scholarly journals On Water Density Fluctuations with Helices of Hydrogen Bonds

2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
Alexander Shimkevich ◽  
Inessa Shimkevich
Keyword(s):  
Hydrogen Bonds ◽  
Liquid Water ◽  
Condensed Matter ◽  
Matter Density ◽  
Density Fluctuations ◽  
Point Of View ◽  
Spectral Series ◽  
Adaptive Model ◽  
Water Density ◽  
The One

An adaptive model is developed here for the liquid water density fluctuations as momentary dense clusters with helices of hydrogen bonds and nondense tetrahedral clusters of ice. This model can be useful for explanation of liquid water structural anomalies including the high quantity of hydrogen bonds with quasitetrahedral orientation in the nonordered liquid water. The topology of such clusters is essentially differed from the one of the crystalline ice. From this and only this point of view, the liquid water can be considered as a two-structural fluid by dynamic forming the two topological kinds of clusters as a consequence of condensed-matter density fluctuations. Another feature of the dense-water-part clusters is helical ordering of protons which can realize coherent vibrations. A spectral series of such vibrations is determined as a function of the number of molecules into the helical cluster.

scholarly journals Aqueous Nanofluid as a Two-Phase Coolant for PWR

2012 ◽  
Vol 2012 ◽  
pp. 1-6
Author(s):  
Pavel N. Alekseev ◽  
Yury M. Semchenkov ◽  
Alexander L. Shimkevich
Keyword(s):  
Thermal Conductivity ◽  
Hydrogen Bonds ◽  
Liquid Water ◽  
Water Clusters ◽  
Density Fluctuations ◽  
Solid Particles ◽  
Two Phase ◽  
Gaseous Oxygen ◽  
Alternative Approach ◽  
Solubility Of Oxygen

Density fluctuations in liquid water consist of two topological kinds of instant molecular clusters. The dense ones have helical hydrogen bonds and the nondense ones are tetrahedral clusters with ice-like hydrogen bonds of water molecules. Helical ordering of protons in the dense water clusters can participate in coherent vibrations. The ramified interface of such incompatible structural elements induces clustering impurities in any aqueous solution. These additives can enhance a heat transfer of water as a two-phase coolant for PWR due to natural forming of nanoparticles with a thermal conductivity higher than water. The aqueous nanofluid as a new condensed matter has a great potential for cooling applications. It is a mixture of liquid water and dispersed phase of extremely fine quasi-solid particles usually less than 50 nm in size with the high thermal conductivity. An alternative approach is the formation of gaseous (oxygen or hydrogen) nanoparticles in density fluctuations of water. It is possible to obtain stable nanobubbles that can considerably exceed the molecular solubility of oxygen (hydrogen) in water. Such a nanofluid can convert the liquid water in the nonstoichiometric state and change its reduction-oxidation (RedOx) potential similarly to adding oxidants (or antioxidants) for applying 2D water chemistry to aqueous coolant.

Understanding functional illiteracy from a policy, adult education, and cognition point of view: Towards a joint referent framework

2019 ◽  
Vol 30 (2) ◽  
pp. 109-122
Author(s):  
Aleksandar Bulajić ◽  
Miomir Despotović ◽  
Thomas Lachmann
Keyword(s):  
Adult Education ◽  
Operational Definition ◽  
Literacy Skills ◽  
Point Of View ◽  
Industrialized Countries ◽  
Functional Illiteracy ◽  
Scale Levels ◽  
Components Of Reading ◽  
The One ◽  
Definition Of

Abstract. The article discusses the emergence of a functional literacy construct and the rediscovery of illiteracy in industrialized countries during the second half of the 20th century. It offers a short explanation of how the construct evolved over time. In addition, it explores how functional (il)literacy is conceived differently by research discourses of cognitive and neural studies, on the one hand, and by prescriptive and normative international policy documents and adult education, on the other hand. Furthermore, it analyses how literacy skills surveys such as the Level One Study (leo.) or the PIAAC may help to bridge the gap between cognitive and more practical and educational approaches to literacy, the goal being to place the functional illiteracy (FI) construct within its existing scale levels. It also sheds more light on the way in which FI can be perceived in terms of different cognitive processes and underlying components of reading. By building on the previous work of other authors and previous definitions, the article brings together different views of FI and offers a perspective for a needed operational definition of the concept, which would be an appropriate reference point for future educational, political, and scientific utilization.

