scholarly journals Chemical Composition and Thermogravimetric Behaviors of Glanded and Glandless Cottonseed Kernels

Molecules ◽  
2022 ◽  
Vol 27 (1) ◽  
pp. 316
Author(s):  
Zhongqi He ◽  
Sunghyun Nam ◽  
Hailin Zhang ◽  
Ocen Modesto Olanya

Common “glanded” (Gd) cottonseeds contain the toxic compound gossypol that restricts human consumption of the derived products. The “glandless” (Gl) cottonseeds of a new cotton variety, in contrast, show a trace gossypol content, indicating the great potential of cottonseed for agro-food applications. This work comparatively evaluated the chemical composition and thermogravimetric behaviors of the two types of cottonseed kernels. In contrast to the high gossypol content (3.75 g kg−1) observed in Gd kernels, the gossypol level detected in Gl kernels was only 0.06 g kg−1, meeting the FDA’s criteria as human food. While the gossypol gland dots in Gd kernels were visually observed, scanning electron microcopy was not able to distinguish the microstructural difference between ground Gd and Gl samples. Chemical analysis and Fourier transform infrared (FTIR) spectroscopy showed that Gl kernels and Gd kernels had similar chemical components and mineral contents, but the former was slightly higher in protein, starch, and phosphorus contents. Thermogravimetric (TG) processes of both kernels and their residues after hexane and ethanol extraction were based on three stages of drying, de-volatilization, and char formation. TG-FTIR analysis revealed apparent spectral differences between Gd and Gl samples, as well as between raw and extracted cottonseed kernel samples, indicating that some components in Gd kernels were more susceptible to thermal decomposition than Gl kernels. The TG and TG-FTIR observations suggested that the Gl kernels could be heat treated (e.g., frying and roasting) at an optimal temperature of 140–150 °C for food applications. On the other hand, optimal pyrolysis temperatures would be much higher (350–500 °C) for Gd cottonseed and its defatted residues for non-food bio-oil and biochar production. The findings from this research enhance the potential utilization of Gd and Gl cottonseed kernels for food applications.

2020 ◽  
Vol 28 (4) ◽  
pp. 214-223
Author(s):  
Junqian Mo ◽  
Wenbo Zhang ◽  
Xiaohui Fu ◽  
Wei Lu

This study investigated the feasibility of using near infrared spectroscopy technology to predict color and chemical composition in the heat-treated bamboo processing industry. The quantitative presentations of the changes in the chemical components were discussed using the difference spectra method of the 2nd derivative NIR spectra of the heat-treated bamboo samples. Then, the relationships between the color changes of the heat-treated bamboo and its near infrared spectra were constructed using the changes in the chemical components of the bamboo samples during the heating process. The prediction of color and chemical composition of both the outer and inner sides of the heat-treated bamboo surface were constructed using partial least squares regression method combined with a leave-one-out cross-validation process. Then, the results were validated by independent sample sets. The proposed prediction models were found to produce high r2P (above 0.93), RPD (above 3.13), and low RMSEP for both the outer and inner sides of the heat-treated bamboo samples. These studies’ results confirmed that the proposed models, especially outer side models, were perfectly suitable for the in-process inspections of the color and chemical content changes of heat-treated bamboo.


