scholarly journals Impact of the Incorporation of Nano-Sized Cellulose Formate on the End Quality of Polylactic Acid Composite Film

Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 1
Author(s):  
Yidong Zhang ◽  
Chao Liu ◽  
Meiyan Wu ◽  
Zhenqiu Li ◽  
Bin Li

Polylactic acid (PLA) films with good sustainable and biodegradable properties have been increasingly explored recently, while the poor mechanical property of PLA limits its further application. Herein, three kinds of nano-sized cellulose formate (NCF: cellulose nanofibril (CNF), cellulose nanocrystal (CNC), and regenerated cellulose formate (CF)) with different properties were fabricated via a one-step formic acid (FA) hydrolysis of tobacco stalk, and the influence of the properties of NCF with different morphologies, crystallinity index (CrI), and degree of substitution (DS) on the end quality of PLA composite film was systematically compared. Results showed that the PLA/CNC film showed the highest increase (106%) of tensile strength compared to the CNF- and CF-based films, which was induced by the rod-like CNC with higher CrI. PLA/CF film showed the largest increase (50%) of elongation at the break and more even surface, which was due to the stronger interfacial interaction between PLA and the CF with higher DS. Moreover, the degradation property of PLA/CNF film was better than that of other composite films. This fundamental study was very beneficial for the development of high-quality, sustainable packaging as an alternative to petroleum-based products.

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2481
Author(s):  
Zhuo Zhao ◽  
Fang Fang ◽  
Junsheng Wu ◽  
Xinru Tong ◽  
Yanwen Zhou ◽  
...  

Research on the preparation and performance of graphene composite materials has become a hotspot due to the excellent electrical and mechanical properties of graphene. Among such composite materials, zinc oxide/graphene (ZnO/graphene) composite films are an active research topic. Therefore, in this study, we used the vacuum thermal evaporation technique at different evaporation voltages to fabricate an amorphous ZnO/graphene composite film on a flexible polyethylene terephthalate (PET). The amorphous ZnO/graphene composite film inherited the great transparency of the graphene within the visible spectrum. Moreover, its electrical properties were better than those of pure ZnO but less than those of graphene, which is not consistent with the original theoretical research (wherein the performance of the composite films was better than that of ZnO film and slightly lower than that of graphene). For example, the bulk free charge carrier concentrations of the composite films (0.13, 1.36, and 0.47 × 1018 cm−3 corresponding to composite films with thicknesses of 40, 75, and 160 nm) were remarkably lower than that of the bare graphene (964 × 1018 cm−3) and better than that of the ZnO (0.10 × 1018 cm−3). The underlying mechanism for the abnormal electrical performance was further demonstrated by X-ray photoelectron spectroscopy (XPS) detection and first-principles calculations. The analysis found that chemical bonds were formed between the oxide (O) of amorphous ZnO and the carbon (C) of graphene and that the transfer of the π electrons was restricted by C=O and C-O-C bonds. Given the above, this study further clarifies the mechanism affecting the photoelectric properties of amorphous composite films.


2014 ◽  
Vol 513-517 ◽  
pp. 37-40
Author(s):  
Heng Guang Zhang ◽  
Fu Xin Yang ◽  
Ye Lu

PE/thermochromic composite membrane is a kind of new functional materials which is composited by PE and thermochromic membrane.PE/thermochromic composite films retain the thermochromic membrane performance of changing the color by absorbing the heat. The composite film cannot be dissolved by water because of the structure which PE film is attached to the both sides of thermochromic film.The effect of the composite film and Nylon/low density polyethylene (LDPE) film on quality of fresh pork meat stored were investigated respectively. The treated meat samples were analyzed periodically for color difference. The results indicate that preservation effect of both films has no significant difference when the fresh pork are stored at 3-5°C, but PE/thermochromic composite films has better preservation effect at 30°C in compared to the Nylon/ LDPE. filmsfilms


2018 ◽  
Vol 24 (4) ◽  
pp. 330-340 ◽  
Author(s):  
Khaled F Mahmoud ◽  
Heba I Abo-Elmagd ◽  
Manal M Housseiny

The present study aimed to compare the pectinase forms produced from Trichoderma viride—free, micro-capsule, and nano-capsule—in sodium alginate to analyze the pectin that causes the turbidity of orange juice. This was performed along with an estimation of viscosity, residual of pectin, and turbidity. The extracted and purified enzyme was 24.35-fold better than that of the crude enzyme. After application of free one, it loses most of the activity on low degrees of acidity and remains constant on the temperatures of pasteurization. Therefore, the tested enzyme was encapsulated by two different ways using the same polymer. The morphology of the three pectinase forms was obtained by transmission electron microscopy, and the micrographs clearly showed the pores on the surface of sodium alginate matrix after encapsulation. The size of the wall (sodium alginate) ranged from 3.24 to 3.76 µm diameter but was 3.15 µm for core of enzyme. Micro-capsuled and nano-capsuled pectinase can be used in the hydrolysis of pectic substances in orange juice with natural ways and maintaining the quality of final product. Consequently, the cost of juice clarifying can be reduced due to reusing the enzyme several times.


