scholarly journals Enhanced Interfacial and Mechanical Properties of PBX Composites via Surface Modification on Energetic Crystals

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1308 ◽  
Author(s):  
Chengcheng Zeng ◽  
Zhijian Yang ◽  
Jianhu Zhang ◽  
Yubin Li ◽  
Congmei Lin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Interfacial Interaction ◽  
Polar Component ◽  
Sem Images ◽  
Polymer Binders ◽  
A Value ◽  
Polymer Bonded Explosives ◽  
Two Phases ◽  
Energetic Composites

The mechanical properties of composites are highly dependent on the interfacial interaction. In the present work, inspired by marine mussel, the adhesion between energetic crystals of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) and polymer binders was improved. Three types of linear polymeric agents of glycidyl azide polymer (GAP), polyethylene glycol (PEG), and polytetramethylene ether glycol (PTMEG) were grafted onto TATB particles bridged through polydopamine (PDA) films. SEM images showed that 5% grafting contents could evidently form roughness shells on the surface. With a reinforcement at the interface produced by grafting shells, the mechanical properties of polymer-bonded explosives (PBXs) exhibited outstanding mechanical performance, especially for the PTMEG-grafting sample. Examined by the contact-angle test, the PTMEG-grafting sample possessed a value of polar component similar to that of fluoropolymer, leading to an excellent wettability of the two phases. Additionally, different contents of PTMEG were grafted to reveal that the mechanical properties could be improved even with content as little as 0.5 wt.% PTMEG. These results might highlight a correlation between interfacial interaction and macroscopic properties for mechanically energetic composites, while providing a versatile route of grafting on highly loaded composites.

Evaluation of the Mechanical Properties of Self-Compacting Lightweight Concrete Exposed to Wet and Dry Cycles in Saltwater

2016 ◽  
Vol 711 ◽  
pp. 218-223
Author(s):  
Sherif Yehia ◽  
Sharef Farrag
Keyword(s):  
Mechanical Properties ◽  
Phase Ii ◽  
Lightweight Concrete ◽  
Experimental Program ◽  
Strength Development ◽  
Sem Images ◽  
Paper Properties ◽  
Two Phases ◽  
Wet And Dry Cycles ◽  
Exposure Conditions

In this paper, properties of a self-compacting lightweight concrete that has been exposed to cycles of wetting in saltwater and drying in air are investigated. Such exposure conditions are common in marine structures with pronounced sea level variation. The experimental program consisted of two phases; Phase I included monitoring of the strength development for 28 days, while in Phase II samples were exposed to wet/dry cycles for 12 months. In addition, control samples were kept in room temperature without exposure for comparison. Compressive and flexural strength, modulus of elasticity and Rapid Chloride Penetration (RCP) were included in the investigation. In addition, Scanning Electron Microscopy (SEM) was conducted to examine the microstructure of the samples in phase II. Results from the experimental program indicate that there was a negligible effect on the mechanical properties or RCP due to the exposure conditions. However, a close inspection of the SEM images showed salt deposits and micro cracking in the cement paste. This may affect the long-term durability and can lead to deterioration of the concrete structure, hence reducing the structure’s service life.

Molecular dynamics simulations for 5,5′-bistetrazole-1,1′-diolate (TKX-50) and its PBXs

RSC Advances ◽  
2016 ◽  
Vol 6 (24) ◽  
pp. 20034-20041 ◽  
Author(s):  
Yuehai Yu ◽  
Shusen Chen ◽  
Xin Li ◽  
Jiaping Zhu ◽  
Hui Liang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Molecular Dynamics ◽  
Molecular Dynamics Simulations ◽  
Binding Energies ◽  
Detonation Properties ◽  
Polymer Binders ◽  
Polymer Bonded Explosives ◽  
Dynamics Simulations

Molecular dynamics has been carried out to study the mechanical properties, moldability, binding energies, and detonation properties of TKX-50 and TKX-50 based polymer bonded explosives (PBXs) with four commonly used polymer binders.

