scholarly journals Strength Development in Bio Mineralised Steelslag Bricks using Micp Process

2020 ◽  
Vol 9 (4) ◽  
pp. 2975-2980
Keyword(s):  
Steel Slag ◽  
Mineralogical Composition ◽  
Waste Materials ◽  
Firing Process ◽  
Strength Development ◽  
Composition Analysis ◽  
Calcium Carbonate Precipitation ◽  
Paper Mills ◽  
Carbonation Process ◽  
Steel Industries

Steel slag annual production in India is about 12 million tonnes per annum. Steel slag is one of the industrial residue came out from steel industries. The amount of steel slag produced from different steel industries is 150-200kg per tonnes of steel produced These steel slag is dumped in land and pollute the environment. Paper mills produce the large amount of lime sludge is about 5 lakh tonnes per annum. These steel slag used as binder material and coarse aggregate also in different sieve sizes. These both steel slag and lime material contains large amount of calcium mineral compared than other waste materials. The conventional burnt clay brick manufacturing firing process develops the 750 million tonnes of co2 emissions per year. The Bio mineralised steel slag bricks developed by using these waste materials and bacillus bacteria. These microbes generates the calcium carbonate precipitation in the steel slag bricks. The strength development of these BMSS bricks were achieved by addition of NBU medium supply and carbonation process. The scanning electron microscope (SEM), mineralogical composition analysis, X-ray diffraction analysis, compressive strength and water absorption test are conducted to support the strength development in bio mineralised steel slag bricks.

Conversion of Red Muds into Pozzolans

1991 ◽  
Vol 245 ◽  
Author(s):  
Jean Pera
Keyword(s):  
Red Mud ◽  
Mineralogical Composition ◽  
Waste Materials ◽  
Strength Development ◽  
Blended Cements ◽  
Temperature Range ◽  
Lime Consumption ◽  
Red Muds ◽  
Mineralogical Compositions

ABSTRACTRed muds are waste materials obtained from the aluminium extraction industry. They consist mainly of clays, aluminium and iron hydrated oxides. Three muds were studied; they differed in chemical and mineralogical compositions. They were converted into reactive pozzolans by calcination in the temperature range 600–800°C for five hours. Pozzolanicity was investigated on calcined red mud-OPC mixes studying strength development and lime consumption as evaluated by DTA. The nature of hydrates formed during hardening was also identified.The mineralogical composition of the mud is the most important factor affecting its pozzolanicity. Blended cements containing 30% calcined red mud develop significant strengths.

scholarly journals Development of UHPC Mixtures Utilizing Natural and Industrial Waste Materials as Partial Replacements of Silica Fume and Sand

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Shamsad Ahmad ◽  
Ibrahim Hakeem ◽  
Mohammed Maslehuddin
Keyword(s):  
Silica Fume ◽  
Industrial Waste ◽  
Steel Slag ◽  
Limestone Powder ◽  
Waste Materials ◽  
Cement Kiln ◽  
Test Results ◽  
Strength Criteria ◽  
Natural Pozzolana ◽  
Kiln Dust

In the exploratory study presented in this paper, an attempt was made to develop different mixtures of ultrahigh performance concrete (UHPC) using various locally available natural and industrial waste materials as partial replacements of silica fume and sand. Materials such as natural pozzolana (NP), fly ash (FA), limestone powder (LSP), cement kiln dust (CKD), and pulverized steel slag (PSS), all of which are abundantly available in Saudi Arabia at little or no cost, were employed in the development of the UHPC mixtures. A base mixture of UHPC without replacement of silica fume or sand was selected and a total of 24 trial mixtures of UHPC were prepared using different percentages of NP, FA, LSP, CKD, and PSS, partially replacing the silica fume and sand. Flow and 28-d compressive strength of each UHPC mixture were determined to finally select those mixtures, which satisfied the minimum flow and strength criteria of UHPC. The test results showed that the utilization of NP, FA, LSP, CKD, and PSS in production of UHPC is possible with acceptable flow and strength. A total of 10 UHPC mixtures were identified with flow and strength equal to or more than the minimum required.

