scholarly journals Assessment of High Salinity Wastewater Treatment with Dewatered Alum Sludge-Aerobic Membrane Reactor

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wei Kang ◽  
Xiyu Cui ◽  
Yanrui Cui ◽  
Linlin Bao ◽  
Kaili Ma

Abstract The discharge of wastewater containing both high salinity and high organic content without prior treatment is detrimental to aquatic life and water hygiene. In order to integrate the advantages of membrane treatment and biological treatment, and exert the phosphorus removal efficiency of dewatered alum sludge, in this study, an aerobic membrane reactor based on dehydrated alum sludge was used to treat mustard tuber wastewater with salinity of 6.8-7.3 % under the conditions of 30 °C, 20 kPa trans-membrane pressure (TMP) and chemical oxygen demand (COD) of 3300-3900 mg/L. Three replicate reactors were applied to assess the operational performance under different organic loading rate (OLR). The results showed that all reactors were effective in removing COD, ammonia nitrogen (NH4 +-N) and soluble phosphate (SP) under the conditions of 30 °C and 20 kPa of TMP. Meanwhile, the effluent concentration of COD, NH4 +-N and SP all increased while OLR was changed from 1.0 to 3.0 kg COD/m3/day, and the effluent COD and NH4 +-N concentration except for SP could reach the B-level of Chinese “Wastewater quality standards for discharge to municipal sewers” when OLR was less than 3.0 kg COD/m3/day. This indicates that dewatered alum sludge-based aerobic membrane reactor is a promising bio-measure for treating high salinity wastewater.

2014 ◽  
Vol 955-959 ◽  
pp. 1907-1910
Author(s):  
Su Chen ◽  
Lei Chao ◽  
Ning Chen ◽  
Lin Shan Wang ◽  
Xue Shao ◽  
...  

When the reactor is added with ectoine of concentrations of 0, 0.1, 1 and 10 mmol/L, the impacts on brine waste treatment efficiency are investigated. The results show that the outflow COD and ammonia nitrogen removal rates are the highest, when the ectoine concentration is 0.1 mmol/L. The brine waste treatment efficiency under addition of ectoine of 1 and 10 mmol/L is even worse than that without ectoine addition. It can be preliminarily determined that the best ectoine dosage is in between 0.1-1.0 mmol/L. When ectoine concentrations added in reactors are 0.2, 0.5, 0.8 and 1.0 mmol/L, the results show that the average reactor outflow COD and ammonia nitrogen removal rates are increased compared with those of reactor without adding ectoine. But when ectoine of 1.0 mmol/L is added, the outflow COD and ammonia nitrogen removal rates decrease. When ectoine dosage is 0.5 mmol/L, the reactor outflow COD and ammonia nitrogen values are the lowest, the removal rates are the highest, the average COD removal rate is 74.46%, and the average ammonium nitrogen removal rate is 54.97%. Compared with reactor without adding ectoine, COD and ammonium nitrogen removal rates are increased by 13.16% and 26.81%. Therefore, the best dosage of ectoine is 0.5 mmol/L.


2020 ◽  
Vol 27 (1) ◽  
pp. 129-137
Author(s):  
Şevket Tulun

AbstractThe composition of local solid waste consists mainly of biodegradable waste with high moisture and organic content. After being landfilled, the waste decomposes through a series of combined physico-chemical and biological processes, resulting in the generation of landfill leachate. Unless treated properly, the leachate poses a serious threat to the environment and to public health. In this study, the use of an engineered system consisting of an up-flow anaerobic sludge blanket reactor and a vertical flow subsurface constructed wetland for the treatment of landfill leachate was investigated. The leachate obtained from a landfill facility in Aksaray, Turkey was fed into both systems and laboratory tests showed that, over the 6-week study period, the systems were able to efficiently remove chemical oxygen demand (88.6 %) and total nitrogen (80.7 %). The results of this study suggested that Typha angustifolia significantly increased the removal of total nitrogen. The higher ammonia removal occurred in the anaerobic system and also the removal efficiency increased in planted bed, it is presumed to be the result of the ammonia nitrogen uptake by the roots of the plant.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Zarimah Mohd Hanafiah ◽  
Wan Hanna Melini Wan Mohtar ◽  
Hassimi Abu Hasan ◽  
Henriette Stokbro Jensen ◽  
Anita Klaus ◽  
...  

