THE ACTION OF CARBON DISULPHIDE ON ALUMINA GEL

1933 ◽  
Vol 9 (5) ◽  
pp. 424-431 ◽  
Author(s):  
L. A. Munro ◽  
J. W. McCubbin
Keyword(s):  
Room Temperature ◽  
Carbon Disulphide ◽  
Residual Water ◽  
Reaction Products ◽  
Yellow Color ◽  
Alumina Gel ◽  
Yellow Coloration ◽  
Higher Temperature ◽  
Carbonyl Sulphide ◽  
By Products

The authors have investigated the yellow color observed when carbon disulphide was adsorbed by c.p. alumina at room temperature. The color is due to by-products of the reactions of carbon disulphide with residual water in the gel. The investigators of the CS2 + H2O reaction at higher temperature attribute the yellow to sulphur or aluminium sulphide. The color formed at room temperature is not due to either of these. The reaction products consist largely of hydrogen sulphide, water, and carbon dioxide, with small amounts of carbonyl sulphide and carbon monoxide. The yellow coloration has been found to be a mixture of sodium sulphide, sodium hydrosulphide, and sodium polysulphide. A mechanism is proposed for its formation.

On the Chemistry of Tetrabenzyl Thiuram Disulfide and Tetramethyl Thiuram Disulfide with Bis (Triethoxysilylpropyl) Tetrasulfide in Silica Compounds

2003 ◽  
Vol 76 (4) ◽  
pp. 876-891 ◽  
Author(s):  
R. N. Datta ◽  
A. G. Talma ◽  
S. Datta ◽  
P. G. J. Nieuwenhuis ◽  
W. J. Nijenhuis ◽  
...  
Keyword(s):  
High Performance ◽  
Room Temperature ◽  
Succinic Anhydride ◽  
Dynamic Properties ◽  
The Other ◽  
Resonance Spectroscopy ◽  
Reaction Products ◽  
Negative Effect ◽  
Higher Temperature ◽  
Analytical Tools

Abstract The use of thiurams such as Tetramethyl thiuram disulfide (TMTD) or Tetrabenzyl thiuram disulfide (TBzTD) has been explored to achieve higher cure efficiency. The studies suggest that a clear difference exists between the effect of TMTD versus TBzTD. TMTD reacts with Bis (triethoxysilylpropyl) tetrasulfide (TESPT) and this reaction can take place even at room temperature. On the other hand, the reaction of TBzTD with TESPT is slow and takes place only at higher temperature. High Performance Liquid Chromatography (HPLC) with mass (MS) detection, Nuclear Magnetic Resonance Spectroscopy (NMR) and other analytical tools have been used to understand the differences between the reaction of TMTD and TESPT versus TBzTD and TESPT. The reaction products originating from these reactions are also identified. These studies indicate that unlike TMTD, TBzTD improves the cure efficiency allowing faster cure without significant effect on processing characteristics as well as dynamic properties. The loading of TESPT is reduced in a typical Green tire compound and the negative effect on viscosity is repaired by addition of anhydrides, such as succinic anhydride, maleic anhydride, etc.

PYROLYSIS OF ETHYL MERCAPTAN

1955 ◽  
Vol 33 (8) ◽  
pp. 1281-1285 ◽  
Author(s):  
Jean L. Boivin ◽  
Roderick MacDonald
Keyword(s):  
Hydrogen Sulphide ◽  
Carbon Disulphide ◽  
Optimum Temperature ◽  
Mass Spectral Analysis ◽  
Mass Spectral ◽  
Ethyl Mercaptan ◽  
Catalyst Metal ◽  
Free Sulphur ◽  
Carbonyl Sulphide ◽  
By Products

The decomposition of ethyl mercaptan to ethylene and hydrogen sulphide was studied at various temperatures, with and without a catalyst. Metal sulphides (copper, nickel, and cadmium) proved to be the most efficient catalysts for cracking ethyl mercaptan into unsaturated end products, the optimum temperature being 500–600 °C. When no catalyst was used a 40–50% yield of ethylene and a nearly quantitative conversion to hydrogen sulphide was observed between 600 and 700 °C. Other products identified in the exit gas were carbon disulphide, carbonyl sulphide, methane, hydrogen, ethane, thiophene, diethyl sulphide, and free sulphur. Identification of these products was aided by infrared and mass spectral analysis of the gas. A tentative mechanism for the reaction justifying the presence of the above by-products is outlined.

