scholarly journals Synthetic fatty acid from crude oil of Tamsagbulag petroleum deposit (Mongolia)

2021 ◽  
Vol 22 (48) ◽  
pp. xx-xx
Author(s):  
Myagmargerel Bayanmunkh ◽  
Khulan Bayasgalan ◽  
Gantsetseg Byambasuren ◽  
Khongorzul Batchuluun ◽  
Tuya Murneren
Keyword(s):  
Fatty Acids ◽  
Experimental Study ◽  
Fatty Acid ◽  
Crude Oil ◽  
Normal Condition ◽  
Oxidation Process ◽  
Raw Materials ◽  
Synthetic Fatty Acid ◽  
Physicochemical Characteristics ◽  
Solid Paraffin

In this work, we studied to obtain synthetic fatty acids raw materials to produce surfactants and various detergents from paraffin. The solid paraffin extracted from the Tamsagbulag petroleum deposit was 46 mass%, distilled 350-450°C, by complexing with urea. Experimental study indicates paraffin's physicochemical characteristics from this petroleum are more suitable to use in the production of synthetic fatty acids. By solid paraffin oxidation, we obtained 33.01% of the synthetic fatty acids containing monocarboxylic acids.We suggest obtaining the synthetic fatty acid by oxidation process in normal condition from petroleum paraffin.

scholarly journals Enzyme-Assisted Extraction of Fish Oil from Whole Fish and by-Products of Baltic Herring (Clupea harengus membras)

Foods ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 1811
Author(s):  
Ella Aitta ◽  
Alexis Marsol-Vall ◽  
Annelie Damerau ◽  
Baoru Yang
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Fish Oil ◽  
Crude Oil ◽  
Proteolytic Enzymes ◽  
Clupea Harengus ◽  
Omega 3 Fatty Acids ◽  
Omega 3 ◽  
Baltic Herring ◽  
By Products

Baltic herring (Clupea harengus membras) is one of the most abundant commercially caught fish species from the Baltic Sea. Despite the high content of fat and omega-3 fatty acids, the consumption of Baltic herring has decreased dramatically over the last four decades, mostly due to the small sizes and difficulty in processing. At the same time there is an increasing global demand for fish and fish oil rich in omega-3 fatty acids. This study aimed to investigate enzyme-assisted oil extraction as an environmentally friendly process for valorizing the underutilized fish species and by-products to high quality fish oil for human consumption. Three different commercially available proteolytic enzymes (Alcalase®, Neutrase® and Protamex®) and two treatment times (35 and 70 min) were investigated in the extraction of fish oil from whole fish and by-products from filleting of Baltic herring. The oil quality and stability were studied with peroxide- and p-anisidine value analyses, fatty acid analysis with GC-FID, and volatile compounds with HS-SPME-GC-MS. Overall, longer extraction times led to better oil yields but also increased oxidation of the oil. For whole fish, the highest oil yields were from the 70-min extractions with Neutrase and Protamex. Protamex extraction with 35 min resulted in the best fatty acid composition with the highest content of eicosapentaenoic acid (EPA; 20:5n-3) and docosahexaenoic acid (DHA; 22:6n-3) but also increased oxidation compared to treatment with other enzymes. For by-products, the highest oil yield was obtained from the 70-min extraction with Protamex without significant differences in EPA and DHA contents among the oils extracted with different enzymes. Oxidation was lowest in the oil produced with 35-min treatment using Neutrase and Protamex. This study showed the potential of using proteolytic enzymes in the extraction of crude oil from Baltic herring and its by-products. However, further research is needed to optimize enzymatic processing of Baltic herring and its by-products to improve yield and quality of crude oil.

scholarly journals Effect of Pork Meat Replacement by Fish Products on Fatty Acid Content, Physicochemical, and Sensory Properties of Pork Pâtés

2020 ◽  
Vol 11 (1) ◽  
pp. 188
Author(s):  
Piotr Skałecki ◽  
Agnieszka Kaliniak-Dziura ◽  
Piotr Domaradzki ◽  
Mariusz Florek ◽  
Ewa Poleszak ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Acid Content ◽  
Raw Materials ◽  
Fatty Acid Content ◽  
Calorific Value ◽  
Thiobarbituric Acid ◽  
Acid Value ◽  
Sensory Properties ◽  
Control Group

