ANALYSIS OF WORK ON NANOSTRUCTURED MATERIALS IN ORTHOPEDIC DENTISTRY UNDER THE DIRECTION OF PROFESSOR E.S. KALIVRADZHIYAN

Author(s):  
Жанна Владимировна Вечеркина ◽  
Наталия Владимировна Чиркова ◽  
Михаил Анатольевич Крючков ◽  
Виктор Сергеевич Калиниченко

Развитие технологий, основанных на использовании низкотоксичных материалов, позволит в скором будущем начать их применение в медицине. Применение наночастиц серебра, меди, кремния, цинка, титана, кобальта в качестве модифицирующей добавки позволит оказать активное влияние на структуру исходных материалов и изменение их свойств, а именно улучшение физико-механических, физико-химических и токсико-гигиенических свойств материалов. Наноразмерные частицы кремния, введенные в фиксирующие стоматологические материалы, приводят к улучшению физико-химических, физико-механических свойств кристаллизующихся материалов, а малая теплопроводность кремния может увеличить его рабочее время и снизить выделение тепла при реакции кристаллизации. Так как от этих характеристик зависит объем манипуляций, при фиксации ортопедических конструкций на опорных зубах целесообразно было бы привести рабочее время твердения к чистому времени твердения, что позволит увеличить объем манипуляций приготовленной массой без ухудшения ее свойств. Разработка высокопрочных, биосовместимых, высокотехнологичных нанопластмасс для базисов съемных пластиночных протезов является актуальной проблемой повышения качества жизни пациентов. Модификация наноразмерными частицами серебра, кремния акрилового полимера позволит улучшить такие физико-механические свойства, как ударную вязкость, прочность, температуростойкость, барьерные свойства, уменьшить усадку полимера на этапе полимеризации, в отличие от уже известных отечественных и дорогостоящих импортных полимеров. Наноразмерные частицы кремния, серебра являются сокатализаторами метилметакрилата, влияющими на уменьшение количества остаточного мономера после процесса полимеризации, тем самым повышая санитарно-химические и токсико-гигиенические характеристики полимера. Все вышеизложенное позволило сформулировать цель исследований по наноструктурированным материалам под руководством профессора …посвящается памяти профессора, д.м.н. Каливраджияна Э.С. The development of technologies based on the use of low-toxic materials will make it possible to begin their application in medicine in the near future. The use of nanoparticles of silver, copper, silicon, zinc, titanium, cobalt as a modifying additive will make it possible to actively influence the structure of the starting materials and change their properties, namely, improve the physicomechanical, physicochemical and toxicohygienic properties of materials. Nanosized silicon particles introduced into fixing dental materials lead to an improvement in the physicochemical, physicomechanical properties of crystallizing materials, and the low thermal conductivity of silicon can increase its working time and reduce heat generation during the crystallization reaction. Since the volume of manipulations depends on these characteristics, when fixing orthopedic structures on abutment teeth, it would be advisable to bring the working time of hardening to a pure hardening time, which will increase the volume of manipulations with the prepared mass without deteriorating its properties. The development of high-strength, biocompatible, high-tech nanoplastics for the bases of removable plate prostheses is an urgent problem to improve the quality of life of patients. Modification of acrylic polymer with nano-sized particles of silver and silicon will improve such physical and mechanical properties as impact strength, strength, temperature resistance, barrier properties, and reduce polymer shrinkage at the stage of polymerization, in contrast to the already known domestic and expensive imported polymers. Nanosized particles of silicon, silver are cocatalysts of methyl methacrylate, affecting the reduction of the amount of residual monomer after the polymerization process, thereby increasing the sanitary-chemical and toxic-hygienic characteristics of the polymer. All of the above made it possible to formulate the goal of research on nanostructured materials under the guidance of the professor …dedicated to the memory of the professor, d.m.s. Kalivrajiyan E.S.