2021 ◽  
Vol 4 (2) ◽  
pp. 13-17
Author(s):  
I. F. Bezpalyi

The purpose of the work is an experimental substantiation of biotechnological processes that ensure the maturation of honey during the processing of nectar by bees. During the whole period (7–9 days) of nectar treatment by bees there is a simultaneous partial dehydration of the liquid and biochemical transformations, among which the hydrolysis of sucrose and the accumulation of monosaccharides have the most significant effect on the quality of the mature product. In all series of experiments, the maturity of processed honey in the beehive at the water limit of less than 20 % occurs after 5–6 days of treatment by bees. The mature product in terms of water content remains open in almost completely filled cells for another 3–5 days, slightly reducing the water content from 19.78–20.07 % up to 16.40–18.38 %. Dynamic changes in the ratio of monosaccharides and sucrose in the process of nectar processing by bees, starting from the honey stomach during gathering from flowers to sealing in honeycomb cells have been detected. At the honey stomach-cell stage, a small amount of sucrose is hydrolyzed during the incomplete first day of processing and, as a rule, 0.48–4.11 % of monosaccharides calculated relative to the dry weight of the product are added. Sucrose inversion is more intense during the next 5–6 days, when a total of 12.94–31.42 % of splitted sugars are added, depending on their initial number and strength of families. The main processes of conversion of nectar into honey by bees are characterized by the advance of the reduction of water content in comparison with the splitting of sucrose and the accumulation of monosaccharides. According to the water content (less than 20 %), honey becomes suitable for pumping 3–5 days before it is sealed in the cells. The influence of the mass of bees of different families on the intensity of sucrose inversion in the cells and the accumulation of monosaccharides in the product has been experimentally proved. The maturity of honey in the ratio of sugars in the beehives of strong families is better than in weak ones.


2006 ◽  
Vol 11-12 ◽  
pp. 555-558
Author(s):  
Hong Mei Chai ◽  
Dong Lin Zhao ◽  
Zeng Min Shen

The carbon nanotube/PMMA/PVAc composite film was prepared by solution casting. The carbon nanotube (CNT) and graphitized carbon nanotube (GCNT) were employed as conductive fillers in the composite films. The conductivity of the GCNT/PMMA/PVAc film is better than that of CNT/PMMA/PVAc film. The electrical percolation thresholds were at 5wt% and 2wt% respectively in the CNT/PMMA/PVAc film and GCNT/PMMA/PVAc film. The volume electric resistivities of CNT/PMMA/PVAc and GCNT/PMMA/PVAc composite film are at 0.044⋅m and 0.007⋅m respectively at 15wt% carbon nanotube. The significant difference of resistivity for the both types of composite film was due to different structure and crystallinity of CNT and GCNT.


2014 ◽  
Vol 936 ◽  
pp. 419-423
Author(s):  
Wei Yao ◽  
Guang Zhong Xie ◽  
Hui Ling Tai ◽  
Ya Dong Jiang ◽  
Yong Zhou

Abstract: In this paper, Polyepichlorohyron(PECH)/multi-wall carbon nanotubes(MWCNTs) composite films and PECH/multi-wall carbon nanotubes twolayer film were deposited on interdigitated electrodes by airbrush technology to detect ethanol vapor of various concentrations at room temperature. Thickness and structure of the film were taken into account, so films of different thicknesses and with different structures were prepared respectively. The responses of the sensors to ethanol showed that composite film had a higher response thantwolayer film, and the thick composite film performed better than its counterpart when they were exposed to ethanol vapor.


RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16340-16347 ◽  
Author(s):  
Yongming Li ◽  
Xiuyuan Ni

A nonvolatile rewritable memory composite film consisting of PEDOT and GO has been prepared by using GO-initiated photopolymerization.


