Application of the ADUFR Process to Brewery Effluent on a Laboratory Scale

1992 ◽  
Vol 25 (10) ◽  
pp. 95-105 ◽  
Author(s):  
N. K. H. Strohwald ◽  
W. R. Ross

The application of the high rate ADUFR (Anaerobic Digestion - Ultrafiltration) process to brewery effluent was investigated over an 80 day test period. Performance data on both the anaerobic digester and ultrafiltration unit is presented. At stabilised conditions, space load rates of 15 kgCOD.m−3.d−1 could be achieved at hydraulic residence times of 0.5-0.8 days, with COD removal efficiencies between 96 and 99%. Linear flow velocity across the membrane surface and suspended solids concentration of the biomass were found to have a substantial effect on ultrafiltration membrane flux. No membrane fouling was experienced throughout the test period and flux values of 10-18 l.m−2.h−1 (LMH) could be maintained without resorting to chemical cleaning. Dormant sludge was reactivated rapidly, after a two month rest period. A space load rate of 8 kgCOD.m−3.d−1 at a retention time of 0.5 days could be reached within seven days from restart.

Author(s):  
Alain Zarragoitia ◽  
Sylvie Schetrite ◽  
Ulises J. Jauregui-Haza ◽  
Claire Albasi

A mathematical model was developed for the filtration process and the influence of aeration on Submerged Membrane Bioreactors. The dynamics of sludge attachment to and detachment from the membrane, in relation to the filtration and a strong intermittent aeration, were included in the model. The influence on the membrane fouling of intermittent aeration injected on the membrane surface, and its synchronization with intermittent filtration, were studied numerically and experimentally. For the evaluation of filtration cake development, the assumption of the presence of two cake layers (one dynamic and the other stable) was considered. The model development and simulation focused on the description of existing relationships among important system variables like mixed liquor suspended solids concentration, aeration, temperature of the sludge suspension, transmembrane pressure, and the fouling increase during the filtration process. The model obtained offers the possibility of improving the design configuration and operation strategies of Submerged Membrane Bioreactors in wastewater treatment, and it allows the of aeration-filtration cycles to be optimized.


Water SA ◽  
2019 ◽  
Vol 45 (3 July) ◽  
Author(s):  
Marjana Simonič

Membrane surface properties and their effect on the efficiency of ultrafiltration (UF) of real waste oily emulsions was studied. Experiments were performed in cross-flow operation at total recycle condition in a lab-scale system. The ceramic UF membrane in the tubular type module was employed. During the experiments permeate flux was measured. The most important influential factors, such as temperature, TMP, and pH, were considered during the experiments. Zeta potential was measured in order to explain the phenomena on the membrane surface. The isoelectric point of the fouled membrane was shifted to the alkaline range. COD removal efficiency reached 89%. Gas chromatography measurements were performed in order to determine the composition of waste emulsions. SEM micrographs showed the formation of calcite on the membrane, which contributed to membrane fouling. Chemical cleaning was examined using alkaline and acid solutions, and a cleaning strategy was determined.


2014 ◽  
Vol 1073-1076 ◽  
pp. 751-754
Author(s):  
Jun Xia Liu ◽  
Bing Zhi Dong ◽  
Wei Wei Huang

The main objective of this study was to investigate membrane fouling caused by natural organic matter (NOM). Flux measurement, fourier transform spectroscopy (FTIR), scanning electron microscopy (SEM) were employed to compare the surface morphology of fouled membrane and chemically cleaned membrane. Sodium hypochlorite (NaClO), sodium hydroxide (NaOH), hydrochloric acid (HCl) were used as chemical cleaning agents respectively. Flux analysis demonstrated that chemical cleaning have little effect on flux recovery. FTIR spectrometry revealed that polysaccharide and protein took the major responsibility for membrane fouling. SEM showed that foulants filled the pores and blocked the membrane surface which led to the flux decline.


1992 ◽  
Vol 25 (10) ◽  
pp. 27-39 ◽  
Author(s):  
W. R. Ross ◽  
J. P. Barnard ◽  
N. K. H. Strohwald ◽  
C. J. Grobler ◽  
J. Sanetra

ADUFR (anaerobic digestion ultrafiltration) is a membrane-assisted process for positive separation of biomass from the treated effluent. Pilot and full-scale ADUFR studies were carried out on a maize-processing effluent (15 kgCOD/m3) at the Meyerton mill of Messrs. African Products, South Africa. The results after 15 months of full-scale operation have illustrated the merits of the process for the production of a colloid-free effluent at a mean COD removal efficiency of 97%. The permeate flux varied in the range 37 to 8 l.m−2.h−1 at 35°C, inlet pressure of 450 kPa, linear tube velocity of 1.6 m/s and digester suspended solids concentration of 21 kg/m3. Periodic chemical cleaning of the unsupported tubular polyethersulphone membranes with EDTA was only commenced after 13 months operation. A mean plant space load rate of 3 kgCOD.m−3.d−1 guaranteed reliability to withstand high COD shock loadings due to variations in the feed load. Bio-membrane separation technology of this nature holds important economic advantages for the treatment of a wide spectrum of organic industrial effluents.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 583
Author(s):  
Yu-Hsuan Chiao ◽  
Arijit Sengupta ◽  
Micah Belle Marie Yap Ang ◽  
Shu-Ting Chen ◽  
Teow Yeit Haan ◽  
...  

