PENGGESERAN REAKSI KESETIMBANGAN HIDROLISIS MINYAK DENGAN PENGAMBILAN GLISEROL UNTUK MEMPEROLEH ASAM LEMAK JENUH DARI MINYAK BIJI KARET

EKUILIBIUM ◽  
2012 ◽  
Vol 12 (2) ◽  
Author(s):  
Dwi Ardiana Setyawardani
Keyword(s):  
Fatty Acids ◽  
Unsaturated Fatty Acids ◽  
Agricultural Waste ◽  
Saturated Fatty Acids ◽  
Batch Process ◽  
Rubber Seed Oil ◽  
Rubber Seed ◽  
Hydrolysis Process ◽  
Equilibrium Conversion ◽  
Reaction Equilibrium

<p>Abstract: Indonesia is one of the largest rubber producers in the world. Rubber seed is obtained<br />as agricultural waste. This is a potential feedstock for biodiesel because of its high proportion of<br />oil. The oil is hydrolyzed to produce saturated and unsaturated fatty acids. Unsaturated fatty acids<br />such as oleic, linoleic and linolenic acids are good for health. Besides, saturated fatty acids are<br />suitable for high-quality biodiesel by esterification. Batch process of rubber seed hydrolysis was<br />conducted on this research to produce fatty acids and glycerine. In case of its reversible reaction,<br />continuously separation of product or increasing reactant-concentration was needed to achieve<br />equilibrium conversion. In this batch process, continuously separation of glycerine was done by<br />settling it stage by stage (multi stages). The objection of this research was to find optimum<br />condition on multi stages hydrolysis to produce fatty acids. It was processed on hydrochloric-acid<br />catalyzed, fifty-fifty ratio of oil and water, and reacted in 70<br />C. In each stage of hydrolysis,<br />glycerine and water was separated from reaction mixture by settling on 24 hours. The fatty acids<br />were re-hydrolyzed with fresh water like the stage before. The process was stopped while it<br />reached maximum conversion (almost completely). Based on this research, we concluded that<br />for the shorter time of each stage on hydrolysis-process gives higher conversion of oil to fatty<br />acids.<br />o<br />Keywords: fatty acids, multi stages hydrolysis, Rubber Seed Oil, reaction equilibrium.</p>

Composition Analysis of Fatty Acids and Phytosterols in Rubber Seed Oil from Yunnan

2018 ◽  
Vol 17 (2) ◽  
pp. 148-152
Author(s):  
Liu Yun ◽  
Fan Fang-Yu ◽  
Zhu Yi-Xin ◽  
Wang Yun-Xiang ◽  
Lv Zhao-lin ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Gas Chromatography ◽  
Yunnan Province ◽  
Seed Oil ◽  
Unsaturated Fatty Acids ◽  
Gas Chromatography Mass Spectrometry ◽  
Composition Analysis ◽  
Rubber Seed Oil ◽  
Rubber Seed ◽  
Development And Utilization

Crude and refined rubber seed oil (RSO) produced from Xishuangbanna, Yunnan Province was analyzed. After methylation and saponification, the contents of fatty acids and phytosterols were determined by gas chromatography and gas chromatography-mass spectrometry. Results showed that both the crude and refined RSOs contained high levels of unsaturated fatty acids and phytosterols. Four unsaturated fatty acid contents of 83.56% and 83.25% are found in both crude and refined RSOs, respectively. Six to seven types of phytosterols are found in both crude and refined RSOs. The contents of β-sitosterol are 12.13 and 11.22 mg/g in crude and refined RSO, respectively. This study provided fundamental instruction on the research, development, and utilization of RSO.

scholarly journals Biodiesel Production from a Mixture of Rubber Seed Oil and Waste Oil Through the Alcoholysis Process with Catalysts Based on Vegetable Waste

2021 ◽  
Vol 1 (4) ◽  
pp. 109-113
Author(s):  
I Ibrahim ◽  
A M Syam ◽  
M Muhammad ◽  
Zainuddin Ginting ◽  
S Maliki
Keyword(s):  
Fatty Acids ◽  
Alternative Fuels ◽  
Fossil Fuels ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Biodiesel Production ◽  
Rubber Seed Oil ◽  
Main Fatty Acid ◽  
The Times ◽  
Plantation Crops

