scholarly journals Adsorption of As(V) from Aqueous Solution on Chitosan-Modified Diatomite

2020 ◽  
Vol 17 (2) ◽  
pp. 429 ◽  
Author(s):  
Qintao Yang ◽  
Liang Gong ◽  
Lili Huang ◽  
Qinglin Xie ◽  
Yijian Zhong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Removal Efficiency ◽  
Ph Effect ◽  
Freundlich Isotherm ◽  
Xrd Analysis ◽  
Optimal Value ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Desorption ◽  
Modified Diatomite

A novel chitosan (CS)-modified diatomite (Dt) was prepared by a simple mixture in the mass ratio to remove As(V) from aqueous solution in this research. The CS-modified Dt adsorbent was characterized by scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and X-ray powder diffraction (XRD) analysis. The parameters to influence the adsorption of As(V) ion were studied under such conditions as kinetics, adsorption isotherm, and pH effect. The results revealed that adsorption of As(V) was initially rapid and the equilibrium time was reached after 40 min. The optimal value of the pH was 5.0 for better adsorption. The equilibrium data were well fitted to the Langmuir isotherm compared to the Freundlich isotherm, and exhibited the highest capacity and removal efficiency of 94.3% under an initial As(V) concentration of 5 mg/L. The kinetic data were well described by the pseudo-second-order model. In addition, 0.1 M NaOH has the best desorption efficiency of As(V) adsorbed on CS-modified Dt, and the removal efficiency of As(V) was still higher than 90% when after six adsorption-desorption cycles. These results showed that the CS-modified Dt could be considered as a potential adsorbent for the removal of As(V) in aqueous solution.

Adsorption of methyl orange from aqueous solution using chitosan/diatomite composite

2017 ◽  
Vol 75 (7) ◽  
pp. 1633-1642 ◽  
Author(s):  
Peng Zhao ◽  
Runhu Zhang ◽  
Jianglin Wang
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Removal Rate ◽  
Ph Effect ◽  
Aqueous Media ◽  
Freundlich Isotherm ◽  
Electron Microscopy Analysis ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption And Desorption Performance

A novel chitosan/diatomite composite was prepared by a simple mixture in the mass ratio to remove methyl orange (MO) from aqueous media in this study. The composite adsorbent was characterized by Fourier transform infrared spectroscopy and scanning electron microscopy analysis. The parameters to influence the adsorption of MO were studied under such conditions as kinetics, adsorption isotherm, pH effect, and thermodynamics. The results revealed that adsorption of MO was initially rapid and the equilibrium time was reached after 40 min. The optimal value of the pH was 5.0 for better adsorption. The equilibrium data were well fitted to the Langmuir isotherm compared to the Freundlich isotherm, and exhibited the highest capacity and a removal rate of 88.37% under an initial dye concentration of 50 mg/L. The kinetic data were well described by the pseudo-second order model. The thermodynamic calculations revealed that the sorption was viable, spontaneous, and exothermic under the conditions studied. In addition, the chitosan/diatomite composite had good adsorption and desorption performance with respect to reusability after six cycles. These results showed that the chitosan/diatomite could be considered as a potential adsorbent for the removal of MO in aqueous solution.

scholarly journals Fabrication of magnetic lignin-based adsorbent for removal of methyl orange dye from aqueous solution

BioResources ◽  
2021 ◽  
Vol 16 (3) ◽  
pp. 5436-5449
Author(s):  
Chao Cao ◽  
Lupeng Shao ◽  
Lucian A. Lucia ◽  
Yu Liu
Keyword(s):  
Aqueous Solution ◽  
Methyl Orange ◽  
Influence Factors ◽  
Maximum Adsorption Capacity ◽  
X Ray Diffraction ◽  
Adsorption Mechanisms ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Methyl Orange Dye ◽  
Adsorption Desorption