The Effect on Cement Mortar and Concrete by Admixture of Spray Drying Absorption Products

1989 ◽  
Vol 178 ◽  
Author(s):  
Kirsten G. Jeppesen
Keyword(s):  
Grain Size ◽  
Fly Ash ◽  
Cement Mortar ◽  
Setting Time ◽  
Mineralogical Composition ◽  
Cement Clinker ◽  
Strength Development ◽  
Fall Meeting ◽  
Freeze Thaw ◽  
Spray Dried

AbstractSpray dried absorption products (SDA) having special characteristics are used as substitutes for cement in the preparation of mortars; the qualities of the resulting mixed mortars are described. Conditions are described for mortar mixes, data for which were presented at the MRS Fall Meeting 1987.The influence of the composition of the SDA on water requirement and setting time has been studied. A full scale project involving 3 precast, reinforced concrete front-elements containing 20 and 30 wt.% SDA is described. Strength development, mineralogical composition and corrosion were monitored for two years.A non-standard freeze-thaw experiment was performed which compares mortars containing SDA and fly ash (FA) and also shows the effect of superplasticizer.The possibility of improving the SDA by grinding has been tested and a limited improvement has been found. The strength of the mixed mortars seems slightly influenced by the grain size of SDAGypsum (CaSO4·2H2O), synthetic calcium-sulphite (CaSO3·½H2O) and 2 SDAs have been used as retarders for cement clinker. Mortar test prisms have been cast and comparative strengths after curing for 3 years are reported

scholarly journals Neutralization of Acidic Wastewater from a Steel Plant by Using CaO-Containing Waste Materials from Pulp and Paper Industries

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2653
Author(s):  
Tova Jarnerud ◽  
Andrey V. Karasev ◽  
Pär G. Jönsson
Keyword(s):  
Fly Ash ◽  
Pulp And Paper ◽  
Waste Materials ◽  
Paper Mills ◽  
Steel Mills ◽  
Lime Mud ◽  
Set Up ◽  
Pulp And Paper Industries ◽  
The Given ◽  
Acidic Wastewater

In this study, CaO-containing wastes from pulp and paper industries such as fly ash (FA) and calcined lime mud (LM) were utilized to neutralize and purify acidic wastewaters from the pickling processes in steel mills. The investigations were conducted by laboratory scale trials using four different batches of wastewaters and additions of two types of CaO-containing waste materials. Primary lime (PL), which is usually used for the neutralization, was also tested in the same experimental set up in the sake of comparison. The results show that these secondary lime sources can effectively increase the pH of the acidic wastewaters as good as the commonly used primary lime. Therefore, these secondary lime sources could be potential candidates for application in neutralization processes of industrial acidic wastewater treatment. Moreover, concentrations of metals (such as Cr, Fe, Ni, Mo and Zn) can decrease dramatically after neutralization by using secondary lime. The LM has a purification effect from the given metals, similar to the PL. Application of fly ash and calcined lime mud as neutralizing agents can reduce the amount of waste from pulp and paper mills sent to landfill and decrease the need for nature lime materials in the steel industry.

scholarly journals Characterization and Analysis of the Carbonation Process of a Lime Mortar Obtained from Phosphogypsum Waste

2021 ◽  
Vol 18 (12) ◽  
pp. 6664
Author(s):  
María Isabel Romero-Hermida ◽  
Antonio María Borrero-López ◽  
Vicente Flores-Alés ◽  
Francisco Javier Alejandre ◽  
José María Franco ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mineralogical Composition ◽  
Barium Sulphate ◽  
Negative Influence ◽  
Raw Material ◽  
Porous System ◽  
Waste Products ◽  
Liesegang Rings ◽  
Carbonation Process ◽  
Ultrasonic Propagation

This work addresses the reuse of waste products as a raw material for lime putties, which are one of the components of mortar. 1:3 Lime/sand mortars very similar to conventional construction mortars were prepared using a lime putty obtained from the treatment of phosphogypsum with sodium hydroxide. The physical, rheological and mechanical properties of this phosphogypsum-derived mortar have been studied, as well as the mineralogical composition, microstructure by scanning electron microscope (SEM) and curing process by monitoring carbonation and ultrasonic propagation velocity. Considering the negative influence of sulphates on the hardened material, the behaviour of the material after sulphates precipitation by adding barium sulphate was additionally tested. Carbonation progressed from the outside to the inside of the specimen through the porous system by Liesegang rings patterns for mortars with soluble sulphates, while the carbonation with precipitated sulphates was controlled by diffusion-precipitation. Overall, the negative influence of low-sulphate contents on the mechanical properties of mortars was verified. It must be highlighted the importance of their precipitation to obtain adequate performance.