Author(s):  
I.R. Antypes ◽  
◽  
V.V. Zaitsev ◽  

Currently, the use of composite materials is increasingly used in various areas of the national economy, including the aviation industry. The materials of this article are devoted to the study of the use of composite materials for the manufacture of aircraft landing gear in comparison with the traditionally used brand of steel. As a result of the work carried out, it was found that the slope made of carbon fiber showed a critical stress twice as high as its design made of 30xgsn2a steel. In addition, carbon plastics are superior to high-strength steel in terms of specific strength, stiffness, and tensile strength.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3370
Author(s):  
Emmanouil-George C. Tzanakakis ◽  
Evangelos Skoulas ◽  
Eudoxie Pepelassi ◽  
Petros Koidis ◽  
Ioannis G. Tzoutzas

Lasers have been well integrated in clinical dentistry for the last two decades, providing clinical alternatives in the management of both soft and hard tissues with an expanding use in the field of dental materials. One of their main advantages is that they can deliver very low to very high concentrated power at an exact point on any substrate by all possible means. The aim of this review is to thoroughly analyze the use of lasers in the processing of dental materials and to enlighten the new trends in laser technology focused on dental material management. New approaches for the elaboration of dental materials that require high energy levels and delicate processing, such as metals, ceramics, and resins are provided, while time consuming laboratory procedures, such as cutting restorative materials, welding, and sintering are facilitated. In addition, surface characteristics of titanium alloys and high strength ceramics can be altered. Finally, the potential of lasers to increase the adhesion of zirconia ceramics to different substrates has been tested for all laser devices, including a new ultrafast generation of lasers.


Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 164
Author(s):  
Kenneth N. Han

Rare earth elements (REEs) have become an important group of metals used in many high-tech industries, including high-strength magnets, plasma TVs, various military applications, and clean and efficient green energy industries [...]


2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Eethar Thanon Dawood ◽  
Mahyuddin Ramli

This study was conducted to determine some physical and mechanical properties of high-strength flowable mortar reinforced with different percentages of palm fiber (0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, and 1.6% as volumetric fractions). The density, compressive strength, flexural strength, and toughness index were tested to determine the mechanical properties of this mortar. Test results illustrate that the inclusion of this fiber reduces the density of mortar. The use of 0.6% of palm fiber increases the compressive strength and flexural strength by about 15.1%, and 16%, respectively; besides, the toughness index (I5) of the high-strength flowable mortar has been significantly enhanced by the use of 1% and more of palm fiber.


2018 ◽  
Vol 212 ◽  
pp. 01013
Author(s):  
Vadim Balabanov ◽  
Victor Baryshok ◽  
Nikita Epishkin

The sharply continental climate of the Irkutsk region is characterized by wide temperature intervals throughout the year. The repeated cyclicity of freezing and thawing of building materials in the water-saturated state influences the change in technical characteristics and the durability of concrete products and structures. The concrete products’ features in such climatic conditions create the need for the production of concretes with improved indicators of physical and mechanical properties. The effect of modifying additives on the technological characteristics of sulfur concrete is established. The effect of all elements of sulfur concrete on its strength and frost resistance. The composition of sulfuric concrete is obtained, which meets all the requirements and also has high strength and increased frost resistance. Formulations with a certain ratio of structural sulfuric concrete mixtures were developed. As a result of the use of technical sulfur in the composition of concrete products, the problem of utilizing annually accumulating reserves of technical sulfur is partially solved. The strength properties of sulfuric concretes easily compete with high-quality brands of concrete, special types of concretes that have in their composition additives.


Author(s):  
A. A. Deev ◽  
G. Yu. Kalinin ◽  
K. E. Sadkin

This article shows the possibility of using high-strength nitrogen-containing corrosion-resistant steel grade 04Kh20N6G11M2AFB for the construction of critical elements and units of marine equipment operating at low temperatures, including the Arctic. The advantages of nitrogen-containing steel over clad steel AB2 + 08Kh18N10T always used in shipbuilding and welded steel of F500W category are considered. According to the assessment of testing of homogeneous nitrogen steel sheets, the level of its physical and mechanical properties exceeds the analogous parameters of traditional AB2 + 08Kh18N10T steels in a wide temperature range, up to –90°C.


2021 ◽  
Vol 899 ◽  
pp. 137-143
Author(s):  
Yulia A. Sokolova ◽  
Marina A. Akulova ◽  
Baizak R. Isakulov ◽  
Alla G. Sokolova ◽  
Berikbay B. Kul’sharov ◽  
...  