The increasing types of people needs along with the times have resulted in the need for energy increasing so that the supply of energy, especially energy that cannot be renewed (unrenewable energy) is decreasing. Currently, almost 80% of the world's energy needs are met by fossil fuels. In fact, the use of fossil fuels can cause global warming. To reduce dependence on fossil fuels as an energy source, it is necessary to search for energy sources that can be used as alternative fuels that are environmentally friendly. Indonesia is an agricultural country that is overgrown with plantation crops that produce various kinds of waste such as rubber seeds which contain oil. This plant produces a lot of wasted seeds that are not useful. Therefore, researchers want to research the oil from rubber seeds to be a biodiesel product and in order to get high quality results. This study regulates several independent variables, namely the alcoholysis temperatures: 650C, 700C and 750C and the alcohol volume: 200 ml, 250 ml and 300 ml. The process is carried out by extraction using the alkolysis method. The best yield yielded 60.5%, with the best yield of biodiesel from alcoholysis obtained at a volume of 250 ml of ethanol and a temperature of 75oC with a density of 09 kg/m3 and a viscosity of 3,285 mm2/s (cSt), fulfilling the requirements of SNI 7182:2015. Based on the results of GC analysis, the main fatty acid components in the sample were at peak 1, namely saturated fatty acids in the form of palmitic acid at 44,28% and peak 4, namely unsaturated fatty acids in the form of oleic acid at 31.99%.

DEVELOPMENT OF AN EXPERIMENTAL MODEL OF AVITAMINOSIS F

2020 ◽  
Vol 20 (2) ◽  
pp. 38-40
Author(s):  
A. Levitsky ◽  
A. Lapinska ◽  
I. Selivanskaya
Keyword(s):  
Fatty Acids ◽  
Experimental Model ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Coconut Oil ◽  
The Body ◽  
Regulatory Function ◽  
Omega 3 ◽  
White Rats ◽  
Arachidonic Acids

The article analyzes the role of essential polyunsaturated fatty acids (PUFA), especially omega-3 series in humans and animals. The biosynthesis of essential PUFA in humans and animals is very limited, so they must be consumed with food (feed). Тhe ratio of omega-3 and omega-6 PUFA is very important. Biomembranes of animal cells contain about 30% PUFA with a ratio of ω-6/ ω-3 1-2. As this ratio increases, the physicochemical properties of biomembranes and the functional activity of their receptors change. The regulatory function of essential PUFA is that in the body under the action of oxygenase enzymes (cyclooxygenase, lipoxygenase) are formed extremely active hormone-like substances (eicosanoids and docosanoids), which affect a number of physiological processes: inflammation, immunity, metabolism. Moreover, ω-6 PUFA form eicosanoids, which have pro-inflammatory, immunosuppressive properties, and ω-3 PUFAs form eicosanoids and docosanoids, which have anti-inflammatory and immunostimulatory properties. Deficiency of essential PUFA, and especially ω-3 PUFA, leads to impaired development of the body and its state of health, which are manifestations of avitaminosis F. Prevention and treatment of avitaminosis F is carried out with drugs that contain PUFA. To create new, more effective vitamin F preparations, it is necessary to reproduce the model of vitamin F deficiency. An experimental model of vitamin F deficiency in white rats kept on a fat –free diet with the addition of coconut oil, which is almost completely free of unsaturated fatty acids, and saturated fatty acids make up almost 99 % of all fatty acids was developed. The total content of ω-6 PUFA (sum of linoleic and arachidonic acids), the content of ω-3 PUFA (α-linolenic, eicosapentaenoic and docosahexaenoic acids) in neutral lipids (triglycerides and cholesterol esters) defined. Тhe content of ω-6 PUFA under the influence of coconut oil decreased by 3.3 times, and the content of ω-3 PUFA - by 7.5 times. Тhe influence of coconut oil, the content of ω-6 PUFA decreased by 2.1 times, and the content of ω-3 PUFA - by 2.8 times. The most strongly reduces the content of ω-3 PUFA, namely eicosapentaenoic, coconut oil, starting from 5 %. Consumption of FFD with a content of 15 % coconut oil reduces the content of eicosapentaenoic acid to zero, ie we have an absolute deficiency of one of the most important essential PUFAs, which determined the presence of vitamin F deficiency.

EFFECT OF GINGER, LEMURU FISH OIL SAPONIFICATION AND OLIVE OIL ON COMPOSITION FATTY ACID OF BEEF

2014 ◽  
Vol 4 (1) ◽  
pp. 31-39
Author(s):  
Siwitri Kadarsih
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Fish Oil ◽  
Olive Oil ◽  
Rice Bran ◽  
Dry Matter ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Omega 3 ◽  
Omega 6

