen. Tujuan penelitian ini adalah untuk mengetahui dampak stimulus subsidi pada industri kulit terhadap subtitusi impor kulit, dukungan multiplier sektor kulit terhadap sektor alas kaki, serta terhadap devisa ekspor Indonesia. Penelitian ini menggunakan simulasi model Computable General Equilibrium (CGE). Hasil simulasi menunjukkan stimulus subsidi sebesar 100 milyar rupiah pada sektor kulit memberikan substitusi bahan baku kulit sebesar 7,94 juta rupiah, menaikkan devisa ekspor sektor alas kaki sebesar 1.1 miliar rupiah, serta secara keseluruhan menambah defisit neraca berjalan Indonesia sebesar 68 miliar rupiah. Kata kunci: alas kaki, Computable General Equilibrium (CGE), devisa ekspor, kulit, subsidi.

New surface treatment techniques to minimize copper alloy leaching in drinking water

2012 ◽  
Vol 7 (4) ◽  
Author(s):  
Norikazu Sugaya
Keyword(s):  
Surface Treatment ◽  
Raw Materials ◽  
Organic Film ◽  
Forming Process ◽  
Mixed Acid ◽  
Treatment Techniques ◽  
Acid Washing ◽  
Washing Process ◽  
Film Forming ◽  
Materials Used

This new surface treatment is simple and easy as well as low in cost. The processes can even be performed by hand. Pharmaceutical raw materials used for the surface treatment, such as hydrochloric acid and nitric acid used in a mixed acid washing process and vegetable oil used in an organic film forming process, are easily obtained in many countries.

scholarly journals Bio-Based Alternatives to Phenol and Formaldehyde for the Production of Resins

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2237 ◽  
Author(s):  
P. R. Sarika ◽  
Paul Nancarrow ◽  
Abdulrahman Khansaheb ◽  
Taleb Ibrahim
Keyword(s):  
Raw Materials ◽  
Phenol Formaldehyde ◽  
Raw Material ◽  
Wood Industry ◽  
Suitable Material ◽  
The Past ◽  
Wide Range ◽  
Recent Developments ◽  
Sustainable Materials ◽  
Materials Used

Phenol–formaldehyde (PF) resin continues to dominate the resin industry more than 100 years after its first synthesis. Its versatile properties such as thermal stability, chemical resistance, fire resistance, and dimensional stability make it a suitable material for a wide range of applications. PF resins have been used in the wood industry as adhesives, in paints and coatings, and in the aerospace, construction, and building industries as composites and foams. Currently, petroleum is the key source of raw materials used in manufacturing PF resin. However, increasing environmental pollution and fossil fuel depletion have driven industries to seek sustainable alternatives to petroleum based raw materials. Over the past decade, researchers have replaced phenol and formaldehyde with sustainable materials such as lignin, tannin, cardanol, hydroxymethylfurfural, and glyoxal to produce bio-based PF resin. Several synthesis modifications are currently under investigation towards improving the properties of bio-based phenolic resin. This review discusses recent developments in the synthesis of PF resins, particularly those created from sustainable raw material substitutes, and modifications applied to the synthetic route in order to improve the mechanical properties.

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