Mixed Polymers and Vulcanizable Plasticizers. Relation to the Vulcanization of Rubber

1941 ◽  
Vol 14 (4) ◽  
pp. 826-834
Author(s):  
B. S. Garvey ◽  
C. H. Alexander ◽  
F. E. Küng ◽  
D. E. Henderson

Abstract The vital role played by rubber in modern civilization is due in part to the physical properties displayed by soft vulcanized rubber in service and in part to the characteristics of unvulcanized milled rubber which make it amenable to manufacturing operations. Vulcanization of rubber is a change in condition usually induced by heating it with sulfur, and is best defined by contrasting the difference in physical properties: To illustrate, compare a mill-mixed composition before and after vulcanization. Before vulcanization it is easily pulled apart and, if considerably extended, shows little tendency to retract, although, under impact, the recovery or rebound is considerable. If heated it becomes even softer and more plastic, and can easily be formed into any desired shape. If cooled to 0° C or somewhat lower, it becomes stiff and boardy. It is readily soluble in hydrocarbon solvents. When two fresh surfaces are pressed together, they coalesce and become practically integral. This tack, as it is called, is valuable in manufacturing operations. After vulcanization, rubber is tough and strong and, after even a slow distortion, returns rapidly to its original shape. It has little tendency to flow and is devoid of tack. It swells but does not dissolve in hydrocarbon solvents. These characteristics change very little from −40° to well above 100° C.

2020 ◽  
Vol 32 (3) ◽  
pp. 214
Author(s):  
Fakhrurrazi Fakhrurrazi ◽  
Rachmi Fanani Hakim ◽  
Ayu Anisah Reghina

Introduction: Saliva is a complex oral fluid that is secreted by the major and minor salivary glands which have a vital role in sustaining oral hard and soft tissues. The calcium ion is one of the inorganic components of saliva, which plays a vital role in maintaining the tooth enamel integrity through the remineralisation process. The compliance of calcium intake for the body and the enhancement of calcium ions in saliva can be affected by consumption of fruits that comprise lots of calcium. Consumption of fruit containing high calcium can increase buffer capacity, support remineralisation and prevent demineralisation. One of the fruits with rich calcium is red dragon fruit (Hylocereus polyrhizus). The purpose of this study was to analyse the difference between the salivary calcium ion level before and after consumption of red dragon fruit (Hylocereus polyrhizus) on the students of Faculty of Dentistry Syiah Kuala University batch 2017. Methods: This study was pre-experimental with one group pretest-posttest design. The number of subjects in this study was 32 people with one group pretest-posttest design. Saliva was collected by spitting method five times. Results: The average salivary calcium ion before consumption of red dragon fruit (Hylocereus polyrhizus) was 1.972, and the average value of salivary calcium ion after consumption of red dragon fruit (Hylocereus polyrhizus) was 2.378. Results of the statistical test using the paired t-test showed a significant difference of the salivary calcium ion before and after consumption of red dragon fruit (Hylocereus polyrhizus) with the p-value = 0.000 (p < 0.05). Conclusion: There is a difference of the salivary calcium ion level before and after consumption of red dragon fruit (Hylocereus polyrhizus).


1934 ◽  
Vol 7 (1) ◽  
pp. 89-102 ◽  
Author(s):  
B. S. Garvey ◽  
W. D. White

Abstract For a series of rubber-sulfur compounds and for four commercial, high-gum accelerated compounds the changes during cure have been measured by a series of physical tests. The change in combined sulfur has also been measured for the rubber-sulfur compounds. Experimental conditions have been so controlled that all results are comparable. Based on the experimental results, a set of criteria has been selected with approximate limiting values for unvulcanized and for vulcanized rubber. Conditions are specified under which the criteria can be used to measure the degree of vulcanization. The selection of these criteria is, in effect, a definition in terms of the changes in physical properties which limits the meaning of the term “vulcanization” in a manner useful for the study of the phenomenon. The difference in the rate of change of the several properties is interpreted as evidence that during vulcanization a mechanical structure is built up.


