The effect of clam shell powder on kinetics of water absorption of jute epoxy composite

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Hemalata Jena ◽  
Abinash Panigrahi

Purpose Here, attempts have been made to explore the possible use of Marine waste as filler materials into the bio-fibre composites. Clam shell is a type of marine waste which belongs to the class of Bivalvia. It is mainly made of aragonite crystalline polymorphs. This paper aims to develop a new class of natural fibre composite in which jute fibre as reinforcement, epoxy as matrix and clam shell, as particulate microsphere filler. The study investigates the effects of different amounts of clam shell powder on the kinetics of water absorption of jute fibre-reinforced epoxy composite. Two different environmental conditions at room temperature, i.e. distilled water and seawater, are collected for this purpose. Moisture absorption reduces when clam shell is added to the jute-epoxy composite. The curve of water absorption of jute-epoxy composites with filler loading at both environmental conditions follows as Fickian behaviour. Design/methodology/approach Hand lay-up technique to fabricate the composite – Experimental observation Findings The incorporation of Clam shell filler in jute epoxy composite modified the water absorption property of the composite. Hence the present marine waste is an potential filler in jute fibre reinforced polymer composite. Originality/value The paper demonstrates a new class hybrid composite material which uses a marine waste as important phase in the bio-fibre-reinforced composite. It is a new work submitted for original research paper.

2020 ◽  
pp. 152808372097442
Author(s):  
Parul Sahu ◽  
MK Gupta

Recently, researchers and scientists are trying to overcome the environmental burden by using biocomposites in engineering applications as far as possible. The main source of biocomposites is cellulosic fibres which is a class of natural fibres. Instead of many advantages of cellulosic fibres, they and their polymer composites suffer from some limitations as well. The environmental conditions are one of the most important issues to degradation behavior of the cellulosic fibres polymer composites (CFPCs). Among the environmental conditions, water absorption is an important ground to degradation in the mechanical performance of the CFPCs, which resists them to be used in outdoor applications. Several studies have been presented on water absorption characteristics of cellulosic fibres and its polymer-based biocomposites. Further, the consequence of water uptake on the mechanical performance of biocomposites was also reported in many studies. In most of the cases, a negative effect of water absorption was observed, whereas in a few cases a positive effect was also seen. In the present study, mechanics and kinetics of water absorption for CFPCs are discussed. Further, a detailed literature review on water absorption of cellulosic fibres and their different types of polymer-based biocomposites has also been carried out. Furthermore, studies reported on the effect of water absorption on the mechanical properties were also systematically presented. Moreover, all the possible remedies to lower the water absorption capacity were also discussed in the present review paper.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Shailendra Singh Chauhan ◽  
Vaibhav Singh ◽  
Gauranshu Saini ◽  
Nitin Kaushik ◽  
Vishal Pandey ◽  
...  

Purpose The growing environmental awareness all through the world has motivated a standard change toward planning and designing better materials having good performance, which are very much suited to the environmental factors. The purpose of this study is to investigate the impact on mechanical, thermal and water absorption properties of sawdust-based composites reinforced by epoxy, and the amount of sawdust in each form. Design/methodology/approach Manufacturing of the sawdust reinforced epoxy composites is the main area of the research for promoting the green composite by having good mechanical properties, biodegradability or many applications. Throughout this research work, the authors emphasize the importance of explaining the methodology for the evaluation of the mechanical and water absorption properties of the sawdust reinforced epoxy composites used by researchers. Findings In this paper, a comprehensive review of the mechanical properties of sawdust reinforced epoxy composite is presented. This study is reported about the use of different Wt.% of sawdust composites prepared by different processes and their mechanical, thermal and water absorption properties. It is studied that after optimum filler percentage, mechanical, thermal properties gradually decrease, but water absorption property increases with Wt.% of sawdust. The changes in the microstructure are studied by using scanning electron microscopy. Originality/value The novelty of this study lies in its use of a systematic approach that offers a perspective on choosing suitable processing parameters for the fabrication of composite materials for persons from both industry and academia. A study of sawdust reinforced epoxy composites guides new researchers in the fabrication and characterization of the materials.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Joan Carlos Alves Pereira ◽  
Wilton Pereira da Silva ◽  
Renato Costa da Silva ◽  
Cleide Maria Diniz P.S. e Silva ◽  
Josivanda Palmeira Gomes