The Effect of Alkalization Treatment on Fiber-Matrix Compatibility in Natural Fiber Reinforced Composite

2020 ◽  
Vol 847 ◽  
pp. 28-33
Author(s):  
Evana Yuanita ◽  
Yuli Amalia Husnil ◽  
Myrna Ariati Mochtar ◽  
Rahma Lailani ◽  
Mochamad Chalid
Keyword(s):  
Tensile Strength ◽  
Surface Energy ◽  
Natural Fiber ◽  
Contact Angle Measurement ◽  
Angle Measurement ◽  
Interfacial Interaction ◽  
Polar Component ◽  
Sem Images ◽  
Treated Fiber ◽  
Fiber Matrix

This work was aimed to investigate the effect of alkalization treatment on the fiber-matrix interfacial interaction and hence their compatibility. Kenaf fiber was treated using a 6% NaOH solution for 8 hours. The composites were produced by mixing the treated fiber with PP at various temperatures, duration, and fiber composition. Alteration on the surface chemistry of the fiber was identified by performing FTIR analysis. The surface energy of the treated fiber was mathematically derived from the contact angle measurement results. The compatibility level between treated fiber and PP matrix was visualized through FESEM analysis. Tensile strength tests were also conducted to obtain data necessary for exploring the relationship between the thermodynamic aspects of the fiber-matrix interfacial interaction and the mechanical properties of the composites. The FTIR spectra show that there was significant increase in the %transmittance at wavelength range of 3100-3600 cm-1 indicating that O-H groups were degraded during treatment. However, the polar component of the surface energy for treated fiber was instead higher compared to the untreated one. The SEM images show that there are no noticeable reduction in the size of the treated fibers as expected. On the other hand, the tensile strength of the PP-treated fibers composites reached its highest value when the matrix were loaded with fibers at the lowest percentage i.e. 5%.

Weldability - Behavior of Welded Reinforcement

2019 ◽  
Vol 70 (10) ◽  
pp. 3469-3472
Keyword(s):  
Mechanical Properties ◽  
Chemical Composition ◽  
Mechanical Characteristics ◽  
Mechanical Performance ◽  
Current Work ◽  
Carbon Equivalent ◽  
Work Process ◽  
Ultimate Limit

Weldability involves two aspects: welding behavior of components and safety in operation. The two aspects will be reduced to the mechanical characteristics of the elements and to the chemical composition. In the case of steel reinforcing rebar’s, it is reduces to the percentage of Cech(carbon equivalent) and to the mechanical characteristics: the yielding limit, the ultimate limit, and the elongations which after that represent the ductility class in which the re-bars is framed. The paper will present some types of steel reinforcing rebar’s with its mechanical characteristics and the welding behavior of those elements. In the current work, process-related behavior of welded reinforcement, joint local and global mechanical properties, and their correlation with behavior of normal reinforcement and also the mechanical performance resulted in this type of joints. Keywords: welding behavior, ultimate limit, reinforcing rebar’s

scholarly journals Preparation of Long Sisal Fiber-Reinforced Polylactic Acid Biocomposites with Highly Improved Mechanical Performance

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1124
Author(s):  
Zhifang Liang ◽  
Hongwu Wu ◽  
Ruipu Liu ◽  
Caiquan Wu
Keyword(s):  
Mechanical Properties ◽  
Polylactic Acid ◽  
Mechanical Performance ◽  
Tensile Elongation ◽  
Sisal Fiber ◽  
Fiber Reinforced ◽  
Impact Performance ◽  
The Matrix ◽  
Blending Process ◽  
Extension Direction

Green biodegradable plastics have come into focus as an alternative to restricted plastic products. In this paper, continuous long sisal fiber (SF)/polylactic acid (PLA) premixes were prepared by an extrusion-rolling blending process, and then unidirectional continuous long sisal fiber-reinforced PLA composites (LSFCs) were prepared by compression molding to explore the effect of long fiber on the mechanical properties of sisal fiber-reinforced composites. As a comparison, random short sisal fiber-reinforced PLA composites (SSFCs) were prepared by open milling and molding. The experimental results show that continuous long sisal fiber/PLA premixes could be successfully obtained from this pre-blending process. It was found that the presence of long sisal fibers could greatly improve the tensile strength of LSFC material along the fiber extension direction and slightly increase its tensile elongation. Continuous long fibers in LSFCs could greatly participate in supporting the load applied to the composite material. However, when comparing the mechanical properties of the two composite materials, the poor compatibility between the fiber and the matrix made fiber’s reinforcement effect not well reflected in SSFCs. Similarly, the flexural performance and impact performance of LSFCs had been improved considerably versus SSFCs.

scholarly journals Tribological and Mechanical Properties of Multicomponent CrVTiNbZr(N) Coatings

Coatings ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 41
Author(s):  
Yin-Yu Chang ◽  
Cheng-Hsi Chung
Keyword(s):  
Mechanical Properties ◽  
Nitrogen Content ◽  
Adhesion Strength ◽  
Mechanical Performance ◽  
Bulk Material ◽  
High Entropy Alloy ◽  
Composition Gradient ◽  
Multilayered Structures ◽  
High Entropy ◽  
Alloy Target