Forward osmosis (FO) is an important desalination method to produce potable water. It was also used to treat different wastewater streams, including industrial as well as municipal wastewater. Though FO is environmentally benign, energy intensive, and highly efficient; it still suffers from four types of fouling namely: organic fouling, inorganic scaling, biofouling and colloidal fouling or a combination of these types of fouling. Membrane fouling may require simple shear force and physical cleaning for sufficient recovery of membrane performance. Severe fouling may need chemical cleaning, especially when a slimy biofilm or severe microbial colony is formed. Modification of FO membrane through introducing zwitterionic moieties on the membrane surface has been proven to enhance antifouling property. In addition, it could also significantly improve the separation efficiency and longevity of the membrane. Zwitterion moieties can also incorporate in draw solution as electrolytes in FO process. It could be in a form of a monomer or a polymer. Hence, this review comprehensively discussed several methods of inclusion of zwitterionic moieties in FO membrane. These methods include atom transfer radical polymerization (ATRP); second interfacial polymerization (SIP); coating and in situ formation. Furthermore, an attempt was made to understand the mechanism of improvement in FO performance by zwitterionic moieties. Finally, the future prospective of the application of zwitterions in FO has been discussed.


Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 245
Author(s):  
Shaolin Ge ◽  
Zhao Zhang ◽  
Haiyang Yan ◽  
Muhammad Irfan ◽  
Yingbo Xu ◽  
...  

In the papermaking industry (reconstituted tobacco), a large number of tobacco stems, dust, and fines are discharged in the wastewater. This high salinity wastewater rich in ionic constituents and nicotine is difficult to be degraded by conventional biological treatment and is a serious threat that needs to be overcome. Electrodialysis (ED) has proved a feasible technique to remove the inorganic components in the papermaking wastewater. However, the fouling in ion exchange membranes causes deterioration of membranes, which causes a decrease in the flux and an increase in the electrical resistance of the membranes. In this study, the fouling potential of the membranes was analyzed by comparing the properties of the pristine and fouled ion exchange membranes. The physical and chemical properties of the ion exchange membranes were investigated in terms of electrical resistance, water content, and ion exchange capacity, as well as studied by infrared spectroscopy (IR) spectra, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) analyses. The results indicated that the membrane fouling is caused by two different mechanisms. For the anion exchange membranes, the fouling is mainly caused by the charged organic anions. For the cation exchange membrane, the fouling is caused by minerals such as Ca2+ and Mg2+. These metal ions reacted with OH− ions generated by water dissociation and precipitated on the membrane surface. The chemical cleaning with alkaline and acid could mitigate the fouling potential of the ion exchange membranes.


Author(s):  
М.К. Джубари ◽  
Н.В. Алексеева

Многие отрасли промышленности ежедневно производят большие объемы сточных вод, содержащих органические соединения, неорганические соли и взвешенные примеси. Неотъемлемой частью современных промышленных очистных сооружений является система мембранной очистки. Область применения мембранных процессов разделения ограничены рядом требований: отсутствие взвешенных частиц в обрабатываемых водных растворах, имеется ряд ограничений в кислотности и температуре разделяемых растворов. Одной из важнейших задач в обеспечении рентабельности всего процесса обработки является длительный срок службы мембран, которого возможно достичь предотвращением обрастания поверхности мембран. Наиболее распространенным процессом очистки вод является обратноосмотический процесс разделения. В работе рассмотрен процесс осадкообразования на обратноосмотических мембранах, особое внимание уделяется химической очистке. Проведен анализ работ, посвященных вопросу обрастания обратноосмотических мембран в различных растворах. Рассмотрены различные конструкции мембранных элементов, описан механизм переноса через обратноосмотическую мембрану, учитывая явления концентрационной поляризации у поверхности мембраны. Подробно описаны различные способы борьбы с загрязнением мембран в промышленных сточных водах: предварительная обработка, очистка мембран и модификация поверхности. Авторы резюмируют, что состав исходного раствора является важным фактором, влияющим на производительность обратноосмотической установки. Кроме того, предварительная обработка водных растворов перед процессом обратноосмотического разделения приводит к уменьшению обрастания мембранной поверхности и значительно увеличивает срок службы мембранного элемента. Эффективно в качестве процесса предварительной обработки использовать процесс ультрафильтрационного разделения. Many industries produce large volumes of wastewater on a daily basis containing organic compounds, inorganic salts and suspended impurities. An integral part of modern industrial treatment facilities is a membrane cleaning system. The application area of membrane separation processes is limited by a number of requirements: the absence of suspended particles in the treated aqueous solutions, there are a number of limitations in the acidity and temperature of the separated solutions. One of the most important concerns in ensuring the cost-effectiveness of the entire processing process is the long membrane life, which can be achieved by preventing fouling of the membrane surface. The most common water treatment process is the reverse osmosis separation process. The paper considers the process of sedimentation on reverse osmosis membranes, with special attention paid to chemical cleaning. The analysis of works devoted to the issue of fouling of reverse osmosis membranes in various solutions is carried out. Various designs of membrane elements are considered, the mechanism of transfer through a reverse osmosis membrane is described, taking into account the phenomena of concentration polarization at the membrane surface. Various methods for controlling membrane fouling in industrial wastewater are described in detail: pretreatment, membrane cleaning and surface modification. The authors summarize that the composition of the initial solution is an important factor affecting the performance of a reverse osmosis system. In addition, the pretreatment of aqueous solutions before the reverse osmosis separation process leads to a decrease in fouling of the membrane surface and significantly increases the service life of the membrane element. It is effective to use an ultrafiltration separation process as a pretreatment process.


