scholarly journals Ultrasonic enhanced water washing method for extracting sodium fluoride from spent pot lining

2021 ◽  
Vol 2079 (1) ◽  
pp. 012004
Author(s):  
Yongrong Qi ◽  
Yuan Gong ◽  
Haibin Wang ◽  
Li Peng ◽  
Liting Fan ◽  
...  
Keyword(s):  
Low Cost ◽  
Ultrasonic Waves ◽  
Raw Material ◽  
Process Conditions ◽  
Ultrasonic Power ◽  
Water Washing ◽  
Washing Process ◽  
Leaching Solution ◽  
Washing Method ◽  
Leaching Efficiency

Abstract A large amount of spent pot lining (SPL) is produced by cryolite-alumina melting electrolysis process, and the fluoride content in the leaching solution is up to 6000 mg/L, which belongs to hazardous waste. If SPL is not handled effectively, it will cause great harm to the environment. Because the NaF rich in SPL is an important raw material for the synthesis of cryolite by carbonation, this paper uses SPL as the raw material to extract NaF. On the basis of exploring the process conditions of water washing leaching NaF, ultrasonic wave was introduced to enhance mass transfer and the effects of ultrasonic cavitation on water washing process was compared. The results show that ultrasonic waves can effectively shorten the time for water washing to reach equilibrium and further improve the efficiency of NaF leaching. Under the optimal process conditions determined by the experiment, when the ultrasonic power is 400 W, the time for washing to reach equilibrium is shortened from 50 min to 40 min, and the NaF leaching efficiency is increased from 67.25 % to 70.42 %. While improving the leaching efficiency, the water consumption is effectively reduced, and the purity of the recovered product NaF is 96.82 %. This research provides a technical reference for the harmless and low cost leaching of NaF from SPL in the aluminium electrolysis industry.

scholarly journals A Low Cost of Burning Raw Material For PO43−-P And F− Solidification/Stabilization In Phosphogypsum

2021 ◽  
Author(s):  
Li Bing ◽  
Shu Jiancheng ◽  
Chen Mengjun ◽  
Zeng Xiangfei ◽  
Liu Renlong
Keyword(s):  
Economic Evaluation ◽  
Low Cost ◽  
Weight Ratio ◽  
Treatment Method ◽  
Raw Material ◽  
Soluble Phosphate ◽  
Leaching Test ◽  
Liquid Ratio ◽  
The Sustainable Development ◽  
Leaching Solution

Abstract Phosphogypsum (PG) contains a lot of soluble phosphate (PO4 3−-P) and fluorine ion (F−), which seriously has hindered the sustainable development of phosphorous chemical industry. In this study, a new burning raw material (BRM) was used for the stabilize of PO43−-P and F− in PG. The characteristics of PG and BRM, stabilize mechanism of PO43−-P and F−, leaching test and economic evaluation were investigated. The effect of PG and BRM weight ratio, solid to liquid ratio, reaction time and reaction temperature on the concentrations of PO43−-P and F− were studied. The results showed that the concentration of F− in PG leaching solution was 8.65 mg/L and the removal efficiency of PO43−-P was 99.78 %, as well as the pH of PG leaching solution was 8.12, when the weight ratio of PG and BRM was 100:2, and the solid to liquid ratio was 4:1, reacting for 24 h at the temperature of 30 ℃. PO43−-P and F− were mostly solidified as Ca5(PO4)3F, CaPO3(OH), Ca5(PO4)3(OH), Ca2P2O7·2H2O, CaSO4PO3(OH)·4H2O, CaF2, and CaFPO3·2H2O. Leaching test results indicated that the concentrations of PO4 3−-P, F− and heavy metals were less than the integrated wastewater discharge standard (GB8978-1996). Economic evaluation revealed that the cost of PG treatment was $ 0.88/ton. This study provides a new low cost and harmless treatment method for PG.

scholarly journals Ultrasound-Assisted Extraction of Flavonoids from Kiwi Peel: Process Optimization and Bioactivity Assessment

2021 ◽  
Vol 11 (14) ◽  
pp. 6416
Author(s):  
Miguel Giordano ◽  
José Pinela ◽  
Maria Inês Dias ◽  
Ricardo C. Calhelha ◽  
Dejan Stojković ◽  
...  
Keyword(s):  
Phenolic Compounds ◽  
Low Cost ◽  
Vero Cells ◽  
Extraction Yield ◽  
Raw Material ◽  
Ultrasonic Power ◽  
Ultrasound Assisted Extraction ◽  
Food Preservatives ◽  
Assisted Extraction ◽  
Ultrasound Assisted