PurposeTo describe water absorption by the rice grains over time, diffusion and empirical models were used. Also, an optimization software was developed in this study to determine parameters and their uncertainties for the diffusion models (LS Optimizer, for partial differential equations). Parameters (and their uncertainties) for empirical models were determined by LAB Fit Curve Fitting Software.Design/methodology/approachHeat and mass diffusion phenomena are found in various processes of technological interest, including pasteurization, drying and water immersion of agricultural products, among others. The objective of this work was to study the process of water absorption by rice grains with and without husk, using diffusion and empirical models to describe the absorption kinetics. Rice grains were immersed (approximately 10 g for each experiment) in drinking water maintained at constant temperatures of 28, 40 and 50 C. In the experiments, the water contents absorbed by rice grains over time were obtained by the gravimetric method.FindingsAmong empirical models, Peleg was the most satisfactory to describe the kinetics of water absorption by rice without husk, while the Silva et alii model had the best statistical indicators for rice with husk. It was also verified that a diffusion model with boundary condition of the first kind showed the best (or equivalent) results in the description of all processes of kinetics of water absorption by rice grains, with and without husk. For grains without husk, the effective mass diffusivities were (1.186 ± 0.045) × 10−9, (1.312 ± 0.024) × 10−9 and (2.133 ± 0.028) × 10−9 m2 min−1, for the immersion temperatures of 28, 40 and 50C, respectively. For grains with husk, diffusivities were (0.675 ± 0.011) × 10−9 and (1.269 ± 0.017) × 10−9 m2 min−1, for temperatures of 28 and 50 C, respectively.Originality/valueThis work developed a solver for the diffusion equation in cylindrical geometry and presented the LS Optimizer software developed to determine differential equation parameters through experimental data sets.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ajibola B. Oyedeji ◽  
Olajide P. Sobukola ◽  
Ezekiel Green ◽  
Oluwafemi A. Adebo

AbstractThe physical properties and water absorption kinetics of three varieties of Mucuna beans (Mucuna pruriens, Mucuna rajada and Mucuna veracruz) were determined in this study. Physical properties including length, width, thickness, geometric mean diameter, sphericity, porosity, bulk density, area, volume and one thousand seed mass were calculated while hydration kinetics was studied by soaking Mucuna beans in water at 30 °C, 40 °C and 50 °C and measuring water uptake at 9 h interval. Peleg’s equation was used to model the hydration characteristics and Arrhenius equation was used to describe the effect of temperature on Peleg’s rate constant k1 and to obtain the activation energies for soaking. Significant variations were observed in almost all the physical properties of the different varieties, however, there were no significant differences (p < 0.05) in their thicknesses and bulk densities. The effectiveness of fit of Peleg’s model (R2) increased with increase in soaking temperature. Peleg’s rate constant k1 decreased with increase in soaking temperature while k2 increased with temperature increase. Activation energies of Mucuna pruriens, Mucuna rajada and Mucuna veracruz were 1613.24 kJ/mol, 747.95 kJ/mol and 2743.64 kJ/mol, respectively. This study provides useful information about the properties of three varieties of Mucuna beans that could be of importance to processors and engineers for process design and optimization.


2011 ◽  
Vol 55 (9) ◽  
pp. 4211-4217 ◽  
Author(s):  
J. Pannu ◽  
A. McCarthy ◽  
A. Martin ◽  
T. Hamouda ◽  
S. Ciotti ◽  
...  

ABSTRACTNB-003 and NB-003 gel formulations are oil-in-water nanoemulsions designed for use in bacterial infections.In vitrosusceptibility ofPropionibacterium acnesto NB-003 formulations and comparator drugs was evaluated. Both NB-003 formulations were bactericidal against allP. acnesisolates, including those that were erythromycin, clindamycin, and/or tetracycline resistant. In the absence of sebum, the MIC90s/minimum bactericidal concentrations (MBC90s) for NB-003, NB-003 gel, salicylic acid (SA), and benzoyl peroxide (BPO) were 0.5/2.0, 1.0/2.0, 1,000/2,000, and 50/200 μg/ml, respectively. In the presence of 50% sebum, the MIC90s/MBC90s of NB003 and BPOs increased to 128/1,024 and 400/1,600 μg/ml, respectively. The MIC90s/MBC90s of SA were not significantly impacted by the presence of sebum. A reduction in the MBC90s for NB-003 and BPO was observed when 2% SA or 0.5% BPO was integrated into the formulation, resulting in MIC90s/MBC90s of 128/256 μg/ml for NB003 and 214/428 μg/ml for BPO. The addition of EDTA enhanced thein vitroefficacy of 0.5% NB-003 in the presence or absence of 25% sebum. The addition of 5 mM EDTA to each well of the microtiter plate resulted in a >16- and >256-fold decrease in MIC90and MBC90, yielding a more potent MIC90/MBC90of ≤1/<1 μg/ml. The kinetics of bactericidal activity of NB-003 againstP. acneswere compared to those of a commercially available product of BPO. Electron micrographs ofP. acnestreated with NB-003 showed complete disruption of bacteria. Assessment of spontaneous resistance ofP. acnesrevealed no stably resistant mutant strains.