The objective was to get beef that contain unsaturated fatty acids (especially omega 3 and 6), so as to improve intelligence, physical health for those who consume. The study design using CRD with 3 treatments, each treatment used 4 Bali cattle aged approximately 1.5 years. Observations were made 8 weeks. Pasta mixed with ginger provided konsentrat. P1 (control); P2 (6% saponification lemuru fish oil, olive oil 1%; rice bran: 37.30%; corn: 62.70%; KLK: 7%, ginger paste: 100 g); P3 (lemuru fish oil saponification 8%, 2% olive oil; rice bran; 37.30; corn: 62.70%; KLK: 7%, ginger paste: 200 g). Konsentrat given in the morning as much as 1% of the weight of the cattle based on dry matter, while the grass given a minimum of 10% of the weight of livestock observation variables include: fatty acid composition of meat. Data the analyzies qualitative. The results of the study showed that the composition of saturated fatty acids in meat decreased and an increase in unsaturated fatty acids, namely linoleic acid (omega 6) and linolenic acid (omega 3), and deikosapenta deikosaheksa acid.Keywords : 

Differential Effects of Dietary Fatty Acids on Body Composition and Adiposity

2020 ◽  
Vol 16 (2) ◽  
pp. 142-154 ◽  
Author(s):  
Hadi Emamat ◽  
Zahra Yari ◽  
Hossein Farhadnejad ◽  
Parvin Mirmiran
Keyword(s):  
Fatty Acids ◽  
Body Composition ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Total Body Weight ◽  
Fat Distribution ◽  
Monounsaturated Fatty Acids ◽  
Dietary Fatty Acids ◽  
Dietary Fats ◽  
Total Body

Recent evidence has highlighted that fat accumulation, particularly abdominal fat distribution, is strongly associated with metabolic disturbance. It is also well-recognized that the metabolic responses to variations in macronutrients intake can affect body composition. Previous studies suggest that the quality of dietary fats can be considered as the main determinant of body-fat deposition, fat distribution, and body composition without altering the total body weight; however, the effects of dietary fats on body composition have controversial results. There is substantial evidence to suggest that saturated fatty acids are more obesogen than unsaturated fatty acids, and with the exception of some isomers like conjugate linoleic acid, most dietary trans fatty acids are adiposity enhancers, but there is no consensus on it yet. On the other hand, there is little evidence to indicate that higher intake of the n-3 and the n-6 polyunsaturated fatty acids can be beneficial in attenuating adiposity, and the effect of monounsaturated fatty acids on body composition is contradictory. Accordingly, the content of this review summarizes the current body of knowledge on the potential effects of the different types of dietary fatty acids on body composition and adiposity. It also refers to the putative mechanisms underlying this association and reflects on the controversy of this topic.

scholarly journals Explore the gene network regulating the composition of fatty acids in cottonseed

2021 ◽  
Vol 21 (1) ◽  
Author(s):  
Lihong Ma ◽  
Xinqi Cheng ◽  
Chuan Wang ◽  
Xinyu Zhang ◽  
Fei Xue ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Linoleic Acid ◽  
Linolenic Acid ◽  
Gene Network ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Accumulation Pattern ◽  
Time Points ◽  
Expression Characteristics

Abstract Background Cottonseed is one of the major sources of vegetable oil. Analysis of the dynamic changes of fatty acid components and the genes regulating the composition of fatty acids of cottonseed oil is of great significance for understanding the biological processes underlying biosynthesis of fatty acids and for genetic improving the oil nutritional qualities. Results In this study, we investigated the dynamic relationship of 13 fatty acid components at 12 developmental time points of cottonseed (Gossypium hirsutum L.) and generated cottonseed transcriptome of the 12 time points. At 5–15 day post anthesis (DPA), the contents of polyunsaturated linolenic acid (C18:3n-3) and saturated stearic acid (C18:0) were higher, while linoleic acid (C18:2n-6) was mainly synthesized after 15 DPA. Using 5 DPA as a reference, 15,647 non-redundant differentially expressed genes were identified in 10–60 DPA cottonseed. Co-expression gene network analysis identified six modules containing 3275 genes significantly associated with middle-late seed developmental stages and enriched with genes related to the linoleic acid metabolic pathway and α-linolenic acid metabolism. Genes (Gh_D03G0588 and Gh_A02G1788) encoding stearoyl-ACP desaturase were identified as hub genes and significantly up-regulated at 25 DPA. They seemed to play a decisive role in determining the ratio of saturated fatty acids to unsaturated fatty acids. FAD2 genes (Gh_A13G1850 and Gh_D13G2238) were highly expressed at 25–50 DPA, eventually leading to the high content of C18:2n-6 in cottonseed. The content of C18:3n-3 was significantly decreased from 5 DPA (7.44%) to 25 DPA (0.11%) and correlated with the expression characteristics of Gh_A09G0848 and Gh_D09G0870. Conclusions These results contribute to our understanding on the relationship between the accumulation pattern of fatty acid components and the expression characteristics of key genes involved in fatty acid biosynthesis during the entire period of cottonseed development.