The aim of the study was to assess the influence of the addition of fish raw materials (roe or fish meat) on the quality and nutritional value of pork pâtés. The control group (n = 4) consisted of pork pâtés, I experimental group (n = 6) of pâtés with 20% addition of roe (perch and pike), and II group of pâtés with 20% addition of fish (perch and pike meat) (n = 6). The pâtés’ pH, color, and profiled texture analysis were instrumentally measured and water, protein, fat, ash, and fatty acid content were determined by reference methods. To assess the oxidative stability of lipids the measurement of peroxide number, thiobarbituric acid reactive substances and content of conjugated dienes and trienes was used. The degree of fat hydrolysis was determined on the basis of acid value. Sensory analysis was carried out using the scaling method, taking into account 12 unit quality characteristics. Products with roe and meat contained less fat (accordingly 15.9% and 14.1%) and showed lower calorific value (accordingly 225.6 and 208.6 kcal/100 g) compared to pork pâtés (20.2% of lipids, 267 kcal/100 g). Moreover, the addition of fish raw materials improved the index of nutritional quality for protein (from 3.2 to 3.9) and beneficially reduced the nutritional index for fat (from 2.2 to 1.9). Fish constituents modified, to a certain extent, the color, texture, and sensory properties of pâtés, while maintaining full acceptability in consumer assessment. The addition of fish roe significantly increased the healthful quality by improving the fatty acid profile of pâtés, in which the significantly highest content of n-3 fatty acids, including eicosapentaenoic and docosahexaenoic acids (accordingly 252.21, 43.17, and 107.94 mg/100 g product), as well the highest concentration of saturated branched chain fatty acids were determined (18.75 mg/100 g product).

Technology of biscuits with a balanced fatty acid composition

2021 ◽  
Vol 30 (11) ◽  
pp. 34-39
Author(s):  
G.V. Posnova ◽  
◽  
N.G. Ivanova ◽  
I.A. Nikitin ◽  
G.A. Shinov ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Healthy Lifestyle ◽  
Raw Materials ◽  
Control Sample ◽  
School Age Children ◽  
Plant Raw Materials ◽  
Degree Of Satisfaction

The article presents the results of research on the development of the technology of biscuits using non-traditional plant raw materials. In the course of the work, the replacement of a part of the premium wheat flour in the dairy crust recipe with a mixture of rice (17%) and sesame (11%) and the replacement of butter with camelina butter in an amount of 5% by weight of the product was justified. It was found that the introduction of functional raw materials gives the products a moderately sweet milk taste with a pleasant nutty aftertaste and orange color. The resulting products are characterized by a balanced fatty acid composition of ω-3 and ω-6, enriched with minerals and vitamins. Calculation of the nutritional value showed that the consumption of 100 g of the developed biscuits covers the daily need of an adult for polyunsaturated fatty acids of the ω-3 and ω-6 families by 37–75% and 19,4–31,5, respectively. The protein content rises by 1,5 times, and the carbohydrate content decreases by 1,16 times. At the same time, the degree of satisfaction of the daily requirement for potassium increases – by 2,3%, in calcium – by 7–7,5%, in phosphorus – by 12,6%, in magnesium – by 16,3%, in iron – by 7,3–13,3%. The degree of satisfaction of the daily requirement for vitamins B1 also increases – by 19,7–20,9%, B2 – by 2,2–2,3%, PP – by 8,1–9,3%, E – by 1,6–1,7% compared to the control sample of dairy cakes. The developed products can be recommended for preventive nutrition, people adhering to a healthy lifestyle, as well as school-age children, pregnant and lactating women who have a deficiency of ω-3 and ω-6 fatty acids in the diet

scholarly journals Fatty acid composition of night-scented stock (Matthiola bicornis (Sibth. & Sm.) DC.) raw materials

2021 ◽  
Vol 34 (1) ◽  
pp. 34-41
Author(s):  
Viktoriia O. Pinkevych ◽  
Moeen F. Dababneh ◽  
Nadiia Ye. Burda ◽  
Iryna O. Zhuravel
Keyword(s):  
Fatty Acids ◽  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Polyunsaturated Fatty Acids ◽  
Acid Composition ◽  
Raw Materials ◽  
Similar Fatty Acid Composition ◽  
Domestic Plant ◽  
Plant Sources