Author(s):  
Aziz Amjadi ◽  
D. Chomko

Ground waters of Shyraz Intermountain Trough are widely used for water-supply, watering crops, in industry, and for other purposes. It is currently being planned to make extensive use of ground waters of the Horamabad Trough. Discriminating large areas of ground waters of similar chemical composition and compounds containing over 10 elements is becoming a challenging task. Chemical composition of ground waters results from a number of natural and anthropogenic processes, which affect both interchange of chemical components and the nature of their bonds. However, these bonds do not remain unaffected, and are, virtually, the outcome of a number of processes. We offer a new method that is based on the use of cluster analysis, the application of which will make it possible to discriminate ground waters of similar chemical composition in different areas. This will enable both revealing similarities and differences in the processes of water supply and discharge, which define the chemical make-up of the ground waters, threats of pollution and depletion, and taking measures on ground water preservation. The method was tested on sampling chemical composition of ground waters of Shyraz and Horamabad Intermountain Troughs in Iran. Based on the cluster analysis data of the first matrix (Shyraz Intermountain Trough) and the second matrix (Horamabad Intermountain Trough) step-by-step diagrams of merging intervals are built, and dendrograms, namely. The claster analysis data being processed, the following conclusions can be made: 1. within Shyraz Intermountain Trough, there are discriminated three areas of ground waters bearing similar chemical composition in claster 1; two areas located in claster 2; three areas in claster 3; two areas in claster 4; and one area in claster 5; 2. within Horamabad Intermountain Trough, there are discriminated two areas of ground waters bearing similar chemical composition in claster 1; three areas located in claster 2; two areas in claster 3; four areas in claster 4; and per one area in clasters 5 and 6, correspondingly; 3. changes in ground water chemical composition in Shyraz and Horamabad Intermountain Troughs are interdependent; 4. the method mentioned can be used for chemical zoning of the ground waters.


2021 ◽  
Vol 11 (9) ◽  
pp. 3901
Author(s):  
Varsha Satankar ◽  
Mohan Singh ◽  
Vellaichamy Mageshwaran ◽  
Durwesh Jhodkar ◽  
Sushil Changan ◽  
...  

Cottonseed is one of the important by-products of the cotton crop. Researchers claim that cottonseed with less than 0.45% of gossypol is quite good for human consumption and animal feeding because it is a rich source of protein, edible oil, and energy. Total and free gossypols are the influencing parameters that reduce the edible nature of the cottonseed. In the present work, multiple quadratic regression models have been prepared to predict the reduction in the free and total gossypol percent. This response surface method (RSM)-based approach was applied to investigate the combined effect between input parameters such as acetone level, time of extraction, liquid-to-solid ratio (LSR), and the number of extraction cycles, whereas output responses are free and total gossypol reduction percentage. Analysis of Variance (ANOVA) has been performed to determine the highly significant parameter. The optimum combination of input parameters was determined using the RSM-based desirability approach, and confirmatory experiments were performed to validate the combination. Results revealed that the number of extraction cycles and liquid-to-solid ratio significantly affects the reduction of free and total gossypol levels. The values of r-square were found above 0.9, which indicates that the developed models are suitable and reliable for predicting free and total gossypol reduction percentage.


ZOOTEC ◽  
2016 ◽  
Vol 36 (2) ◽  
pp. 447
Author(s):  
Tiltje Andretha Ransaleleh

CHEMICAL COMPOSITION AND ORGANOLEPTIC CHARACTERISTICS OF PROCESSING BAT (Pteropus alecto) FRESH MEAT. Study was done to evaluate chemical composition and preference degree of the consumers on the processing bat meat compared with beef, chicken and cakalang fish using steam cooking method, flavor cooking and spicy cooking method. Chemical composition was analyzed by proximate analysis using procedures of the Association of Official Analytical Chemists. The organoleptic test was done by hedonic test. Data of the hedonic test were analyzed using Kruskal-Wallis method. To evaluate data distribution of the panelist respons on the sample test, the data were using plot graphic box. The hedonic scales were using 1 to 7. The variables used were including color, taste, flavor, tenderness and general acceptance. Results of proximate analyses of bat meat based on fresh meat indicated that water content was 67.21 percents and protein was 20.48 percents. Based on dry matter, the protein contents of bat meat, pork, chicken, and cakalang fish were 48.97 percents, 69.08 percents, 67.14 percents, and 69.41 percents, respectively. The water contents were 5.76 percents, 9.92 percents, 8.27 percents, and 9.90 percents, repsectively; the calcium (Ca) contents were also 10.62 percents, 1.09 percents, 1.36 percents, 1.38 percents, respectively; while Phosphor (P) contents were 1.46 percents, 0.69 percents, 0.66 percents, and 0.72 percents, respectively. Variance analysis for organoleptic test showed that meat type with different processing affected significantly on taste, color, flavor, tenderness and general preference of bat meat, beef meat, chicken meat and cakalang fish by steam cooking, chicken flavor, and spicy cooking methods. Conclusion, bat meat contained protein relatively lower than that in pork meat, chicken meat, and cakalang fish, but mineral contents were relative higher. Results of organoleptic test showed that preference degree of processing meat were higher on using spicy flavor. The specific test on taste, color, flavor, tenderness and general responsed showed relatively the same responses by the panelists.   Key word: Chemical composition, organoleptic test, processing bat meat


