scholarly journals Aging Mechanism and Rejuvenating Possibility of SBS Copolymers in Asphalt Binders

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 92 ◽  
Author(s):  
Fusong Wang ◽  
Lei Zhang ◽  
Xiaoshan Zhang ◽  
Hechuan Li ◽  
Shaopeng Wu
Keyword(s):  
Physical Properties ◽  
Chemical Structure ◽  
Asphalt Pavement ◽  
Asphalt Binder ◽  
Road Construction ◽  
Rheological Characteristic ◽  
Waste Cooking Oil ◽  
Asphalt Binders ◽  
Negative Effects ◽  
Modified Asphalt

The styrene–butadiene–styrene (SBS)-modified asphalt pavement has been in growing demand in the road construction field owing to its workable mechanical property and temperature durability. This paper prepared a penetrative rejuvenator (PR) with waste cooking oil (WCO) and emulsified asphalt, then applied PR on SBS copolymers to investigate its aging and rejuvenating effects in an asphalt binder. After a thin film oven test (TFOT) and ultraviolet (UV) aging of SBS copolymers, Fourier transform infrared (FTIR) spectra were used to analyse the aged copolymers’ chemical structure. Moreover, both aged and rejuvenated SBS copolymers were added into a fresh asphalt binder to get two kinds of modified asphalt binders, namely, MAAC (modified by aged copolymer) and MARC (modified by rejuvenated copolymer). Aiming to analyse the monomer effect of SBS copolymers in the asphalt binder, the rheological characteristic with dynamic shear rheometer (DSR), chemical structure with FTIR and physical properties with penetration, soft point and ductility tests were investigated using MAAC and MAAC samples. The results showed that rejuvenated SBS copolymer could improve MAAC’s viscoelasticity, but from FTIR spectral analysis, PR resulted in no chemical changes to SBS copolymers. A tough coat which made MAAC of higher stiffness was observed on the copolymer surface after thermal treatment. UV caused evidently negative effects on SBS copolymer because of accelerating oxidation by ozone, which brought about high possibility of cracks during servicing periods of asphalt pavement. In addition, MAAC was inferior in both rheological and physical properties, which reflected the significance and necessity in consideration of alleviating SBS copolymer aging in field.

PHYSICAL PROPERTIES AND STORAGE STABILITY OF GEOPOLYMER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-2) ◽  
Author(s):  
Ahmad Nazrul Hakimi Ibrahim ◽  
Nur Izzi Md. Yusoff ◽  
Norliza Mohd Akhir ◽  
Muhamad Nazri Borhan
Keyword(s):  
Physical Properties ◽  
Storage Stability ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Potential Alternative ◽  
Modified Binder ◽  
And Storage

This study was conducted to investigate the physical properties and storage stability of the 80/100 penetration grade asphalt modified with geopolymer. In this research, fly ash and alkali activators, namely sodium silicate (Na2SiO3) and sodium hydroxide (NaOH), were used as geopolymer components. The penetration, Ring and Ball softening point, ductility, and viscosity tests were conducted to determine the physical properties of geopolymer modified asphalt (GMA). Five samples of asphalt binders with varying percentages of geopolymer, namely 0, 3, 5, 7 and 9%, by weight of asphalt binder were studied. Results show that geopolymer has good compatibility with asphalt binder. The addition of geopolymer into asphalt binder resulted in improved permanent deformation resistance of the modified binder compared to that of the conventional asphalt. In conclusion, geopolymer could be considered as a potential alternative in the modification of the properties of asphalt binder.

Effect of Antioxidant Characteristic from Waste Cooking Oil in Modified Asphalt Binder

2016 ◽  
Vol 700 ◽  
pp. 197-206 ◽  
Author(s):  
Wan Nur Aifa Wan Azahar ◽  
Mastura Bujang ◽  
Ramadhansyah Putra Jaya ◽  
Mohd Rosli Hainin ◽  
Norzita Ngadi ◽  
...  
Keyword(s):  
Aging Process ◽  
Asphalt Pavement ◽  
Asphalt Binder ◽  
Waste Cooking Oil ◽  
Short Term ◽  
Aging Rate ◽  
Modified Asphalt ◽  
Cooking Oil ◽  
Modified Asphalt Binder

