Processing and Mechanical Properties of Starch and PVA Composite Reinforced by MCC

2012 ◽  
Vol 583 ◽  
pp. 32-35 ◽  
Author(s):  
Wen Yong Liu ◽  
Kai Tan ◽  
Yu Gang Huang ◽  
Yi Chen ◽  
Xiang Gang Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Materials ◽  
Polyvinyl Alcohol ◽  
Mechanical Strength ◽  
Weight Ratio ◽  
Glycerol Content ◽  
Rheological Measurements

The thermoplastic processing and mechanical properties of starch and polyvinyl alcohol (PVA) composites reinforced with microcrystal cellulose (MCC) were investigated. Glycerol with 30 wt% was chosen as the plasticizer for starch and PVA, respectively. MCC with 2 wt% was used to reinforce the starch/PVA composite. The results showed that the mechanical properties of the obtained starch/PVA blend were best when the glycerol content was 30% of starch and 20% of PVA, and the weight ratio of PVA and starch was 4/6 (wPVA/wstarch). After the addition of MCC, the mechanical properties of the starch/PVA blends were improved, and the tensile strength was increased by 52%. Moreover, it was confirmed by rheological measurements that MCC could interact with the composite materials, which results in the improvement of the mechanical strength of the starch/PVA composites.

Processing and Mechanical Properties of Starch and PVA Composite Reinforced by Nano-SiO2

2012 ◽  
Vol 557-559 ◽  
pp. 201-204 ◽  
Author(s):  
Wen Yong Liu ◽  
Yi Chen ◽  
Xi Tu ◽  
Yue Jun Liu ◽  
Xi Hai Hao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Materials ◽  
Polyvinyl Alcohol ◽  
Weight Ratio ◽  
Weight Percent ◽  
Nano Silica ◽  
Glycerol Content ◽  
Rheological Measurements ◽  
Reinforcing Agent

The thermoplastic processing and mechanical properties of starch and polyvinyl alcohol (PVA) composites were studied. Glycerol was chosen as the plasticizer and nano-silica (nano-SiO2) as the reinforcing agent of the starch/PVA composites. The results showed that the mechanical properties of the obtained starch/PVA blend were best when the glycerol content was 30% of starch and 20% of PVA, and the weight ratio of PVA and starch was 0.8 (wPVA/ wstarch= 0.8/1). After the addition of nano-SiO2, the mechanical properties of the starch/PVA blends were improved. When the weight percent of nano-SiO2was 2%, the mechanical properties of the SiO2/starch/PVA composite were most excellent. It was shown that the tensile strength was increased by 16% and the elongation increased by 72%. Moreover, it was confirmed by rheological measurements that nano-SiO2could interact with the composite materials, which results in the improvement of the mechanical strength of the starch/PVA composites.

Processing and Mechanical Properties of Starch and PCL Composite Reinforced by Nano-SiO2

2012 ◽  
Vol 496 ◽  
pp. 134-137 ◽  
Author(s):  
Wen Yong Liu ◽  
Yi Chen ◽  
Long Ouyang ◽  
Yue Jun Liu ◽  
Xi Hai Hao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Materials ◽  
Mechanical Strength ◽  
Weight Percent ◽  
Nano Silica ◽  
Rheological Measurements

The thermoplastic processing and mechanical properties of starch and polycaprolactone (PCL) composites reinforced by nano-silica (nano-SiO2) were studied. The results showed that the mechanical properties of the starch/PCL blends improved significantly with the increase of PCL. After the addition of nano-SiO2, the mechanical properties of the starch/PCL blends further improved. When the weight percent of nano-SiO2 was 1.8%, the mechanical properties of the SiO2/TPS/PCL composite were most excellent. By comparison with the starch/PCL (50/50) blends, the tensile strength of the SiO2/TPS/PCL composite with 1.8% SiO2 was increased by 20% and the elongation increased by 33%. Moreover, it was confirmed by rheological measurements that nano-SiO2 could interact with the composite materials, which results in the improvement of the mechanical strength of the TPS/PCL composites.

