scholarly journals Detailed Thermal Characterization of Acrylonitrile Butadiene Styrene and Polylactic Acid Based Carbon Composites Used in Additive Manufacturing

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2960
Author(s):  
Zoltan Ujfalusi ◽  
Attila Pentek ◽  
Roland Told ◽  
Adam Schiffer ◽  
Miklos Nyitrai ◽  
...  

Currently, 3D printing is an affordable technology for industry, healthcare, and individuals. Understanding the mechanical properties and thermoplastic behaviour of the composites is critical for the users. Our results give guidance for certain target groups including professionals in the field of additive manufacturing for biomedical components with in-depth characterisation of the examined commercially available ABS and PLA carbon-based composites. The study aimed to characterize these materials in terms of thermal behaviour and structure. The result of the heating-cooling loops is the thermal hysteresis effect of Ohmic resistance with its accommodation property in the temperature range of 20–84 °C for ESD-ABS and 20–72 °C for ESD-PLA. DSC-TGA measurements showed that the carbon content of the examined ESD samples is ~10–20% (m/m) and there is no significant difference in the thermodynamic behaviour of the basic ABS/PLA samples and their ESD compounds within the temperature range typically used for 3D printing. The results support the detailed design process of 3D-printed electrical components and prove that ABS and PLA carbon composites are suitable for prototyping and the production of biomedical sensors.

BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 7954-7964
Author(s):  
Diego Gomez-Maldonado ◽  
Maria Soledad Peresin ◽  
Christina Verdi ◽  
Guillermo Velarde ◽  
Daniel Saloni

As the additive manufacturing process gains worldwide importance, the need for bio-based materials, especially for in-home polymeric use, also increases. This work aims to develop a composite of polylactic acid (PLA) and nanofibrillated cellulose (NFC) as a sustainable approach to reinforce the currently commercially available PLA. The studied materials were composites with 5 and 10% NFC that were blended and extruded. Mechanical, structural, and thermal characterization was made before its use for 3D printing. It was found that the inclusion of 10% NFC increased the modulus of elasticity in the filaments from 2.92 to 3.36 GPa. However, a small decrease in tensile strength was observed from 55.7 to 50.8 MPa, which was possibly due to the formation of NFC aggregates in the matrix. This work shows the potential of using PLA mixed with NFC for additive manufacturing.


Author(s):  
Xiaobin Le ◽  
Rami Akouri ◽  
Anthony Latassa ◽  
Brett Passemato ◽  
Ryan Wales

3D printing known as additive manufacturing has been widely used in academics and industries to make various 3D objects for various applications. The strength of the 3D printing parts is different from its original material strength due to this additive manufacturing technique. The 3D printing parts should be treated as anisotropic materials. However, the information of mechanical property such as the ultimate strength of 3D printing parts is very limited. There is little information about the mechanical property of 3D printing parts at different print angles. This research was focused on exploring the mechanical properties of 3D printing objects. The tensile test specimen of two different materials: acrylonitrile butadiene styrene-electrostatic dissipative (ABS-ESD) and Nylon 12 were printed at the 5 different print angles through the Fortus 450mc 3D printer. Tensile test results, data analysis, detailed discussion and the empirical formula of the tensile strength of 3D printing objects vs different print angles will be presented.


Crystals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 398 ◽  
Author(s):  
Attila Pentek ◽  
Miklos Nyitrai ◽  
Adam Schiffer ◽  
Hajnalka Abraham ◽  
Matyas Bene ◽  
...  

Additive manufacturing technologies are dynamically developing, strongly affecting almost all fields of industry and medicine. The appearance of electrically conductive polymers has had a great impact on the prototyping process of different electrical components in the case of upper limb prosthetic development. The widely used FFF 3D printing technology mainly uses PLA (polylactic acid) and ABS (acrylonitrile butadiene styrene) based composites, and despite their presence in the field, a detailed, critical characterization and comparison of them has not been performed yet. Our aim was to characterize two PLA and ABS based carbon composites in terms of electrical and mechanical behavior, and extend the observations with a structural and signal transfer analysis. The measurements were carried out by changing the different printing parameters, including layer resolution, printing orientation and infill density. To determine the mechanical properties, static and dynamic tests were conducted. The electrical characterization was done by measuring the resistance and signal transfer characteristics. Scanning electron microscopy was used for the structural analysis. The results proved that the printing parameters had a significant effect on the mechanical and electrical characteristics of both materials. As a major novelty, it was concluded that the ABS carbon composite has more favorable behavior in the case of additive manufacturing of electrical components of upper limb prosthetics, and they can be used as moving, rotating parts as well.


Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4273
Author(s):  
Helen A. Little ◽  
Nagendra G. Tanikella ◽  
Matthew J. Reich ◽  
Matthew J. Fiedler ◽  
Samantha L. Snabes ◽  
...  

