Attraction and repulsion of floating particles

1982 ◽  
Vol 60 (23) ◽  
pp. 2889-2895 ◽  
Author(s):  
M. A. Fortes
Keyword(s):  
Capillary Force ◽  
Cylindrical Symmetry ◽  
Contact Angles ◽  
Single Parameter ◽  
The Other ◽  
Horizontal Force ◽  
Wetting Properties ◽  
General Geometry ◽  
Floating Particles ◽  
Floating Cylinders

The horizontal force that has to be applied to floating cylinders to equilibrate the capillary force is calculated for a general geometry with cylindrical symmetry and for any wetting characteristics of the cylinders. The force on a cylinder can be related to a single parameter of each of the two menisci that contact the cylinder. It is found that the force between parallel vertical plates or parallelipipeds can be repulsive if one of the contact angles is acute and the other obtuse. The force on cylinders between fixed walls is also calculated and the results suggest that it may be possible to separate floating particles with different wetting properties by placing them between two walls with different contact angles.

scholarly journals Effect of Photofunctionalization with 6 W or 85 W UVC on the Degree of Wettability of RBM Titanium in Relation to the Irradiation Time

2021 ◽  
Vol 11 (12) ◽  
pp. 5427
Author(s):  
Arturo Sanchez-Perez ◽  
Nuria Cano-Millá ◽  
María José Moya Villaescusa ◽  
José María Montoya Carralero ◽  
Carlos Navarro Cuellar
Keyword(s):  
Light Source ◽  
Ultraviolet Light ◽  
Irradiation Time ◽  
Contact Angles ◽  
The Other ◽  
Control Group ◽  
Hydrophilic Surface ◽  
Biological Ageing ◽  
Ultraviolet C ◽  
Group A

Photoactivation with ultraviolet C light can reverse the effects derived from biological ageing by restoring a hydrophilic surface. Ten titanium discs were randomly divided into three groups: a control group, a 6 W group, and an 85 W group. A drop of double-distilled, deionized, and sterile 10 µL water was applied to each of the discs. Each disc was immediately photographed in a standardized and perpendicular manner. Measurements were taken based on the irradiation time (15, 30, 60, and 120 min). UVC irradiation improved the control values in both groups. There was no difference in its effect between the 6 W group and the other groups during the first 30 min. However, after 60 min and up to 120 min, 85 W had a significantly stronger effect. The contact angles with the 85 W ultraviolet light source at 60 and 120 min were 19.43° and 31.41°, respectively, whereas the contact angles for the 6 W UVC source were 73.8° and 61.45°. Power proved to be the most important factor, and the best hydrophilicity result was obtained with a power of 85 W for 60 min at a wavelength of 254 nm.

scholarly journals Benefits of Nonthermal Atmospheric Plasma Treatment on Dentin Adhesion

2018 ◽  
Vol 43 (6) ◽  
pp. E288-E299 ◽  
Author(s):  
AP Ayres ◽  
PH Freitas ◽  
J De Munck ◽  
A Vananroye ◽  
C Clasen ◽  
...  
Keyword(s):  
Plasma Treatment ◽  
Young’S Modulus ◽  
Young's Modulus ◽  
Water Storage ◽  
Contact Angles ◽  
The Other ◽  
Atmospheric Plasma ◽  
Hybrid Layer ◽  
Water Contact ◽  
Dentin Surface

