Metal Line Interconnects Produced by Means of Printable Copper Precursor Solutions

2006 ◽  
Author(s):  
Manish Tiwari ◽  
Constantine Megaridis ◽  
Prodyut Majumder ◽  
Christos Takoudis ◽  
John Belot ◽  
...  

Patterned metal films are essential to a wide range of applications, from printed circuits and thin film displays in large area electronics, to electrodes in biomedical implants. Current fabrication techniques are usually photolithographic, and rely on either patterning a blanket metal film or patterning a planar substrate into which the metal is deposited, followed by polishing away excess metal (the "Damascene" process). However, photolithographic techniques are expensive and more suitable for relatively small substrates. Conventional printing techniques such as inkjet, flexographic, offset and screen printing for both printable metal films and emergent organic elements, have lower resolution, but offer advantages of flexibility, overall cost savings, scalability to large substrates or those with complex topologies. In addition, these methods have environmental benefits [1].

Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2931
Author(s):  
Soumya Banerjee ◽  
Ek Adhikari ◽  
Pitambar Sapkota ◽  
Amal Sebastian ◽  
Sylwia Ptasinska

Atmospheric pressure plasma (APP) deposition techniques are useful today because of their simplicity and their time and cost savings, particularly for growth of oxide films. Among the oxide materials, titanium dioxide (TiO2) has a wide range of applications in electronics, solar cells, and photocatalysis, which has made it an extremely popular research topic for decades. Here, we provide an overview of non-thermal APP deposition techniques for TiO2 thin film, some historical background, and some very recent findings and developments. First, we define non-thermal plasma, and then we describe the advantages of APP deposition. In addition, we explain the importance of TiO2 and then describe briefly the three deposition techniques used to date. We also compare the structural, electronic, and optical properties of TiO2 films deposited by different APP methods. Lastly, we examine the status of current research related to the effects of such deposition parameters as plasma power, feed gas, bias voltage, gas flow rate, and substrate temperature on the deposition rate, crystal phase, and other film properties. The examples given cover the most common APP deposition techniques for TiO2 growth to understand their advantages for specific applications. In addition, we discuss the important challenges that APP deposition is facing in this rapidly growing field.


Author(s):  
Allan Matthews ◽  
Adrian Leyland

Over the past twenty years or so, there have been major steps forward both in the understanding of tribological mechanisms and in the development of new coating and treatment techniques to better “engineer” surfaces to achieve reductions in wear and friction. Particularly in the coatings tribology field, improved techniques and theories which enable us to study and understand the mechanisms occurring at the “nano”, “micro” and “macro” scale have allowed considerable progress to be made in (for example) understanding contact mechanisms and the influence of “third bodies” [1–5]. Over the same period, we have seen the emergence of the discipline which we now call “Surface Engineering”, by which, ideally, a bulk material (the ‘substrate’) and a coating are combined in a way that provides a cost-effective performance enhancement of which neither would be capable without the presence of the other. It is probably fair to say that the emergence and recognition of Surface Engineering as a field in its own right has been driven largely by the availability of “plasma”-based coating and treatment processes, which can provide surface properties which were previously unachievable. In particular, plasma-assisted (PA) physical vapour deposition (PVD) techniques, allowing wear-resistant ceramic thin films such as titanium nitride (TiN) to be deposited on a wide range of industrial tooling, gave a step-change in industrial productivity and manufactured product quality, and caught the attention of engineers due to the remarkable cost savings and performance improvements obtained. Subsequently, so-called 2nd- and 3rd-generation ceramic coatings (with multilayered or nanocomposite structures) have recently been developed [6–9], to further extend tool performance — the objective typically being to increase coating hardness further, or extend hardness capabilities to higher temperatures.


1990 ◽  
Vol 43 (5) ◽  
pp. 583
Author(s):  
GL Price

Recent developments in the growth of semiconductor thin films are reviewed. The emphasis is on growth by molecular beam epitaxy (MBE). Results obtained by reflection high energy electron diffraction (RHEED) are employed to describe the different kinds of growth processes and the types of materials which can be constructed. MBE is routinely capable of heterostructure growth to atomic precision with a wide range of materials including III-V, IV, II-VI semiconductors, metals, ceramics such as high Tc materials and organics. As the growth proceeds in ultra high vacuum, MBE can take advantage of surface science techniques such as Auger, RHEED and SIMS. RHEED is the essential in-situ probe since the final crystal quality is strongly dependent on the surface reconstruction during growth. RHEED can also be used to calibrate the growth rate, monitor growth kinetics, and distinguish between various growth modes. A major new area is lattice mismatched growth where attempts are being made to construct heterostructures between materials of different lattice constants such as GaAs on Si. Also described are the new techniques of migration enhanced epitaxy and tilted superlattice growth. Finally some comments are given On the means of preparing large area, thin samples for analysis by other techniques from MBE grown films using capping, etching and liftoff.


Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4222
Author(s):  
Kemi Adeyeye ◽  
John Gallagher ◽  
Aonghus McNabola ◽  
Helena M. Ramos ◽  
Paul Coughlan

Most renewable energy (RE) studies focus on technology readiness, environmental benefits and/or cost savings. The market permeation, viability and adoption of RE technologies such as micro hydropower (MHP), however, require the alignment of other interrelated factors, such as the socio-technical, institutional and political dimensions. This is particularly the case where the energy recovery potential in decentralised water networks is being explored as part of a wholesome sustainability strategy by and for individual and communal prosumers. This study employs a socio-technical approach to understand factors that influence the perceived viability and adoption of MHP in group water-energy schemes. Methods included a progressive literature review to formulate a conceptual framework for the implementation of MHP systems. The framework was validated using survey data from representative stakeholders from groups schemes in Ireland and Spain. These stakeholders were sampled and surveyed at the stage of considering the adoption of MHP in their water networks. The findings highlight the push–pull factors and discusses the opportunities and barriers to the adoption of MHP systems. It confirms that the market, institutional and policy context, cost and financial benefits, social support and collaborative services combine to influence the adoption of MHP technology. Thus, a framework for evaluating the socio-technical viability of MHP systems based on these more realistic integrated, multi-dimensional criteria is proposed.


2011 ◽  
Vol 368-373 ◽  
pp. 3628-3631
Author(s):  
Jun Liu ◽  
Wei Xian Zhang

Along with the development of society and the popularity of private cars, more and more parking lots are to be needed. Consequently, large sized parking lots will be built in many cities. But the traditional parking lots were paved by a large area of concrete. So much concrete will be bound to create heat pollution. Meanwhile, a large area of parking lot occupies mass openspace. The existing parking lots lead to a waste of resources. This paper introduces a new term of saving parking lot and presents some key principles that stem from a wide range of contributions. The newfashioned parking lot may also give rise to the sustainable development.


Breathe ◽  
2016 ◽  
Vol 12 (2) ◽  
pp. 113-119 ◽  
Author(s):  
Phyllis Murphie ◽  
Nick Hex ◽  
Jo Setters ◽  
Stuart Little

“Non-delivery” home oxygen technologies that allow self-filling of ambulatory oxygen cylinders are emerging. They can offer a relatively unlimited supply of ambulatory oxygen in suitably assessed people who require long-term oxygen therapy (LTOT), providing they can use these systems safely and effectively. This allows users to be self-sufficient and facilitates longer periods of time away from home. The evolution and evidence base of this technology is reported with the experience of a national service review in Scotland (UK). Given that domiciliary oxygen services represent a significant cost to healthcare providers globally, these systems offer potential cost savings, are appealing to remote and rural regions due to the avoidance of cylinder delivery and have additional lower environmental impact due to reduced fossil fuel consumption and subsequently reduced carbon emissions. Evidence is emerging that self-fill/non-delivery oxygen systems can meet the ambulatory oxygen needs of many patients using LTOT and can have a positive impact on quality of life, increase time spent away from home and offer significant financial savings to healthcare providers.Educational aimsProvide update for oxygen prescribers on options for home oxygen provision.Provide update on the evidence base for available self-fill oxygen technologies.Provide and update for healthcare commissioners on the potential cost-effective and environmental benefits of increased utilisation of self-fill oxygen systems.


2008 ◽  
Vol 1087 ◽  
Author(s):  
Marco Palumbo ◽  
Simon J. Henley ◽  
Thierry Lutz ◽  
Vlad Stolojan ◽  
David Cox ◽  
...  

AbstractRecent results in the use of Zinc Oxide (ZnO) nano/submicron crystals in fields as diverse as sensors, UV lasers, solar cells, piezoelectric nanogenerators and light emitting devices have reinvigorated the interest of the scientific community in this material. To fully exploit the wide range of properties offered by ZnO, a good understanding of the crystal growth mechanism and related defects chemistry is necessary. However, a full picture of the interrelation between defects, processing and properties has not yet been completed, especially for the ZnO nanostructures that are now being synthesized. Furthermore, achieving good control in the shape of the crystal is also a very desirable feature based on the strong correlation there is between shape and properties in nanoscale materials. In this paper, the synthesis of ZnO nanostructures via two alternative aqueous solution methods - sonochemical and hydrothermal - will be presented, together with the influence that the addition of citric anions or variations in the concentration of the initial reactants have on the ZnO crystals shape. Foreseen applications might be in the field of sensors, transparent conductors and large area electronics possibly via ink-jet printing techniques or self-assembly methods.