Kinetics of carbon monoxide methanation on a Ni/SiO2 catalyst

1990 ◽  
Vol 55 (7) ◽  
pp. 1678-1685
Author(s):  
Vladimír Stuchlý ◽  
Karel Klusáček
Keyword(s):  
Carbon Monoxide ◽  
Reaction Rate ◽  
Catalyst Activity ◽  
Adsorbed Hydrogen ◽  
Reaction Products ◽  
Co Methanation ◽  
Molar Ratios ◽  
Rate Determining Step ◽  
Higher Temperature ◽  
Kinetics Of

Kinetics of CO methanation on a commercial Ni/SiO2 catalyst was evaluated at atmospheric pressure, between 528 and 550 K and for hydrogen to carbon monoxide molar ratios ranging from 3 : 1 to 200 : 1. The effect of reaction products on the reaction rate was also examined. Below 550 K, only methane was selectively formed. Above this temperature, the formation of carbon dioxide was also observed. The experimental data could be described by two modified Langmuir-Hinshelwood kinetic models, based on hydrogenation of surface CO by molecularly or by dissociatively adsorbed hydrogen in the rate-determining step. Water reversibly lowered catalyst activity and its effect was more pronounced at higher temperature.

Thermal Resistance of Fly Ash Geopolymers with Alumina as Additive

2018 ◽  
Vol 281 ◽  
pp. 182-188
Author(s):  
Yong Sing Ng ◽  
Yun Ming Liew ◽  
Cheng Yong Heah ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Kamarudin Hussin
Keyword(s):  
Elevated Temperature ◽  
Fly Ash ◽  
Thermal Resistance ◽  
Sodium Hydroxide ◽  
Sodium Silicate ◽  
Room Temperature ◽  
Strength Degradation ◽  
Alumina Addition ◽  
Higher Temperature ◽  
Temperature Exposure

The present work investigates the effect of alumina addition on the thermal resistance of fly ash geopolymers. Fly ash geopolymers were synthesised by mixing fly ash with activator solution (A mixture of 12M sodium hydroxide and sodium silicate) at fly ash/activator ratio of 2.5 and sodium silicate/sodium hydroxide ratio of 2.5. The alumina (0, 2 and 4 wt %) was added as an additive. The geopolymers were cured at room temperature for 24 hours and 60°C for another 24 hours. After 28 days, the geopolymers was heated to elevated temperature (200 - 1000°C). For unexposed geopolymers, the addition of 2 wt % of alumina increased the compressive strength of fly ash geopolymers while the strength decreased when the content increased to 4 wt.%. The temperature-exposed geopolymers showed enhancement of strength at 200°C regardless of the alumina content. The strength reduced at higher temperature exposure (> 200°C). Despite the strength degradation at elevated temperature, the strength attained was relatively high in the range of 13 - 45 MPa up to 1000°C which adequately for application as structural materials.

Newly Developed Heat Resistant Magnesium Alloy by Thixomolding®

2005 ◽  
Vol 488-489 ◽  
pp. 287-290 ◽  
Author(s):  
Tadayoshi Tsukeda ◽  
Ken Saito ◽  
Mayumi Suzuki ◽  
Junichi Koike ◽  
Kouichi Maruyama
Keyword(s):  
Aluminum Alloy ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Die Casting ◽  
The Other ◽  
Heat Resistant ◽  
Higher Temperature ◽  
Better Than

We compared the newly developed heat resistant magnesium alloy with conventional ones by Thixomolding® and aluminum alloy by die casting. Tensile properties at elevated temperatures of AXEJ6310 were equal to those of ADC12. In particular, elongation tendency of AXEJ6310 at higher temperature was better than those of the other alloys. Creep resistance of AXEJ6310 was larger than that of AE42 by almost 3 orders and smaller than that of ADC12 by almost 2 orders of magnitude. Fatigue limits at room temperature and 423K of AXEJ6310 was superior among conventional magnesium alloys.

scholarly journals Microstructure Features of Ternary Alkali-activated Binder Based on Tungsten Mining Waste, Slag and Metakaolin

2020 ◽  
Author(s):  
Naim Sedira ◽  
João Castro-Gomes
Keyword(s):  
Sodium Silicate ◽  
Room Temperature ◽  
Mining Waste ◽  
Dense Matrix ◽  
Microstructural Properties ◽  
Reaction Products ◽  
Granulated Blast Furnace Slag ◽  
Alkaline Activator ◽  
Furnace Slag ◽  
Alkali Activated