Liquidity ◽  
2018 ◽  
Vol 2 (2) ◽  
pp. 151-159
Author(s):  
Pitri Yandri

The purpose of this study is (1) to analyze public perception on urban services before and after the expansion of the region, (2) analyze the level of people's satisfaction with urban services, and (3) analyze the determinants of the variables that determine what level of people's satisfaction urban services. This study concluded that first, after the expansion, the quality of urban services in South Tangerang City is better than before. Secondly, however, public satisfaction with the services only reached 48.53% (poor scale). Third, by using a Cartesian Diagram, the second priority that must be addressed are: (1) clarity of service personnel, (2) the discipline of service personnel, (3) responsibility for care workers; (4) the speed of service, (5) the ability of officers services, (6) obtain justice services, and (7) the courtesy and hospitality workers.


2019 ◽  
Vol 9 (01) ◽  
pp. 47-54
Author(s):  
Rabbai San Arif ◽  
Yuli Fitrisia ◽  
Agus Urip Ari Wibowo

Voice over Internet Protocol (VoIP) is a telecommunications technology that is able to pass the communication service in Internet Protocol networks so as to allow communicating between users in an IP network. However VoIP technology still has weakness in the Quality of Service (QoS). VOPI weaknesses is affected by the selection of the physical servers used. In this research, VoIP is configured on Linux operating system with Asterisk as VoIP application server and integrated on a Raspberry Pi by using wired and wireless network as the transmission medium. Because of depletion of IPv4 capacity that can be used on the network, it needs to be applied to VoIP system using the IPv6 network protocol with supports devices. The test results by using a wired transmission medium that has obtained are the average delay is 117.851 ms, jitter is 5.796 ms, packet loss is 0.38%, throughput is 962.861 kbps, 8.33% of CPU usage and 59.33% of memory usage. The analysis shows that the wired transmission media is better than the wireless transmission media and wireless-wired.


2018 ◽  
Vol 5 (2) ◽  
pp. 102
Author(s):  
Enike Dwi Kusumawati ◽  
Selvinus Lawu Woli ◽  
Aju Tjatur Nugroho Krisnaningsih ◽  
Waluyo Edi Susanto ◽  
Syam Rahadi

ABSTRAKPenelitian ini dilakukan untuk mengetahui motilitas dan viabilitas spermatozoa ayam kampung pada suhu 5oC menggunakan pengencer dan lama simpan yang berbeda. Metode yang digunakan dalam penelitian ini adalah penelitian laboratorium menggunakan Rancangan Acak Lengkap (RAL) Faktorial dengan pengencer ringer lactat solution, air kelapa dan tanpa pengencer serta lama simpan 0, 3, 6, 9, 12, 15, 18, 21, 24, 27, 30, masing-masing diulang 10 kali. Variabel yang diamati yaitu motilitas dan viabilitas spermatozoa. Analisa data yang digunakan adalah analisis varian. Hasil analisis data menunjukkan bahwa motilitas dan viabilitas spermatozoa menggunakan pengencer ringer lactat solution lebih tinggi (P<0,01) serta dapat bertahan sampai lama simpan 24 jam dibandingkan air kelapa dan tanpa pengencer. Adapun nilai motilitas ringer lactat solution, air kelapa dan tanpa pengencer pada lama simpan 24 jam masing-masing sebesar 43,5±17,17%; 8±4,83%; 6,5±2,4%, sedangkan nilai viabilitasnya sebesar 83,2±7,25%; 64,6±3,20%; dan 63,1±2,33%. Kesimpulan dari hasil penelitian ini adalah ringer lactat solution lebih baik dibandingkan air kelapa dan tanpa pengencer dalam mempertahankan kualitas semen ayam kampung pada suhu simpan 5oC sampai lama simpan 24 jam.Kata Kunci : air kelapa, ayam kampung, motilitas, spermatozoa, viabilitas  ABSTRACTThis study was conducted to determine the motility and viability of spermatozoa of Native chickens at 5oC using different diluents and time storage. The method used in this study was laboratory research using Factorial Completely Randomized Design with ringer lactate solution, coconut water and without diluent at 0, 3, 6, 9, 12, 15, 18, 21, 24, 27, 30 hours of time storage each repeated 10 times. The variables observed were motility and viability of sperm. Data analysis used is variance analysis. The results of data analysis showed that the motility and viability of spermatozoa using ringer lactate solution diluents was higher (P <0.05) than coconut water and without diluents. The motility values of ringer lactat solution, coconut water and without diluents were 43,5±17,17%; 8±4,83%; 6,5±2,4% respectively, while the viability values were 83,2±7,25%; 64,6±3,20% and 63,1±2,33%. The conclusion of this study is that ringer lactat solution is better than coconut water an without diluents in maintaining the quality of Native chicken semen at a storage temperature of 5oC until 24 hours.Keywords: coconut water, motility, native chicken, sperm, viability


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