2015 ◽  
Vol 17 (16) ◽  
pp. 10953-10962 ◽  
Author(s):  
Chengyue Lai ◽  
Yongchun Liu ◽  
Jinzhu Ma ◽  
Qingxin Ma ◽  
Hong He

The degradation kinetics of dehydroabietic acid by OH radicals were investigated under various environmental conditions.


2021 ◽  
Vol 302 ◽  
pp. 124156
Author(s):  
Kun Liang ◽  
Yingjie Hou ◽  
Jianchun Sun ◽  
Xiaoguang Li ◽  
Jiahong Bai ◽  
...  

2014 ◽  
Vol 58 (9) ◽  
pp. 5297-5305 ◽  
Author(s):  
Tiffany R. Keepers ◽  
Marcela Gomez ◽  
Chris Celeri ◽  
Wright W. Nichols ◽  
Kevin M. Krause

ABSTRACTAvibactam, a non-β-lactam β-lactamase inhibitor with activity against extended-spectrum β-lactamases (ESBLs), KPC, AmpC, and some OXA enzymes, extends the antibacterial activity of ceftazidime against most ceftazidime-resistant organisms producing these enzymes. In this study, the bactericidal activity of ceftazidime-avibactam against 18Pseudomonas aeruginosaisolates and 15Enterobacteriaceaeisolates, including wild-type isolates and ESBL, KPC, and/or AmpC producers, was evaluated. Ceftazidime-avibactam MICs (0.016 to 32 μg/ml) were lower than those for ceftazidime alone (0.06 to ≥256 μg/ml) against all isolates except for 2P. aeruginosaisolates (1blaVIM-positive isolate and 1blaOXA-23-positive isolate). The minimum bactericidal concentration/MIC ratios of ceftazidime-avibactam were ≤4 for all isolates, indicating bactericidal activity. Human serum and human serum albumin had a minimal effect on ceftazidime-avibactam MICs. Ceftazidime-avibactam time-kill kinetics were evaluated at low MIC multiples and showed time-dependent reductions in the number of CFU/ml from 0 to 6 h for all strains tested. A ≥3-log10decrease in the number of CFU/ml was observed at 6 h for allEnterobacteriaceae, and a 2-log10reduction in the number of CFU/ml was observed at 6 h for 3 of the 6P. aeruginosaisolates. Regrowth was noted at 24 h for some of the isolates tested in time-kill assays. These data demonstrate the potent bactericidal activity of ceftazidime-avibactam and support the continued clinical development of ceftazidime-avibactam as a new treatment option for infections caused byEnterobacteriaceaeandP. aeruginosa, including isolates resistant to ceftazidime by mechanisms dependent on avibactam-sensitive β-lactamases.


Author(s):  
N Carrere ◽  
N Tual ◽  
T Bonnemains ◽  
E Lolive ◽  
P Davies

In this study, a damage model that accounts for the effect of seawater ageing is proposed. The model is based on a failure criterion that takes into account the effect of the ply thickness, while the kinetics of the damage development are based on a Finite Fracture Mechanics approach. The stiffness degradation is identified by a multiscale approach. The parameters of the model are physically based which facilitates the identification and the coupling with the ageing. These and their evolution as a function of the time of immersion in seawater have been identified for a carbon/epoxy composite. The changes in crack density as a function of the applied load for three ageing times are quite well predicted by the model. The model explains why the damage threshold is strongly influenced by the ageing while the kinetics of the crack propagation remain quasi-constant.


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