This study determines the effect of ground granulated blast furnace slag (GGBFS) and metakaolin (MK) on the microstructural properties of the tungsten mining waste-based alkali-activated binder (TMWM). During this investigation, TMWM was partially replaced with 10 wt.% GGBFS and 10 wt.% MK to improve the microstructure of the binder. In order to understand the effect of the substitutions on the microstructure, two pastes were produced to make a comparative study between the sample contain 100% TMWM and the ternary precursors. Both precursors were activated using a combination of alkaline activator solutions (sodium silicate and sodium hydroxide) with the ratio of 1:3 (66.6 wt.% sodium silicate combined with 33.33 wt.% of NaOH 8M). The alkali-activated mixes were cured in oven at temperature of 60 °C in the first day and at room temperature for the next 27 days. The reaction products N-A-S-H gel and (N,M)-A-S-H gel resulted from the alkaline activation reaction process. In addition, a formation of natrite (Na2CO3) with needles shape occurred as a reaction product of the fluorescence phenomena. However, a dense matrix resulted from the alkline activation of the ternary precursors containg different gels such as N-A-S-H, C-A-S-H and (N,M)-C-A-S-H gel, these results were obtained through SEM-EDS analyses, as well FTIR tests. Keywords: Mining Waste, Alkali-activated, Microstructure, Slag, Metakaolin

scholarly journals Studi Kemampuan Penyerapan Panas pada Atap Rumah Seng Berwarna Terhadap Intensitas Matahari dalam Mengatasi Global Warming

2020 ◽  
Vol 4 (3) ◽  
pp. 114
Author(s):  
Nazaruddin Nazaruddin ◽  
Teuku Zulfadli ◽  
Andi Mulkan
Keyword(s):  
Global Warming ◽  
Temperature Difference ◽  
Research Method ◽  
Room Temperature ◽  
Environmental Temperature ◽  
Heat Absorption ◽  
Temperature Observation ◽  
Yellow Color ◽  
Black Color

The environmental temperature has increased significantly reaching 33oC as felt by the community, one of which is in the Aceh region which triggers Global Warming. As a result of the increase in temperature in the Aceh area, many buildings and houses become uncomfortable especially during the daytime because most house with zinc roof. This will cause the temperature in the house and the air around it to increase. Therefore, it is necessary to do research on the study of heat absorption on colored zinc roofs. This research method is to calculate the heat absorption (sun intensity) in zinc that has been coated with several kinds of colors such as white, red, blue, yellow and black. The purpose of this study was to determine the color that has the least amount of heat absorption to the sun's intensity. The highest room temperature on zinc-coated black is 49.2° C and the lowest is in white.  40.9°C from the pen. In the environmental temperature observation, there is the highest temperature at 12.00.  Room temperature increased the highest temperature at 12.00 on black zinc.  The distribution of room temperature can be averaged with a yellow color of 46.0°C, a black color of 49.2°C, a blue of 45.5°C and a white zinc of 40.9 oC.  The heat absorbed in the room is 47.9 joules, so from the overall average of the test it can be described that the room temperature is 45.6 and the zinc temperature is 53.8oC from the highest temperature difference at 12.00 WIB, room temperature and 13.00 WIB the highest absorption occurs at zinc temperature.

Sulfur Linkage in Vulcanized Rubber. Reaction of Methyl Iodide with Sulfur Compounds

1949 ◽  
Vol 22 (1) ◽  
pp. 1-7
Author(s):  
M. L. Selker
Keyword(s):  
Methyl Iodide ◽  
Room Temperature ◽  
Sulfur Compounds ◽  
Point Of View ◽  
Secondary Reaction ◽  
Reaction Products ◽  
Sulfide Sulfur ◽  
Vulcanized Rubber ◽  
Allyl Sulfide

Abstract The work described here is an extension of the study of the reaction of methyl iodide with sulfur compounds originally begun with the purpose of using such data in determining the sulfur linkage in vulcanized rubber. A previous paper dealt with the reactions of methyl iodide with propanethiol, propyl sulfide, propyl disulfide, allyl sulfide, and thiophene. This article adds to the list, n-butyl methallyl sulfide, allyl disulfide, allyl tetrasulfide, n-propyl tetrasulfide, and trithiane. The removal of combined sulfur from vulcanized rubber as trimethylsulfonium iodide on treatment with methyl iodide at room temperature was persuasive evidence of the presence of sulfide sulfur linked to allylic type residues. The evidence offered, however, did not constitute exclusive proof because it was not known whether still other types of sulfur linkage would also yield trimethylsulfonium iodide. To shed more light on this question, the sulfur linkages most likely to occur in vulcanizates—the allyl-alkyl monosulfide, diallyl and dialkyl di- and polysulfide—were investigated. The trithiane reaction is of interest mostly from the point of view of the reaction of overcured stocks or secondary reaction products stemming from the original polysulfides. The reactions were carried out using the method described in a previous paper.