2005 ◽  
Vol 5 (5) ◽  
pp. 1-8 ◽  
Author(s):  
K.Y. Choi ◽  
B.A. Dempsey

The objective of the research was to evaluate in-line coagulation to improve performance during ultrafiltration (UF). In-line coagulation means use of coagulants without removal of coagulated solids prior to UF. Performance was evaluated by removal of contaminants (water quality) and by resistance to filtration and recovery of flux after hydraulic or chemical cleaning (water production). We hypothesized that coagulation conditions inappropriate for conventional treatment, in particular under-dosing conditions that produce particles that neither settle nor are removed in rapid sand filters, would be effective for in-line coagulation prior to UF. A variety of pre-treatment processes for UF have been investigated including coagulation, powdered activated carbon (PAC) or granular activated carbon (GAC), adsorption on iron oxides or other pre-formed settleable solid phases, or ozonation. Coagulation pre-treatment is often used for removal of fouling substances prior to NF or RO. It has been reported that effective conventional coagulation conditions produced larger particles and this reduced fouling during membrane filtration by reducing adsorption in membrane pores, increasing cake porosity, and increasing transport of foulants away from the membrane surface. However, aggregates produced under sweep floc conditions were more compressible than for charge neutralization conditions, resulting in compaction when the membrane filtration system was pressurized. It was known that the coagulated suspension under either charge-neutralization or sweep floc condition showed similar steady-state flux under the cross-flow microfiltration mode. Another report on the concept of critical floc size suggested that flocs need to reach a certain critical size before MF, otherwise membranes can be irreversibly clogged by the coagulant solids. The authors were motivated to study the effect of various coagulation conditions on the performance of a membrane filtration system.


2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


2005 ◽  
Vol 40 (2) ◽  
pp. 191-201 ◽  
Author(s):  
Nadia Berday ◽  
Driss Zaoui ◽  
Abdeljaouad Lamrini ◽  
Mustapha Abi

Abstract The effect of silver carp (Hypophthalmichthys molitrix Val.) feeding activity on the plankton communities in a high-rate pond technology system (HRPTS) effluent was investigated over a period of 100 days. The experiment was conducted at the experimental wastewater treatment plant of the Agronomic and Veterinary Medicine Institute (AVI) of Rabat, Morocco, using a HRPTS in a fish pond receiving the plant effluent. The effluent was highly dominated by phytoplankton (99.95%). Silver carp could survive and grow in the fish pond. Production was 37 kg with a very low mortality rate (12%). The high specific intestine weight (7%) and intake rates of biomass and phytoplankton by silver carp (616 g kg-1 of fish day-1 and 1.6 x 1011 cell kg-1 of fish day-1, respectively) demonstrated the importance of the feeding activity of the fish. Zooplankton intake rates were lower (2 x 107 bodies kg-1 of fish day-1). The high intestine index (3 to 4.3 for fish sizes of 14 to 22 cm) and the dominance of phytoplankton in the gut contents (99.95%) confirmed an omnivorous/ phytoplanctivorous diet. Silver carp were efficient in removing plankton from the HRPTS effluent. The net removal yields of biomass were 285 g m-3 day-1 and 322 g kg-1 of fish day-1, 7 x 1010 algal cells kg-1 of fish day-1 and 8.7 x 107 zooplankton bodies kg-1 of fish day-1, with net removal rates of 47, 64 and 62%, respectively. The total suspended solids concentration decreased from 211 in the inflow to 112 mg L-1 in the fish pond.


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