Water uptake of clay and desert dust aerosol particles at sub- and supersaturated water vapor conditions

2009 ◽  
Vol 11 (36) ◽  
pp. 7804 ◽  
Author(s):  
Hanna Herich ◽  
Torsten Tritscher ◽  
Aldona Wiacek ◽  
Martin Gysel ◽  
Ernest Weingartner ◽  
...  
Author(s):  
Matus E. Diveky ◽  
Michael J. Gleichweit ◽  
Sandra Roy ◽  
Ruth Signorell

2001 ◽  
Vol 1 (1) ◽  
pp. 51-60 ◽  
Author(s):  
J. Joutsensaari ◽  
P. Vaattovaara ◽  
M. Vesterinen ◽  
K. Hämeri ◽  
A. Laaksonen

Abstract. A novel method to characterize the organic composition of aerosol particles has been developed. The method is based on organic vapor interaction with aerosol particles and it has been named an Organic Tandem Differential Mobility Analyzer (OTDMA). The OTDMA method has been tested for inorganic (sodium chloride and ammonium sulfate) and organic (citric acid and adipic acid) particles. Growth curves of the particles have been measured in ethanol vapor and as a comparison in water vapor as a function of saturation ratio. Measurements in water vapor show that sodium chloride and ammonium sulfate as well as citric acid particles grow at water saturation ratios (S) of 0.8 and above, whereas adipic acid particles do not grow at S <  0.96. For sodium chloride and ammonium sulfate particles, a deliquescence point is observed at S = 0.75 and S = 0.79, respectively. Citric acid particles grow monotonously with increasing saturation ratios already at low saturation ratios and no clear deliquescence point is found. For sodium chloride and ammonium sulfate particles, no growth can be seen in ethanol vapor at saturation ratios below 0.93. In contrast, for adipic acid particles, the deliquescence takes place at around S = 0.95 in the ethanol vapor. The recrystallization of adipic acid takes place at S < 0.4. Citric acid particles grow in ethanol vapor similarly as in water vapor; the particles grow monotonously with increasing saturation ratios and no stepwise deliquescence is observed. The results show that the working principles of the OTDMA are operational for single-component aerosols. Furthermore, the results indicate that the OTDMA method may prove useful in determining whether aerosol particles contain organic substances, especially if the OTDMA is operated in parallel with a hygroscopicity TDMA, as the growth of many substances is different in ethanol and water vapors.


2001 ◽  
Vol 106 (D16) ◽  
pp. 18047-18054 ◽  
Author(s):  
Ilan Koren ◽  
Eliezer Ganor ◽  
Joachim H. Joseph

2017 ◽  
Author(s):  
Emmanouil Proestakis ◽  
Vassilis Amiridis ◽  
Eleni Marinou ◽  
Aristeidis K. Georgoulias ◽  
Stavros Solomos ◽  
...  

Abstract. We present a 3-D climatology of the desert dust distribution over South-East Asia derived using CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) data. To distinguish desert dust from total aerosol load we apply a methodology developed in the framework of EARLINET (European Aerosol Research Lidar Network), the particle linear depolarization ratio and updated lidar ratio values suitable for Asian dust, on multiyear CALIPSO observations (01/2007–12/2015). The resulting dust product provides information on the horizontal and vertical distribution of dust aerosols over SE (South-East) Asia along with the seasonal transition of dust transport pathways. Persistent high D_AOD (Dust Aerosol Optical Depth) values, of the order of 0.6, are present over the arid and semi-arid desert regions. Dust aerosol transport (range, height and intensity) is subject to high seasonality, with highest values observed during spring for northern China (Taklimakan/Gobi deserts) and during summer over the Indian subcontinent (Thar Desert). Additionally we decompose the CALIPSO AOD (Aerosol Optical Depth) into dust and non-dust aerosol components to reveal the non-dust AOD over the highly industrialized and densely populated regions of SE Asia, where the non-dust aerosols yield AOD values of the order of 0.5. Furthermore, the CALIPSO-based short-term AOD and D_AOD time series and trends between 01/2007 and 12/2015 are calculated over SE Asia and over selected sub-regions. Positive trends are observed over northwest and east China and the Indian subcontinent, whereas over southeast China are mostly negative. The calculated AOD trends agree well with the trends derived from Aqua/MODIS (Moderate Resolution Imaging Spectroradiometer), although significant differences are observed over specific regions.


