scholarly journals Recommendations for Ensuring Environmental Safety of Ecosystem Restoration After Fire

Purpose. To find ways to improve the soil properties of forest ecosystems after the action of the pyrogen- ic factor: to propose technological measures to restore the quality and improve the soil properties of the ecosystem; to prove the effectiveness of using clay in soil cleaning as a sorbent. Methods. The introduction of clay as a potential sorbent for cleaning fertile soils from trace metals is proposed. The mineral composition of the clay was determined by X-ray phase analysis. Clay materials can be successfully used in adsorption cleaning technologies. The method of phytoremediation with the help of dandelion to concentrate trace metal was used also. The concentration of trace metal was determined by atomic adsorption analysis. Results. The task of the experimental study was to substantiate the possibility of using cheap natural clay raw materials without its prior activation to remove trace metals from the soil solution. In the case of post-pyrogenic relaxation of ecosystems under conditions of man-caused load, the soil in the restored area may be contaminated with VM and other hazardous substances. The clay of the Kharkiv region was chosen for the experiment. The experiment proved the effectiveness of the use of clay in soil purification as a sorbent, and phytoremediation of dandelion in relation to heavy metals. Thus, both technical and biological methods of VM sorption to prepare the soil for planting can be recommended for the restoration of the forest ecosystem after a fire. The proposed technological measures to restore the quality and soil properties of the ecosystem include the implementation of design and survey work, including field research; implementation of the state ecological research (monitoring); cleaning the affected area from damaged trees; reclamation of soil fertility of regenerative territories, provided by design of restoration, depending on characteristic features of damages of sites and the subsequent application of regenerative territories. Conclusions. At postpyrogenic relaxation of ecosystems, in the conditions of technogenic loading, the efficiency of using clay in soil cleaning as a sorbent and phytoremediation with dandelion in relation to heavy metals has been proved.

Author(s):  
Philip S. Rainbow

AbstractA century or so after the cessation of almost all mining in Cornwall, certain estuaries still have extremely high sediment concentrations of toxic trace metals, particularly copper and arsenic, but also lead and zinc. These high trace metal loadings in the sediments are to a large degree bioavailable to the local infauna, especially sediment-ingesting invertebrates. Some sediment trace metal bioavailabilities are so high as to be of ecotoxicological concern, with deleterious effects on the local biota at levels of biological organization up to and including changed community structure. The estuaries of interest here are those of the Rivers Carnon (Restronguet Creek), Tamar (and Tavy), Gannel, West Looe and Hayle. These estuaries are especially attractive field sites for comparative trace metal ecophysiology and ecotoxicology research for they lack the confounding presence of other anthropogenic contaminants inevitably present in most estuaries in the developed world. The estuaries also offer a range of combinations of different trace metals and a comparative gradient of sediment bioavailabilities of these trace metals.


Author(s):  
N. A. Vinogradova

The influence of technogenic pollution on the dynamics of the content of biologically active substances and the antioxidant activity of the previously poorly studied species Rosa lupulina Dubovik was studied for the first time. The compliance of R. lupulina fruits growing in the Donbas with the requirements of regulatory documentation was evaluated. The relationship between the content of heavy metals (lead, cadmium, mercury) in the fruits of R. lupulina and the soil on which they grow was studied. The environmental safety of raw materials was evaluated.