Abstract The fluctuation of domestic wastewater characteristic inhibits the current conventional microbial-based treatment. The bioremediation fungi has received attention and reported to be an effective alternative to treat industrial wastewater. Similar efficient performance is envisaged for domestic wastewater whereby assessed performance of fungi for varying carbon-to-nitrogen ratios in domestic wastewater is crucial. Thus, the performance of pre-grown wild-Serbian Ganoderma lucidum mycelial pellets (GLMPs) was evaluated on four different synthetic domestic wastewaters under different conditions of initial pH (pH 4, 5, and 7) and chemical oxygen demand (COD) to nitrogen (COD/N) ratio of 3.6:1, 7.1:1, 14.2:1, and 17.8:1 (C3.6N1, C7.1N1, C14.2N1, and C17.8N1). The COD/N ratios with a constant concentration of ammonia–nitrogen (NH3–N) were chosen on the basis of the urban domestic wastewater characteristics sampled at the inlet basin of a sewage treatment plant (STP). The parameters of pH, COD, and NH3–N were measured periodically during the experiment. The wild-Serbian GLMPs efficiently removed the pollutants from the synthetic sewage. The COD/N ratio of C17.8N1 wastewater had the best COD and NH3–N removal, as compared to the lower COD/N ratio, and the shortest treatment time was obtained in an acidic environment at pH 4. The highest percentage for COD and NH3–N removal achieved was 96.0% and 93.2%, respectively. The results proved that the mycelium of GLMP has high potential in treating domestic wastewater, particularly at high organic content as a naturally sustainable bioremediation system.


2013 ◽  
Vol 67 (11) ◽  
pp. 2549-2559 ◽  
Author(s):  
S. Wang ◽  
J. Hovland ◽  
R. Bakke

The anaerobic biodegradation of reclaimer MEA (monoethanolamine) waste (MEAw) with easily degradable co-substrates was investigated in a laboratory-scale bioreactor at room temperature during a 160 d experimental run. The reactor that was constructed with three phases to facilitate attached biofilm and suspended biomass retention for degradation of the complex and challenging MEAw performed well. A feed strategy of step-wise increasing organic loading rate (OLR) by either increasing feed MEAw concentration or the hydraulic loading rate was applied. The system performance was evaluated by chemical oxygen demand (COD) removal efficiency, methane yield, MEA removal, and the accumulation of ammonia and volatile fatty acid (VFA). The total COD removal efficiency initially was 93% when the feed was mainly easily degradable co-substrate. The total removal dropped to 75% at the end when MEAw constituted 60% of the feed COD. Ion chromatography results show that the MEA and some unidentified feed chemicals were almost completely consumed. The main products of MEAw degradation were ammonia, VFAs and biogas. The ammonia nitrogen concentration reached about 2.0 g/L, which may explain the observed inhibition of acetoclastic methanogenesis leading to acetate accumulation. Methane accounted for up to 80% of the biogas generated. The highest methane yield was 0.34 L/g-COD while the yield was 0.16 L/g-COD at the highest load. This study shows that more than 80% reclaimer MEAw COD degradation with a co-substrate can be maintained in a hybrid anaerobic bioreactor operated in a wide loading range.


Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3871
Author(s):  
Courtney Moore ◽  
Weijue Gao ◽  
Pedram Fatehi

The radical polymerization of acid-washed and unwashed softwood kraft lignin with [2-(methacryloyloxy) ethyl] trimethylammonium chloride (METAC) was attempted to investigate the production of lignin-based flocculants for simulated wastewater. The incorporation of METAC onto lignin resulted in a cationic charge density (2.3–3.3 meq/g), increased water solubility (89–96% in neutral pH), and increased molecular weight (70,000–210,000 g/mol) of lignin. The lignin–METAC polymers generated from acid-washed lignin had higher molecular weights than those generated from unwashed lignin. The lignin–METAC polymers showed lower resistance to thermal decomposition than unmodified lignin due to the inclusion of PolyMETAC. The unmodified acid-washed lignin samples did not significantly affect the COD of the wastewater, while the unmodified unwashed lignin samples contributed to the COD, implying that unmodified lignin was not suitable for wastewater treatment. The flocculation of wastewater with lignin–METAC led to the chemical oxygen demand (COD) reduction of 17–23% and total organic carbon (TOC) drop of 51–60%. The lignin–METAC polymer with the highest molecular weight (produced from acid-washed lignin) reached the highest COD removal, while lignin–METAC polymer with the highest charge density (produced from unwashed lignin) reached the highest TOC removal. Focused beam reflectance measurement (FBRM) studies revealed that the lignin–METAC polymer produced from acid-washed lignin with a high molecular weight generated larger and more flocs in wastewater than the lignin–METAC polymer produced from unwashed lignin. The comparison of theoretical and experimental dosages required for neutralizing the charges of wastewater demonstrated that charge neutralization was the main flocculation mechanism, although a bridging mechanism was also involved for component removals from wastewater. The use of 1 mg/L of alum along with 65 mg/L lignin–METAC in a dual coagulation–flocculation system led to higher average phosphorous (42%) and COD (44%) removals than the singular flocculation system only using 65 mg/L of lignin–METAC (with phosphorous removals of 3.4% and COD removals of 18.7%). However, lignin–METAC flocculant slightly increased the ammonia–nitrogen content in both singular flocculation and dual coagulation–flocculation systems due to the residual ammonia content of lignin–METAC. The coagulation–flocculation system determined that the use of lignin–METAC (65 mg/L) could reduce the alum dosage significantly while maintaining a similar organic content reduction of 44% for wastewater.