SUMMARY Objectives: This study aimed to evaluate the influence of two nonthermal atmospheric plasma (NTAP) application times and two storage times on the microtensile bond strength (μTBS) to dentin. The influence of NTAP on the mechanical properties of the dentin-resin interface was studied by analyzing nanohardness (NH) and Young's modulus (YM). Water contact angles of pretreated dentin and hydroxyapatite blocks were also measured to assess possible alterations in the surface hydrophilicity upon NTAP. Methods and Materials: Forty-eight human molars were used in a split-tooth design (n=8). Midcoronal exposed dentin was flattened by a 600-grit SiC paper. One-half of each dentin surface received phosphoric acid conditioning, while the other half was covered with a metallic barrier and remained unetched. Afterward, NTAP was applied on the entire dentin surface (etched or not) for 10 or 30 seconds. The control groups did not receive NTAP treatment. Scotchbond Universal (SBU; 3M ESPE) and a resin-based composite were applied to dentin following the manufacturer's instructions. After 24 hours of water storage at 37°C, the specimens were sectioned perpendicular to the interface to obtain approximately six specimens or bonded beams (approximately 0.9 mm2 in cross-sectional area) representing the etch-and-rinse (ER) approach and another six specimens representing the self-etch (SE) approach. Half of the μTBS specimens were immediately loaded until failure, while the other half were first stored in deionized water for two years. Three other bonded teeth were selected from each group (n=3) for NH and YM evaluation. Water contact-angle analysis was conducted using a CAM200 (KSV Nima) goniometer. Droplet images of dentin and hydroxyapatite surfaces with or without 10 or 30 seconds of plasma treatment were captured at different water-deposition times (5 to 55 seconds). Results: Two-way analysis of variance revealed significant differences in μTBS of SBU to dentin after two years of water storage in the SE approach, without differences among treatments. After two years of water aging, the ER control and ER NTAP 10-second groups showed lower μTBS means compared with the ER NTAP 30-second treated group. Nonthermal atmospheric plasma resulted in higher NH and YM for the hybrid layer. The influence of plasma treatment in hydrophilicity was more evident in the hydroxyapatite samples. Dentin hydrophilicity increased slightly after 10 seconds of NTAP, but the difference was higher when the plasma was used for 30 seconds. Conclusions: Dentin NTAP treatment for 30 seconds contributed to higher μTBS after two years of water storage in the ER approach, while no difference was observed among treatments in the SE evaluation. This result might be correlated to the increase in nanohardness and Young's modulus of the hybrid layer and to better adhesive infiltration, since dentin hydrophilicity was also improved. Although some effects were observed using NTAP for 10 seconds, the results suggest that 30 seconds is the most indicated treatment time.

Development of breathable Janus superhydrophobic polyester fabrics using alkaline hydrolysis and blade coating

2018 ◽  
Vol 89 (6) ◽  
pp. 959-974 ◽  
Author(s):  
Seonyoung Youn ◽  
Chung Hee Park
Keyword(s):  
Mechanical Properties ◽  
Alkaline Hydrolysis ◽  
Structural Changes ◽  
Treatment Time ◽  
Volume Ratio ◽  
Alkaline Treatment ◽  
The Other ◽  
Solution Temperature ◽  
Optimal Conditions ◽  
Wetting Properties

Alkaline hydrolysis is a common finishing method that is used to give polyester (polyethylene terephthalate, PET) a more natural touch and improved luster via chemical or physical changes in the fibers. However, its potential as a tool for surface modification in the development of single-sided superhydrophobic materials has not been studied yet. In this research, Janus superhydrophobic PET fabrics with asymmetric wetting properties (one side of the PET surface was rendered superhydrophobic while the other side was simply hydrophobic) were fabricated in two steps. Fine roughness was first achieved on the surface of PET fabrics by alkaline hydrolysis. Subsequently, optimized foam-coating emulsions were applied on only one surface of the alkaline-hydrolyzed PET. Alkaline treatment time, solution temperature, and viscosity of the foam-coating emulsions were varied to find optimal conditions in terms of structural changes, mechanical properties, superhydrophobicity, and absorption ability. The specimen treated with an aqueous solution of 8% sodium hydroxide at 70℃ for 60 min and coated with the mixture of the fluoro-emulsion and thickener in the volume ratio of 40:2 was determined to be the optimal conditions for the Janus superhydrophobic property. This sample showed a contact angle of 162.8° and a shedding angle of 5.6° on one side, whereas it completely permitted the percolation of water drops on the other side within 109 s. The mechanical properties of the developed Janus PET under the optimal conditions did not decrease significantly; its weight and tensile strength were found to have decreased by 3.3% and 19.2%, respectively. Furthermore, the single-sided superhydrophobic specimen demonstrated higher moisture transmissibility than the double-sided coated PET under the same alkaline treatment conditions. The method developed herein eliminates the requirement for an additional process to deliver nanoscale surface roughness and has the potential to produce waterproof–breathable PET fabrics for outdoor clothing.

scholarly journals Surface, Volumetric, and Wetting Properties of Oleic, Linoleic, and Linolenic Acids with Regards to Application of Canola Oil in Diesel Engines

2019 ◽  
Vol 9 (17) ◽  
pp. 3445 ◽  
Author(s):  
Anna Zdziennicka ◽  
Katarzyna Szymczyk ◽  
Bronisław Jańczuk ◽  
Rafał Longwic ◽  
Przemysław Sander
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Diesel Engines ◽  
Canola Oil ◽  
Contact Angles ◽  
Physiochemical Properties ◽  
Engine Valve ◽  
Wetting Properties ◽  
Main Components ◽  
Adhesion Work

Oleic, linoleic, and linolenic acids are the main components of canola oil and their physiochemical properties decide on the use of canola oil as fuel for diesel engines. Therefore, the measurements of the surface tension of oleic, linoleic, and linolenic acids being the components of the canola oil, as well as their contact angles on the polytetrafluoroethylene (PTFE), poly(methyl methacrylate) (PMMA), and engine valve, were made. Additionally, the surface tension and contact angle on PTFE, PMMA, and the engine valve of the oleic acid and n-hexane mixtures were measured. On the basis of the obtained results, the components and parameters of oleic, linoleic, and linolenic acids’ surface tension were determined and compared to those of the canola oil. Next, applying the components and parameters of these acids, their adhesion work to PTFE, PMMA, and the engine valve was calculated by means of various methods.