2021 ◽  
pp. 71-74
Author(s):  
С.В. ШИЛОВ ◽  
Г.О. УСТЕНОВА ◽  
Л.Н. КИЕКБАЕВА ◽  
И.С. КОРОТЕЦКИЙ

Целью данной работы являлось изучение минерального состава надземной части и корня растения Onosma gmelinii. Количественное содержание минеральных элементов определяли методом атомно-абсорбционной спектрометрии на базе Центра физико-химических методов исследования и анализа. Концентрацию тяжелых металлов в растительном сырье определяли в ТОО «Нутритест». В результате исследования установлено, что элементный состав растения Onosma gmelinii включают 9 элементов. Анализ тяжелых металлов свидетельствует об экологической безопасности растительного сырья. Полученные данные позволяют утверждать о наличии значительного количества важных минеральных веществ в растении и перспективности использования данного сырья в медицине The goal of this work was to study the mineral composition of the aerial part and root of the plant Onosma gmelinii. The quantitative content of mineral elements was determined by atomic absorption spectrometry at the Center of Physicochemical Methods of Research and Analysis. The concentration of heavy metals in the plant raw material was determined at Nutritest LLP. As a result of the study, it was found that the elemental composition of the Onosma gmelinii plant includes 9 elements. Analysis of heavy metals evidences the environmental safety of plant raw materials. The data obtained allow us to assert the presence of a significant amount of essential minerals in the plant and the prospects for the use of this raw material in the medical field.


2020 ◽  
pp. 160-167
Author(s):  
S. Razanov ◽  
S. Tkachyk ◽  
A. Razanova

The aim of the research is to study the intensity of heavy metals accumulation in milk thistle leaf mass under fertilization with the latest types of fertilizers and to assess the environmental safety of such raw materials. Two experiments were laid in the research: the effect of fertilizing milk thistle with organo-mineral fertilizer Growth-concentrate on the intensity heavy metals accumulation by its leaf mass; the effect of fertilizing milk thistle with chelated fertilizers Phosphorus-chelate and Potassium-chelate on the intensity on heavy metals accumulation by the leaf mass. The use of a chelated Phosphorus chelate fertilizer for the fertilization of milk thistle crops leads to a 1.1 times decrease in the contamination of its leaf mass with cadmium and copper in comparison with the option without fertilizing its crops, and the increase in the concentration of lead and zinc compared to the control is insignificant and is within the range errors of experience. The use of fertilization of crops of milk thistle chelated fertilizer Potassium-chelate helps to reduce the contamination of its leaf mass with cadmium compared to the control, and the change in its contamination with copper is within the margin of error. At the same time, replacing the Growth-concentrate fertilizer with Phosphorus-chelate or Potassium-chelate when fertilizing milk thistle crops will lead to a decrease in the contamination of its leaf mass with lead, cadmium and copper, but will increase the contamination with zinc, compared to the control. The most environmentally safe leaf raw material of milk thistle in terms of lead, cadmium and copper content will be observed when fertilizing its crops with chelated fertilizers Phosphorus-chelate, and in terms of zinc content – when fertilizing with organo-mineral fertilizer Growth-concentrate. It is advisable to use Phosphorus-chelate fertilizer for the plant fertilization to reduce the contamination of the leaf mass of the medicinal raw material of milk thistle with heavy metals, in particular cadmium – by 9 % and copper – by 11 %,. To reduce contamination of the leaf mass with zinc by 81 %, it is recommended to use the organic-mineral fertilizer Growth-concentrate. Key words: milk thistle, medicinal raw materials, environmental safety, heavy metals, pollution, fertilizers.


2019 ◽  
Vol 28 (3) ◽  
pp. 409-416 ◽  
Author(s):  
Y. Buts ◽  
V. Asotskyi ◽  
O. Kraynyuk ◽  
R. Ponomarenko ◽  
P. Kovalev