2021 ◽  
Author(s):  
Enza Di Tomaso ◽  
Jerónimo Escribano ◽  
Paul Ginoux ◽  
Sara Basart ◽  
Francesca Macchia ◽  
...  

&lt;p&gt;Desert dust is the most abundant aerosol by mass residing in the atmosphere. It plays a key role in the Earth&amp;#8217;s system by influencing the radiation balance, by affecting cloud formation and cloud chemistry, and by acting as a fertilizer for the growth of phytoplankton and for soil through its deposition over the ocean and land.&lt;/p&gt;&lt;p&gt;Due to the nature of its emission and transport, atmospheric dust concentrations are highly variable in space and time and, therefore, require a continuous monitoring by measurements. Dust observations are best exploited by being combined with model simulations for the production of analyses and reanalyses, i.e., complete and consistent four dimensional reconstructions of the atmosphere. Existing aerosol (and dust) reanalyses for the global domain have been produced by total aerosol constraint and at relatively coarse spatial resolution, while regional reanalyses exclude some of the regions containing the major sources of desert dust in Northern Africa and the Middle East.&lt;/p&gt;&lt;p&gt;We present here a 10-year reanalysis data set of desert dust at a horizontal resolution of 0.1&amp;#176;, and which covers the domain of Northern Africa, the Middle East and Europe. The reanalysis has been produced by assimilating in the MONARCH chemical weather prediction system (Di Tomaso et al., 2017) satellite retrievals over dust source regions with specific dust observational constraint (Ginoux et al., 2012; Pu and Ginoux, 2016).&lt;/p&gt;&lt;p&gt;Furthermore, we describe its evaluation in terms of data assimilation diagnostics and comparison against independent observations. Statistics of analysis departures from assimilated observations prove the consistency of the data assimilation system showing that the analysis is closer to the observations than the first-guess. Temporal mean of analysis increments show that the assimilation led to an overall reduction of dust with pattern of systematic corrections that vary with the seasons, and can be linked primarily to misrepresentation of source strength.&lt;/p&gt;&lt;p&gt;Independent evaluation of the analysis with AERONET observations indicates that the reanalysis data set is highly accurate, and provides therefore a reliable historical record of atmospheric desert dust concentrations in a recent decade.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;References&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;Di Tomaso, E., Schutgens, N. A. J., Jorba, O., and P&amp;#233;rez Garc&amp;#237;a-Pando, C. (2017): Assimilation of MODIS Dark Target and Deep Blue observations in the dust aerosol component of NMMB-MONARCH version 1.0, Geosci. Model Dev., 10, 1107-1129.&lt;/p&gt;&lt;p&gt;Ginoux, P., Prospero, J. M., Gill, T. E., Hsu, N. C. and Zhao, M. (2012): Global-Scale Attribution of Anthropogenic and Natural Dust Sources and Their Emission Rates Based on Modis Deep Blue Aerosol Products. Rev Geophys 50.&lt;/p&gt;&lt;p&gt;Pu, B., and Ginoux, P. (2016). The impact of the Pacific Decadal Oscillation on springtime dust activity in Syria. Atmospheric Chemistry and Physics, 16(21), 13431-13448.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Acknowledgements &lt;/strong&gt;&lt;/p&gt;&lt;p&gt;The authors acknowledge the DustClim project which is part of ERA4CS, an ERA-NET initiated by JPI Climate, and funded by FORMAS (SE), DLR (DE), BMWFW (AT), IFD (DK), MINECO (ES), ANR (FR) with co-funding by the European Union (435690462); PRACE (eDUST/eFRAGMENT1/eFRAGMENT2), RES (AECT-2020-3-0013/AECT-2019-3-0001/AECT-2020-1-0007) for awarding access to MareNostrum at BSC and for technical support.&lt;/p&gt;


2020 ◽  
Vol 12 (16) ◽  
pp. 2554
Author(s):  
Christopher J. Merchant ◽  
Owen Embury

