Isotopic-geochemical features of thermal water of the Kyndyg deposit (Republic of Abkhazia)

Subject. The aim of the work is to study the mechanism and sources of water formation, as well as the peculiarities of carbonate mineralization in the aquifer of the Kyndyg thermal water deposit. Materials and methods. The samples of water (8) and deposited carbonates (15), collected at different seasons at three sites, characterized by different temperatures and distances from the source, were investigated. pH, Eh, and electrical conductivity were determined by an electrochemical method. For the determination of HCO3 – , Cl– , SO4 2–, titrimetric, mercurymetric and turbidimetric methods were used. Trace element composition was determined by ICP-MS (NexION 300S); strontium isotopic composition – by MC-ICP-MS (Neptune Plus) using the bracketing technique after Sr chromatographic separation. Results. The chloride-calcium hydrochemical type prevails in the studied waters. A number of trace elements in water exceeds the clarke concentrations for groundwater in the supergene zone of mountain landscapes. 87Sr/86Sr isotope ratios (0.7065–0.7072) in thermal waters suggest that their composition is determined rather by the isotopic characteristics of the rocks through which water drains than by the influence of sea water. Among the newly formed carbonates, aragonite prevails. In contrast to thermal water, the concentrations of most metals in carbonates are below the clarke values; only Sr and Se are increased, which content is significantly increased in water as well. Deposited carbonates are characterized by 87Sr/86Sr values (0.7028–0.7074), which are lower than in the source thermal waters. Conclusions. On the basis of hydrogeological, hydrochemical and geochemical data, it can be assumed that the waters of this aquifer complex are formed mainly due to fresh fractured karst waters of lower Cretaceous limestones with submerged monocline dipping into the zone of slow circulation and mixing with sedimentogenic sodium chloride waters. The geochemical data and the presence of scandium anomaly suggest that the underlying Jurassic volcanogenic rocks also participate in water exchange.

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NEW ISOTOPE-GEOCHEMICAL DATA ON THERMAL WATERS OF THE TALSKOE DEPOSIT (MAGADAN OBLAST)

Tikhookeanskaya Geologiya ◽

10.30911/0207-4028-2021-40-6-111-119 ◽

2021 ◽

Vol 40 (6) ◽

pp. 111-119

Author(s):

I.V. Bragin ◽

◽

G.A. Chelnokov ◽

N.A. Kharitonova ◽

◽

...

Keyword(s):

Thermal Water ◽

Atmospheric Precipitation ◽

Geochemical Data ◽

Thermal Waters ◽

Alkaline Ph ◽

Magadan Oblast ◽

Sulfate Ion ◽

Water Formation ◽

Stable Oxygen ◽

Deep Reservoir

In this paper, we summarize new data on the chemical and isotopic composition of thermal wa-ters of the Talskoye deposit in the Magadan Oblast. We were the first to obtain the data on the content of stable oxygen (δ18O) and hydrogen (δD) isotopes in thermal and background waters, as well as oxygen (δ18O) and carbon in bicarbonate ion (δ13C), even though this is the largest ex-ploited deposit of low-mineralized alkaline nitric thermal waters in the region. The thermal water is fresh (M = 980 mg/l), alkaline (pH = 8.9), hydrocarbonate-chloride-sulphate sodium with a high content of fluorine (up to 17 mg/l) and silicic acid (up to 152 mg/l). The deposit is fed by atmospheric precipitation; we did not find traces of melting underground ice supply. A sequential scheme for calculating the temperature of a deep reservoir was applied, which allowed the temperature of water formation to be constrained at 108 °C suggesting an input of fluids rich in potassium and sulfate ion.

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Radiocarbon Concentration and Origin of Thermal Karst Waters in the Region of the Bükk Mountains, Northeastern Hungary

Radiocarbon ◽

10.1017/s0033822200031039 ◽

1995 ◽

Vol 37 (2) ◽

pp. 543-550 ◽

Cited By ~ 1

Author(s):

Ede Hertelendi ◽

Mihály Veres ◽

István Futó ◽

Éva Svingor ◽

Lajos Mikó ◽

...