The Capillary Force Between an AFM Tip and a Surface at Different Humidity

2008 ◽  
Author(s):  
Sheng Chau Chen ◽  
Jen Fin Lin
Keyword(s):  
Relative Humidity ◽  
Capillary Force ◽  
Present Model ◽  
Hydrophobic Surface ◽  
Contact Angles ◽  
Solid Surfaces ◽  
Hydrophilic Surface ◽  
Solid Bodies ◽  
Force Equilibrium ◽  
Good Agreement

In the present study, the meniscus profiles of water bridges formed at different relative humidity are determined using the geometric relationships including the Kelvin equation and the force equilibrium formula established for the meniscus. The pull-off forces predicted by the present model show good agreement with the experimental results reported in the literatures. When the contact angles at two solid bodies are equal, the pull-off force is slightly elevated by an increase of the relative humidity of air, and is significantly elevated by an increase of the asperity radius. Furthermore, two hydrophobic surfaces with equally large contact angles lower the pull-off force. If a difference exists between the contact angles of two solid surfaces, the asperity with a hydrophilic surface incorporating with a smooth flat plate with a hydrophobic surface reduces the pull-off force.

scholarly journals The adhesion model considering capillarity for gecko attachment system

2007 ◽  
Vol 5 (20) ◽  
pp. 319-327 ◽  
Author(s):  
Tae Wan Kim ◽  
Bharat Bhushan
Keyword(s):  
Capillary Force ◽  
Adhesion Force ◽  
Adhesive Force ◽  
Contact Angles ◽  
Adhesion Forces ◽  
Real Area Of Contact ◽  
Wide Range ◽  
Elliptical Integral ◽  
Gecko Adhesion ◽  
Surface Construction

Geckos make use of approximately a million microscale hairs (setae) that branch off into hundreds of nanoscale spatulae to cling to different smooth and rough surfaces and detach at will. This hierarchical surface construction gives the gecko the adaptability to create a large real area of contact with surfaces. It is known that van der Waals force is the primary mechanism used to adhere to surfaces, and capillary force is a secondary effect that can further increase adhesive force. To investigate the effects of capillarity on gecko adhesion, we considered the capillary force as well as the solid-to-solid interaction. The capillary force expressed in terms of elliptical integral is calculated by numerical method to cope with surfaces with a wide range of contact angles. The adhesion forces exerted by a single gecko spatula in contact with planes with different contact angles for various relative humidities are calculated, and the contributions of capillary force to total adhesion force are evaluated. The simulation results are compared with experimental data. Finally, using the three-level hierarchical model recently developed to simulate a gecko seta contacting with random rough surface, the effect of the relative humidity and the hydrophobicity of surface on the gecko adhesion is investigated.

Wetting properties of Nd:YAG laser treated copper by SAC solders

2017 ◽  
Vol 29 (2) ◽  
pp. 69-74 ◽  
Author(s):  
József Hlinka ◽  
Miklós Berczeli ◽  
Gábor Buza ◽  
Zoltán Weltsch
Keyword(s):  
Surface Treatment ◽  
Laser Treatment ◽  
Contact Angles ◽  
Laser Surface ◽  
Lead Free Solder ◽  
Solder Paste ◽  
Laser Surface Treatment ◽  
Content Type ◽  
Wetting Properties ◽  
Free Solder

Purpose This paper aims to discuss the effect of surface treatment on the wettability between copper and a lead-free solder paste. The industrial applications of laser technologies are increasing constantly. A specific laser treatment can modify the surface energy of copper and affect the wetting properties. Design/methodology/approach The surfaces of copper plates were treated using an Nd:YAG laser with varying laser powers. After laser surface treatment, wetting experiments were performed between the copper plates and SAC305 lead-free solder paste. The effect of laser treatment on copper surface was analysed using optical microscopy and scanning electron microscopy (SEM). Findings The experimental results showed that the wetting contact angles changed with the variation in laser power. Furthermore, it means that the surface energy of copper plates was changed by the laser treatment. The results demonstrated that the contact angles also changed when a different soldering paste was used. Originality/value Previous laser surface treatment can be a possible way to optimize the wettability between solders and substrates and to increase the quality of the soldered joints.