The nutritional quality of kiwifruit has been highlighted by several studies, while its peel is typically discarded as a by-product with no commercial value. This study was carried out to optimize the ultrasound-assisted extraction (UAE) of phenolic compounds from kiwi peel. Three independent variables (time (t), ultrasonic power (P) and ethanol concentration (EtOH)) were combined in a five-level central composite rotatable design coupled with the response surface methodology (RSM). The extraction yield determined gravimetrically and the content of phenolic compounds identified by HPLC-DAD-ESI/MSn (namely two quercetin glycosides, one catechin isomer and one B-type (epi)catechin dimer) were the experimental responses used in the optimization. The polynomial models were successfully fitted to the experimental data and used to determine the optimal UAE conditions. The sonication of the sample at 94.4 W for 14.8 min, using 68.4% ethanol, resulted in a maximum of 1.51 ± 0.04 mg of flavonoids per g of extract, a result that allowed the experimental validation of the predictive model. The kiwi peel extract obtained under optimized conditions showed somehow promising bioactive properties, including antioxidant and antimicrobial effects, and no toxicity to Vero cells. Overall, this study contributes to the valorization of kiwi peel as a low-cost raw material for the development of natural ingredients (such as food preservatives) and also to the resource-use efficiency and circular bioeconomy.

scholarly journals Utilization of Cumbeba (Tacinga inamoena) Residue: Drying Kinetics and Effect of Process Conditions on Antioxidant Bioactive Compounds

Foods ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 788
Author(s):  
João Paulo de Lima Ferreira ◽  
Alexandre José de Melo Queiroz ◽  
Rossana Maria Feitosa de Figueirêdo ◽  
Wilton Pereira da Silva ◽  
Josivanda Palmeira Gomes ◽  
...  
Keyword(s):  
Phenolic Compounds ◽  
Bioactive Compounds ◽  
Fixed Bed ◽  
Drying Kinetics ◽  
Raw Material ◽  
Process Conditions ◽  
Temperature Range ◽  
Water Diffusivity ◽  
Pharmaceutical Industries ◽  
Effective Water

The residue generated from the processing of Tacinga inamoena (cumbeba) fruit pulp represents a large amount of material that is discarded without proper application. Despite that, it is a raw material that is source of ascorbic acid, carotenoids and phenolic compounds, which are valued in nutraceutical diets for allegedly combating free radicals generated in metabolism. This research paper presents a study focused on the mathematical modeling of drying kinetics and the effect of the process on the level of bioactive of cumbeba residue. The experiments of cumbeba residue drying (untreated or whole residue (WR), crushed residue (CR) and residue in the form of foam (FR)) were carried out in a fixed-bed dryer at four air temperatures (50, 60, 70 and 80 °C). Effective water diffusivity (Deff) was determined by the inverse method and its dependence on temperature was described by an Arrhenius-type equation. It was observed that, regardless of the type of pretreatment, the increase in air temperature resulted in higher rate of water removal. The Midilli model showed better simulation of cumbeba residue drying kinetics than the other models tested within the experimental temperature range studied. Effective water diffusivity (Deff) ranged from 6.4890 to 11.1900 × 10−6 m2/s, 2.9285 to 12.754 × 10−9 m2/s and 1.5393 × 10−8 to 12.4270 × 10−6 m2/s with activation energy of 22.3078, 46.7115 and 58.0736 kJ/mol within the temperature range of 50–80 °C obtained for the whole cumbeba, crushed cumbeba and cumbeba residue in the form of foam, respectively. In relation to bioactive compounds, it was observed that for a fixed temperature the whole residue had higher retention of bioactive compounds, especially phenolic compounds, whereas the crushed residue and the residue in the form of foam had intermediate and lower levels, respectively. This study provides evidence that cumbeba residue in its whole form can be used for the recovery of natural antioxidant bioactive compounds, mainly phenolic compounds, with the possibility of application in the food and pharmaceutical industries.