Multi-element material coating systems have received much attention for improving the mechanical performance in industry. However, they are still focused on ternary systems and seldom beyond quaternary ones. High entropy alloy (HEA) bulk material and thin films are systems that are each comprised of at least five principal metal elements in equally matched proportions, and some of them are found possessing much higher strength than traditional alloys. In this study, CrVTiNbZr high entropy alloy and nitrogen contained CrVTiNbZr(N) nitride coatings were synthesized using high ionization cathodic-arc deposition. A chromium-vanadium alloy target, a titanium-niobium alloy target and a pure zirconium target were used for the deposition. By controlling the nitrogen content and cathode current, the CrNbTiVZr(N) coating with gradient or multilayered composition control possessed different microstructures and mechanical properties. The effect of the nitrogen content on the chemical composition, microstructure and mechanical properties of the CrVTiNbZr(N) coatings was investigated. Compact columnar microstructure was obtained for the synthesized CrVTiNbZr(N) coatings. The CrVTiNbZrN coating (HEAN-N165), which was deposited with nitrogen flow rate of 165 standard cubic centimeters per minute (sccm), exhibited slightly blurred columnar and multilayered structures containing CrVN, TiNbN and ZrN. The design of multilayered CrVTiNbZrN coatings showed good adhesion strength. Improvement of adhesion strength was obtained with composition-gradient interlayers. The CrVTiNbZrN coating with nitrogen content higher than 50 at.% possessed the highest hardness (25.2 GPa) and the resistance to plastic deformation H3/E*2 (0.2 GPa) value, and therefore the lowest wear rate was obtained because of high abrasion wear resistance.

Experimental investigation of the mechanical behavior of glass fiber/high fluidity polyamide-based composites for automotive market

2021 ◽  
pp. 073168442110140
Author(s):  
Hossein Ramezani-Dana ◽  
Moussa Gomina ◽  
Joël Bréard ◽  
Gilles Orange
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
Mechanical Performance ◽  
Physical And Mechanical Properties ◽  
Ultimate Strain ◽  
Uniaxial Tensile ◽  
Compression Tests ◽  
Automotive Market ◽  
Glass Fiber Reinforced ◽  
Glass Fiber Reinforcement

In this work, we examine the relationships between the microstructure and the mechanical properties of glass fiber–reinforced polyamide 6,6 composite materials ( V f = 54%). These materials made by thermocompression incorporate different grades of high fluidity polyamide-based polymers and two types of quasi-UD glass fiber reinforcement. One is a classic commercial fabric, while the other specially designed and manufactured incorporates weaker tex glass yarns (the spacer) to increase the planar permeability of the preform. The effects of the viscosity of the polymers and their composition on the wettability of the reinforcements were analyzed by scanning electron microscopy observations of the microstructure. The respective influences of the polymers and the spacer on the mechanical performance were determined by uniaxial tensile and compression tests in the directions parallel and transverse to the warp yarns. Not only does the spacer enhance permeability but it also improves physical and mechanical properties: tensile longitudinal Young’s modulus increased from 38.2 GPa to 42.9 GPa (13% growth), tensile strength increased from 618.9 MPa to 697 MPa (3% growth), and decrease in ultimate strain from 1.8% to 1.7% (5% reduction). The correlation of these results with the damage observed post mortem confirms those acquired from analyses of the microstructure of composites and the rheological behaviors of polymers.

scholarly journals Effects of a Twin-Screw Extruder Equipped with a Molten Resin Reservoir on the Mechanical Properties and Microstructure of Recycled Waste Plastic Polyethylene Pellet Moldings

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1058
Author(s):  
Hikaru Okubo ◽  
Haruka Kaneyasu ◽  
Tetsuya Kimura ◽  
Patchiya Phanthong ◽  
Shigeru Yao
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Value Added ◽  
Industrial Applications ◽  
Twin Screw Extruder ◽  
Screw Extruder ◽  
Polymer Properties ◽  
Wide Range ◽  
Twin Screw ◽  
Recycled Plastics