Recommendations of The Ombudsman’s Dilemma: Between Law Enforcement Officials and Protection of Credibility

2018 ◽  
Vol 2 ◽  
pp. 1-12
Author(s):  
Dyah Adriantini Sintha Dewi
Keyword(s):  
Law Enforcement ◽  
Public Service ◽  
Public Services ◽  
Point Of View ◽  
Law Enforcement Officials ◽  
Muslim Majority ◽  
The Republic ◽  
The Government ◽  
The One ◽  
Oversight Body

The Ombudsman as an external oversight body for official performance, in Fikih Siyasah (constitutionality in Islam) is included in the supervision stipulated in legislation (al-musahabah al-qomariyah). Supervision is done so that public service delivery to the community is in accordance with the rights of the community. This is done because in carrying out its duties, officials are very likely to conduct mal administration, which is bad public services that cause harm to the community. The Ombudsman is an institution authorized to resolve the mal administration issue, in which one of its products is by issuing a recommendation. Although Law No. 37 of 2018 on the Ombudsman of the Republic of Indonesia states that the recommendation is mandatory, theombudsman's recommendations have not been implemented. This is due to differences in point of view, ie on the one hand in the context of law enforcement, but on the other hand the implementation of the recommendation is considered as a means of opening the disgrace of officials. Recommendations are the last alternative of Ombudsman's efforts to resolve the mal administration case, given that a win-win solution is the goal, then mediation becomes the main effort. This is in accordance with the condition of the Muslim majority of Indonesian nation and prioritizes deliberation in resolving dispute. Therefore, it is necessary to educate the community and officials related to the implementation of the Ombudsman's recommendations in order to provide good public services for the community, which is the obligation of the government.

Defending the Difference

2017 ◽  
Keyword(s):  
Social Sciences ◽  
Natural Sciences ◽  
Point Of View ◽  
True Nature ◽  
Natural Entities ◽  
The Social ◽  
The World ◽  
Methodological Difference ◽  
The Difference ◽  
The One

Dreyfus argues that there is a basic methodological difference between the natural sciences and the social sciences, a difference that derives from the different goals and practices of each. He goes on to argue that being a realist about natural entities is compatible with pluralism or, as he calls it, “plural realism.” If intelligibility is always grounded in our practices, Dreyfus points out, then there is no point of view from which one can ask about or provide an answer to the one true nature of ultimate reality. But that is consistent with believing that the natural sciences can still reveal the way the world is independent of our theories and practices.

scholarly journals Twisted 6d (2, 0) SCFTs on a circle

2021 ◽  
Vol 2021 (7) ◽  
Author(s):  
Zhihao Duan ◽  
Kimyeong Lee ◽  
June Nahmgoong ◽  
Xin Wang
Keyword(s):  
Lie Groups ◽  
Point Of View ◽  
Partition Functions ◽  
Congruence Subgroups ◽  
Gauge Groups ◽  
Simple Lie Groups ◽  
Instanton Contribution ◽  
Elliptic Genera ◽  
Supersymmetric Gauge ◽  
The One

Abstract We study twisted circle compactification of 6d (2, 0) SCFTs to 5d $$ \mathcal{N} $$ N = 2 supersymmetric gauge theories with non-simply-laced gauge groups. We provide two complementary approaches towards the BPS partition functions, reflecting the 5d and 6d point of view respectively. The first is based on the blowup equations for the instanton partition function, from which in particular we determine explicitly the one-instanton contribution for all simple Lie groups. The second is based on the modular bootstrap program, and we propose a novel modular ansatz for the twisted elliptic genera that transform under the congruence subgroups Γ0(N) of SL(2, ℤ). We conjecture a vanishing bound for the refined Gopakumar-Vafa invariants of the genus one fibered Calabi-Yau threefolds, upon which one can determine the twisted elliptic genera recursively. We use our results to obtain the 6d Cardy formulas and find universal behaviour for all simple Lie groups. In addition, the Cardy formulas remain invariant under the twist once the normalization of the compact circle is taken into account.

scholarly journals Linkages between Energy Delivery and Economic Growth from the Point of View of Sustainable Development and Seaports

Energies ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4255
Author(s):  
Elżbieta Szaruga ◽  
Zuzanna Kłos-Adamkiewicz ◽  
Agnieszka Gozdek ◽  
Elżbieta Załoga
Keyword(s):  
Sustainable Development ◽  
Crude Oil ◽  
Cross Correlation ◽  
Point Of View ◽  
Oil Products ◽  
Modern Approach ◽  
Economic Cycles ◽  
Study Results ◽  
The One ◽  
Oil And Oil Products

This paper presents the synchronisation of economic cycles of GDP and crude oil and oil products cargo volumes in major Polish seaports. On the one hand, this issue fits into the concept of sustainable development including decoupling; on the other hand, the synchronisation may be an early warning tool. Crude oil and oil products cargo volumes are a specific barometer that predicts the next economic cycle, especially as they are primary sources of energy production. The research study applies a number of TRAMO/SEATS methods, the Hodrick–Prescott filter, spectral analysis, correlation and cross-correlation function. Noteworthy is the modern approach of using synchronisation of economic cycles as a tool, which was described in the paper. According to the study results, the cyclical components of the cargo traffic and GDP were affected by the leakage of other short-term cycles. However, based on the cross-correlation, it was proved that changes in crude oil and oil products cargo volumes preceded changes in GDP by 1–3 quarters, which may be valuable information for decision-makers and economic development planners.

scholarly journals Cosmological model parameter dependence of the matter power spectrum covariance from the DEUS-PUR Cosmo simulations