Magnetic lignin-based adsorbent (MLA) was successfully fabricated to remove methyl orange dye from aqueous solution. The synthesized MLA was characterized by means of Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), N2 adsorption-desorption, scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). In the process of adsorption, influence factors and recycling performance were considered, and the adsorption mechanisms such as isotherm and kinetics were investigated. The result showed that the equilibrium data was consisted with the Langmuir model with a maximum adsorption capacity of 85.0 mg/g. The adsorption kinetics followed a pseudo-second-order model. Based the adsorption performance, MLA showed good recyclability. Therefore, these results demonstrate that MLA could offer a great potential as an efficient and reusable adsorbent in the wastewater treatments.

scholarly journals Hydrazinolyzed cellulose-g-polymethyl acrylate as adsorbent for efficient removal of Cd(II) and Pb(II) ions from aqueous solution

2016 ◽  
Vol 75 (5) ◽  
pp. 1051-1058 ◽  
Author(s):  
Qiujin Jia ◽  
Wanting Zhang ◽  
Dongping Li ◽  
Yulong Liu ◽  
Yuju Che ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Physical Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Model ◽  
Initial Ph ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Adsorption Desorption ◽  
Efficient Adsorbent

Hydrazinolyzed cellulose-graft-polymethyl acrylate (Cell-g-PMA-HZ), an efficient adsorbent for removal of Cd(II) and Pb(II) from aqueous solution, has been prepared by ceric salt-initiated graft polymerization of methyl acrylate from microcrystalline cellulose surface and subsequent hydrazinolysis. The influences of initial pH, contact time, and temperature on adsorption capacity of Cell-g-PMA-HZ as well as adsorption equilibrium, kinetic and thermodynamic properties were examined in detail. As for Cd(II) adsorption, kinetic adsorption can be explained by pseudo-second-order, while adsorption isotherm fits well with Langmuir isotherm model, from which maximum equilibrium adsorption capacity can be derived as 235.85 mg g−1 at 28 °C. Further thermodynamic investigation indicated that adsorption of Cd(II) by adsorbent Cell-g-PMA-HZ is endothermic and spontaneous under studied conditions. On the other hand, isotherm of Pb(II) adsorption fits well with Freundlich isotherm model and is more likely to be a physical-adsorption-dominated process. Consecutive adsorption–desorption experiments showed that Cell-g-PMA-HZ is reusable with satisfactory adsorption capacity.

scholarly journals Batch Adsorption of Maxilon Red GRL from Aqueous Solution by Natural Sugarcane Stalks Powder

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Gamal Owes El-Sayed ◽  
Talaat Younis Mohammed ◽  
Ashraf Abd-Allah Salama
Keyword(s):  
Aqueous Solution ◽  
Dye Removal ◽  
Dye Adsorption ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Textile Dye ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Pseudo Second Order

Sugarcane stalks powder was tested for its efficiency of removing a textile dye Maxilon Red GRL from aqueous solution. Different parameters affecting dye removal efficiency were studied. These parameters include contact time, initial dye concentration, adsorbent dose, ionic strength, pH, and temperature. Langmuir and Freundlich isotherm models were applied to the equilibrium data. The data fitted well with the Langmuir isotherm (). The maximum monolayer adsorption capacity () was found to be 20.96 mg/g at an initial pH of 7.2. The temperature variation study showed that dye adsorption is exothermic and spontaneous with increased randomness at the solid solution interface. The results indicated that sugarcane stalks could be an alternative for more costly adsorbents used for dye removal. The kinetic of the adsorption process followed the pseudo second-order kinetics model.

scholarly journals Malachite Green Dye Removal Using the Seaweed Enteromorpha

2011 ◽  
Vol 8 (2) ◽  
pp. 649-656 ◽  
Author(s):  
R. Jayaraj ◽  
M. Chandra Mohan ◽  
P. Martin Deva Prasath ◽  
T. Hidhayathullah Khan
Keyword(s):  
Aqueous Solution ◽  
Malachite Green ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Model Parameters ◽  
Adsorption Method ◽  
Malachite Green Dye ◽  
Equilibrium Data ◽  
Pseudo Second Order

Malachite green adsorption from an aqueous solution onto activatedEnteromorphacarbon has been studied experimentally using batch adsorption method. Adsorption kinetics and equilibrium were investigated as a function of initial dye concentration, pH, contact time and adsorbent dosage. Kinetics studies indicated that the adsorption followed pseudo second order reaction. Equilibrium data was analyzed using Langmuir and Freundlich isotherm models. The adsorption capacity ofEnteromorphawas found to be 94.74%. On the basis of experimental results and the model parameters, it can be inferred that the carbonaceousEnteromorphais effective for the removal of malachite green from aqueous solution.