Aging process especially in asphalt binder material can occur throughout the life cycle of asphalt pavement starting from mixing, placement and during the service life. During this process, the more stiffer and brittle of asphalt binder is produced due to age hardening and gives an indication of initial factor of deterioration in asphalt pavement. A number of noteworthy researchers have focused on oil based modification to produce modified asphalt binder by using Waste Cooking Oil (WCO), due to the presence of natural antioxidant properties possessed in WCO. Antioxidant has played the role as an oxidative inhibition and has the potential to minimize the aging rate to occur. The aging process is conducted by separating between short term and long term aging where short term oxidative aging of binders was simulated using rolling thin film oven (RTFO) while long term aging was performed using pressure aging vessel (PAV). The laboratory evaluation was carried out to investigate the relationship between the qualities of WCO that affect the availability of antioxidant amount towards the susceptibility of aging rate by conducting Dynamic Shear Rheometer (DSR). The result from rheological studies demonstrated that the lowest Aging Index (AI) is presented as 2.14, 2.18 and 1.79 for replacement by using WCO in December sample at concentration of 3%, 4% and 5% for short term aging while AI at 3% = 5.17 and 5% = 7.22 for long term aging. Therefore, the high quality of oil represented by WCO in December sample has indicated the high availability of antioxidant content that can minimize the aging susceptibility in the asphalt binder modified by WCO.

Polyacrylate Modified Binder for Sustainable Asphalt Pavement Performances Using Superpave Mix Design

2015 ◽  
Vol 747 ◽  
pp. 238-241
Author(s):  
Wan Adilah Ismail ◽  
Intan Rohani Endut ◽  
Sit Zaharah Ishak
Keyword(s):  
Material Selection ◽  
Asphalt Pavement ◽  
Asphalt Binder ◽  
Binder Content ◽  
Mix Design ◽  
Asphalt Binders ◽  
Air Voids ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Pavement Construction

Sustainable asphalt pavement is important in decreasing material costs by improving the existing material such as modified asphalt binders. It is also needed to provide a quality riding for road users. In achieving quality riding, the material selection and mix design must be correctly examined before using in pavement construction. Then, the aims of this study are to determine suitability of material selected by examining the aggregate properties and modified asphalt binder. In modified asphalt binder, 6% of polyacrylate polymer was added as an additive in 500g of binder content to dissolve. It was checked through Superpave gyratory compactor in determining air voids samples in term of height after compacted. The samples were mixed with different percentages of binder content; 5%, 5.5%, 6% and 6.5% to produce control and polyacrylate modified samples. 8 gyratory for Ninitialand 100 gyratory for Ndesignwere used in compaction of samples to determine air voids in term of height. The results show that 5.5% of binder content of polyacrylate modified samples has lower air voids compare than control samples. Thus, modified binders are able to minimize binder usage and save natural sources and also cost by improving bonding between mixtures to prevent pavement failure

scholarly journals Impact of Ultraviolet Radiation on the Aging Properties of SBS-Modified Asphalt Binders

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1111 ◽  
Author(s):  
Huanan Yu ◽  
Xianping Bai ◽  
Guoping Qian ◽  
Hui Wei ◽  
Xiangbing Gong ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Uv Radiation ◽  
Asphalt Pavement ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Shrinkage Stress ◽  
Uv Aging ◽  
Modified Asphalt ◽  
Aging Properties ◽  
Sbs Modified Asphalt

Styrene Butadiene Styrene (SBS) polymer-modified asphalt binders have become widely used in asphalt pavement because of their advantages in high- and low-temperature performance and fatigue resistance. Asphalt pavement is inevitably exposed to sunlight and ultraviolet (UV) radiation during its construction and service life. However, consideration of the aging effect of UV radiation is still limited in current pavement design and evaluation systems. In order to evaluate the impact of UV radiation on the aging properties of SBS-modified asphalt binders, UV aging tests were performed on Rolling Thin Film Oven Test (RTFOT)-aged samples with different UV radiation intensities and aging times. Sixteen different groups of tests were conducted to compare the rheological properties and functional group characteristics of SBS-modified asphalt binders. Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR), FTIR, and SEM tests were conducted to evaluate the aging mechanisms in various UV aging conditions. The results found that UV radiation seriously destroys the network structure formed by the cross-linking effect in SBS-modified asphalt binders, which aggravates the degradation of SBS and results in a great change of rheological properties after UV aging. The nature of SBS-modified asphalt binder aging resulted from the degradation of SBS and the changes of asphalt binder base composition, which lead to the transformation of colloidal structure and the deterioration of asphalt binder performance. The tests also found that continuous UV radiation can increase shrinkage stress in the asphalt binder surface and leads to surface cracking of the asphalt binder.

scholarly journals A COMPARATIVE STUDY OF PHYSICAL PROPERTIES USING VARIOUS GRADES ASPHALT BINDER WITH DIFFERENT TYPE OF FIBERS

2020 ◽  
Vol 17 (1) ◽  
pp. 34
Author(s):  
Sady A. Tayh ◽  
Rana A. Yousif ◽  
Qais S. Banyhussan
Keyword(s):  
Physical Properties ◽  
Asphalt Concrete ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Interior Structure ◽  
Modified Bitumen ◽  
Climate Conditions ◽  
Modified Asphalt ◽  
Long Time ◽  
Pavement Construction