Author(s):  
R.A. Herring

Rapid thermal annealing (RTA) of ion-implanted Si is important for device fabrication. The defect structures of 2.5, 4.0, and 6.0 MeV As-implanted silicon irradiated to fluences of 2E14, 4E14, and 6E14, respectively, have been analyzed by electron diffraction both before and after RTA at 1100°C for 10 seconds. At such high fluences and energies the implanted As ions change the Si from crystalline to amorphous. Three distinct amorphous regions emerge due to the three implantation energies used (Fig. 1). The amorphous regions are separated from each other by crystalline Si (marked L1, L2, and L3 in Fig. 1) which contains a high concentration of small defect clusters. The small defect clusters were similar to what had been determined earlier as being amorphous zones since their contrast was principally of the structure-factor type that arises due to the difference in extinction distance between the matrix and damage regions.


1979 ◽  
Vol 42 (04) ◽  
pp. 1332-1339 ◽  
Author(s):  
Hiroh Yamazaki ◽  
Takeshi Motomiya ◽  
Minoru Sonoda ◽  
Noboru Miyagawa

SummaryChanges in platelets in 48 patients with uterine myoma before and after hysterectomy with and without ovariectomy were examined. Bilateral ovariectomy in 25 cases (ovariec-tomized group) and unilateral or non-ovariectomy in 23 cases (control group) were performed at the hysterectomy. Platelet count and an appearance rate of secondary aggregation decreased at one day after and increased at one week after the operation, similarly in both the ovariectomized and the control group. The appearance rate of secondary aggregation was reflected in an intensity of aggregation at 5 min after the addition of reagent to PRP. At one month after the operation, the appearance rate of secondary aggregation induced by 3 μM ADP showed a statistically significant decrease in comparison with the preoperation value (P <0.05) and the enhancement of 5-min aggregation was still observed in the control group, while ceased in the ovariectomized group. The difference between the two groups was significant (P < 0.05). There was almost no change in the speed and intensity of primary and secondary aggregation during the observation period. No significant differences in collagen-induced aggregation were noted between the two groups. The results suggest that ovarian hormones, mainly estrogen, facilitate platelet activation which is mediated by the so-called secondary aggregation.


Author(s):  
Niken Setyaningrum ◽  
Andri Setyorini ◽  
Fachruddin Tri Fitrianta

ABSTRACTBackground: Hypertension is one of the most common diseases, because this disease is suffered byboth men and women, as well as adults and young people. Treatment of hypertension does not onlyrely on medications from the doctor or regulate diet alone, but it is also important to make our bodyalways relaxed. Laughter can help to control blood pressure by reducing endocrine stress andcreating a relaxed condition to deal with relaxation.Objective: The general objective of the study was to determine the effect of laughter therapy ondecreasing elderly blood pressure in UPT Panti Wredha Budhi Dharma Yogyakarta.Methods: The design used in this study is a pre-experimental design study with one group pre-posttestresearch design where there is no control group (comparison). The population in this study wereelderly aged over> 60 years at 55 UPT Panti Wredha Budhi Dharma Yogyakarta. The method oftaking in this study uses total sampling. The sample in this study were 55 elderly. Data analysis wasused to determine the difference in blood pressure before and after laughing therapy with a ratio datascale that was using Pairs T-TestResult: There is an effect of laughing therapy on blood pressure in the elderly at UPT Panti WredhaBudhi Dharma Yogyakarta marked with a significant value of 0.000 (P <0.05)


2020 ◽  
Vol 22 (3) ◽  
pp. 341-361
Author(s):  
Gonzalo Grau-Pérez ◽  
J. Guillermo Milán

In Uruguay, Lacanian ideas arrived in the 1960s, into a context of Kleinian hegemony. Adopting a discursive approach, this study researched the initial reception of these ideas and its effects on clinical practices. We gathered a corpus of discursive data from clinical cases and theoretical-doctrinal articles (from the 1960s, 1970s and 1980s). In order to examine the effects of Lacanian ideas, we analysed the difference in the way of interpreting the clinical material before and after Lacan's reception. The results of this research illuminate some epistemological problems of psychoanalysis, especially the relationship between theory and clinical practice.