Optically Transparent Polymethyl Methacrylate Composites made with Glass Fibers of Varying Refractive Index

1997 ◽  
Vol 12 (4) ◽  
pp. 1091-1101 ◽  
Author(s):  
Seunggu Kang ◽  
Hongy Lin ◽  
Delbert E. Day ◽  
James O. Stoffer
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Refractive Index ◽  
Mechanical Strength ◽  
Glass Fiber ◽  
Polymethyl Methacrylate ◽  
Optical Transmission ◽  
Annealing Temperature ◽  
Glass Fibers ◽  
Optically Transparent

The dependence of the optical and mechanical properties of optically transparent polymethyl methacrylate (PMMA) composites on the annealing temperature of BK10 glass fibers was investigated. Annealing was used to modify the refractive index (R.I.) of the glass fiber so that it would more closely match that of PMMA. Annealing increased the refractive index of the fibers and narrowed the distribution of refractive index of the fibers, but lowered their mechanical strength so the mechanical properties of composites reinforced with annealed fibers were not as good as for composites containing as-pulled (chilled) glass fibers. The refractive index of as-pulled 17.1 μm diameter fibers (R.I. = 1.4907) increased to 1.4918 and 1.4948 after annealing at 350 °C to 500 °C for 1 h or 0.5 h, respectively. The refractive index of glass fibers annealed at 400 °C/1 h best matched that of PMMA at 589.3 nm and 25 °C, so the composite reinforced with those fibers had the highest optical transmission. Because annealed glass fibers had a more uniform refractive index than unannealed fibers, the composites made with annealed fibers had a higher optical transmission. The mechanical strength of annealed fiber/PMMA composites decreased as the fiber annealing temperature increased. A composite containing fibers annealed at 450 °C/1 h had a tensile strength 26% lower than that of a composite made with as-pulled fibers, but 73% higher than that for unreinforced PMMA. This decrease was avoided by treating annealed fibers with HF. Composites made with annealed and HF (10 vol. %)-treated (for 30 s) glass fibers had a tensile strength (∼200 MPa) equivalent to that of the composites made with as-pulled fibers. However, as the treatment time in HF increased, the tensile strength of the composites decreased because of a significant reduction in diameter of the glass fiber which reduced the volume percent fiber in the composite.

Preparation Techniques and Property Evaluations of Highly Air Permeable Needle-Punched Geotextiles

2015 ◽  
Vol 749 ◽  
pp. 278-281
Author(s):  
Jia Horng Lin ◽  
Jing Chzi Hsieh ◽  
Jin Mao Chen ◽  
Wen Hao Hsing ◽  
Hsueh Jen Tan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Service Life ◽  
Mechanical Strength ◽  
Pore Structure ◽  
Test Results ◽  
Needle Punching ◽  
Pet Fibers ◽  
Environmental Requirements ◽  
Preparation Techniques

Geotextiles are made of polymers, and their conjunction with different processes and materials can provide geotextiles with desirable characteristics and functions, such as filtration, separation, and drainage, and thereby meets the environmental requirements. Chemical resistant and mechanical strong polymers, including polyester (PET) and polypropylene (PP), are thus used to prolong the service life of the products made by such materials. This study proposes highly air permeable geotextiles that are made with different thicknesses and various needle punching speeds, and the influences of these two variables over the pore structure and mechanical properties are then examined. PET fibers, PP fibers, and recycled Kevlar fibers are blended, followed by being needle punched with differing spaces and speeds to form geotextiles with various thicknesses and porosities. The textiles are then evaluated for their mechanical strength and porosity. The test results show that a thickness of 4.5 cm and 1.5 cm demonstrate an influence on the tensile strength of the geotextiles, which is ascribed to the webs that are incompletely needle punched. However, the excessive needle punching speed corresponding to a thickness of 0.2 cm results in a decrease in tensile strength, but there is also an increase in the porosity of the geotextiles.