2016 ◽  
Vol 11 (4) ◽  
pp. 774-783 ◽  
Author(s):  
Alexsandro dos Santos Reis ◽  
Savia Gavazza ◽  
Simone Machado Santos

For this work, a pilot scale anaerobic digester was used to assess the treatability of food waste from a canteen. The digester was operated for 720 days, and its efficiency in removing organic matter and suspended solids as well as producing biogas were assessed. At the beginning of operation, the digester failed and alkalinity buffering was required until stabilization. A maximum chemical oxygen demand (COD) and total solids removal efficiency of 71% and 87% were, respectively, found for the organic loading rate of 0.59 kg COD m−3 d−1. The maximum gas production rate and specific gas production were 0.4 m3 m−3 d−1 and 0.76 m3 (kg TVS)−1, respectively, with a methane average of 60% in the biogas composition. Although achieving satisfactory levels of pollutant removal, the effluent characteristics particularly for COD and ammonia nitrogen indicated that recirculation is the best option to use effluent.


2015 ◽  
Vol 1092-1093 ◽  
pp. 1033-1036
Author(s):  
Kang Xie ◽  
Jing Song ◽  
Si Qing Xia ◽  
Li Ping Qiu ◽  
Jia Bin Wang ◽  
...  

In this study, high salinity wastewater was treated by an intermittently aerated membrane bioreactor (IAMBR) and the salinity loadings were set at 35g/L. The activated sludge was inoculated from the municipal wastewater treatment plant. The influent salinity level gradually increased from 0 to 35 g/L with every 5 g/L. With the salt concentration increased to 35 g/L, the performance of IAMBR was significantly affected by higher salinity. The removal efficiencies of the total organic carbon (TOC), ammonia nitrogen (NH4+-N) and total nitrogen (TN) were about 83%, 70% and 51%, respectively. It is indicated that the domestication of activated sludge from municipal wastewater treatment cannot obtain a better performance at high salinity.


2013 ◽  
Vol 67 (9) ◽  
pp. 2124-2131 ◽  
Author(s):  
Moonil Kim ◽  
Dukkyu Han ◽  
Fenghao Cui ◽  
Wookeun Bae

The treatment of textile wastewater is difficult because of its recalcitrant organic content. The biological removal of recalcitrant organics requires a long retention time for microbial growth. Activated sludge was immobilized in a polyethylene glycol pellet to allow for sufficient sludge retention time. The pellets were filled in an aerobic cell-immobilized pellet column (CIPC) reactor in order to investigate the removal of recalcitrant organics from textile wastewater. A textile wastewater effluent treated by a conventional activated sludge reactor was used as a target wastewater. The chemical oxygen demand (COD) removal efficiency of the aerobic CIPC reactor at various empty bed contact times was in the range of 42.2–60.5%. Half of the input COD was removed in the lower part (bottom 25% of the reactor volume) of the reactor when the organic loading rate was less than 1.5 kg COD/(m3•d). About 15–30% of the input COD was removed in the remaining part of the column reactor. The COD removed in this region was limitedly biodegradable. The biodegradation of recalcitrant organics could be carried out by the interactional functions of the various bacteria consortia by using a cell-immobilization process. The CIPC process could effectively treat textile wastewater using a short retention time because the microorganisms that degrade limitedly biodegradable organics were dominant in the reactor.