Atmospheric desert-dust aerosol, primarily from north Africa, causes negative biases in remotely sensed climate data records of sea surface temperature (SST). Here, large-scale bias adjustments are deduced and applied to the v2 climate data record of SST from the European Space Agency Climate Change Initiative (CCI). Unlike SST from infrared sensors, SST measured in situ is not prone to desert-dust bias. An in-situ-based SST analysis is combined with column dust mass from the Modern-Era Retrospective analysis for Research and Applications, Version 2 to deduce a monthly, large-scale adjustment to CCI analysis SSTs. Having reduced the dust-related biases, a further correction for some periods of anomalous satellite calibration is also derived. The corrections will increase the usability of the v2 CCI SST record for oceanographic and climate applications, such as understanding the role of Arabian Sea SSTs in the Indian monsoon. The corrections will also pave the way for a v3 climate data record with improved error characteristics with respect to atmospheric dust aerosol.


2020 ◽  
Vol 12 (5) ◽  
pp. 785 ◽  
Author(s):  
Tong Wu ◽  
Zhanqing Li ◽  
Jun Chen ◽  
Yuying Wang ◽  
Hao Wu ◽  
...  

Water uptake by aerosol particles alters its light-scattering characteristics significantly. However, the hygroscopicities of different aerosol particles are not the same due to their different chemical and physical properties. Such differences are explored by making use of extensive measurements concerning aerosol optical and microphysical properties made during a field experiment from December 2018 to March 2019 in Beijing. The aerosol hygroscopic growth was captured by the aerosol optical characteristics obtained from micropulse lidar, aerosol chemical composition, and aerosol particle size distribution information from ground monitoring, together with conventional meteorological measurements. Aerosol hygroscopicity behaves rather distinctly for mineral dust coarse-mode aerosol (Case I) and non-dust fine-mode aerosol (Case II) in terms of the hygroscopic enhancement factor, f β ( R H , λ 532 ) , calculated for the same humidity range. The two types of aerosols were identified by applying the polarization lidar photometer networking method (POLIPHON). The hygroscopicity for non-dust aerosol was much higher than that for dust conditions with the f β ( R H , λ 532 ) being around 1.4 and 3.1, respectively, at the relative humidity of 86% for the two cases identified in this study. To study the effect of dust particles on the hygroscopicity of the overall atmospheric aerosol, the two types of aerosols were identified and separated by applying the polarization lidar photometer networking method in Case I. The hygroscopic enhancement factor of separated non-dust fine-mode particles in Case I had been significantly strengthened, getting closer to that of the total aerosol in Case II. These results were verified by the hygroscopicity parameter, κ (Case I non-dust particles: 0.357 ± 0.024; Case II total: 0.344 ± 0.026), based on the chemical components obtained by an aerosol chemical speciation instrument, both of which showed strong hygroscopicity. It was found that non-dust fine-mode aerosol contributes more during hygroscopic growth and that non-hygroscopic mineral dust aerosol may reduce the total hygroscopicity per unit volume in Beijing.


2017 ◽  
Vol 10 (3) ◽  
pp. 1269-1280 ◽  
Author(s):  
Sergey S. Vlasenko ◽  
Hang Su ◽  
Ulrich Pöschl ◽  
Meinrat O. Andreae ◽  
Eugene F. Mikhailov

Abstract. A tandem arrangement of Differential Mobility Analyser and Humidified Centrifugal Particle Mass Analyser (DMA-HCPMA) was developed to measure the deliquescence and efflorescence thresholds and the water uptake of submicron particles over the relative humidity (RH) range from 10 to 95 %. The hygroscopic growth curves obtained for ammonium sulfate and sodium chloride test aerosols are consistent with thermodynamic model predictions and literature data. The DMA-HCPMA system was applied to measure the hygroscopic properties of urban aerosol particles, and the kappa mass interaction model (KIM) was used to characterize and parameterize the concentration-dependent water uptake observed in the 50–95 % RH range. For DMA-selected 160 nm dry particles (modal mass of 3.5 fg), we obtained a volume-based hygroscopicity parameter, κv ≈  0.2, which is consistent with literature data for freshly emitted urban aerosols.Overall, our results show that the DMA-HCPMA system can be used to measure size-resolved mass growth factors of atmospheric aerosol particles upon hydration and dehydration up to 95 % RH. Direct measurements of particle mass avoid the typical complications associated with the commonly used mobility-diameter-based HTDMA technique (mainly due to poorly defined or unknown morphology and density).


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