Influence of the Composition of Cement Mortars Modified by Lime or Polymers on the Mechanical Properties and Microstructure of Mortars

2013 ◽  
Vol 592-593 ◽  
pp. 647-650 ◽  
Author(s):  
Małgorzata Lenart
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Reinforced Concrete ◽  
Flexural Strength ◽  
Polyvinyl Alcohol ◽  
Polymer Composites ◽  
Adhesion Strength ◽  
Hardened Cement ◽  
Cement Mortars ◽  
Styrene Butadiene

Cement – polymer composites are nowadays widely used in repair systems not only in case of concrete or reinforced concrete constructions but also in masonry. Polymers addition for example already at 5% m.c. modifies the structure of the cement – polymer composite in a way that many of the mechanical properties such as flexural strength, tensile strength or adhesion to substrates are improved. The paper presents the results of tests such as flexural, compressive or adhesion strength to ceramic substrate of hardened cement mortars with different composition, as well as selected cement mortars modified by two polymers: polyvinyl alcohol and styrene – butadiene polymer dosed at 5 % m.c. Four types of cement mortars modified by lime (component used in historical constructions as well as in contemporary masonry mortars) are also examined for comparison.

scholarly journals Fabrication and Characterization of Electrospun Polycaprolactone Blended with Chitosan-Gelatin Complex Nanofibrous Mats

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Yongfang Qian ◽  
Zhen Zhang ◽  
Laijiu Zheng ◽  
Ruoyuan Song ◽  
Yuping Zhao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Weight Ratio ◽  
Degree Of Crystallinity ◽  
X Ray Diffraction ◽  
Tissue Engineering Scaffolds ◽  
Elongation At Break ◽  
Nanofibrous Scaffolds ◽  
Two Peaks

Design and fabrication of nanofibrous scaffolds should mimic the native extracellular matrix. This study is aimed at investigating electrospinning of polycaprolactone (PCL) blended with chitosan-gelatin complex. The morphologies were observed from scanning electron microscope. As-spun blended mats had thinner fibers than pure PCL. X-ray diffraction was used to analyze the degree of crystallinity. The intensity at two peaks at 2θof 21° and 23.5° gradually decreased with the percentage of chitosan-gelatin complex increasing. Moreover, incorporation of the complex could obviously improve the hydrophilicity of as-spun blended mats. Mechanical properties of as-spun nanofibrous mats were also tested. The elongation at break of fibrous mats increased with the PCL content increasing and the ultimate tensile strength varied with different weight ratios. The as-spun mats had higher tensile strength when the weight ratio of PCL to CS-Gel was 75/25 compared to pure PCL. Both as-spun PCL scaffolds and PCL/CS-Gel scaffolds supported the proliferation of porcine iliac endothelial cells, and PCL/CS-Gel had better cell viability than pure PCL. Therefore, electrospun PCL/Chitosan-gelatin nanofibrous mats with weight ratio of 75/25 have better hydrophilicity mechanical properties, and cell proliferation and thus would be a promising candidate for tissue engineering scaffolds.

Effect of Heat Setting Methods on Structures and Properties of High Strength Polyvinyl Alcohol Fibre

2015 ◽  
Vol 815 ◽  
pp. 643-648
Author(s):  
Yin Zhu ◽  
Jiong Xin Zhao
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Polyvinyl Alcohol ◽  
Setting Time ◽  
High Strength ◽  
Single Fibre ◽  
X Ray Diffraction ◽  
Heat Setting ◽  
Heat Treated ◽  
Setting Process

The effect of heat setting methods on the structures and mechanical properties of high strength polyvinyl alcohol (PVA) fibre is studied in this article. The microstructure and mechanical properties of heat treated PVA fibre is investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and single fibre electronic tensile strength tester. Results show that the heat setting method with constant tension is a good heat setting method which can largely enhance the tensile strength of PVA fibre. During the heat setting process, the mechanical properties of PVA fibre are greatly affected by the temperature, tension and setting time. When the temperature is 220°C, tension is 5cN/dtex and setting time is 90sec, the tensile strength of PVA fibre increases from 12.0cN/dtex to 16.4cN/dtex in compare with the PVA fibre without heat setting

Effect of Wood Filler Concentration on Physical and Mechanical Properties of PLA-Based Composites