Catalysts ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 76
Author(s):  
Emmanuel Kweinor Tetteh ◽  
Sudesh Rathilal

This study presents the bio-photocatalytic upgrading of biogas utilising carbon dioxide (CO2) as a potential option for beginning fossil fuel depletion and the associated environmental risks in the pursuit of sustainable development. Herein, magnetite photocatalyst (Fe-TiO2) was employed with an integrated anaerobic-photomagnetic system for the decontamination of municipality wastewater for biogas production. The Fe-TiO2 photocatalyst used, manufactured via a co-precipitation technique, had a specific surface area of 62.73 m2/g, micropore volume of 0.017 cm3/g and pore size of 1.337 nm. The results showed that using the ultraviolet-visible (UV-Vis) photomagnetic system as a post-treatment to the anaerobic digestion (AD) process was very effective with over 85% reduction in colour, chemical oxygen demand (COD) and turbidity. With an organic loading rate (OLR) of 0.394 kg COD/L·d and hydraulic retention time (HTR) of 21 days, a 92% degradation of the organic content (1.64 kgCOD/L) was attained. This maximised the bioenergy production to 5.52 kWh/m3 with over 10% excess energy to offset the energy demand of the UV-Vis lamp. Assuming 33% of the bioenergy produced was used as electricity to power the UV-Vis lamp, the CO2 emission reduction was 1.74 kg CO2 e/m3, with good potential for environmental conservation.


2014 ◽  
Vol 4 (02) ◽  
Author(s):  
Rina S. Soetopo ◽  
Sri Purwati ◽  
Henggar Hardiani ◽  
Mukharomah Nur Aini ◽  
Krisna Adhitya Wardhana

A continuous pilot scale study has been conducted to investigate the effectiveness of anaerobic digestion of biological sludge. The sludge has a total solid content of 0.53% - 1.1%, pH of 7.20 to 7.32. Its organic content is about 97 %, The research were conducted in two stages, which are acidification (performed in 3 m3 the Continously Stirred Tank Reactor/CSTR at pH of 5.5 to 6.0) and methanation (performed in 5 m3 the Up Flow Anaerobic Sludge Blanket/UASB reactor at pH 6.5 to 7.0). The retention time (RT) was gradually shortened from 6 days to 1 day for acidification and from 8 days to 2 days for methanation. The results showed that operating the CSTR at the RT of 1 day and the organic loading of 8.23 g Volatile Solid (VS)/m3.day could produce Volatile Fatty Acid (VFA) at an average value of 17.3 g/kg VS.day. Operating the UASB reactor at the RT of 2 days and the organic loading (Chemical Oxygen Demand/COD) of 2.4 kg COD/m3.day could produce biogas at an average value of 66.3 L/day, with an average methane content of 69.9%, methane rate of 0.17 L CH4/g COD reduction or 19.06 L CH4/kg VS. Furthermore, methanation could reduce COD at an average value of 51.2 %, resulting in the effluent average value of COD filtrate and COD total of 210.1 mg/L and 375.2 mg /L, respectively.Keywords: acidification, methanation, CSTR, UASB, biogas ABSTRAKPercobaan digestasi anaerobik lumpur IPAL biologi industri kertas secara kontinyu skala pilot telah dilakukan di industri kertas dengan tujuan mengkaji efektivitas proses digestasi anaerobik dalam mengolah lumpur tersebut. Lumpur yang digunakan memiliki total solids sekitar 0,53% – 1,1%, pH netral (7,20 – 7,32) dengan komponen utama senyawa organik sekitar 97%. Percobaan dilakukan dalam dua tahap yaitu asidifikasi dalam reaktor CSTR berkapasitas 3 m3 pada pH 5,5 – 6,0 dan metanasi dalam reaktor UASB berkapasitas 5 m3 pada pH 6,5 – 7,0. Percobaan dilakukan dengan waktu retensi yang dipersingkat secara bertahap dari 6 hari ke 1 hari untuk proses asidifikasi dan dari 8 hari ke 2 hari untuk proses metanasi. Hasil percobaan menunjukkan bahwa pengoperasian reaktor CSTR dengan waktu retensi 1 hari dan beban organik 8,3 g VS/m3.hari dapat menghasilkan VFA rata-rata 17,3 g/kg VS.hari dengan kisaran 8,36 – 30,59 g/kg VS.hari, sedangkan pengoperasian reaktor UASB pada waktu retensi 2 hari dan beban organik 2,4 kg COD/m3.hari dapat menghasilkan biogas rata-rata 66,3 L/hari dengan kadar metana rata-rata 69,9% atau 0,17 L CH4/g COD reduksi atau 19,06 L CH4/kg VS. Selain itu proses metanasi dapat menurunkan COD terlarut rata-rata 51,2%, dengan konsentrasi efluen COD terlarut  rata-rata 210,1 mg/L dan COD total rata-rata 375,2 mg/L.Kata kunci: asidifikasi, metanasi, CSTR, UASB, biogas


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