Characterization and A Preliminary Study of TiO2 Synthesis from Lampung Iron Sand

2020 ◽  
Vol 849 ◽  
pp. 113-118
Author(s):  
Yayat Iman Supriyatna ◽  
Slamet Sumardi ◽  
Widi Astuti ◽  
Athessia N. Nainggolan ◽  
Ajeng W. Ismail ◽  
...  
Keyword(s):  
Food Packaging ◽  
Xrd Analysis ◽  
Major Elements ◽  
Raw Material ◽  
Solid Residue ◽  
X Ray Diffraction ◽  
X Ray ◽  
Leaching Solution ◽  
Ti Content

The purpose of this study is to characterize Lampung iron sand and to conduct preliminary experiments on the TiO2 synthesis which can be used for the manufacturing of functional food packaging. The iron sand from South Lampung Regency, Lampung Province that will be utilized as raw material. The experiment was initiated by sieving the iron sand on 80, 100, 150, 200 and 325 mesh sieves. Analysis using X-Ray Fluorescence (XRF) to determine the element content and X-Ray Diffraction (XRD) to observe the mineralization of the iron sand was conducted. The experiment was carried out through the stages of leaching, precipitation, and calcination. Roasting was applied firstly by putting the iron sand into the muffle furnace for 5 hours at a temperature of 700°C. Followed by leaching using HCl for 48 hours and heated at 105°C with a stirring speed of 300 rpm. The leaching solution was filtered with filtrate and solid residue as products. The solid residue was then leached using 10% H2O2 solution. The leached filtrate was heated at 105°C for 40 minutes resulting TiO2 precipitates (powder). Further, the powder was calcined and characterized. Characterization of raw material using XRF shows the major elements of Fe, Ti, Mg, Si, Al and Ca. The highest Ti content is found in mesh 200 with 9.6%, while iron content is about 80.7%. While from the XRD analysis, it shows five mineral types namely magnetite (Fe3O4), Rhodonite (Mn, Fe, Mg, Ca) SiO3, Quart (SiO2), Ilmenite (FeOTiO2) and Rutile (TiO2). The preliminary experiment showed that the Ti content in the synthesized TiO2 powder is 21.2%. The purity of TiO2 is low due to the presence of Fe metal which is dissolved during leaching, so that prior to precipitation purification is needed to remove impurities such as iron and other metals.

scholarly journals Removal of Cadmium(II) from Water using Modified Citrus limettioides Peels: Thermodynamic and Isotherm Studies

2019 ◽  
Vol 32 (1) ◽  
pp. 73-78
Author(s):  
P. Janaki ◽  
R. Sudha ◽  
T.S. Sribharathi ◽  
P. Anitha ◽  
K. Poornima ◽  
...  
Keyword(s):  
Adsorption Process ◽  
Low Cost ◽  
Raw Material ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Adsorption Method ◽  
Chemically Modified ◽  
Adsorption Performance ◽  
Monolayer Adsorption ◽  
Isotherm Equations

The adsorption performance of sulphuric acid treated low cost adsorbent synthesized by using Citrus limettioides peel as an effective raw material for the removal of cadmium(II) from water. The batch adsorption method was carried out to optimize some parameters like contact time, pH and adsorbent dose. The nonlinear isotherm equations were used to calculate the different isotherm constant of five isotherm models namely Freundlich, Langmuir, Dubinin-Radushkevich, Redlich-Peterson and Sips. The Langmuir monolayer adsorption capacity of chemically modified Citrus limettioides peel was found to be 287.60 mg g-1. The negative values of ΔGº and ΔHº showed that the adsorption process is spontaneous and exothermic.

Feasibility of cereal straw for industrial utilization in Minnesota

2000 ◽  
Vol 15 (1) ◽  
pp. 2-8 ◽  
Author(s):  
N.C. Wagner ◽  
S. Ramaswamy ◽  
U. Tschirner
Keyword(s):  
Animal Feed ◽  
Raw Materials ◽  
Low Cost ◽  
Economic Feasibility ◽  
Raw Material ◽  
Cereal Straw ◽  
Industrial Utilization ◽  
Industrial Use ◽  
On Farm ◽  
And Storage

AbstractA pre-economic feasibility study was undertaken to determine the potential of cereal straw for industrial utilization in Minnesota. Specifically, utilizing straw for pulp and paper manufacture was of interest. The availability of cereal straw fiber supplies at various locations across the state of Minnesota, along with pre-processing issues such as transportation, harvesting, handling, and storage, are discussed and priced. The greatest economic advantage of straw for industrial use appears to be the low cost of the raw material compared to traditional raw materials. This also provides an excellent opportunity for additional income for farmers. The methodology and information provided here should be helpful in evaluating the feasibility of utilizing straw for other industrial purposes in other parts of the world. However, in some Third World countries, long-standing on-farm, traditional uses of cereal straws for fuel, fiber, and animal feed may limit their availability for industrial utilization.