Keyword(s):

Thermal Water ◽

Inorganic Carbon ◽

Dissolved Inorganic Carbon ◽

Karst Aquifer ◽

Thermal Waters ◽

Karst Water ◽

Recharge Area ◽

Karst Springs ◽

Karst Waters ◽

Karst Systems

Karst springs are abundant in Hungary, and many are thermal (temperatures >30°). As thermal springs are a significant part of Hungary's water resources, it is important to quantify their travel times in the karst systems. Thus, we chose to measure T and δ18O in the water and δ13C and 14C in dissolved inorganic carbon (DIC) in water from 50 thermal and nonthermal springs and wells in the Bükk Mountains, northeastern Hungary. Environmental isotope data confirm the karst water-flow pattern implied by earlier studies. We found the water in warm springs and boreholes to be mixtures of cold young and old thermal water. We also determined short mean-residence times for some large cold springs. The 14C activities measured in these springs indicate that the recharge area of the karst aquifer is open to the atmosphere, and atmospheric CO2 contributes to the 14C activity of these groundwaters. We observed good correlation between 14C and 3H activities and we determined negative correlations between 14C concentration and δ13C values and temperature. From the δ18O values of the oldest thermal waters, we attribute their origin to precipitation during colder temperatures than at present.

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Static and Dynamic Studies of Gasoline in View of its Octane Number and its Toxic Effect

JOURNAL OF ADVANCES IN CHEMISTRY ◽

10.24297/jac.v12i7.2802 ◽

2013 ◽

Vol 12 (7) ◽

pp. 451-459

Author(s):

Ashraf Yehia El-Naggar ◽

Mohamed A. Ebiad

Keyword(s):

Toxic Effect ◽

Aromatic Hydrocarbons ◽

Octane Number ◽

Liquid Fuel ◽

Positive Impact ◽

Hydrocarbon Composition ◽

Different Temperatures ◽

Different Seasons ◽

The One ◽

The Impact

Gasoline come primarily from petroleum cuts, it is the preferred liquid fuel in our lives. Two gasoline samples of octane numbers 91 and 95 from Saudi Arabia petrol stations were studied. This study was achieved at three different temperatures 20oC, 30oC and 50oC representing the change in temperatures of the different seasons of the year. Both the evaporated gases of light aromatic hydrocarbons (BTEX) of gasoline samples inside the tank were subjected to analyze qualitatively and quantitatively via capillary gas chromatography. The detailed hydrocarbon composition and the octane number of the studied gasoline samples were determined using detailed hydrocarbon analyzer. The idea of research is indicating the impact of light aromatic compounds in gasoline on the toxic effect of human and environment on the one hand, and on octane number of gasoline on the other hand. Although the value of octane number will be reduced but this will have a positive impact on the environment as a way to produce clean fuel.

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A Comparative Electrochemical and Morphological Investigation on the Behavior of NiCr and CoCr Dental Alloys at Various Temperatures

Metals ◽

10.3390/met11020256 ◽

2021 ◽

Vol 11 (2) ◽

pp. 256

Author(s):

Florentina Golgovici ◽

Mariana Prodana ◽

Florentina Gina Ionascu ◽

Ioana Demetrescu

Keyword(s):

Low Temperatures ◽

Artificial Saliva ◽

Electrochemical Stability ◽

Morphological Investigation ◽

Dental Alloys ◽

Ion Release ◽

Icp Ms ◽

Different Temperatures ◽

Good Concordance ◽

Increasing Temperature

The purpose of our study is to compare the behavior of two reprocessed dental alloys (NiCr and CoCr) at different temperatures considering the idea that food and drinks in the oral cavity create various compositions at different pH levels; the novelty is the investigation of temperature effect on corrosion parameters and ion release of dental alloys. Electrochemical stability was studied together with morphology, elemental composition and ions release determination. The results obtained are in good concordance: electrochemistry studies reveal that the corrosion rate is increasing by increasing the temperature. From SEM coupled with EDS, the oxide film formed on the surface of the alloys is stable at low temperatures and a trend to break after 310K. ICP-MS results evidence that in accordance with increasing temperature, the quantities of ions released from the alloys immersed in artificial saliva also increase, though they still remain small, less than 20 ppm.

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The Survival of Haloferax mediterranei under Stressful Conditions

Microorganisms ◽

10.3390/microorganisms9020336 ◽

2021 ◽

Vol 9 (2) ◽

pp. 336

Author(s):

Laura Matarredona ◽

Mónica Camacho ◽

Basilio Zafrilla ◽

Gloria Bravo-Barrales ◽

Julia Esclapez ◽

...