Abstract Introduction. With due consideration of the properties of fatty acids, as well as their importance for normal life activity and human development, research into the fatty acid composition of poorly studied plants and the search for new domestic plant sources of polyunsaturated fatty acids is a mainstream trend in modern pharmacy. Aim. Aim of research – determination of fatty acid qualitative composition and content in threshed grass, stalks, roots and seeds of Night-scented stock ‘Queen of Night’ and ‘Evening Scent’ cultivars as grown in Ukraine. Methods. Gas chromatography. Results. Both cultivars of Night-scented stock taken for analysis had similar fatty acid composition – 5 saturated, 5 (4 for seeds) monounsaturated and 2 polyunsaturated fatty acids, Quantitatively, in all tested parts of the herb polyunsaturated and monounsaturated fatty acid dominated, making in total 88.92% and 88.62% in the seeds of Queen of Night and Evening Scent cultivars, respectively, and averaging 65% in other parts of the tested cultivars. Linolenic and linoleic acids prevailed among the polyunsaturated fatty acids, whereas oleic acid prevailed among the monounsaturated. Conclusion. Night-scented stock can be utilized as a source of polyunsaturated fatty acids for the development of drugs and for standardization of tested raw materials.

scholarly journals Sintesis Merkaptoetil Karboksilat sebagai Bahan Baku Stabiliser Termal Polivinil Klorida: Variasi Sumber Asam Lemak

2020 ◽  
Vol 18 (2) ◽  
pp. 47
Author(s):  
I Dewa Gede Arsa Putrawan ◽  
Adli Azharuddin ◽  
Dendy Adityawarman ◽  
Dicka Ar Rahim
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Polyvinyl Chloride ◽  
Raw Materials ◽  
Batch Reactor ◽  
Strong Acid ◽  
Raw Material ◽  
Thermal Stabilizer ◽  
Palm Fatty Acid Distillate ◽  
Rigid Pvc

Abstrak. Merkaptoetil karboksilat merupakan bahan baku stabiliser termal polivinil klorida atau polyvinyl chloride (PVC) berbasis timah organik. Stabiliser termal perlu ditambahkan ke dalam resin PVC sebelum diekstrusi untuk mencegah kerusakan karena pengerjaan panas. Stabiliser termal PVC dari timah organik dikenal sangat efektif, khususnya untuk aplikasi PVC kaku seperti pipa dan bingkai jendela. Penelitian ini bertujuan mengevaluasi sintesis merkaptoetil karboksilat dari asam lemak dan merkapto etanol dengan variasi sumber asam lemak yang meliputi asam lemak sawit, dedak padi dan biji kapuk. Percobaan dilakukan dalam sebuah reaktor partaian (batch) dengan asam kuat sebagai katalis. Percobaan dilakukan pada temperatur 60-80°C dan ekses merkapto etanol 10%. Kinerja sintesis dievaluasi melalui pengukuran kadar gugus merkaptan dan angka asam dalam produk serta perolehan produk. Pada rentang temperatur 60-80°C, ketiga asam lemak memberikan produk dengan kadar merkaptan pada rentang 6,4-7,8%.  Temperatur 70°C merupakan temperatur terbaik karena menghasilkan produk dengan kadar merkaptan tertinggi tanpa memadat selama penyimpanan. Pada temperatur ini, produk memiliki angka asam pada rentang 11-41 mg KOH/g dan perolehan pada rentang 70-81%. Ketiga sumber asam lemak memberikan produk dengan kadar merkaptan yang mencukupi untuk dapat digunakan sebagai bahan baku stabiliser PVC. Mempertimbangkan kualitas produk dan ketersediaan di pasaran, distilat asam lemak sawit dipandang sebagai bahan baku yang paling baik. Kata kunci: asam lemak, merkaptoetil karboksilat, polivinil klorida, stabiliser termal. Abstract. Synthesis of Mercaptoethyl Carboxylate as Raw Materials for Polyvinyl Chloride Thermal Stabilizer: Variation in Fatty Acid Source. Mercaptoethyl carboxylate is a raw material for organotin-based polyvinyl chloride (PVC) thermal stabilizer. Thermal stabilizers need to be added to the PVC resin before extruded to prevent degradation due to heat treatment. Organotin PVC stabilizers are known to be very effective, especially for rigid PVC applications such as pipes and frames. This study was aimed to evaluate the synthesis of mercaptoethyl carboxylate from fatty acids and mercaptoethanol with various sources of fatty acids including palm, rice bran and kapok seed fatty acids. The experiment was carried out in a batch reactor with a strong acid as a catalyst. The experiments were conducted at 60-80°C and 10% mercapto ethanol excess. The performance of synthesis was evaluated by measuring mercaptan and acid contents and yield. In the range of 60-80°C, all three fatty acids provided products with mercaptan levels in the range of 6.4-7.8%. A temperature of 70°C is the best temperature as it gave a product with the highest mercaptan content without solidification during storage. At this temperature, the product had acid values in the range 11-41 mg KOH/g and yields in the range of 70-81%. Considering product quality and availability in the market, palm fatty acid distillate was seen as the best raw material. Keywords: fatty acid, mercaptoethyl carboxylate, polyvinyl chloride, thermal stabilizer. Graphical Abstract