Reactive wetting of polycrystalline TiC by molten Zr55Cu30Al10Ni5 metallic glass alloy

2009 ◽  
Vol 24 (7) ◽  
pp. 2420-2427 ◽  
Author(s):  
Ping Shen ◽  
Qiaoli Lin ◽  
Qichuan Jiang ◽  
Hidetoshi Fujii ◽  
Kiyoshi Nogi
Keyword(s):  
Metallic Glass ◽  
Reaction Layer ◽  
Triple Junction ◽  
Sessile Drop ◽  
Contact Angles ◽  
Sessile Drop Method ◽  
The Other ◽  
Reactive Wetting ◽  
Exponential Functions ◽  
Glass Alloy

The isotherm wetting and spreading behaviors of polycrystalline TiC by molten Zr55Cu30Al10Ni5 alloy were investigated at 1133 to 1253 K in a vacuum by using a modified sessile drop method. The system displays good wettability with the initial and final stable contact angles of 44 to 50° and 10 to 14°, respectively, mildly depending on the temperature. The spreading kinetics follows well defined exponential functions and could be described by a molecular dynamic model. On the other hand, a ZrC reaction layer was formed at the interface. The wetting was primarily promoted by the Zr adsorption at the triple junction and then by the formation of the reaction layer.

scholarly journals Catheter contact angle influences local impedance drop during radiofrequency catheter ablation: Insight from a porcine experimental study with 2 different LI-sensing catheters

2021 ◽  
Author(s):  
Gen Matsuura ◽  
Hidehira Fukaya ◽  
Emiyu Ogawa ◽  
Sota Kawakami ◽  
Hitoshi Mori ◽  
...  
Keyword(s):  
Experimental Study ◽  
Contact Angle ◽  
Catheter Ablation ◽  
Angular Dependence ◽  
Radiofrequency Catheter Ablation ◽  
Lesion Size ◽  
Contact Angles ◽  
The Other ◽  
Tissue Temperature ◽  
The Difference

Background: Local impedance (LI) can indirectly measure catheter contact and tissue temperature during radiofrequency catheter ablation (RFCA). However, data on the effects of catheter contact angle on LI parameters are scarce. This study aimed to evaluate the influence of catheter contact angle on LI changes and lesion size with 2 different LI-sensing catheters in a porcine experimental study. Methods: Lesions were created by the INTELLANAV MiFi™ OI (MiFi) and the INTELLANAV STABLEPOINT™ (STABLEPOINT). RFCA was performed with 30 watts and a duration of 30 seconds. The CF (0, 5, 10, 20, and 30 g) and catheter contact angle (30°, 45°, and 90°) were changed in each set (n=8 each). The LI rise, LI drop, and lesion size were evaluated. Results: The LI rise increased as CF increased. There was no angular dependence with the LI rise under all CFs in the MiFi. On the other hand, the LI rise at 90° was lower than at 30° under 5 and 10 g of CF in STABLEPOINT. The LI drop increased as CF increased. Regarding the difference in catheter contact angles, the LI drop at 90° was lower than that at 30° for both catheters. The maximum lesion widths and surface widths were smaller at 90° than at 30°, whereas there were no differences in lesion depths. Conclusion: The LI drop and lesion widths at 90° were significantly smaller than those at 30°, although the lesion depths were not different among the 3 angles for the MiFi and STABLEPOINT.

Exact Solution for Freezing in Cylindrical Symmetry with Extended Freezing Temperature Range

1979 ◽  
Vol 101 (2) ◽  
pp. 331-334 ◽  
Author(s):  
M. N. O¨zis¸ik ◽  
J. C. Uzzell
Keyword(s):  
Solid Solution ◽  
Solid Fraction ◽  
Freezing Temperature ◽  
Cylindrical Symmetry ◽  
Infinite Medium ◽  
The Other ◽  
Phase Zone ◽  
Two Phase ◽  
Temperature Range ◽  
Liquidus Temperatures

The problem of solidification by a line heat sink in an infinite medium with cylindrical symmetry for a substance having an extended freezing temperature range between the solidus and liquidus temperatures is solved exactly for two different cases characterizing the distribution of the solid fraction within the two-phase zone. In one of the models, the solid fraction is assumed to vary linearly with the temperature and in the other solidification within the two-phase zone is assumed to have a linear relationship with the distance. The analysis is applicable for both eutectic and solid solution alloys.

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