scholarly journals Use of a Mixture of Polyols Based on Metasilicic Acid and Recycled PLA for Synthesis of Rigid Polyurethane Foams Susceptible to Biodegradation

2020 ◽  
Vol 22 (1) ◽  
pp. 69
Author(s):  
Joanna Paciorek-Sadowska ◽  
Marcin Borowicz ◽  
Ewelina Chmiel ◽  
Jacek Lubczak
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Raw Materials ◽  
Weight Ratio ◽  
Acid Number ◽  
Polyurethane Foams ◽  
Poly Lactic Acid ◽  
Rigid Polyurethane Foams ◽  
Sustainable Resource Management ◽  
Metasilicic Acid

Two polyol raw materials were obtained in the conducted research, one based on metasilicic acid (MSA), the other based on poly(lactic acid) (PLA) waste. The obtained polyols were characterized in terms of their applicability for the production of rigid polyurethane foams (RPUFs). Their basic analytical properties (hydroxyl number, acid number, elemental analysis) and physicochemical properties (density, viscosity) were determined. The assumed chemical structure of the obtained new compounds was confirmed by performing FTIR and 1H NMR spectroscopic tests. Formulations for the synthesis of RPUFs were developed on the basis of the obtained research results. A mixture of polyols based on MSA and PLA in a weight ratio of 1:1 was used as the polyol component in the polyurethane formulation. The reference foam in these tests was a foam that was synthesized only on the basis of MSA-polyol. The obtained RPUFs were tested for basic functional properties (apparent density, compressive strength, water absorption, thermal conductivity coefficient etc.). Susceptibility to biodegradation in soil environment was also tested. It was found that the use of mixture of polyols based on MSA and PLA positively affected the properties of the obtained foam. The polyurethane foam based on this polyol mixture showed good thermal resistance and significantly reduced flammability in comparison with the foam based MSA-polyol. Moreover, it showed higher compressive strength, lower thermal conductivity and biodegradability in soil. The results of the conducted tests confirmed that the new foam was characterized by very good performance properties. In addition, this research provides information on new waste management opportunities and fits into the doctrine of sustainable resource management offered by the circular economy.

The Synthesis and Application of a Novel Class of Polyols for Preparation of Polyurethane

2013 ◽  
Vol 357-360 ◽  
pp. 1441-1445
Author(s):  
Xiao Lin Li ◽  
Zheng Fang ◽  
Dong Ji ◽  
Zhi Dong Wan ◽  
Kai Guo
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Polyurethane Foams ◽  
Low Density ◽  
Cell Content ◽  
Low Thermal Conductivity ◽  
High Compressive Strength ◽  
Rigid Polyurethane Foams ◽  
Closed Cell ◽  
Rigid Foams

The synthesis of a novel class of diamine-based polyols derivatives and the potentials and the limitations of these polyols were reported. This class of diamine-based polyols with high hydroxyl values and no acid values can be used in rigid polyurethane foams. The prepared rigid foams show the properties of low density, high closed cell content, low thermal conductivity, and high compressive strength.

scholarly journals Wood Bottom Ash and GeoSilex: A By-Product of the Acetylene Industry as Alternative Raw Materials in Calcium Silicate Units

Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 489
Author(s):  
Manuel Angel Felipe-Sesé ◽  
Luis Pérez-Villarejo ◽  
Eulogio Castro ◽  
Dolores Eliche-Quesada
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Calcium Silicate ◽  
Building Materials ◽  
Raw Materials ◽  
Bottom Ash ◽  
Weight Ratio ◽  
Experimental Program ◽  
Environmental Costs

The main objective of this research was to obtain calcium silicate units from alternative raw materials, such as the bottom ashes from the combustion of wooden boards (WBA), as a source of silica, and GeoSilex (G), a by-product with low energy and environmental costs generated in the manufacture of acetylene, as a source of lime. Once the raw materials were physically, mineralogically and chemically characterized, calcium silicate units were obtained by mixing different amounts of WBA residue (90–20 wt%) and G by-product (10–80 wt%). The mixtures were compressed at 10 MPa and cured in water for 28 days. The calcium silicate units were subjected to a wide experimental program that included the determination of physical properties (bulk density, apparent porosity and water absorption), mechanical properties (compressive strength), and thermal properties (thermal conductivity). Optimum values are obtained for calcium silicate units that contain a 1/1 WBA/G weight ratio, which have an optimal amount of SiO2 and CaO for the cementation reaction. The 50WBA-50g units have compressive strength values of 46.9 MPa and a thermal conductivity value of 0.40 W/mK. However, all calcium silicate units obtained comply with the European Standard EN 771-2: 2011 to be used as structural building materials.