In soils after fires trace metals sharply change their migration ability and can form poorly-soluble hydroxides which are hazardous chemical formations, the nature of which has not been fully explored until now. In addition, in interstitial water, there is a probability of the formation by metals of hydroxocomplexes with different amounts of hydroxide ions. We studied the range of dynamics of migration capacity of sedimentation of hydroxides and the region of predominance of soluble hydroxocomplexes by developing logarithmic concentration diagrams (LCD). We developed logarithmic concentration diagrams, the equation of formation of prevailing forms, using which it is possible to clearly determine the regions of maximum sedimentation (accumulation) of hydroxides and hydroxocomplexes of heavy metals after the influence of the pyrogenic factor. The obtained calculations of the results of the predictive modeling of the dynamics of migration capacity and postpyrogenic migration geochemical processes in ecogeosystems have been organized and systematized. The determined patterns can be useful for the analysis of possible geochemical migration (accumulation) of heavy metals in ecological systems in the study of technogenic and ecological situation after fires. Based on the calculations made, mathematical models of heavy metals` behaviour are developed, which are useful for drawing up a forecast estimation of the dynamics of their geochemical migration and accumulation in ecological systems as a result of the influence of the technogenic loading of the pyrogenic factor. The conditions of concentration and migration of compounds of heavy metals were determined, and the equation for calculating the concentration of mobile forms of trace metal compounds has been developed. The developed map of the activity of geochemical migration of heavy metals under the influence of the technogenic loading of pyrogenic factor will make it possible to elaborate the migratory capacity of trace metals and provide a forecast of their behaviour in ecological systems after fires. This will allow preventive measures to be taken to ensure environmental safety and prevent adverse effects on human health and the condition of the components of the environment. The creation of similar cartographic material may be extrapolated to other regions of Ukraine, affected by technogenic loading of pyrogenic factor. The development of logarithmic concentration diagrams allows us to predict the capacity of compounds of lead, nickel, chromium,and copper for migration or accumulation of heavy metals due to changes in the acidity of soils under the influence of the pyrogenic factor. Having used the map of the soils of the Kharkiv region, we analyzed and provided a forecast of the migration ability of lead compounds in cases of fire in different types and subtypes of different environmental conditions.


Author(s):  
Weijun Guo ◽  
Jibing Zou ◽  
Sihong Liu ◽  
Xuewen Chen ◽  
Xiangpeng Kong ◽  
...  

Spatial–seasonal variations in dissolved heavy metals in surface seawater were analyzed based on surveys at 87 sampling sites and water samples from six rivers across Liaodong Bay. The concentrations of copper (Cu), lead (Pb), cadmium (Cd), and zinc (Zn) had ranges of 0.20–40.00 (5.45 ± 5.67), 0.51–33.64 (4.68 ± 3.93), 0.03–13.47 (2.22 ± 2.01), and 0.50–80.09 μg/L (14.22 ± 16.32), respectively, throughout the four seasons of 2020. The trace metal concentration showed a spatial gradient of high to low from river to estuary and from inshore to offshore areas. A combination of pollution levels and marine sensitivity was employed to assess the pollution degree of the heavy metals. As a whole, the single pollution factors of trace metals in Liaodong Bay were ranged in the order Pb > Zn > Cu > Cd. The total pollution degree was relatively high in autumn and summer due to increased riverine inputs after the rainy season, while relatively low in spring and winter. These findings provide baseline data for future targeting policies to protect marine environments in Liaodong Bay.


Author(s):  
I. A. Ilina ◽  
I. A. Machneva ◽  
E. S. Bakun

  The article is devoted to the study of the chemical composition, physical and thermal-pfysical characteristics of damp apple pomaces and the identifying patterns of influence of drying temperature the functional composition and gel-forming ability of pectin. The research is aimed at obtaining initial data for the subsequent calculation of the main technological, hydro-mechanical, thermal, structural and economic characteristics of devices for drying the plant raw materials, ensuring the environmental safety and high quality of pectin-containing raw materials, the reducing heat and energy costs. As a result of the study of the thermal characteristics of apple pomaces, the critical points (temperature conductivity – 16.5 x 10-8 m2/s, thermal conductivity – 0.28 W/m K, heat capacity – 1627 j/(kg K)) at a humidity of 56 % are determined, which characterizing the transition from the extraction of weakly bound moisture to the extraction of moisture with strong bonds (colloidal, adsorption). It was found that the pomaces obtained from apples of late ripening have a higher content of solids (21-23 %), soluble pectin and protopectin (2.5-4.5 %). Dried pomaces obtained from apple varieties of late ripening contain up to 25 % pectin, which allow us to recommend them as a source of raw materials for the production of pectin. The optimum modes of preliminary washing of raw materials are offered, allowing to the remove the ballast substances as much as possible. It is established that when the drying temperature increases, the destructive processes are catalyzed: the strength of the pectin jelly and the uronide component and the degree of pectin esterification are reduced. The optimum drying temperature of damp apple pomaces is 80 0C, at which the quality of pectin extracted from the dried raw materials is maintained as much as possible. It is shown that the most effective for the pectin production is a fraction with a particle size of 3-5 mm, which allow us to extract up to 71 % of pectin from raw materials.


