scholarly journals Mycotoxins in Pistachios (Pistacia vera L.): Methods for Determination, Occurrence, Decontamination

Toxins ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 682
Author(s):  
Ana Rita Soares Mateus ◽  
Sílvia Barros ◽  
Angelina Pena ◽  
Ana Sanches Silva
Keyword(s):  
State Of The Art ◽  
Screening Methods ◽  
Pistacia Vera ◽  
Fungal Contamination ◽  
The Public ◽  
Chemical Hazards ◽  
Important Benefit ◽  
The Matrix ◽  
Low Levels

The consumption of pistachios (Pistacia vera L.) has been increasing, given their important benefit to human health. In addition to being an excellent nutritional source, they have been associated with chemical hazards, such as mycotoxins, resulting in fungal contamination and its secondary metabolism. Aflatoxins (AFs) are the most common mycotoxins in pistachio and the most toxic to humans, with hepatotoxic effects. More mycotoxins such as ochratoxin A (OTA), fumonisins (FBs), zearalenone (ZEA) and trichothecenes (T2, HT2 and DON) and emerging mycotoxins have been involved in nuts. Because of the low levels of concentration and the complexity of the matrix, the determination techniques must be very sensitive. The present paper carries out an extensive review of the state of the art of the determination of mycotoxins in pistachios, concerning the trends in analytical methodologies for their determination and the levels detected as a result of its contamination. Screening methods based on immunoassays are useful due to their simplicity and rapid response. Liquid chromatography (LC) is the gold standard with new improvements to enhance accuracy, precision and sensitivity and a lower detection limit. The reduction of Aspergillus’ and aflatoxins’ contamination is important to minimize the public health risks. While prevention, mostly in pre-harvest, is the most effective and preferable measure to avoid mycotoxin contamination, there is an increased number of decontamination processes which will also be addressed in this review.

Minimal Rare Pattern-Based Outlier Detection Approach For Uncertain Data Streams Under Monotonic Constraints

2021 ◽  
Author(s):  
Saihua Cai ◽  
Jinfu Chen ◽  
Haibo Chen ◽  
Chi Zhang ◽  
Qian Li ◽  
...  
Keyword(s):  
Outlier Detection ◽  
Data Streams ◽  
State Of The Art ◽  
Uncertain Data ◽  
Small Scale ◽  
Detection Accuracy ◽  
Detection Approach ◽  
The Matrix ◽  
Uncertain Data Streams

Abstract Existing association-based outlier detection approaches were proposed to seek for potential outliers from huge full set of uncertain data streams ($UDS$), but could not effectively process the small scale of $UDS$ that satisfies preset constraints; thus, they were time consuming. To solve this problem, this paper proposes a novel minimal rare pattern-based outlier detection approach, namely Constrained Minimal Rare Pattern-based Outlier Detection (CMRP-OD), to discover outliers from small sets of $UDS$ that satisfy the user-preset succinct or convertible monotonic constraints. First, two concepts of ‘maximal probability’ and ‘support cap’ are proposed to compress the scale of extensible patterns, and then the matrix is designed to store the information of each valid pattern to reduce the scanning times of $UDS$, thus decreasing the time consumption. Second, more factors that can influence the determination of outlier are considered in the design of deviation indices, thus increasing the detection accuracy. Extensive experiments show that compared with the state-of-the-art approaches, CMRP-OD approach has at least 10% improvement on detection accuracy, and its time cost is also almost reduced half.

An energy-based equivalent inclusion for the determination of nanocomposite behavior

2015 ◽  
Vol 22 (5) ◽  
Author(s):  
Yamen Maalej ◽  
Luc Dormieux ◽  
Eric Lemarchand
Keyword(s):  
Polymer Nanocomposites ◽  
Elastic Moduli ◽  
New Class ◽  
Inclusion Phase ◽  
Equivalent Inclusion ◽  
Mechanical And Physical Properties ◽  
The Matrix ◽  
Low Levels ◽  
Good Agreement

AbstractAchieving remarkable mechanical properties for very low levels of reinforcement, nanocomposites are nowadays a new class of materials with high potential. Thanks to the stiffening aspect of the interface region between the matrix and the inclusions, nanocomposites often exhibit improved mechanical and physical properties compared to the conventional composites reinforced with micron-sized particles. This paper presents a strategy based on the introduction of an equivalent inclusion phase that allows managing the ellipsoidal morphology of inhomogeneous inclusion nanophase in the determination of estimates for the homogenized elastic moduli. Application to clay-polymer nanocomposites is presented in the framework of the dilute scheme. The latter gives theoretical estimates in good agreement with experimental results reported in the literature.