scholarly journals Physicochemical characterization of the pulp oil of bacuri Attalea phalerata Mart. ex Spreng. (Arecaceae)

2020 ◽  
Vol 21 (3) ◽  
pp. 1-11
Author(s):  
Michelle Cardoso Coimbra ◽  
Débora Maria Moreno Luzia ◽  
Neuza Jorge
Keyword(s):  
Fatty Acids ◽  
Gas Chromatography ◽  
Refractive Index ◽  
Fatty Acid ◽  
Potassium Hydroxide ◽  
High Performance ◽  
Physicochemical Characterization ◽  
Physicochemical Characteristics ◽  
Total Phenolic

The aim of the study was to characterize the pulp oil of bacuri Attalea phalerata Mart. ex Spreng. (Arecaceae) according to official analytical methods. Total phenolic and carotenoids contents were evaluated by spectrophotometry, and tocopherols composition by high-performance liquid chromatography. The fatty acid profile was obtained through gas chromatography from samples transesterified with potassium hydroxide in methanol and n-hexane. According to the proximate composition, bacuri pulp contained 41.5 % carbohydrates and 39.2 % lipids. Regarding its physicochemical properties, the oil showed a free fatty acids content of 0.7 %, a peroxide value of 1.4 meq/kg, a refractive index of 1.463, an iodine number of 84.3 g I2/100 g, a saponification number of 193.5 mg KOH/g, an unsaponifiable matter of 0.5 %, and 48.7 h of oxidative stability. Total phenolic, carotenoids, and tocopherols contents recorded values of 2.4 mg GAE/g, 243.0 µg/g, and 86.8 mg/kg, respectively. The bacuri oil showed a fatty acid composition similar to olive oil and a high percentage of unsaturation, finding 67.3 % of monounsaturated acids, and 11.3 % of polyunsaturated acids. The main fatty acids were oleic (67.3 %), palmitic (13.3 %), and linoleic (10.5 %). Due to its physicochemical characteristics, bacuri oil has a great potential to be used in food preparations, such as salad oil or in margarine formulation.

scholarly journals Research of the process of receiving and preparing for to use of ecologically pure biofuel on the basis of tall oil

2020 ◽  
Vol 24 (5) ◽  
pp. 97-103
Author(s):  
A.N. Ivankin ◽  
◽  
A.N. Zarubinа ◽  
G.L. Oliferenko ◽  
A.S. Kuleznev ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Raw Materials ◽  
Methyl Esters ◽  
General Scheme ◽  
Total Content ◽  
Component Composition ◽  
Gas Liquid Chromatography ◽  
Organic Substances ◽  
Tall Oil

The article discusses the scientific and technical issues of the methodology for producing liquid biofuel from renewable raw materials of plant origin. As raw materials used wastes from the production of pulp and paper mills — tall oil. The purpose of the work was to study the process of obtaining and determining ways to use the product. The optimal conditions for obtaining biodiesel are determined. The processing of raw materials was carried out by heating it with methanol in a ratio of 1:0,3 at a temperature of 50–65 °C for 2 hours in the presence of 2 % catalyst. The product, after separation of the resulting intermediate, was finally washed with water from the catalyst residues. The process was controlled spectrophotometrically. Using gas-liquid chromatography with mass spectrometric detection, the complete chemical composition of the used raw materials of various degrees of purification was established. It is shown that the main content in the processed oil is represented by natural lipids. Their fatty acid composition is described, comprising more than thirty C10–C24 fatty acids. A general scheme for producing biodiesel, which is a mixture of fatty acid alkyl esters, has been developed. The product was obtained by chemical transformation in the presence of acid catalysts, followed by the formation of fatty acid methyl esters. The component composition of the obtained product, biodiesel, was studied and it was shown that it consists of a mixture of methyl esters of fatty acids more than 95 %. In biodiesel, more than two hundred organic substances are also contained in the form of an insignificant amount of microimpurities. Their number fluctuated around 0,001 %. The basic physico-chemical characteristics of the obtained biodiesel are described in comparison with international requirements for biofuels. The analyzed product samples obtained from distilled TM, according to mass spectrometry, did not contain harmful impurities bromine, iodine, phosphorus and sulfur-substituted compounds. The total content of chlorine-substituted organic substances in all samples did not exceed 0,07 ± 0,02 %, and N-substituted derivatives did not exceed 0,05 ± 0,01 %, which indicates a rather high ecological purity of bitumen fuel. The main directions of the possible use of the product as liquid fuel for mini-boiler nozzles, as well as for operation in conventional diesel engines, are determined.