Crystallization of simonkolleite (Zn5Cl2(OH)8 ∙ H2O) in powder samples prepared for mineral composition analysis by quantitative X-ray diffraction (QXRD)

Nafta-Gaz ◽  
2021 ◽  
Vol 77 (5) ◽  
pp. 293-298
Author(s):  
Urszula Zagórska ◽  
◽  
Sylwia Kowalska ◽  
Keyword(s):  
Quantitative Analysis ◽  
Internal Standard ◽  
Mineralogical Composition ◽  
Hydrocarbon Exploration ◽  
Composition Analysis ◽  
Internal Standard Method ◽  
X Ray Diffraction ◽  
Method Error ◽  
X Ray ◽  
Significant Difference

The analysis of mineralogical composition by quantitative X-ray diffraction (QXRD) is one of the standard research methods used in hydrocarbon exploration. In order to improve it and to obtain better results, the methodology of quantitative analysis used at Well Logging Department is being periodically (more or less) modified. After the introduction of the improvements, comparative analyses were performed on archival samples. Reflections from an unidentified phase which did not occur in the tested Rotliegend sandstone samples were noticed on X-ray diffractograms of archival samples. Reflections of a mineral called simonkolleite were identified in the X-ray diffraction database. Chemically it is a hydrated zinc chloride of the formula: Zn5Cl2(OH)8 × H2O. Analysis of the composition of samples in which simonkolleite crystallised, indicated that the mineral is being formed in the result of the slow reaction of zinc oxide with halite (NaCl) and water vapour. An attempt was made to determine the influence of the presence of this mineral on the results of the quantitative analysis of mineralogical composition. The above methodology was applied on a group of ten samples. The results of the quantitative analysis conducted for archival samples stored with added zincite standard containing simonkolleite and for new, freshly grinded (without artifact) samples were compared. The comparison of the obtained results showed a slight influence of this mineral on the quantitative composition of the remaining components. The difference between the results usually did not exceed the method error. At the same time a significant difference in the calculated content of the internal standard was noted – on average 1% less in archival than in new samples. This shows that the reaction occurring in the archival samples will affect the evaluation of the quality of the obtained quantitative analysis, at the same time excluding the possibility of determining the rock’s amorphous substance content with the internal standard method.

scholarly journals Correction: Toda, K., et al. Key Factors Affecting Strength Development of Steel Slag-Dredged Soil Mixtures. Minerals 2018, 8(5), 174

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 473
Author(s):  
Kanako Toda ◽  
Haruna Sato ◽  
Nilan Weerakoon ◽  
Tsubasa Otake ◽  
Satoshi Nishimura ◽  
...  
Keyword(s):  
Steel Slag ◽  
Strength Development ◽  
Key Factors ◽  
Factors Affecting ◽  
Dredged Soil ◽  
Soil Mixtures

The authors wish to make the following corrections to this paper [...]

scholarly journals Enhancing the Flexural Strength of Concrete using Recycled Iron and Steel Slag Aggregate

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
A. A Raheem
Keyword(s):  
Tensile Strength ◽  
Flexural Strength ◽  
Concrete Beams ◽  
Steel Slag ◽  
Aggregate Size ◽  
Mineralogical Composition ◽  
Maximum Aggregate Size ◽  
Considerable Effort ◽  
Iron And Steel ◽  
Coefficient Of Uniformity

Concrete is strong in compression but weak in tension hence, considerable effort is required to improve concrete’s tensile strength by the use of pre-stressed concrete and addition of admixtures or additives. In this study, the use of recycled iron and steel slag (RISS) aggregate to improve the tensile strength of concrete was considered. The paper assessed the mineralogical composition of RISS and granite aggregates, and gradation. It also determines the effects of RISS aggregate on the flexural strength of concrete beams of 150 × 150 × 600 mm containing 0, 10, 20, 40 and 60% RISS aggregate replacement in mix ratios 1:1½:3, 1:2:4 and 1:3:6 with water cement ratios 0.65,0.60 and 0.55 respectively. Diffractograph of RISS and granite aggregate showed that RISS contains Magnetite, Ilmenite and Quartz, while granite contains Quartz, Annite, Microcline and Albite as the predominant minerals. The coefficient of uniformity and concavity of RISS and granite aggregate for maximum aggregate size of 37.5 mm are 4.35 and 1.33; and 4.64 and 1.76 respectively. Both aggregates contain quartz as the predominant mineral and are well graded. The result of the Flexural strength at 28 days curing is within 0.135 – 0.250 MPa specified byBS8500 – 2:2015. Flexural strength of concrete beams cast with RISS aggregate is relatively higher than concrete cast with granite aggregate. Flexural strength, a measure of tensile strength of concrete is improved as percentage RISS aggregate increased.