For a long time, bitumen has been utilized as the essential material for asphalt pavement construction. The factors of increasing axle loads, increasing traffic movement, critical climate conditions and many forms failures in construction have steered many researchers to seek some methods to enhance the asphalt binder properties. Even though various types of modifiers have been utilized in strengthening asphalt concrete, fibers have attracted the most attention due to their high and desirable characteristics. It is realized that the good distribution of the modifier in asphalt binder can generate a strong network in the interior structure of the blend, causing bitumen mastic to be more coherent. In this study, a laboratory investigation of the rheological and physical properties of various grades of bitumen modified by two types of fibers was conducted. Three grades of asphalt were used in this study (60-70 penetration grade, 80-100 penetration grade and PG-76 grade) with two types of fibers with different percentages- Cellulose oil palm fiber (COPF) (0.15, 0.3, 0.45, 0.6, and 0.75%) by weight of asphalt and carbon fiber (0.75, 1.25, 1.75, 2.25, and 2.75%) by weight of asphalt. The results showed enhancement in physical performance of the modified bitumen in terms of the decrease in penetration values, as well as a rise in the softening point and viscosity values. The fibers’ modified asphalt binders showed improved rheological properties and can raise the grade of asphalt depending on the base asphalt type.

scholarly journals Material Properties and Environmental Benefits of Hot-Mix Asphalt Mixes Including Local Crumb Rubber Obtained from Scrap Tires

Environments ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 47
Author(s):  
Lim Min Khiong ◽  
Md. Safiuddin ◽  
Mohammad Abdul Mannan ◽  
Resdiansyah
Keyword(s):  
Asphalt Binder ◽  
Crumb Rubber ◽  
Environmental Benefits ◽  
Asphalt Binders ◽  
Rubber Content ◽  
Scrap Tires ◽  
Asphalt Mixes ◽  
Temperature Resistance ◽  
Modified Asphalt ◽  
Marshall Stability

This paper presents the results of a laboratory-based experimental investigation on the properties of asphalt binder and hot-mix asphalt (HMA) mixes modified by locally available crumb rubber, which was used as a partial replacement of asphalt by weight. In this study, fine crumb rubber with a particle size in the range of 0.3–0.6 mm, obtained from scrap tires, was added to the asphalt binder through the wet process. Crumb rubber contents of 5%, 10%, 15%, and 19% by weight of asphalt were added to the virgin binder in order to prepare the modified asphalt binder samples, while the unmodified asphalt binder was used as the control sample. The crumb rubber modified binder samples were examined for measuring viscosity indirectly using the penetration test, and temperature resistance using the softening point test. Later, both the modified and unmodified asphalt binders were used to produce HMA mixes. Two categories of HMA mix commonly used in Malaysia—namely, AC 14 (dense-graded) and SMA 14 (gap-graded)—were produced using the modified asphalt binders containing 5%, 10%, 15%, and 19% crumb rubber. Two AC 14 and SMA 14 control mixes were also produced, incorporating the unmodified asphalt binder (0% crumb rubber). All of the AC 14 and SMA 14 asphalt mixes were examined in order to determine their volumetric properties, such as bulk density, voids in total mix (VTM), voids in mineral aggregate (VMA), and voids filled with asphalt (VFA). In addition, the Marshall stability, Marshall flow, and stiffness of all of the AC 14 and SMA 14 mixes were determined. Test results indicated that the modified asphalt binders possessed higher viscosity and temperature resistance than the unmodified asphalt binder. The viscosity and temperature resistance of the asphalt binders increased with the increase in their crumb rubber content. The increased crumb rubber content also led to improvements in the volumetric properties (bulk density, VTM, VMA, and VFA) of the AC 14 and SMA 14 mixes. In addition, the performance characteristics of the AC 14 and SMA 14 mixes—such as Marshall stability, Marshall flow, and stiffness—increased with the increase in crumb rubber content. However, the AC 14 mixes performed much better than the SMA 14 mixes. The overall research findings suggest that crumb rubber can be used to produce durable and sustainable HMA mixes, with manifold environmental benefits, for use in flexible pavements carrying the heavy traffic load of highways.

scholarly journals Impact of Graphene Oxide on Zero Shear Viscosity, Fatigue Life and Low-Temperature Properties of Asphalt Binder

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3073
Author(s):  
Abbas Mukhtar Adnan ◽  
Chaofeng Lü ◽  
Xue Luo ◽  
Jinchang Wang
Keyword(s):  
Graphene Oxide ◽  
Fatigue Life ◽  
Low Temperature ◽  
Shear Viscosity ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Test Results ◽  
Zero Shear Viscosity ◽  
Modified Asphalt

