scholarly journals NIR–vis–UV Light‐Responsive High Stress‐Generating Polymer Actuators with a Reduced Creep Rate

2021 ◽  
pp. 2100157
Author(s):  
Xinglong Pan ◽  
Rob C. P. Verpaalen ◽  
Huiyi Zhang ◽  
Michael G. Debije ◽  
Tom A. P. Engels ◽  
...  
Author(s):  
Hossein Ashrafizadeh ◽  
Ryan Schultz ◽  
Bo Xu ◽  
Pierre Mertiny

Abstract High strength-to-weight ratio, excellent corrosion resistance, flexibility, superior fatigue performance, and cost competitiveness have made thermoplastic fiber reinforced polymer composites (TP-FRPCs) a material of choice for the manufacture of pipe products for use in the oil and gas industry. The TP matrix not only protects the composite structure from brittle cracking caused by dynamic loads, it also provides improved flexibility for bending of pipes to enable easier field installation and reduces the requirement for pre-fabricated bent connections. Despite the attractive mechanical performance, the design, development and qualification evaluation of TP-FRPC components for a large portion relies on experimental testing. The time and expense of manufacturing new composite prototypes and performing full-scale testing emphasizes the value of a predictive modeling. But, modeling TP-FRPC structures is not a trivial task due to their anisotropic and time-dependent properties. In this study, a new technique based on the finite element method is proposed to model anisotropic time-dependent behavior of TP-FRPCs. In the proposed technique the composite mechanical properties are captured by superimposing the properties of two fictitious materials. To that end, two overlapping three-dimensional elements with similar nodes were assigned different material properties. One of the elements is assigned to have time-dependent properties to capture the viscoelastic behavior of the matrix while the other element is given linear anisotropic properties to account for the anisotropy induced by the fiber reinforcement. The model was calibrated using data from uniaxial tensile creep tests on coupons made from pure matrix resin and uniaxial tension tests on TP-FRPC tape parallel to the fiber direction. Combined time hardening creep formulation, ANSYS 19.2 implicit analysis, and ANSYS Composite PrepPost were employed to formulate the three-dimensional finite element model. The model was validated by comparison of model predictions with experimental creep strain obtained from TP FRPC tubes with ±45° fiber layups subjected to uniaxial intermediate and high stress for 8 hours. The results obtained showed that for the tubes subjected to intermediate stress, the model predicted the creep rate in the secondary region with less than 5% error. However, for tubes subjected to high stress, the model overestimated the creep rate with over 30% error. This behavior was due to large deformation at this high level of stress and inability of the model to capture fiber realignment towards the pipe longitudinal direction and, therefore, capture an increase in stiffness. Overall, comparison of the simulation results with experimental data indicated that the technique proposed can be used as a reliable model to account for deformations caused by secondary creep in the design of TP-FRPC structures as far as deformations are relatively small and limited to a certain strain threshold. Acceptable predictions of the model, its simplicity in calibration, and limitations on available models that can simultaneously account for time-dependency and anisotropic properties, further emphasize the value of the developed model.


1994 ◽  
Vol 373 ◽  
Author(s):  
Niyaz N. Khusnatdinov ◽  
Victor F. Petrenko

AbstractThe study of the photoplastic effect (PPE) on ice is essential for both fundamental and applied reasons. It is important for an understanding of dislocation motion as well as the flow of glaciers in cold regions that occurs under intensive solar radiation. It was found that the illumination of ice with UV light (λ < 300 nm) leads to its irreversible hardening1. A prolonged irradiation with a total light exposure of about 8.10−5 J/cm2 at λ= 260 nm can change the creep rate up to 60 percent. Even more pronounced PPE was found in HCI-doped ice with the concentration, n= 1018 cm−3. It is suggested that PPE is caused by the excitation of “autoionization” reaction which was found responsible for the photoconductivity of ice.