Improvement of thermal conductivity of rigid polyurethane foams with aluminum nitride filler

2021 ◽  
pp. 026248932198897
Author(s):  
Serife Akkoyun ◽  
Meral Akkoyun
Keyword(s):  
Thermal Conductivity ◽  
Aluminum Nitride ◽  
Polyurethane Foams ◽  
Thermal Transitions ◽  
Rigid Polyurethane Foams ◽  
Noticeable Increase ◽  
Polyurethane Composite ◽  
Composite Foams ◽  
Step Procedure ◽  
Electrical Conductivities

The aim of this work is the fabrication of electrically insulating composite rigid polyurethane foams with improved thermal conductivity. Therefore, this study is focused on the effect of aluminum nitride (AlN) on the thermal and electrical conductivities of rigid polyurethane foams. For this purpose, aluminum nitride/rigid polyurethane composite foams were prepared using a three-step procedure. The electrical and thermal conductivities of the foams were characterized. The thermal transitions, mechanical properties and morphology of the foams were also examined. The results reveal that AlN induces an increase of the thermal conductivity of rigid polyurethane foam of 24% which seems to be a relatively noticeable increase in polymeric foams. The low electrical conductivity of the foams is preserved.

Bio-based Polyurethane-clay Nanocomposite Foams: Systheses and Properties

2009 ◽  
Vol 1188 ◽  
Author(s):  
Min Liu ◽  
Zoran S. Petrovic ◽  
Yijin Xu
Keyword(s):  
Thermal Conductivity ◽  
Thermal Insulation ◽  
Cell Structure ◽  
Polyurethane Foams ◽  
Mechanical And Thermal Properties ◽  
Cell Content ◽  
Modified Clay ◽  
Rigid Polyurethane Foams ◽  
Nanocomposite Foams ◽  
Organically Modified

AbstractStarting from a bio-based polyol through modification of soybean oil, BIOH™ X-210, two series of bio-based polyurethanes-clay nanocomposite foams have been prepared. The effects of organically-modified clay types and loadings on foam morphology, cell structure, and the mechanical and thermal properties of these bio-based polyurethanes-clay nanocomposite foams have been studied with optical microscopy, compression test, thermal conductivity, DMA and TGA characterization. Density of nanocomposite foams decreases with the increase of clay loadings, while reduced 10% compressive stress and yield stress keep constant up to 2.5% clay loading in polyol. The friability of rigid polyurethane-clay nanocomposite foams is high than that of foam without clay, and the friability for nanofoams from Cloisite® 10A is higher than that from 30B at the same clay loadings. The incorporation of clay nanoplatelets decreases the cell size in nanocomposite foams, meanwhile increases the cell density; which would be helpful in terms of improving thermal insulation properties. All the nanocomposite foams were characterized by increased closed cell content compared with the control foam from X-210 without clay, suggesting the potential to improve thermal insulation of rigid polyurethane foams by utilizing organically modified clay. Incorporation of clay into rigid polyurethane foams results in the increase in glass transition temperature: the Tg increased from 186 to 197 to 204 °C when 30B concentration in X-210 increased from 0 to 0.5 to 2.5%, respectively. Even though the thermal conductivity of nanocomposite foams from 30B is lower than or equal to that of rigid polyurethane control foam from X-210, thermal conductivity of nanocomposite foams from 10A is higher than that of control at all 10A concentrations. The reason for this abnormal phenomenon is not clear at this moment; investigation on this is on progress.

scholarly journals Rigid Polyurethane Foams Modified with Biochar

Materials ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 5616
Author(s):  
Katarzyna Uram ◽  
Maria Kurańska ◽  
Jacek Andrzejewski ◽  
Aleksander Prociak
Keyword(s):  
Thermal Conductivity ◽  
Thermal Stability ◽  
Thermal Insulation ◽  
Foam Cells ◽  
Polyurethane Foams ◽  
Cross Sectional ◽  
Rigid Polyurethane Foams ◽  
Insulation Materials

This paper presents results of research on the preparation of biochar-modified rigid polyurethane foams that could be successfully used as thermal insulation materials. The biochar was introduced into polyurethane systems in an amount of up to 20 wt.%. As a result, foam cells became elongated in the direction of foam growth and their cross-sectional areas decreased. The filler-containing systems exhibited a reduction in their apparent densities of up to 20% compared to the unfilled system while maintaining a thermal conductivity of 25 mW/m·K. Biochar in rigid polyurethane foams improved their dimensional and thermal stability.

Effects of Activating Solution and Liquid/Solid Ratio on Engineering Properties of Metakaolin-Based Geopolymer

2012 ◽  
Vol 204-208 ◽  
pp. 4101-4104 ◽  
Author(s):  
Tzong Ruey Yang ◽  
Ta Peng Chang ◽  
Chun Tao Chen ◽  
Yuan Kai Lee ◽  
Bo Tsun Chen
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Weight Ratio ◽  
Degree Of Polymerization ◽  
Controlling Factors ◽  
Experimental Results ◽  
Raw Material ◽  
Engineering Properties ◽  
Solid Ratio ◽  
Activating Solution

In this paper, the metakaolin is used as the raw material with aluminosilicate compounds to produce the geopolymer. The effects of three levels of two major controlling factors, the degree of polymerization of the activating solution (weight ratio of SiO2 to Na2O) of 0.4, 0.7 and 1.0 and the weight ratio of liquid to solid (L/S) of 0.7, 0.85 and 1.00 on the engineering properties of geopolymer are investigated. The experimental results show that, at age of 28 days, the compressive strength increases from the lowest 37.33 MPa (SiO2/Na2O = 0.4 and L/S = 0.7) to the highest 71.21 MPa (SiO2/Na2O = 0.7 and L/S = 0.7). While, the thermal conductivity increases from the lowest 0.39 w/mk (SiO2/Na2O = 0.4 and L/S = 1.0) to the highest 0.761 w/mk (SiO2/Na2O = 1.0 and L/S = 0.7).