Each year, increasing amounts of plastic waste are generated, causing environmental pollution and resource loss. Recycling is a solution, but recycled plastics often have inferior mechanical properties to virgin plastics. However, studies have shown that holding polymers in the melt state before extrusion can restore the mechanical properties; thus, we propose a twin-screw extruder with a molten resin reservoir (MSR), a cavity between the screw zone and twin-screw extruder discharge, which retains molten polymer after mixing in the twin-screw zone, thus influencing the polymer properties. Re-extruded recycled polyethylene (RPE) pellets were produced, and the tensile properties and microstructure of virgin polyethylene (PE), unextruded RPE, and re-extruded RPE moldings prepared with and without the MSR were evaluated. Crucially, the elongation at break of the MSR-extruded RPE molding was seven times higher than that of the original RPE molding, and the Young’s modulus of the MSR-extruded RPE molding was comparable to that of the virgin PE molding. Both the MSR-extruded RPE and virgin PE moldings contained similar striped lamellae. Thus, MSR re-extrusion improved the mechanical performance of recycled polymers by optimizing the microstructure. The use of MSRs will facilitate the reuse of waste plastics as value-added materials having a wide range of industrial applications.

scholarly journals Microstructure and Mechanical Performance of Resistance Spot Welded Martensitic Advanced High Strength Steel

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1021
Author(s):  
Yunzhao Li ◽  
Huaping Tang ◽  
Ruilin Lai
Keyword(s):  
Mechanical Properties ◽  
Failure Modes ◽  
Mechanical Performance ◽  
Strong Dependence ◽  
High Strength ◽  
Weld Nugget ◽  
Resistance Spot ◽  
Pull Out ◽  
Cross Tension ◽  
Spot Welded

Resistance spot welded 1.2 mm (t)-thick 1400 MPa martensitic steel (MS1400) samples are fabricated and their microstructure, mechanical properties are investigated thoroughly. The mechanical performance and failure modes exhibit a strong dependence on weld-nugget size. The pull-out failure mode for MS1400 steel resistance spot welds does not follow the conventional weld-nugget size recommendation criteria of 4t0.5. Significant softening was observed due to dual phase microstructure of ferrite and martensite in the inter-critical heat affected zone (HAZ) and tempered martensite (TM) structure in sub-critical HAZ. However, the upper-critical HAZ exhibits obvious higher hardness than the nugget zone (NZ). In addition, the mechanical properties show that the cross-tension strength (CTS) is about one quarter of the tension-shear strength (TSS) of MS1400 weld joints, whilst the absorbed energy of cross-tension and tension-shear are almost identical.

scholarly journals Functional Bionanocomposite Fibers of Chitosan Filled with Cellulose Nanofibers Obtained by Gel Spinning

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1563
Author(s):  
Sofia Marquez-Bravo ◽  
Ingo Doench ◽  
Pamela Molina ◽  
Flor Estefany Bentley ◽  
Arnaud Kamdem Tamo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Cellulose Nanofibers ◽  
Microstructural Characterization ◽  
Fiber Formation ◽  
Fiber Direction ◽  
Composite Fibers ◽  
X Ray Diffraction ◽  
Gel Spinning ◽  
X Ray

Extremely high mechanical performance spun bionanocomposite fibers of chitosan (CHI), and cellulose nanofibers (CNFs) were successfully achieved by gel spinning of CHI aqueous viscous formulations filled with CNFs. The microstructural characterization of the fibers by X-ray diffraction revealed the crystallization of the CHI polymer chains into anhydrous chitosan allomorph. The spinning process combining acidic–basic–neutralization–stretching–drying steps allowed obtaining CHI/CNF composite fibers of high crystallinity, with enhanced effect at incorporating the CNFs. Chitosan crystallization seems to be promoted by the presence of cellulose nanofibers, serving as nucleation sites for the growing of CHI crystals. Moreover, the preferential orientation of both CNFs and CHI crystals along the spun fiber direction was revealed in the two-dimensional X-ray diffraction patterns. By increasing the CNF amount up to the optimum concentration of 0.4 wt % in the viscous CHI/CNF collodion, Young’s modulus of the spun fibers significantly increased up to 8 GPa. Similarly, the stress at break and the yield stress drastically increased from 115 to 163 MPa, and from 67 to 119 MPa, respectively, by adding only 0.4 wt % of CNFs into a collodion solution containing 4 wt % of chitosan. The toughness of the CHI-based fibers thereby increased from 5 to 9 MJ.m−3. For higher CNFs contents like 0.5 wt %, the high mechanical performance of the CHI/CNF composite fibers was still observed, but with a slight worsening of the mechanical parameters, which may be related to a minor disruption of the CHI matrix hydrogel network constituting the collodion and gel fiber, as precursor state for the dry fiber formation. Finally, the rheological behavior observed for the different CHI/CNF viscous collodions and the obtained structural, thermal and mechanical properties results revealed an optimum matrix/filler compatibility and interface when adding 0.4 wt % of nanofibrillated cellulose (CNF) into 4 wt % CHI formulations, yielding functional bionanocomposite fibers of outstanding mechanical properties.

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