The Reactivity of CaTi4(PO4)6 with Alumina and Y-TZP Ceramics

2007 ◽  
Vol 361-363 ◽  
pp. 787-790
Author(s):  
Sabina Beranič Klopčič ◽  
Irena Pribošič ◽  
Tomaž Kosmač ◽  
Ute Ploska ◽  
Georg Berger
Keyword(s):  
Room Temperature ◽  
Xrd Analysis ◽  
Second Phase ◽  
Reaction Products ◽  
Stabilized Zirconia ◽  
Monoclinic Zro2 ◽  
Commercial Alumina ◽  
The Matrix ◽  
Different Temperatures ◽  
Edx Analyses

The reactivity of CaTi4(PO4)6 (CTP) with alumina and yttria-stabilized zirconia (Y-TZP) ceramics was studied. CTP powder was synthesized and composites with commercial alumina or zirconia matrices containing 10 wt% of CTP were prepared. They were sintered at different temperatures and characterized using XRD, SEM, and EDX analyses. The results showed that the alumina/CTP and Y-TZP/CTP composites start to react below 1000 °C. In the alumina/CTP composite the first reaction product, detected at 970 °C, was AlPO4. At temperatures above 1280 °C TiO2 and CaTiO3 were also formed and no CTP peaks could be detected using XRD analysis. The composite sintered at 1500 °C consisted of Al2O3 matrix, AlPO4, TiO2, CaTiO3 and Al2TiO5. The reaction products formed in the Y-TZP/CTP composite at 970 °C were TiO2 and Ca2Zr7O16. At higher sintering temperatures, 1280 °C and above, CTP was no longer present, Ca2Zr7O16 decomposed, forming CaO2 and ZrO2, and Y2O3 was consumed to form YPO4. Consequently, upon cooling to room temperature the matrix phase transformed to monoclinic ZrO2. Based on these results it can be concluded that CTP is not a suitable bioactive second phase for the fabrication of CTP composites with alumina or zirconia matrices.

scholarly journals Photochemische Reaktionen von Übergangsmetall-Olefin-Komplexen, V [1]. Die Umsetzung von Tricarbonyl-η-6.6-dimethylfulven-chrom(0) mit 7-Methyl- und 7-Methoxycycloheptatrien / Photochemical Reactions of Transition Metal Olefin Complexes, V [1]. The Reactions of Tricarbonyl-η-6,6-dimethylfulvene-chromium(0) with 7-Methyl- and 7-Methoxycycloheptatriene

1982 ◽  
Vol 37 (10) ◽  
pp. 1322-1326 ◽  
Author(s):  
Cornelius G. Kreiter ◽  
Hans Kurz
Keyword(s):  
Nmr Spectroscopy ◽  
Transition Metal ◽  
Column Chromatography ◽  
Room Temperature ◽  
Photochemical Reactions ◽  
Membered Ring ◽  
Reaction Products ◽  
Methyl Group

Abstract The stereochemistry of the photo reaction products of tricarbonyl-η-6,6-dimethyl-fulvene-chromium(O) (1) with 7-methyl-and 7-methoxycycloheptatriene was studied by NMR-spectroscopy. Both trienes add to 1, displace a CO ligand, and form substituted dicarbonyl-η3-2-cycloheptadienylene-η5-2-cyclopentadienylidene-propane-chromium(0) complexes. With C7H7CH3 only one isomer (3) is formed with the methyl-group in endo-position and the enyl system encompassing C(1′)-C(3′) of the seven membered ring. C7H7OCH3 yields 3 isomers which were separated by column chromatography. 5 has the same constitution as 3. The isomers 4 and 5 bear the OCH3-group in e^o-position. The enyl system of 4 is located on C(1′)-C(3′), that of 6 on C(3′)-C(5′). 6 rearranges at room temperature to 4.

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