2018 ◽  
Vol 46 (2) ◽  
pp. 258-267
Author(s):  
J.M. Alonso Vega ◽  
Pedro H. Toledo

Lessonia berteroana (ex L. nigrescens) is kelp freely harvested from Open Access Areas (OAA), and to some extent controlled, from Management and Exploitation Areas for Benthic Resources (MEABR). Harvesting pressures can change population dynamics, mainly in OAAs. In particular, harvesting may alter the chemical components of plants. Therefore, the aim of this study was to determine the harvesting effects on the chemical composition of L. berteroana from MEABR and OAA sampled during different seasons (spring and fall) and at two sites (Talquilla and Lagunillas) near Coquimbo (30°S), Chile. The crude protein (13.5 ± 1.0%), total lipids (0.9 ± 0.2%), crude fiber (16.3 ± 1.6%), ash (30.1 ± 1.5%), and nitrogen-free extract (39.2 ± 2.0%) contents of L. berteroana were within reference values for Laminariales species. Population descriptors and chemical analyses showed that harvesting had local effects, rather than being affected by a resource management strategy (OAA vs MEABR). The seasonal anticipator nature of L. berteroana may explain the detected seasonality of it's chemical composition. Regarding functional morphological structures, chemical composition in the fronds was more variable than in the stipes and perennial holdfast, probably since leaves are ephemeral structures susceptible to environmental changes and that play a functional, rather than structural, role in kelp. In the context of Chilean kelp resource management, monitoring chemical composition is useful for determining optimal harvesting periods to local scale and for deciding when commercially valuable compounds, such as alginate, should be extracted. These data also complement harvesting pressure indicators based on L. berteroana demographic parameters.


2021 ◽  
Vol 21 (1) ◽  
Author(s):  
Jingzhong Chen ◽  
Xiaolong Huang ◽  
Bingli Tong ◽  
Deng Wang ◽  
Jiming Liu ◽  
...  

Abstract Background This study examined how rhizosphere fungi influence the accumulation of chemical components in fruits of a small population species of Cinnamomum migao. Results Ascomycota and Basidiomycota were dominant in the rhizosphere fungal community of C. migao. Pestalotiopsis and Gibellulopsis were associated with α-Terpineol and sabinene content, and Gibellulopsis was associated with crude fat and carbohydrate content. There were significant differences in rhizosphere fungal populations between watersheds, and there was no obvious change between fruiting periods. Gibberella, Ilyonectria, Micropsalliota, and Geminibasidium promoted sabinene accumulation, and Clitocybula promoted α-Terpineol accumulation. Conclusion The climate-related differentiation of rhizosphere fungal communities in watershed areas is the main driver of the chemical composition of C. migao fruit. The control of the production of biologically active compounds by the rhizosphere fungal community provides new opportunities to increase the industrial and medicinal value of the fruit of C. migao.


Foods ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 251
Author(s):  
Maria Fraga-Corral ◽  
Paz Otero ◽  
Lucia Cassani ◽  
Javier Echave ◽  
Paula Garcia-Oliveira ◽  
...  