scholarly journals The mineral sequestration of CO2 with the use of fly ash from the co-combustion of coal and biomass

2017 ◽  
Vol 33 (4) ◽  
pp. 143-155 ◽  
Author(s):  
Alicja Uliasz-Bocheńczyk ◽  
Aleksandra Pawluk ◽  
Michał Pyzalski
Keyword(s):  
Phase Composition ◽  
Fly Ash ◽  
Co2 Emissions ◽  
Energy Production ◽  
Binding Capacity ◽  
Renewable Energy Sources ◽  
Biomass Combustion ◽  
Composition Analysis ◽  
Fly Ashes ◽  
Carbonation Process

Summary As a result of energy production processes, the power industry is the largest source of CO2 emissions in Poland. Emissions from the energy sector accounted for 52.37% (162 689.57 kt) of the total emissions in 2015, which was estimated at 310.64 million tons of CO2. In recent years, the tightening of regulations on the use of renewable energy sources has resulted in an increased amount of biomass used in the professional energy industry. This is due to the fact that the CO2 emissions from biomass combustion are not included in the total emissions from the combustion of fuels, resulting in the zero- emission factor for biomass. At the same time, according to the hierarchy of waste management methods, recycling is the preferred option for the management of by-products generated during energy production. The fly ashes resulting from the biomass combustion in pulverized boilers (which, due to their chemical composition, can be classified as silicate ash) were subjected to analysis. These ashes can be classified as waste 10 01 17 - fly ash from co-firing other than mentioned in 10 01 16 according to the Regulation of the Minister of the Environment of December 9, 2014 on waste catalogues. The maximum theoretical carbon dioxide binding capacity for the analyzed fly ashes resulting from the co-combustion of biomass is 8.03%. The phase composition analysis of the fly ashes subjected to carbonation process has shown, in addition to the components identified in pure fly ash samples (SiO2, mullite), the presence of calcium carbonate − calcite − the primary product of the carbonation process, as indicated by the results of both X-ray and thermogravimetric analysis.The degree of carbonation has been determined based on the analysis of the results of the phase composition of fly ash resulting from the co-firing of biomass and bituminous coal. The calculated degree of carbonation amounted to 1.51%. The carbonation process is also confirmed by the lowered pH of the water extracts, decreasing from 11.96 for pure ashes to 8.7 for CO2 treated fly ashes. In addition, the carbonation process has reduced the leaching of pollutants, most notably chlorides, sulphates, and potassium.

scholarly journals Effect of Soil Organic Matters in Dredged Soils to Utilization of their Mixtures Made with a Steel Slag

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5450
Author(s):  
Kanako Toda ◽  
Ryosuke Kikuchi ◽  
Tsubasa Otake ◽  
Satoshi Nishimura ◽  
Yuzoh Akashi ◽  
...  
Keyword(s):  
Humic Acid ◽  
Steel Slag ◽  
Construction Materials ◽  
Engineering Application ◽  
Pozzolanic Reaction ◽  
Strength Development ◽  
Organic Matters ◽  
Development Indicators ◽  
Dredged Soil ◽  
Accelerate Evaluation

Dredged soils have been used as construction materials by alkaline activation with steel slag (steel slag-dredged soil mixtures) at harbors. Such mixtures develop strength chiefly by calcium silicate hydrate (C-S-H) formation by the pozzolanic reaction. However, the strength of such mixtures is unpredictable, and in some cases, mixtures have been too soft for the intended engineering application. An identification of strength development indicators would accelerate evaluation processes for strength development to facilitate and promote the utilization of such materials. This paper focuses on the relationship between the characteristics of soil organic matters in dredged soils and the strength development of the mixtures by a comparison of eight dredged soils collected from eight different Japanese harbors. The characteristics of the soil organic matters were identified to determine as indicators of mixtures with weak strength development, i.e., enriched sulfur content in extracted soil organic matter (humic acid) fraction, and the N/C ratio of humic acid similar to land humic acid standards. Increases in the validated fraction of dredged soils and steel slag by replacing fractions disadvantageous to construction resources would contribute to reduce waste production, which would lower the environmental impact of the use, aiming to achieve sustainable utilization of such materials.

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