This study explores the potential to reach a circular economy for post-consumer Recycled Polyethylene Terephthalate (rPET) packaging and bottles by using it as a Distributed Recycling for Additive Manufacturing (DRAM) feedstock. Specifically, for the first time, rPET water bottle flake is processed using only an open source toolchain with Fused Particle Fabrication (FPF) or Fused Granular Fabrication (FGF) processing rather than first converting it to filament. In this study, first the impact of granulation, sifting, and heating (and their sequential combination) is quantified on the shape and size distribution of the rPET flakes. Then 3D printing tests were performed on the rPET flake with two different feed systems: an external feeder and feed tube augmented with a motorized auger screw, and an extruder-mounted hopper that enables direct 3D printing. Two Gigabot X machines were used, each with the different feed systems, and one without and the latter with extended part cooling. 3D print settings were optimized based on thermal characterization, and both systems were shown to 3D print rPET directly from shredded water bottles. Mechanical testing showed the importance of isolating rPET from moisture and that geometry was important for uniform extrusion. The mechanical strength of 3D-printed parts with FPF and inconsistent flow is lower than optimized fused filament, but adequate for a wide range of applications. Future work is needed to improve consistency and enable water bottles to be used as a widespread DRAM feedstock.


Author(s):  
Kazi Md Masum Billah ◽  
Ahmed Arabi Hassen ◽  
Aslan Nasirov ◽  
Gregory Haye ◽  
Jesse Heineman ◽  
...  

Abstract Additive Manufacturing (AM) of carbon fiber (CF) reinforced composite has received growing attention because of the design flexibility, superior mechanical properties, improved thermal properties, and weight reduction. Autoclave tooling was proven to be a successful application for large scale AM technology. The capital cost, and cost associated with heating, and cycle time in a conventional autoclave process is relatively high. Thus, an innovative design of AM mold with an efficient heating scheme is essential. This study represents an innovative method of the resistive heating of composite molds which does not require a room size oven for heating during the curing processing. Therefore, it has the potential to reduce the operating cost drastically. For the design validation and feasibility study, we performed a numerical analysis of the wire embedded and AM mold parts. The goal of this study is to determine and optimize the thermal behavior of the printed mold with embedded wire technology. It is anticipated that the larger distance between the embedded wires along the printing direction (z-direction) increase the cold spot, on the other hand, a close distance of the wire can create the unwanted localize heating, thus melting. Constant thermal properties of the 20 wt.% short CF reinforced acrylonitrile butadiene styrene (ABS) was used for the simulation purpose. Thermal characterization was set to 100°C to avoid the thermal deformation or bulging on the part surface.


Author(s):  
Yuan-Wei Zhang ◽  
Xin Xiao ◽  
Wen-Cheng Gao ◽  
Yan Xiao ◽  
Su-Li Zhang ◽  
...  

Abstract Background This present study is aimed to retrospectively assess the efficacy of three-dimensional (3D) printing assisted osteotomy guide plate in accurate osteotomy of adolescent cubitus varus deformity. Material and methods Twenty-five patients (15 males and 10 females) with the cubitus varus deformity from June 2014 to December 2017 were included in this study and were enrolled into the conventional group (n = 11) and 3D printing group (n = 14) according to the different surgical approaches. The operation time, intraoperative blood loss, osteotomy degrees, osteotomy end union time, and postoperative complications between the two groups were observed and recorded. Results Compared with the conventional group, the 3D printing group has the advantages of shorter operation time, less intraoperative blood loss, higher rate of excellent correction, and higher rate of the parents’ excellent satisfaction with appearance after deformity correction (P < 0.001, P < 0.001, P = 0.019, P = 0.023). Nevertheless, no significant difference was presented in postoperative carrying angle of the deformed side and total complication rate between the two groups (P = 0.626, P = 0.371). Conclusions The operation assisted by 3D printing osteotomy guide plate to correct the adolescent cubitus varus deformity is feasible and effective, which might be an optional approach to promote the accurate osteotomy and optimize the efficacy.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xiaoyu Zhao ◽  
Ye Zhao ◽  
Ming-De Li ◽  
Zhong’an Li ◽  
Haiyan Peng ◽  
...  

AbstractPhotopolymerization-based three-dimensional (3D) printing can enable customized manufacturing that is difficult to achieve through other traditional means. Nevertheless, it remains challenging to achieve efficient 3D printing due to the compromise between print speed and resolution. Herein, we report an efficient 3D printing approach based on the photooxidation of ketocoumarin that functions as the photosensitizer during photopolymerization, which can simultaneously deliver high print speed (5.1 cm h−1) and high print resolution (23 μm) on a common 3D printer. Mechanistically, the initiating radical and deethylated ketocoumarin are both generated upon visible light exposure, with the former giving rise to rapid photopolymerization and high print speed while the latter ensuring high print resolution by confining the light penetration. By comparison, the printed feature is hard to identify when the ketocoumarin encounters photoreduction due to the increased lateral photopolymerization. The proposed approach here provides a viable solution towards efficient additive manufacturing by controlling the photoreaction of photosensitizers during photopolymerization.


Lab on a Chip ◽  
2021 ◽  
Author(s):  
Liang Wu ◽  
Stephen Beirne ◽  
Joan-Marc Cabot Canyelles ◽  
Brett Paull ◽  
Gordon G. Wallace ◽  
...  

Additive manufacturing (3D printing) offers a flexible approach for the production of bespoke microfluidic structures such as the electroosmotic pump. Here a readily accessible fused filament fabrication (FFF) 3D printing...


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