Author(s):  
Rolf Sandström ◽  
Jing Zhang

Abstract Many metals and alloys have a stress exponent for the creep rate that is considerably higher than the value of 3 that is typically predicted by creep recovery models. One example is pure Ni. Creep data from Norman and Duran that are analyzed in the paper give a stress exponent of about 7 in the temperature range 0.3 to 0.55 of the melting point. It has recently been shown that the high creep exponent of Al and Cu in the power-law break down regime can be explained by the presence of strain-induced vacancies. By applying a creep recovery model that does not involve adjustable parameters, it is shown that strain induced vacancies can also explain the high-stress exponent of pure nickel.


2008 ◽  
Vol 22 (31n32) ◽  
pp. 5413-5418 ◽  
Author(s):  
HOLM ALTENBACH ◽  
KONSTANTIN NAUMENKO ◽  
YEVGEN GORASH

Many materials exhibit a stress range dependent creep behavior. The power-law creep observed for a certain stress range changes to the viscous type creep if the stress value decreases. Recently published experimental data for advanced heat resistant steels indicates that the high creep exponent (in the range 5-12 for the power-law behavior) may decrease to the low value of approximately 1 within the stress range relevant for engineering structures. The aim of this paper is to confirm the stress range dependence of creep behavior based on the experimental data of stress relaxation. An extended constitutive model for the minimum creep rate is introduced to consider both the linear and the power law creep ranges. To take into account the primary creep behavior a strain hardening function is introduced. The material constants are identified for published experimental data of creep and relaxation tests for a 12% Cr steel bolting material at 500°C. The data for the minimum creep rate are well-defined only for moderate and high stress levels. To reconstruct creep rates for the low stress range the data of the stress relaxation test are applied. The results show a gradual decrease of the creep exponent with the decreasing stress level. Furthermore, they illustrate that the proposed constitutive model well describes the creep rates for a wide stress range.


1996 ◽  
Vol 460 ◽  
Author(s):  
J. Beddoes ◽  
J. Triantafillou ◽  
L. Zhao

ABSTRACTThe creep behaviour of a binary Ti-48%A1 intermetallic is presented as a function of stress for two fully lamellar microstructures. The two lamellar conditions differ in terms of the lamellar interface spacing and grain boundary morphology. Air cooling (AC) from the single phase a region causes planar grain boundaries and lamellar spacing of 90 to 130 nm, while furnace cooling (FC) causes interlocked lamellae along grain boundaries and 350 to 550 nm lamellar spacing. Monotonie and stress increment creep tests at 760°C indicate that the AC condition exhibits a lower mimimum creep strain rate at stresses between 105 MPa and 290 MPa. The stress exponent increases from ∼ 1 at low stress to ∼ 10 at high stress. Consecutive stress reduction creep tests indicate that the internal stress required for dislocation glide is higher for the AC condition. The results suggest that at low stress the creep rate is controlled by recovery mechanisms, while at high stress the creep rate is predominantly controlled by dislocation glide. It is postulated that at high stresses the lower creep rate of the AC condition, compared to the FC condition, results from the reduced lamellar interface spacing, which increases the internal stress required for dislocation glide.


Author(s):  
R.T. Chen ◽  
M.G. Jamieson ◽  
R. Callahan

“Row lamellar” structures have previously been observed when highly crystalline polymers are melt-extruded and recrystallized under high stress. With annealing to perfect the stacked lamellar superstructure and subsequent stretching in the machine (extrusion) direction, slit-like micropores form between the stacked lamellae. This process has been adopted to produce polymeric membranes on a commercial scale with controlled microporous structures. In order to produce the desired pore morphology, row lamellar structures must be established in the membrane precursors, i.e., as-extruded and annealed polymer films or hollow fibers. Due to the lack of pronounced surface topography, the lamellar structures have typically been investigated by replica-TEM, an indirect and time consuming procedure. Recently, with the availability of high resolution imaging techniques such as scanning tunneling microscopy (STM) and field emission scanning electron microscopy (FESEM), the microporous structures on the membrane surface as well as lamellar structures in the precursors can be directly examined.The materials investigated are Celgard® polyethylene (PE) flat sheet membranes and their film precursors, both as-extruded and annealed, made at different extrusion rates (E.R.).