scholarly journals Meat Quality, Fatty Acid Content and NMR Metabolic Profile of Dorper Sheep Supplemented with Bypass Fats

Foods ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 1133
Author(s):  
Atique Ahmed Behan ◽  
Muhammad Tayyab Akhtar ◽  
Teck Chwen Loh ◽  
Sharida Fakurazi ◽  
Ubedullah Kaka ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Meat Quality ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Fatty Acid Content ◽  
Basal Diet ◽  
Negative Influence ◽  
Significant Difference ◽  
Dorper Sheep

The supplementation of rumen bypass fat (RBF) has remained one of the preferred approaches used to decrease undesirable saturated fatty acids (FA) and increase beneficial unsaturated FA in the meat. This study was planned to evaluate the influences of rumen bypass fats on meat quality, fatty acid and metabolic profiles in male Dorper sheep (n = 36) with 24.66 ± 0.76 kg (mean ± standard error) initial body weight. Treatment comprised a basal diet (30:70 rice straw to concentrate) with no added RBF as a control (CON), basal diet with prilled fat (PF), basal diet with prilled fat plus lecithin (PFL) and basal diet with calcium soap of palm fatty acids (CaS). The findings revealed that cooking loss, drip loss and shear force in longissimus dorsi (LD) muscle were not affected by RBF supplementation, while meat pH was significantly higher in the CaS on aging day 1. However, the diet supplemented with prilled fat and lecithin modified the meat’s fatty acid profile significantly by increasing unsaturated fatty acids and decreasing saturated fats. The relative quantification of the major differentiating metabolites found in LD muscle of sheep showed that total cholesterol, esterified cholesterol, choline, glycerophosphocholine and glycerophospholipids were significantly lower in CaS and PFL diets, while glycerol and sphingomyelin were significantly higher in CaS and PFL diets. Most of the metabolites in the liver did not show any significant difference. Based on our results, the supplementation of protected fats did not have a negative influence on meat quality and the meat from Dorper sheep fed prilled fat with lecithin contained more healthy fatty acids compared to other diets.

Modifying egg fatty acid content by supplementation of laying hen diets with palm olein oil (POO)

2009 ◽  
Vol 2009 ◽  
pp. 212-212
Author(s):  
S J Hosseini Vashan ◽  
N Afzali ◽  
A Golian ◽  
M Malekaneh ◽  
A Allahressani
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Acid Content ◽  
Palm Olein ◽  
Unsaturated Fatty Acids ◽  
Saturated Fatty Acids ◽  
Fatty Acid Content ◽  
Processing Plant ◽  
Optimum Level ◽  
Olein Oil

Palm oil is the most abundant of all oils produced globally. It is very high in saturated fatty acids specifically palmitic acid, but other fatty acids (monounsaturated (MUFA) and polyunsaturated) are presented at low concentrations. In the processing plant some high amount of oleic acid with some other unsaturated fatty acids are extracted and marketed as Palm olein oil, and used to reduce blood or egg cholesterol (Rievelles et al., 1994). The objective of this study was to determine the optimum level of dietary palm olein oil required to enrich the mono-unsaturated fatty acid content of yolk, egg cholesterol and antibody titre.

scholarly journals An Alternative Approach for the Synthesis of Sulfoquinovosyldiacylglycerol

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4275
Author(s):  
Tobias Sitz ◽  
Hendrik Domey ◽  
Judith Fischer ◽  
Sascha Rohn
Keyword(s):  
Fatty Acids ◽  
Functional Foods ◽  
Unsaturated Fatty Acids ◽  
Biological Activities ◽  
Saturated Fatty Acids ◽  
Diverse Range ◽  
Natural Sources ◽  
Model Studies ◽  
Alternative Approach ◽  
Increasing Demand

Sulfoquinovosyldiacylglycerol (SQDG) is a glycolipid ubiquitously found in photosynthetically active organisms. It has attracted much attention in recent years due to its biological activities. Similarly, the increasing demand for vegan and functional foods has led to a growing interest in micronutrients such as sulfolipids and their physiological influence on human health. To study this influence, reference materials are needed for developing new analytical methods and providing enough material for model studies on the biological activity. However, the availability of these materials is limited by the difficulty to isolate and purify sulfolipids from natural sources and the unavailability of chemical standards on the market. Consequently, an alternative synthetic route for the comprehensive preparation of sulfolipids was established. Here, the synthesis of a sulfolipid with two identical saturated fatty acids is described exemplarily. The method opens possibilities for the preparation of a diverse range of interesting derivatives with different saturated and unsaturated fatty acids.

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