1962 ◽  
Vol 41 (1) ◽  
pp. 123-128 ◽  
Author(s):  
Pentti A. Järvinen ◽  
Sykkö Pesonen ◽  
Pirkko Väänänen

ABSTRACT The fractional determination of 17-ketosteroids in the daily urine was performed in nine cases of hyperemesis gravidarum and in four control cases, in the first trimester of pregnancy both before and after corticotrophin administration. The excretion of total 17-KS is similar in the two groups. Only in the hyperemesis group does the excretion of total 17-KS increase significantly after corticotrophin administration. The fractional determination reveals no difference between the two groups of patients with regard to the values of the fractions U (unidentified 17-KS), A (androsterone) and Rest (11-oxygenated 17-KS). The excretion of dehydroepiandrosterone is significantly higher in the hyperemesis group than in the control group. The excretion of androstanolone seems to be lower in the hyperemesis group than in the control group, but the difference is not statistically significant. The differences in the correlation between dehydroepiandrosterone and androstanolone in the two groups is significant. The high excretion of dehydroepiandrosterone and low excretion of androstanolone in cases of hyperemesis gravidarum is a sign of adrenal dysfunction.


1979 ◽  
Vol 7 (1) ◽  
pp. 31-39
Author(s):  
G. S. Ludwig ◽  
F. C. Brenner

Abstract An automatic tread gaging machine has been developed. It consists of three component systems: (1) a laser gaging head, (2) a tire handling device, and (3) a computer that controls the movement of the tire handling machine, processes the data, and computes the least-squares straight line from which a wear rate may be estimated. Experimental tests show that the machine has good repeatability. In comparisons with measurements obtained by a hand gage, the automatic machine gives smaller average groove depths. The difference before and after a period of wear for both methods of measurement are the same. Wear rates estimated from the slopes of straight lines fitted to both sets of data are not significantly different.


Author(s):  
I Ketut Widana

The working practice of the engineering students is part of the learning process that is irreducible and indispensable. The composition of  lecturing between theoretical and practical one is 40% to 60%. With this condition, the students spend more time at the laboratory. Generally, the students perform in the laboratory work by standing position. The design of research is observational cross-sectional. The method applied is observation, interview and measuring. The subjects of research are practicing students amounting to 21 students. Referring to the analysis of statistical test or Wilcoxon signed ranks test, the difference of effect of work position is significant, namely p < 0.05 towards musculoskeletal disorders (MSDs) before and after working. The quantity of the average complaint after working is score 44.62 ± 9.47. The result of Wilcoxon signed rank test shows that there is significant different effects of standing work position, namely p < 0.05 towards fatigue generally before and after working. The degree of the working pulse is on the average of 110.78  ± 17.80 bpm (beats per minutes) which can be categorized into the medium workload. Using paired t-test, the result is p < 0.05.


1979 ◽  
Vol 44 (12) ◽  
pp. 3632-3643 ◽  
Author(s):  
Karel Mach ◽  
Igor Janovský ◽  
Karel Vacek

Total yields of paramagnetic species, their optical bleaching and thermal annealing in acetic, propionic, a-butyric, isobutyric, and pivalic acid γ-irradiated at 77 K were followed by ESR spectroscopy. Radical anions, always found after irradiation, disappear during optical bleaching without formation of any paramagnetic product. During thermal annealing they are converted almost quantitatively into the α-radicals of the respective acid, with the exception of pivalic acid. Amounts of radical anions were estimated from the difference of integrated ESR spectra taken before and after optical bleaching. The results show that approximately equal amounts of the reduction and oxidation paramagnetic products of the γ-irradiation can be detected.


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