The present paper considers the study of creep and deformation properties of sulfur-containing arbolit exposed to various compression stresses. Investigating the creep of lightweight arbolit concretes greatly affecting the performance of bearing and envelope structures draws a special attention during the last years. This issue is of particular relevance in the regions with hot and sharp continental climate. Arbolit concrete is one of the lightest building materials with low thermal conductivity and good soundproof properties. The modern postulates of theory and practice of creation, development of high-strength arbolit concretes on the base of composite sulfur-containing binders have become the methodological framework of the present research. While carrying out scientific research, the following standard measuring and analysis methods of physical and mechanical properties have been used for sulfur-containing arbolit composites. Experimental tests have been implemented on the 28-days samples made of sulfur-containing arbolit, with the cotton plant footstalks as an organic component. The researched samples were vapor sealed with the purpose to eliminate overlapping the processes of contraction and creep. The experimental results have shown that the analysis of prisms deformation in time demonstrates certain derivation from the pattern. Deformation of prisms made of sulfur-containing arbolit loaded at the low stress level were growing at a slower rate that the same deformations at a higher stress level. No derivation has been observed for the prisms of sulfur-containing haydite concrete. For both types of concrete, creep deformation has reached the values exceeding completely recoverable deformation by a factor of 2 or all the samples, the rapid growth of creep deformation has been observed after loading, followed by the gradual slowdown of deformation growth. For sulfur-containing lightweight concretes, as the test shown, the rate of creep deformation growth depends on the hardening curve in time reflecting the process of concrete hardening. This, if compared with sulfur-containing lightweight concretes, creep of sulfur-containing arbolit concrete is significantly lower that eventually leads to the loss of creep deformation at the same stress level. The obtained results can be used when manufacturing an efficient wall material for residential construction, including seismic areas.


2021 ◽  
Author(s):  
◽  
Zane Grigale-Soročina

In the dissertation compositions of urethane diacrylates and monoacrylates have been studied, which when curing under the conditions of UV-activated copolymerization process meeting the requirements of cosmetic varnishes, form cross-linked structure coatings with high strength-deformation, surface hardness, surface light reflectance, adhesion and other parameters. The review of the literature summarizes information on the types of natural nail coatings and the basic components entering them. Restrictions on the choice of basic components entering the system are described. The effect of conditions and components on the natural nail is described. The materials used in the research are described in the methodological part of the work. The process of obtaining compositions is described. The research methods used are described: characterization of rheological properties of non-polymerized compositions, differential thermal analysis of polymerization process, determination of polymerization depth, determination of crosslinked part of polymerized systems, determination of yield tensile strength-deformation, coating surface hardness, surface gloss and surface wear, assessment of adhesion and its durability, in-vitro and in-vivo coating adhesion studies on natural nails, spectroscopic analysis of pigmented coatings and assessment of color constancy, comparison of coating compositions in terms of their functionality and effects on human health. In the experimental part of the work, methodologies for component selection, composite system formation and obtaining appropriate coatings have been developed. A methodology has been developed for the evaluation of the set of structures and properties of the obtained coatings. The influence of the chemical nature and content ratios of urethane diacrylates and monoacrylates suitable for the formation of separate cosmetic coatings on the indicators of cross-linked structures formed in the process of UV-activated copolymerization and the corresponding indicators of coating properties has been studied. The influence of individual additives on the properties of cross-linked coatings, their adhesion to the surface and the durability of the coating at removal process has been evaluated.


Author(s):  
Ivana Schwarzova ◽  
Nadezda Stevulova ◽  
Tomas Melichar

The conventional homogeneous materials can no longer effectively satisfy the growing demands on product capabilities and performance, due to the advancement in products design and materials engineering. Therefore, the fibre reinforced composites with better properties and desirable applications emerged. Natural fibres have high strength to low weight ratios and have good sound and thermal insulation properties. Combination of organic filler and inorganic matrix creates high-quality products such as fibre boards and composites. The great importance is attached to industrial hemp as source of the rapidly renewable fibres and as non-waste material. Industrial hemp fibre has great potential in composite materials reinforcement. However, improving interfacial bonding between fibres and matrix is an important factor for its using in composites. This paper deals with hemp fibre reinforced composites in civil engineering as component part of sustainable construction. Prepared lightweight composites based on original and pre-treated hemp hurds are characterized by selected physical and mechanical properties (density, thermal conductivity, water absorbability, compressive and tensile strength) in dependence on used inorganic binder (traditional Portland cement and alternative MgO-cement).


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