Keyword(s):

Inductively Coupled Plasma ◽

Sea Water ◽

Industrial Applications ◽

Growth Responses ◽

Haloferax Mediterranei ◽

Inductively Coupled ◽

Icp Ms ◽

Wide Range ◽

High Metal ◽

Plasma Mass Spectrometry

Haloarchaea can survive and thrive under exposure to a wide range of extreme environmental factors, which represents a potential interest to biotechnology. Growth responses to different stressful conditions were examined in the haloarchaeon Haloferax mediterranei R4. It has been demonstrated that this halophilic archaeon is able to grow between 10 and 32.5% (w/v) of sea water, at 32–52 °C, although it is expected to grow in temperatures lower than 32 °C, and between 5.75 and 8.75 of pH. Moreover, it can also grow under high metal concentrations (nickel, lithium, cobalt, arsenic), which are toxic to most living beings, making it a promising candidate for future biotechnological purposes and industrial applications. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analysis quantified the intracellular ion concentrations of these four metals in Hfx. mediterranei, concluding that this haloarchaeon can accumulate Li+, Co2+, As5+, and Ni2+ within the cell. This paper is the first report on Hfx. mediterranei in which multiple stress conditions have been studied to explore the mechanism of stress resistance. It constitutes the most detailed study in Haloarchaea, and, as a consequence, new biotechnological and industrial applications have emerged.

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Comparison of the performance of FI-ICP-MS and FI-ETV-ICP-MS systems for the determination of trace elements in sea water

Analytica Chimica Acta ◽

10.1016/s0003-2670(00)01309-x ◽

2001 ◽

Vol 438 (1-2) ◽

pp. 215-225 ◽

Cited By ~ 14

Author(s):

Dirce Pozebon ◽

Valderi Luiz Dressler ◽

Adilson José Curtius

Keyword(s):

Trace Elements ◽

Sea Water ◽

Icp Ms

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Comparison of Magma Oxygen Fugacity and Zircon Hf Isotopes between Xianglushan Tungsten-Bearing Granite and Late Yanshanian Granites in Jiangxi Province, South China

Minerals ◽

10.3390/min10020106 ◽

2020 ◽

Vol 10 (2) ◽

pp. 106

Author(s):

Xing-Yuan Li ◽

Jing-Ru Zhang ◽

Chun-Kit Lai

Keyword(s):

Oxygen Fugacity ◽

South China ◽

Granitic Magma ◽

Geochemical Data ◽

Jiangxi Province ◽

Magmatic Zircon ◽

Late Mesozoic ◽

Icp Ms ◽

T Values ◽

Southern Jiangxi Province

Jiangxi Province (South China) is one of the world’s top tungsten (W) mineral provinces. In this paper, we present a new LA-ICP-MS zircon U-Pb age and Hf isotope data on the W ore-related Xianglushan granite in northern Jiangxi Province. The magmatic zircon grains (with high Th/U values) yielded an early Cretaceous weighted mean U-Pb age of 125 ± 1 Ma (MSWD = 2.5, 2σ). Zircon εHf(t) values of the Xianglushan granite are higher (−6.9 to −4.1, avg. −5.4 ± 0.7) than those of the W ore-related Xihuanshan granite in southern Jiangxi Province (−14.9 to −11.2, avg. −12.5 ± 0.9), implying different sources between the W ore-forming magmas in the northern and southern Jiangxi Province. Compiling published zircon geochemical data, the oxygen fugacity (fO2) of the late Yanshanian granitic magmas in Jiangxi Province (the Xianglushan, Ehu, Dahutang, and Xihuashan plutons) were calculated by different interpolation methods. As opposed to the W ore-barren Ehu granitic magma, the low fO2 of the Xianglushan granitic magma may have caused W enrichment and mineralization, whilst high fO2 may have led to the coexistence of Cu and W mineralization in the Dahutang pluton. Additionally, our study suggests that the absence of late Mesozoic Cu-Mo mineralization in the Zhejiang, Jiangxi, and Anhui Provinces (Zhe-Gan-Wan region) was probably related to low fO2 magmatism in the Cretaceous.

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