This study has investigated the impact of graphene oxide (GO) in enhancing the performance properties of an asphalt binder. The control asphalt binder (60/70 PEN) was blended with GO in contents of 0%, 0.5%, 1%, 1.5%, 2%, and 2.5%. The permanent deformation behavior of the modified asphalt binders was evaluated based on the zero shear viscosity (ZSV) parameter through a steady shear test approach. Superpave fatigue test and the linear amplitude sweep (LAS) method were used to evaluate the fatigue behavior of the binders. A bending beam rheometer (BBR) test was conducted to evaluate the low-temperature cracking behavior. Furthermore, the storage stability of the binders was investigated using a separation test. The results of the ZSV test showed that GO considerably enhanced the steady shear viscosity and ZSV value, showing a significant contribution of the GO to the deformation resistance; moreover, GO modification changed the asphalt binder’s behavior from Newtonian to shear-thinning flow. A notable improvement in fatigue life was observed with the addition of GO to the binder based on the LAS test results and Superpave fatigue parameter. The BBR test results revealed that compared to the control asphalt, the GO-modified binders showed lower creep stiffness (S) and higher creep rate (m-value), indicating increased cracking resistance at low temperatures. Finally, the GO-modified asphalt binders exhibited good storage stability under high temperatures.

Dynamic Properties of Asphalt Binders Containing Fiber Modifiers

2010 ◽  
Vol 97-101 ◽  
pp. 724-727 ◽  
Author(s):  
Qun Shan Ye ◽  
Shao Peng Wu
Keyword(s):  
Shear Test ◽  
Dynamic Properties ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Test Results ◽  
Modified Asphalt ◽  
Rate Versus ◽  
Complex Shear ◽  
Creep Modulus ◽  
Phase Angles

Dynamic shear test and creep shear test were employed to investigate the dynamic properties of various fiber modified asphalt binders with the fiber content of 1.0%. The test results indicate that complex shear modulus of asphalt binders containing fibers are increased while the phase angles are decreased greatly, which implies that the asphalt binder is reinforced by the addition of fibers and the elastic property of asphalt binder is improved significantly, especially at high frequency levels. The total strain during loading period and the residual strain after the creep shear test of asphalt binders are reduced greatly by the addition of fibers. Furthermore, the creep modulus of fiber modified asphalt binders is increased and the development rate versus loading time of creep modulus is decreased.

scholarly journals Evaluating the Rheological, Chemical and Morphological Properties of SBS Modified Asphalt-Binder under Multiple Aging and Rejuvenation Cycles

2021 ◽  
Vol 11 (19) ◽  
pp. 9242
Author(s):  
Xiaobing Chen ◽  
Yunfeng Ning ◽  
Yongming Gu ◽  
Ronglong Zhao ◽  
Jinhu Tong ◽  
...  
Keyword(s):  
Asphalt Binder ◽  
Morphological Properties ◽  
Asphalt Binders ◽  
Laboratory Simulation ◽  
Fatigue Properties ◽  
Type I ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Microscopic Morphology ◽  
Sbs Modified Asphalt

To investigate the influence of multiple cycles of aging and rejuvenation on the rheological, chemical, and morphological properties of styrene–butadiene–styrene (SBS)-modified asphalt-binders, the asphalt-binders were aged using two laboratory simulation methods, namely a rolling thin film oven (RTFO) test for short-term aging and pressure aging vessel (PAV) for long-term aging. The asphalt-binders were then rejuvenated with three types of rejuvenators (Type I, II, and III) with different dosages (i.e., 6%, 10%, and 14% for the first, second, and third rejuvenation, respectively). A dynamic shear rheometer (DSR) was then used to analyze the effect of rejuvenators on the rheological properties of all the asphalt-binders. The changes in the functional groups and microscopic morphology in the process of multiple aging and rejuvenation cycles were studied using Fourier transform infrared (FTIR) and atomic force microscopy (AFM). The results indicated that the three rejuvenators could soften the stiffness and restore the microstructures of the aged asphalt-binders in the process of repeated aging and rejuvenation from DSR and AFM testing. Considering the rutting and fatigue properties, the Type I rejuvenator exhibited the potential to achieve the desired rejuvenation effects under multiple rejuvenation cycles. During the multiple aging and rejuvenation cycles, the aging resistance of SBSMA decreased gradually from the FTIR results. This inherently limited the number of repeated rejuvenation cycles. This research is conducive to promoting the application of repeated penetrating rejuvenation.

Sign in / Sign up

Export Citation Format

Share Document