Tannins are polyphenolic compounds historically utilized in textile and adhesive industries, but also in traditional human and animal medicines or foodstuffs. Since 20th-century, advances in analytical chemistry have allowed disclosure of the chemical nature of these molecules. The chemical profile of extracts obtained from previously selected species was investigated to try to establish a bridge between traditional background and scientific data. The study of the chemical composition of these extracts has permitted us to correlate the presence of tannins and other related molecules with the effectiveness of their apparent uses. The revision of traditional knowledge paired with scientific evidence may provide a supporting background on their use and the basis for developing innovative pharmacology and food applications based on formulations using natural sources of tannins. This traditional-scientific approach can result useful due to the raising consumers’ demand for natural products in markets, to which tannin-rich extracts may pose an attractive alternative. Therefore, it is of interest to back traditional applications with accurate data while meeting consumer’s acceptance. In this review, several species known to contain high amounts of tannins have been selected as a starting point to establish a correlation between their alleged traditional use, tannins content and composition and potential bioaccessibility.


2015 ◽  
Vol 85 (6) ◽  
pp. 920-926 ◽  
Author(s):  
Ricardo Carvalho Bueno ◽  
Roberta Tarkany Basting

ABSTRACT Objective:  To evaluate the proliferation and morphology of human osteoblasts cultured on two brands of mini-implants after 24, 48, and 72 hours, in addition to the chemical composition found on their surface. Materials and Methods:  Two brands of mini-implant (Morelli and Neodent) were evaluated; polystyrene was used as a control group (n  =  3). Osteoblasts were cultured on the surface of sterilized mini-implants in a CO2 incubator at different time periods (24, 48, and 72 hours). Osteoblast proliferation was quantified by scanning electron microscopy using up to 5000× magnification, and cell morphology was analyzed by a single observer. For the chemical analysis, spectroscopy X-ray fluorescence was used to identify and quantify chemical components on the surface of the mini-implants. Results:  Two-way ANOVA showed no significant interaction between the factors studied (P  =  0.686). A Tukey test revealed no significant difference in osteoblast proliferation between the mini-implants at all studied periods; however, a difference in cell proliferation was detected between the Neodent and the control group (P  =  .025). For all groups, time had a direct and positive effect on osteoblast proliferation (P < .001). The significant elements present in both brands of mini-implants were titanium, aluminum, vanadium, and iron. Conclusions:  Osteoblast proliferation was present on the mini-implants studied, which increased over time; however, no significant difference between brands was observed. No difference was seen between the mini-implants evaluated in terms of chemical composition. Cell adhesion after 72 hours suggests that areas of bone remodeling can be achieved, thus initiating the process of mini-implant anchorage.


2005 ◽  
Vol 5 (3) ◽  
pp. 767-779 ◽  
Author(s):  
T. Petäjä ◽  
V.-M. Kerminen ◽  
K. Hämeri ◽  
P. Vaattovaara ◽  
J. Joutsensaari ◽  
...  

Abstract. Hygroscopicity (i.e. water vapour affinity) of atmospheric aerosol particles is one of the key factors in defining their impacts on climate. Condensation of sulphuric acid onto less hygroscopic particles is expected to increase their hygrocopicity and hence their cloud condensation nuclei formation potential. In this study, differences in the hygroscopic and ethanol uptake properties of ultrafine aerosol particles in the Arctic air masses with a different exposure to anthropogenic sulfur pollution were examined. The main discovery was that Aitken mode particles having been exposed to polluted air were more hygroscopic and less soluble to ethanol than after transport in clean air. This aging process was attributed to sulphur dioxide oxidation and subsequent condensation during the transport of these particle to our measurement site. The hygroscopicity of nucleation mode aerosol particles, on the other hand, was approximately the same in all the cases, being indicative of a relatively similar chemical composition despite the differences in air mass transport routes. These particles had also been produced closer to the observation site typically 3–8 h prior to sampling. Apparently, these particles did not have an opportunity to accumulate sulphuric acid on their way to the site, but instead their chemical composition (hygroscopicity and ethanol solubility) resembled that of particles produced in the local or semi-regional ambient conditions.


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