Author(s):  
Debby A. Jennings ◽  
Michael J. Morykwas ◽  
Louis C. Argenta

Grafts of cultured allogenic or autogenic keratlnocytes have proven to be an effective treatment of chronic wounds and burns. This study utilized a collagen substrate for keratinocyte and fibroblast attachment. The substrate provided mechanical stability and augmented graft manipulation onto the wound bed. Graft integrity was confirmed by light and transmission electron microscopy.Bovine Type I dermal collagen sheets (100 μm thick) were crosslinked with 254 nm UV light (13.5 Joules/cm2) to improve mechanical properties and reduce degradation. A single cell suspension of third passage neonatal foreskin fibroblasts were plated onto the collagen. Five days later, a single cell suspension of first passage neonatal foreskin keratinocytes were plated on the opposite side of the collagen. The grafts were cultured for one month.The grafts were fixed in phosphate buffered 4% formaldehyde/1% glutaraldehyde for 24 hours. Graft pieces were then washed in 0.13 M phosphate buffer, post-fixed in 1% osmium tetroxide, dehydrated, and embedded in Polybed 812.


Author(s):  
T.R. Dinger ◽  
G. Thomas

The use of Si3N4, alloys for high temperature, high stress structural applications has prompted numerous studies of the oxynitride glasses which exist as intergranular phases in their microstructures. Oxynitride glasses have been investigated recently in their bulk form in order to understand their crystallization behavior for subsequent Si3N4 applications and to investigate their worth as glass-ceramic precursors. This research investigates the crystallization sequence of a glass having a normalized composition of Y26Si30Al11 ON11 and lying in the A1N-Y2O3-SiO2 section of the Y-Si-Al-O-N system. Such glasses exist as intergranular phases in the technologically important Y2O3/Al2O3-fluxed Si3N4 alloys.


Author(s):  
L. A. Giannuzzi ◽  
C. A. Lewinsohn ◽  
C. E. Bakis ◽  
R. E. Tressler

The SCS-6 SiC fiber is a 142 μm diameter fiber consisting of four distinct regions of βSiC. These SiC regions vary in excess carbon content ranging from 10 a/o down to 5 a/o in the SiC1 through SiC3 region. The SiC4 region is stoichiometric. The SiC sub-grains in all regions grow radially outward from the carbon core of the fiber during the chemical vapor deposition processing of these fibers. In general, the sub-grain width changes from 50nm to 250nm while maintaining an aspect ratio of ~10:1 from the SiC1 through the SiC4 regions. In addition, the SiC shows a <110> texture, i.e., the {111} planes lie ±15° along the fiber axes. Previous has shown that the SCS-6 fiber (as well as the SCS-9 and the developmental SCS-50 μm fiber) undergoes primary creep (i.e., the creep rate constantly decreases as a function of time) throughout the lifetime of the creep test.


Author(s):  
W. Engel ◽  
M. Kordesch ◽  
A. M. Bradshaw ◽  
E. Zeitler

Photoelectron microscopy is as old as electron microscopy itself. Electrons liberated from the object surface by photons are utilized to form an image that is a map of the object's emissivity. This physical property is a function of many parameters, some depending on the physical features of the objects and others on the conditions of the instrument rendering the image.The electron-optical situation is tricky, since the lateral resolution increases with the electric field strength at the object's surface. This, in turn, leads to small distances between the electrodes, restricting the photon flux that should be high for the sake of resolution.The electron-optical development came to fruition in the sixties. Figure 1a shows a typical photoelectron image of a polycrystalline tantalum sample irradiated by the UV light of a high-pressure mercury lamp.


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