scholarly journals Physical and Chemical Properties of oils of three varieties seeds of passion fruit: Passiflora alata Curtis, Passiflora edulis f. flavicarpa and Passiflora quadrangularis

2021 ◽  
Vol 7 ◽  
Author(s):  
Simone Rodrigues Silva ◽  
Elizângela Augusta Dos Santos ◽  
Antônio Alves De Melo Filho
Keyword(s):  
Fatty Acids ◽  
Oleic Acid ◽  
Fatty Acid ◽  
Chemical Properties ◽  
Physicochemical Characteristics ◽  
Major Fatty Acid ◽  
Passion Fruit ◽  
Seed Oils ◽  
Passiflora Edulis ◽  
Total Fatty Acids

This paper reports the physicochemical characteristics of the seed oils from different varieties of passion fruit (Passiflora alata Curtis, Passiflora edulis f. flavicarpa and Passiflora quadrangularis) cultivated in Brazil, Roraima. The oil  from passion fruit, within the range of 19.29±0.02; 21.34±0.22 e 14.24±0.16%, respectively. The physicohemical characteristics of the extracted oils were: free fatty acid contents (0.84±0.01 - 2.73±0.05 % mg KOH g-1 as oleic acid), iodine value (101.63±0.18 - 125.96±0.13 g of I2 100 g-1 of oil), and saponification index (90.56±0.32 - 179.06±0.19 mg KOH g-1 of oil). The oils revealed a reasonable oxidative parameter range as depicted by the determinations of index peroxide value (1.92±0.09 – 3.05±0.03 meqO2 kg-1 of oil). Linoleic acid was the major fatty acid found in all the seed oils with contributions of 55.75-63.42% of the total fatty acids (FA). Other fatty acids detected were known to be oleic acid (19.3-20.1%), palmitic acid (10.8-12.8%) and stearic acid (3.25-4.25%). Through the DPPH test we observed the presence of antioxidants in the three oil samples. The results of the present study indicate that the seeds of the tested passion fruit varieties from Roraima are a potential source of high-linoleic oil and thus can be explored for commercial use and value addition.

scholarly journals Synthesis and Characterization of an Iron-Containing Fatty Acid-Based Ionomer

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
David A. Stone ◽  
Atanu Biswas ◽  
Zengshe Liu ◽  
Veera Boddu ◽  
H. N. Cheng
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Raw Materials ◽  
Low Cost ◽  
Paper Industry ◽  
Alder Reaction ◽  
Size Exclusion ◽  
Molecular Weights ◽  
Exclusion Chromatography ◽  
Solid Film

One of the desirable research goals today is to convert agro-based raw materials into low-cost functional polymers. Among the readily available natural raw materials are the fatty acids that can be obtained from the hydrolysis of plant oils or from the paper industry as byproducts. In this work, a novel iron-containing ionomer has been prepared through the reaction of fatty acids with steel dust or iron powder in the presence of carbon dioxide and water. Characterization has been achieved via 1H and 13C NMR, FT-IR, and size exclusion chromatography. The product has been shown to have an ionomeric structure, consisting of oligomers of fatty acid carboxylates (derived from Diels-Alder reaction) coupled with iron(II) and iron(III) ions (from the oxidation of iron). Because the fatty acid oligomers have low molecular weights, the ionomer easily dissolves in a solvent and can be made into different physical forms, such as liquid, solid, film, or foam.

Sign in / Sign up

Export Citation Format

Share Document