2014 ◽  
Vol 747 ◽  
pp. 119-140 ◽  
Author(s):  
E. Vandre ◽  
M. S. Carvalho ◽  
S. Kumar

AbstractCharacteristic substrate speeds and meniscus shapes associated with the onset of air entrainment are studied during dynamic wetting failure along a planar substrate. Using high-speed video, the behaviour of the dynamic contact line (DCL) is recorded as a tape substrate is drawn through a bath of a glycerol/water solution. Air entrainment is identified by triangular air films that elongate from the DCL above some critical substrate speed. Meniscus confinement within a narrow gap between the substrate and a stationary plate is shown to delay air entrainment to higher speeds for a wide range of liquid viscosities, expanding upon the findings of Vandre, Carvalho & Kumar (J. Fluid Mech., vol. 707, 2012, pp. 496–520). A pressurized liquid reservoir controls the meniscus position within the confinement gap. It is found that liquid pressurization further postpones air entrainment when the meniscus is located near a sharp corner along the stationary plate. Meniscus shapes recorded near the DCL demonstrate that operating conditions influence the size of entrained air films, with smaller films appearing in the more viscous solutions. Regardless of size, air films become unstable to thickness perturbations and ultimately rupture, leading to the entrainment of air bubbles. Recorded critical speeds and air-film sizes compare well to predictions from a hydrodynamic model for dynamic wetting failure, suggesting that strong air stresses near the DCL trigger the onset of air entrainment.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Osama Bedair

PurposeThis paper presents a novel concept for design of concrete support system for chemical reactors used in refineries and petrochemical plants. Graphical method is described that can be used to size the concrete base and piling system. Recommendations are also provided to optimize the parameters required for the design. The procedure is illustrated for design of two reactor models commonly used in gas recovery units.Design/methodology/approachDesign space representation for the foundation system is described for chemical reactors with variable heights. The key points of the design graph are extracted from the numerical finite element models. The reactor load is idealized at discrete points to transfer the loads to the piles. Bilateral spring system is used to model the soil restrains.FindingsThe graphical approach is economical and provides the design engineer the flexibility to select the foundation parameters from wide range of options.Practical implicationsThe concept presented in the paper can be utilized by engineers in the industry for design of chemical reactors. It must be noted that little guidelines are currently available in practice addressing the structural design aspects.Originality/valueA novel concept is presented in this paper based on significant industrial design experience of reactor supports. Using the described method leads to significant cost savings in material quantity and engineering time.


2021 ◽  
Vol 3 (44) ◽  
pp. 111-115
Author(s):  
Tat’yana R. Gallyamova ◽  

When developing modern lighting technologies for objects of the agro-industrial complex, the problem arises of assessing the contribution of reflected light to the normalized illumination. The reflective properties of the surfaces of materials are characterized by a reflection coefficient ρ, which reaches a value of 0.7. This allows us to consider the reflective surfaces as an additional light source and the possibility of reducing energy consumption costs. (Research purpose) The research purpose is in developing a mathematical model that allows us to estimate the spectral reflection coefficient ρ(λ) of materials of construction technologies of the agro-industrial complex in the ultraviolet and visible spectral regions. (Materials and methods) That the disadvantage of various models is the lack of an analytical method for calculating the reflection coefficient in a wide range of wavelengths. We used a probabilistic method to overcome this disadvantage. (Results and discussion) The developed mathematical model makes it possible to estimate the reflection coefficient of the rough surface of materials in a wide range of the spectrum. For concrete, the area of agreement between theory and experiment is in the wavelength range from 250 to 1000 nm. The saturation mode predicted by the theory (the independence of the reflection coefficient from the wavelength) at a reflection coefficient of 0.4 is consistent with the experimental values in the visible range of the spectrum for construction materials of the agro-industrial complex, in particular, gray textured concrete, gray facade paint, light wood, gray silicate brick, new plaster without whitewash. (Conclusions) In the case of normal light incidence, the developed mathematical model allows us to theoretically estimate the reflection coefficient of the rough surfaces of construction technologies of the agro-industrial complex. The proposed model can be used in the development and design of a system of technological lighting of large-area premises (for example, when keeping birds on the floor), as well as for developing recommendations for reducing the energy consumption of existing lighting systems.


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