Adsorption of Congo Red on AB-8 Macroporous Resin

2012 ◽  
Vol 550-553 ◽  
pp. 2138-2141
Author(s):  
Xin Dong Zhai ◽  
Jie Yan Wu
Keyword(s):  
Waste Water ◽  
Aqueous Solution ◽  
Congo Red ◽  
Freundlich Isotherm ◽  
Macroporous Resin ◽  
Order Model ◽  
Initial Concentration ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Agitation Time

Waste water containing Congo red in industrial production has caused many serious environmental problems worldwide. In this paper, AB-8 macroporous resin was used to remove Congo red from an aqueous solution by adsorption technique under varying conditions of pH, adsorbent dosage, agitation time, temperature and initial concentration. The results show the adsorption kinetics is well described by pseudo-second-order model. It was found that the equilibrium data was better represented by the Freundlich isotherm model.

Adsorption Characteristics of Phenol in Aqueous Solution by Pinus massoniana Biochar

2013 ◽  
Vol 295-298 ◽  
pp. 1154-1160 ◽  
Author(s):  
Guo Zhi Deng ◽  
Xue Yuan Wang ◽  
Xian Yang Shi ◽  
Qian Qian Hong
Keyword(s):  
Aqueous Solution ◽  
Ph Value ◽  
Pinus Massoniana ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Adsorbent Dosage ◽  
Salt Ions ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

The objective of this paper is to investigate the feasibility of phenol adsorption from aqueous solution by Pinus massoniana biochar. Adsorption conditions, including contact time, initial phenol concentration, adsorbent dosage, strength of salt ions and pH, have been investigated by batch experiments. Equilibrium can be reached in 24 h for phenol from 50 to 250 mg• L-1. The optimum pH value for this kind of biochar is 5.0. The amount of phenol adsorbed per unit decreases with the increase in adsorbent dosage. The existence of salt ions makes negligible influence on the equilibrium adsorption capacity. The experimental data is analyzed by the Freundlich and Langmuir isotherm models. Equilibrium data fits well to the Freundlich model. Adsorption kinetics models are deduced and the pseudo-second-order kinetic model provides a good correlation for the adsorbent process. The results show that the Pinus massoniana biochar can be utilized as an effective adsorption material for the removal of phenol from aqueous solution.

scholarly journals Equilibrium and Kinetic Study of Anionic and Cationic Pollutants Remediation by Limestone–Chitosan–Alginate Nanocomposite from Aqueous Solution

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2586
Author(s):  
Inas A. Ahmed ◽  
Ahmed H. Ragab ◽  
Mohamed A. Habila ◽  
Taghrid S. Alomar ◽  
Enas H. Aljuhani
Keyword(s):  
Physical Adsorption ◽  
Low Cost ◽  
Freundlich Isotherm ◽  
Entropy Change ◽  
Sem Images ◽  
Bet Analysis ◽  
Adsorption Processes ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Multilayer Formation