Lateral resolution of the electron microbeam analysis

1978 ◽  
Vol 36 (1) ◽  
pp. 542-543
Author(s):  
H.J. Dudek
Keyword(s):  
Quantitative Analysis ◽  
Depth Resolution ◽  
Lateral Resolution ◽  
Cylindrical Particle ◽  
Correction Procedure ◽  
X Ray ◽  
Element Concentrations ◽  
Microbeam Analysis ◽  
The Matrix

The chemical inhomogenities in modern materials such as fibers, phases and inclusions, often have diameters in the region of one micrometer. Using electron microbeam analysis for the determination of the element concentrations one has to know the smallest possible diameter of such regions for a given accuracy of the quantitative analysis.In th is paper the correction procedure for the quantitative electron microbeam analysis is extended to a spacial problem to determine the smallest possible measurements of a cylindrical particle P of high D (depth resolution) and diameter L (lateral resolution) embeded in a matrix M and which has to be analysed quantitative with the accuracy q. The mathematical accounts lead to the following form of the characteristic x-ray intens ity of the element i of a particle P embeded in the matrix M in relation to the intensity of a standard S

Determination of the phase structure of polymerblends by electron microscopy

1978 ◽  
Vol 36 (1) ◽  
pp. 492-493
Author(s):  
Dr. G. Kaemof
Keyword(s):  
Screw Extruder ◽  
Electron Microscopic ◽  
Thin Sections ◽  
Single Screw Extruder ◽  
Transmission Electron ◽  
The Matrix ◽  
Twin Screw ◽  
Special Case ◽  
Microscopic Investigations

A mixture of polycarbonate (PC) and styrene-acrylonitrile-copolymer (SAN) represents a very good example for the efficiency of electron microscopic investigations concerning the determination of optimum production procedures for high grade product properties.The following parameters have been varied:components of charge (PC : SAN 50 : 50, 60 : 40, 70 : 30), kind of compounding machine (single screw extruder, twin screw extruder, discontinuous kneader), mass-temperature (lowest and highest possible temperature).The transmission electron microscopic investigations (TEM) were carried out on ultra thin sections, the PC-phase of which was selectively etched by triethylamine.The phase transition (matrix to disperse phase) does not occur - as might be expected - at a PC to SAN ratio of 50 : 50, but at a ratio of 65 : 35. Our results show that the matrix is preferably formed by the components with the lower melting viscosity (in this special case SAN), even at concentrations of less than 50 %.

Polishing process effect on the image of dispersed precipitates

1984 ◽  
Vol 42 ◽  
pp. 534-535
Author(s):  
C.T. Hu ◽  
C.W. Allen
Keyword(s):  
Matrix Material ◽  
Specimen Preparation ◽  
Second Phase ◽  
Precipitate Particle ◽  
Polishing Process ◽  
Second Phase Particles ◽  
The Matrix ◽  
Surface Profiles ◽  
Thinning Process

One important problem in determination of precipitate particle size is the effect of preferential thinning during TEM specimen preparation. Figure 1a schematically represents the original polydispersed Ni3Al precipitates in the Ni rich matrix. The three possible type surface profiles of TEM specimens, which result after electrolytic thinning process are illustrated in Figure 1b. c. & d. These various surface profiles could be produced by using different polishing electrolytes and conditions (i.e. temperature and electric current). The matrix-preferential-etching process causes the matrix material to be attacked much more rapidly than the second phase particles. Figure 1b indicated the result. The nonpreferential and precipitate-preferential-etching results are shown in Figures 1c and 1d respectively.