2021 ◽  
Vol 887 ◽  
pp. 110-115
Author(s):  
G.A. Sabirova ◽  
R.R. Safin ◽  
N.R. Galyavetdinov
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Elastic Modulus ◽  
Composite Materials ◽  
Impact Strength ◽  
Wood Flour ◽  
Experimental Studies ◽  
Physical And Mechanical Properties ◽  
Filler Concentration ◽  
High Concentration

This paper presents the findings of experimental studies of the physical and mechanical properties of wood-filled composites based on polylactide (PLA) and vegetable filler in the form of wood flour (WF) thermally modified at 200-240 °C. It also reveals the dependence of the tensile strength, impact strength, bending elastic modulus, and density of composites on the amount of wood filler and the temperature of its thermal pre-modification. We established that an increase in the concentration of the introduced filler and the degree of its heat treatment results in a decrease of the tensile strength, impact strength and density of composite materials, while with a lower binder content, thermal modification at 200 °C has a positive effect on bending elastic modulus. We also found that 40 % content of a wood filler heated to 200 °C is sufficient to maintain relatively high physical and mechanical properties of composite materials. With a higher content of a wood filler, the cost can be reduced but the quality of products made of this material may significantly deteriorate. However, depending on the application and the life cycle of this product, it is possible to develop a formulation that includes a high concentration of filler.

The effect of large area graphene oxide (LAGO) nanosheets on the mechanical properties of polyvinyl alcohol

2016 ◽  
Vol 36 (4) ◽  
pp. 399-405 ◽  
Author(s):  
Khalid Nawaz ◽  
Muhammad Ayub ◽  
Noaman Ul-Haq ◽  
M.B. Khan ◽  
Muhammad Bilal Khan Niazi ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Graphene Oxide ◽  
Polyvinyl Alcohol ◽  
Molecular Level ◽  
Large Area ◽  
Graphene Oxides ◽  
Elongation At Break ◽  
Graphene Oxide Sheets ◽  
Excellent Improvement

Abstract Large area graphene oxide sheets were synthesized, dispersed in water and used as nanofiller for mechanical improvement in terms of Young’s modulus and ultimate tensile strength (UTS) of polyvinyl alcohol (PVA) at low loading. The molecular level dispersion and interfacial interactions between the graphene oxides and polymeric matrix PVA were the real challenges. An excellent improvement in mechanical properties at 0.35 wt% loading was observed. Modulus improved from 1.58 GPa to 2.72 GPa (~71% improvement), UTS improved from 120 MPa to 197 MPa (~65% improvement), and in spite of these improvements, interestingly, there was no fall in elongation at break at this loading.

Co-milling-assisted exfoliated graphite nanoplatelets filler introduction in polyethylene and alumina composites

2018 ◽  
Vol 53 (13) ◽  
pp. 1815-1826
Author(s):  
Sheng Cai Tan ◽  
Jimmy KW Chan ◽  
Kian Ping Loh
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Materials ◽  
Exfoliated Graphite ◽  
Flexural Properties ◽  
Graphite Nanoplatelets ◽  
Alumina Composites ◽  
Exfoliated Graphite Nanoplatelets ◽  
Polyethylene Composites

This paper aims to investigate the effect of co-milling-assisted exfoliation of graphite into polyethylene and alumina matrices on the mechanical properties of the composites. Tensile mechanical properties of composite materials based on polyethylene reinforced with graphite and graphite-derived fillers at 0–0.75 wt% loading were investigated, while hardness and flexural properties of alumina composites with 0.25 wt% loading of the same additives were assessed. Exfoliated graphite, applied at 0.25–0.75 wt% in pre-exfoliated form or in a co-milling-assisted fashion, has been demonstrated to be effective in enhancing the tensile strength of polyethylene composites. Similar enhancement in hardness and flexural properties was observed in alumina composites with 0.25 wt% loading of the exfoliated graphite. Co-milling-assisted exfoliated graphite nanoplatelets additive introduction has been found to effect a more desirable mechanical properties enhancement in the composites investigated in this study.

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