In this work, low-cost and readily available limestone was converted into nanolimestone chitosan and mixed with alginate powder and precipitate to form a triple nanocomposite, namely limestone—chitosan–alginate (NLS/Cs/Alg.), which was used as an adsorbent for the removal of brilliant green (BG) and Congo red (CR) dyes in aqueous solutions. The adsorption studies were conducted under varying parameters, including contact time, temperature, concentration, and pH. The NLS/Cs/Alg. was characterized by SEM, FTIR, BET, and TEM techniques. The SEM images revealed that the NLS/Cs/Alg. surface structure had interconnected pores, which could easily trap the pollutants. The BET analysis established the surface area to be 20.45 m2/g. The recorded maximum experimental adsorption capacities were 2250 and 2020 mg/g for CR and BG, respectively. The adsorption processes had a good fit to the kinetic pseudo second order, which suggests that the removal mechanism was controlled by physical adsorption. The CR and BG equilibrium data had a good fit for the Freundlich isotherm, suggesting that adsorption processes occurred on the heterogeneous surface with a multilayer formation on the NLS/Cs/Alg. at equilibrium. The enthalpy change (ΔH0) was 37.7 KJ mol−1 for CR and 8.71 KJ mol−1 for BG, while the entropy change (ΔS0) was 89.1 J K−1 mol−1 for CR and 79.1 J K−1 mol−1 BG, indicating that the adsorption process was endothermic and spontaneous in nature.

scholarly journals Study on the adsorption of methylene blue from aqueous solution using hydrogel glucomannan/graphene oxide

2021 ◽  
Vol 10 (1) ◽  
pp. 59-66
Author(s):  
Son Le Lam ◽  
Phu Nguyen Vinh ◽  
Hieu Le Trung ◽  
Tan Le Thua ◽  
Nhan Dang Thi Thanh ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Graphene Oxide ◽  
Adsorption Capacity ◽  
Organic Dyes ◽  
Dye Adsorption ◽  
Order Kinetic ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Glucomannan/graphene oxide (GM/GO) hydrogel was synthesized by using calcium hydroxide as the crosslinker. The synthesized material was characterized by using IR, XRD, SEM, EDX and RAMAN technology. The composite hydrogel was used for removal of organic dyes from aqueous solution. The results showed that the GM/GO hydrogel had a porous structure and a high adsorption capacity toward methylene blue (MB). The pseudo-second-order kinetic model could fit the rate equation of MB adsorption onto the GM/GO hydrogel. The adsorption of MB onto GM/GO hydrogel was a spontaneous process. In addition, the equilibrium adsorption isotherm data indicated that equilibrium data were fitted to the Langmuir isotherm and the maximum dye adsorption capacity was 198,69 mg.g-1. Moreover, the hydrogel was stable and easily recovered and adsorption capacity was around 97% of the initial saturation adsorption capacity after being used five times.

scholarly journals Investigation on adsorption capacity of TiO2-P25 nanoparticles in the removal of a mono-azo dye from aqueous solution: A comprehensive isotherm analysis

2014 ◽  
Vol 20 (1) ◽  
pp. 97-107 ◽  
Author(s):  
Mohammad Behnajady ◽  
Shahrzad Yavari ◽  
Nasser Modirshahla
Keyword(s):  
Aqueous Solution ◽  
Crystallite Size ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Correlation Coefficients ◽  
Average Crystallite Size ◽  
Isotherm Models ◽  
Equilibrium Data ◽  
Pseudo Second Order

In this work TiO2-P25 nanoparticles with high surface area have been used as adsorbent for the removal of C.I Acid Red 27 (AR27), as an organic contaminant from aqueous solution. Characteristics of phases and crystallite size of TiO2-P25 nanoparticles were achieved from XRD and the surface area and pore size distribution were obtained from BET and BJH techniques. TiO2-P25 nanoparticles with almost 80% anatase and 20% rutile phases, the average crystallite size of 18 nm, have specific surface area of 56.82 m2 g-1. The effect of various parameters like initial AR27 concentration, pH, contact time and adsorbent dosage has been carried out in order to find desired adsorption conditions. The desired pH for adsorption of AR27 onto TiO2-P25 nanoparticles was 3. The equilibrium data were analyzed with various 2-, 3- and 4-parameter isotherm models. Equilibrium data fitted very well by the 4-parameter Fritz-Schluender model. Results of adsorption kinetics study indicated that the pseudo-second order kinetics provided the best fit with correlation coefficients close to unity.

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