Determination of Optimal Public Transportation Routes Using Firefly and Tabu Search Algorithms

2020 ◽  
Vol 4 (5) ◽  
pp. 884-891
Author(s):  
Salwa Salsabila Mansur ◽  
Sri Widowati ◽  
Mahmud Imrona
Keyword(s):  
Tabu Search ◽  
Public Transportation ◽  
Traffic Congestion ◽  
Search Algorithm ◽  
Urban Transportation ◽  
The Public ◽  
Comparison Results ◽  
Congestion Problems ◽  
Transportation Routes

Traffic congestion problems generally caused by the increasing use of private vehicles and public transportations. In order to overcome the situation, the optimization of public transportation’s route is required particularly the urban transportation. In this research, the performance analysis of Firefly and Tabu Search algorithm is conducted to optimize eleven public transportation’s routes in Bandung. This optimization aims to increase the dispersion of public transportation’s route by expanding the scope of route that are crossed by public transportation so that it can reach the entire Bandung city and increase the driver’s income by providing the passengers easier access to public transportations in order to get to their destinations. The optimal route is represented by the route with most roads and highest number of incomes. In this research, the comparison results between the reference route and the public transportation’s optimized route increasing the dispersion of public transportation’s route to 60,58% and increasing the driver’s income to 20,03%.

Spectrophotometric Determination of Raceophenidol in Feed at Very Low Levels

1968 ◽  
Vol 51 (4) ◽  
pp. 752-755
Author(s):  
Edward L Pratt ◽  
Morris E Auerbach
Keyword(s):  
Spectrophotometric Determination ◽  
Growth Promotion ◽  
Ultraviolet Spectrum ◽  
Average Value ◽  
Collaborative Studies ◽  
Low Levels ◽  
Concentration Levels

Abstract Raceophenidol in feed at concentration levels intended for growth promotion of poultry can be estimated by a curvature inversion measurement related to the ultraviolet spectrum of derived p-methylsulfonylbenzaldehyde. The drug can be accurately measured at the 0.0005% level. Collaborative studies on the method showed an average value of 94 ± 10% of claim. The method is recommended for adoption as official, first action.

scholarly journals The Degree of Oxidation of Graphene Oxide

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 560
Author(s):  
Alexandra Carvalho ◽  
Mariana C. F. Costa ◽  
Valeria S. Marangoni ◽  
Pei Rou Ng ◽  
Thi Le Hang Nguyen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Ab Initio ◽  
State Of The Art ◽  
High Accuracy ◽  
Precise Determination ◽  
Photoemission Spectroscopy ◽  
Pristine Graphene ◽  
X Ray ◽  
Degree Of Oxidation

We show that the degree of oxidation of graphene oxide (GO) can be obtained by using a combination of state-of-the-art ab initio computational modeling and X-ray photoemission spectroscopy (XPS). We show that the shift of the XPS C1s peak relative to pristine graphene, ΔEC1s, can be described with high accuracy by ΔEC1s=A(cO−cl)2+E0, where c0 is the oxygen concentration, A=52.3 eV, cl=0.122, and E0=1.22 eV. Our results demonstrate a precise determination of the oxygen content of GO samples.

scholarly journals Characterization and Quantification of Selenoprotein P: Challenges to Mass Spectrometry

2021 ◽  
Vol 22 (12) ◽  
pp. 6283
Author(s):  
Jérémy Lamarche ◽  
Luisa Ronga ◽  
Joanna Szpunar ◽  
Ryszard Lobinski
Keyword(s):  
Mass Spectrometry ◽  
State Of The Art ◽  
Animal Health ◽  
Primary Standard ◽  
Selenoprotein P ◽  
Primary Standards ◽  
Analytical Approaches ◽  
Careful Investigation ◽  
Accurate Quantification

Selenoprotein P (SELENOP) is an emerging marker of the nutritional status of selenium and of various diseases, however, its chemical characteristics still need to be investigated and methods for its accurate quantitation improved. SELENOP is unique among selenoproteins, as it contains multiple genetically encoded SeCys residues, whereas all the other characterized selenoproteins contain just one. SELENOP occurs in the form of multiple isoforms, truncated species and post-translationally modified variants which are relatively poorly characterized. The accurate quantification of SELENOP is contingent on the availability of specific primary standards and reference methods. Before recombinant SELENOP becomes available to be used as a primary standard, careful investigation of the characteristics of the SELENOP measured by electrospray MS and strict control of the recoveries at the various steps of the analytical procedures are strongly recommended. This review critically discusses the state-of-the-art of analytical approaches to the characterization and quantification of SELENOP. While immunoassays remain the standard for the determination of human and animal health status, because of their speed and simplicity, mass spectrometry techniques offer many attractive and complementary features that are highlighted and critically evaluated.

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