2019 ◽  
Author(s):  
Chem Int

A significant flux of heavy metals, among other toxins, reaches the lungs through smoking. This study reports Cd, Pb, Cu and Zn contents in tobacco of 11 brands of cigarette commonly sold in Ethiopia. The heavy metals were determined by atomic absorption spectrophotometry after wet digestion of cigarette tobacco using HNO3 and H2O2. The concentration of trace metals in the cigarettes ranged (mean) (μg/g), Cd: 1.3−7.6 (2.48±0.32), Pb: 0.50−12.50 (6.24±2.2), Cu: 2.89−25.35 (13.70±4.12) and Zn: 24.40−62.55 (36.22±7.50) while Ni was not detected in all the eleven brands of cigarettes. Comparable levels of trace metals were obtained in the tobacco of both imported and Ethiopian cigarettes. The average trace metal contents of cigarettes available in Ethiopia were Cd 1.82±0.39, Pb 4.23±0.97, Cu 10.2±3.1 and Zn 28.2±7.8 μg/cigarette and a person who smokes 20 cigarettes per day is estimated to increase his/her daily Cd, Pb, Cu and Zn retention by approximately 0.036, 0.085, 0.204, 0.564 mg/day, respectively. The results indicate that smoking and exposure to cigarette smoke is a serious problem to be taken into account when carrying out epidemiological studies on human exposure to trace metals.


Author(s):  
SAFITRI NURHIDAYATI ◽  
RIZKI AMELYA SYAM

This study aims to analyze whether the difference that occurs in the cost of raw materials, direct labor, and factory overhead costs between the standard costs and the actual costs in PLTU LATI is a difference that is favorable or unfavorable. Data collection techniques with field research and library research. The analytical tool used is the analysis of the difference in raw material costs, the difference in direct labor costs and the difference in factory overhead costs. The hypothesis in this study is that the difference allegedly occurs in the cost of raw materials, direct labor costs, and factory overhead costs at PT Indo Pusaka Berau Tanjung Redeb is a favorable difference. The results showed that the difference in the cost of producing MWh electricity at PT Indo Pusaka Berau Tanjung Redeb in 2018, namely the difference in the price of raw material costs Rp. 548,029.80, - is favorable, the difference in quantity of raw materials is Rp. 957,216,602, - is (favorable) , the difference in direct labor costs Rp 2,602,642,084, - is (unfavorable), and the difference in factory overhead costs Rp 8,807,051,422, - is (favorable) This shows that the difference in the overall production cost budget is favorable or profitable. This beneficial difference shows that the company is really able to reduce production costs optimally in 2018.  


2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Roxana T. Shafiee ◽  
Poppy J. Diver ◽  
Joseph T. Snow ◽  
Qiong Zhang ◽  
Rosalind E. M. Rickaby

AbstractAmmonia oxidation by archaea and bacteria (AOA and AOB), is the first step of nitrification in the oceans. As AOA have an ammonium affinity 200-fold higher than AOB isolates, the chemical niche allowing AOB to persist in the oligotrophic ocean remains unclear. Here we show that marine isolates, Nitrosopumilus maritimus strain SCM1 (AOA) and Nitrosococcus oceani strain C-107 (AOB) have contrasting physiologies in response to the trace metals iron (Fe) and copper (Cu), holding potential implications for their niche separation in the oceans. A greater affinity for unchelated Fe may allow AOB to inhabit shallower, euphotic waters where ammonium supply is high, but competition for Fe is rife. In contrast to AOB, AOA isolates have a greater affinity and toxicity threshold for unchelated Cu providing additional explanation to the greater success of AOA in the marine environment where Cu availability can be highly variable. Using comparative genomics, we predict that the proteomic and metal transport basis giving rise to contrasting physiologies in isolates is widespread across phylogenetically diverse marine AOA and AOB that are not yet available in pure culture. Our results develop the testable hypothesis that ammonia oxidation may be limited by Cu in large tracts of the open ocean and suggest a relatively earlier emergence of AOB than AOA when considered in the context of evolving trace metal availabilities over geologic time.


Sign in / Sign up

Export Citation Format

Share Document