Advances in absorbents and techniques used in wet and dry FGD: a critical review

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lokesh Kumar ◽  
Susanta Kumar Jana
Keyword(s):  
Power Plants ◽  
Low Cost ◽  
Fine Particulate Matter ◽  
Packed Column ◽  
Toxic Substance ◽  
Cost Effective ◽  
Solid Wastes ◽  
Raw Material ◽  
Process Industries ◽  
Slurry Bubble Columns

Abstract Sulfur dioxide is considered as an extremely harmful and toxic substance among the air pollutants emitted from the lignite- and other high-sulfur-coal based power plants, old tires processing units, smelters, and many other process industries. Various types of absorbents and desulfurization technologies have been developed and adopted by the industries to reduce the emission rate of SO2 gas. The present paper focuses on the ongoing advances in the development of varieties of regenerative and non-regenerative absorbents viz., Ca-based, Mg-based, Fe-based, Na-based, N2-based, and others along with various FGD technology, viz., wet, dry or semi-dry processes. Additionally, different types of contactors viz., packed column, jet column, spray tower, and slurry bubble columns along with their significant operational and design features have also been discussed. In the existing or newly installed limestone-based FGD plants, an increasing trend of the utilization of newly developed technologies such as limestone forced oxidation (LSFO) and magnesium-enhanced lime (MEL) are being used at an increasing rate. However, the development of low-cost sorbents, particularly suitable solid wastes, for the abatement of SO2 emission needs to be explored sincerely. Many such wastes cause air pollution by way of entrainment of fine particulate matter (PM), groundwater contamination by its leaching, or brings damage to crops due to its spreading onto the cultivation land. One such pollutant is marble waste and in this work, this has been suggested as a suitable substitute to limestone and cost-effective sorbent for the desulfurization of flue gases. The product of this process being sellable in the market or may be used as a raw material in several industries, it can also prove to be an important route of recycling and reuse of one of the air and water-polluting solid wastes.

Optimizing Water Washing Process for Sunflower Heads before Pectin Extraction

1996 ◽  
Vol 61 (3) ◽  
pp. 608-612 ◽  
Author(s):  
X.Q. SHI ◽  
K.C. CHANG ◽  
J.G. SCHWARZ ◽  
D. WIESENBORN ◽  
M.C. SHIH
Keyword(s):  
Water Washing ◽  
Washing Process

scholarly journals Analysis of Drying of Brewers’ Spent Grain

Proceedings ◽  
2018 ◽  
Vol 2 (23) ◽  
pp. 1467 ◽  
Author(s):  
José Ignacio Arranz ◽  
María Teresa Miranda ◽  
Francisco José Sepúlveda ◽  
Irene Montero ◽  
Carmen Victoria Rojas
Keyword(s):  
Energy Use ◽  
Low Cost ◽  
Matter Content ◽  
Raw Material ◽  
Dry Matter Content ◽  
Brewing Industry ◽  
Livestock Feed ◽  
Spent Grain ◽  
Very High ◽  
Animal Consumption

Brewing industry generates a main residue, brewers’ spent grain (BSG), which has good properties both for use in animal consumption and for thermal use, but contains a very high content of moisture (20–25% dry matter content), so that its elimination or treatment should be immediate, since it can cause degeneration problems of the product. Currently, brewers often supply this material at low cost for use as livestock feed. This solution is not efficiently carried out without reporting too much benefit to the brewers more than to eliminate waste from their facilities. However, BSG is a raw material of interest for application in different areas due to its low price, availability throughout the year and a valuable chemical composition, so it seems necessary to look for an alternative use to give value to these characteristics. In this paper a drying study is carried out in order to establish the foundations for its energy use by thermal of BSG. BSG has been used from a craft brewery located at Badajoz, Spain. Drying analysis was carried out for various temperatures and inlet air flow by means a convective dryer. The properties studied show that BSG can be used for thermal utilization in large installations, being necessary heat drying processes as a pretreatment in order to obtain a biofuel with acceptable efficiency.

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