Performance Study of Fiber Reinforced New Lightweight Insulation Materials

2013 ◽  
Vol 662 ◽  
pp. 331-334
Author(s):  
Huan Qi Zhao ◽  
Guo Zhong Li
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Bending Strength ◽  
Raw Materials ◽  
The Self ◽  
Performance Study ◽  
Foaming Agent ◽  
Insulation Materials ◽  
Influencing Mechanism ◽  
Coefficient Of Thermal Conductivity

Cement-based lightweight insulation materials were made. Cement and fly ash are main raw materials. The self-developed composite excitation agent and foaming agent are used. The method of foaming is the physical foaming. The inflection of fiber dosage on the performance of lightweight insulation materials was researched. Its influencing mechanism was discussed. Experiments show that foaming lightweight insulation materials were made with 1.22MPa bending strength, 2.95MPa compressive strength and the 0.072W/mk coefficient of thermal conductivity when the fiber mixing content is 1.2%.

Preparation of rigid polyurethane foams with powder filler

2012 ◽  
Vol 32 (2) ◽  
Author(s):  
Joanna Paciorek-Sadowska ◽  
Bogusław Czupryński ◽  
Joanna Liszkowska ◽  
Kazimierz Piszczek
Keyword(s):  
Compressive Strength ◽  
Polyvinyl Chloride ◽  
Softening Point ◽  
Processing Parameters ◽  
Polyurethane Foams ◽  
Favorable Effect ◽  
Start Time ◽  
Rigid Polyurethane Foams ◽  
Powder Filler ◽  
Foam Plastics

Abstract The diversified properties of polyurethane (PUR) foam plastics result from differences in the receipts applied during their preparation. The preparation of rigid polyurethane-polyisocyanurate foams (PUR-PIR) with application of different amounts of polyvinyl chloride (PVC) s-70 as a filler is described in this study. It was found that application of PVC s-70 has an effect on the prolongation of processing parameters, i.e., start time and, to a greater extent, expansion and gelation times. Moreover, it was found that introduction of filler into the foam composition causes a reduction in the capacity of the foam to absorb water; however, a distinct change in the amount of closed cells in comparison with standard foam was not observed. A favorable effect of filler on brittleness and flammability of PUR-PIR foams (significant reduction) as well as on compressive strength and softening point (a significant increase in these values) was observed.

Study on the Preparation and Properties of Fiber Reinforced Foamed Cement Material

2013 ◽  
Vol 327 ◽  
pp. 40-43
Author(s):  
Xiao Long Li ◽  
Guo Zhong Li
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Dry Density ◽  
Fiber Reinforced ◽  
Cement Material ◽  
Insulation Materials

The ordinary portland cement was used to prepare foamed cement insulation materials by physical foaming method. The influence of different process of fiber added to the foamed cement insulation materials on its performance was studied and the optimum mix ratio of raw materials was determined. The results showed that the glass fire could be evenly dispersed in the slurry by dry adding technology and got better enhanced effect. When the dosage of glass fire was 0.9%, the performance of the foamed cement material as follows: dry density of 318 kg/m3, 3d flexural strength of 0.61MPa, 3d compressive strength of 1.05MPa, thermal conductivity of 0.065W/(m·k). The reinforce mechanism of glass fire was explored.

Effect of Borax on Lightweight Material from Cullet and Fly Ash

2016 ◽  
Vol 690 ◽  
pp. 109-113 ◽  
Author(s):  
Sutthima Sriprasertsuk ◽  
Phatthiya Suwannason ◽  
Wanna T. Saengchantara
Keyword(s):  
Thermal Conductivity ◽  
Heat Treatment ◽  
Compressive Strength ◽  
Fly Ash ◽  
Sodium Silicate ◽  
Raw Materials ◽  
Raw Material ◽  
Test Results ◽  
Heat Process ◽  
Lightweight Material

This work investigated the recycling of fly ash waste and cullet as the raw materials for lightweight bodies produced by heat treatment and using sodium silicate as the binder. Borax was mixed with fly ash and cullet, and put into the block in dimension 10x10x2 cm3. The lightweight materials thus produced were then sintered at temperature of 800 °C. Density, compressive strength and thermal conductivity were determined. Borax showed a positive sintering effect on the porosity of lightweight material during the heat process. The compressive strength of lightweight material diminished with the reduction of density and thermal conductivity. Lightweight material manufactured with borax showed the lower density and thermal conductivity accompanied by the higher compressive strength. The test results indicated that using fly ash and cullet as the raw material with borax could obtain the lightweight material, thus enhancing the possibility of its reuse in a sustainable way.

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