2020 ◽  
Vol 500 (2) ◽  
pp. 2532-2542
Author(s):  
Linda Blot ◽  
Pier-Stefano Corasaniti ◽  
Yann Rasera ◽  
Shankar Agarwal
Keyword(s):  
Dark Energy ◽  
Power Spectrum ◽  
Cold Dark Matter ◽  
Matter Density ◽  
Density Fluctuations ◽  
Matrix Analysis ◽  
Model Parameter ◽  
Matter Power Spectrum ◽  
Non Gaussian ◽  
The Impact

ABSTRACT Future galaxy surveys will provide accurate measurements of the matter power spectrum across an unprecedented range of scales and redshifts. The analysis of these data will require one to accurately model the imprint of non-linearities of the matter density field. In particular, these induce a non-Gaussian contribution to the data covariance that needs to be properly taken into account to realize unbiased cosmological parameter inference analyses. Here, we study the cosmological dependence of the matter power spectrum covariance using a dedicated suite of N-body simulations, the Dark Energy Universe Simulation–Parallel Universe Runs (DEUS-PUR) Cosmo. These consist of 512 realizations for 10 different cosmologies where we vary the matter density Ωm, the amplitude of density fluctuations σ8, the reduced Hubble parameter h, and a constant dark energy equation of state w by approximately $10{{\ \rm per\ cent}}$. We use these data to evaluate the first and second derivatives of the power spectrum covariance with respect to a fiducial Λ-cold dark matter cosmology. We find that the variations can be as large as $150{{\ \rm per\ cent}}$ depending on the scale, redshift, and model parameter considered. By performing a Fisher matrix analysis we explore the impact of different choices in modelling the cosmological dependence of the covariance. Our results suggest that fixing the covariance to a fiducial cosmology can significantly affect the recovered parameter errors and that modelling the cosmological dependence of the variance while keeping the correlation coefficient fixed can alleviate the impact of this effect.

scholarly journals ZnOTe Compounds Grown by DC-Magnetron Co-Sputtering

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 570
Author(s):  
Olga Sánchez ◽  
Manuel Hernández-Vélez
Keyword(s):  
Molar Fraction ◽  
Variable Parameter ◽  
Point Of View ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sample Series ◽  
Solid Phases ◽  
The One ◽  
High Bulk ◽  
Substrate Sample

ZnOTe compounds were grown by DC magnetron cosputtering from pure Tellurium (Te) and Zinc (Zn) cathodes in O2/Ar atmosphere. The applied power on the Zn target was constant equal to 100 W, while the one applied on the Te target took two values, i.e., 5 W and 10 W. Thus, two sample series were obtained in which the variable parameter was the distance from the Te targets to the substrate. Sample compositions were determined by Rutherford Backscattering Spectroscopy (RBS) experiments. Structural analysis was done using X-Ray diffraction (XRD) spectrometry and the growth of the hexagonal w-ZnO phase was identified in the XRD spectra. RBS results showed high bulk homogeneity of the samples forming ZnOTe alloys, with variable Te molar fraction (MF) ranging from 0.48–0.6% and from 1.9–3.1% for the sample series obtained at 5 W and 10 W, respectively. The results reflect great differences between the two sample series, particularly from the structural and optical point of view. These experiments point to the possibility of Te doping ZnO with the permanence of intrinsic defects, as well as the possibility of the formation of other Te solid phases when its content increases. The results and appreciable variations in the band gap transitions were detected from Photoluminescence (PL) measurements.

scholarly journals Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH] n

2021 ◽  
Vol 44 (1) ◽  
pp. 213-217
Author(s):  
Waly Diallo ◽  
Hélène Cattey ◽  
Laurent Plasseraud
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Hydrogen Bonds ◽  
Point Of View ◽  
Intermolecular Hydrogen Bonds

Abstract Crystallization of [(Ph3Sn)2SeO4] ⋅ 1.5H2O in methanol leads to the formation of [{(Ph3Sn)2SeO4} ⋅ CH3OH] n (1) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex 1 is arranged in polymeric zig-zag chains, composed of alternating Ph3Sn and SeO4 groups. In addition, pendant Ph3Sn ⋅ CH3OH moieties are branched along chains according to a syndiotactic organization and via Sn-O-Se connections. From a supramolecular point of view, intermolecular hydrogen bonds established between the selenate groups (uncoordinated oxygen) and the hydroxyl functions (CH3OH) of the pendant groups link the chains together.

scholarly journals Percolation and tortuosity in heart-like cells

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
R. Rabinovitch ◽  
Y. Biton ◽  
D. Braunstein ◽  
I. Aviram ◽  
R. Thieberger ◽  
...  
Keyword(s):  
Action Potential ◽  
Forest Fire ◽  
Sinus Node ◽  
Heart Tissue ◽  
Point Of View ◽  
Physical Point ◽  
Electrical Currents ◽  
Single Wave ◽  
Heart Arrhythmia ◽  
The One

AbstractIn the last several years, quite a few papers on the joint question of transport, tortuosity and percolation have appeared in the literature, dealing with passage of miscellaneous liquids or electrical currents in different media. However, these methods have not been applied to the passage of action potential in heart fibrosis (HF), which is crucial for problems of heart arrhythmia, especially of atrial tachycardia and fibrillation. In this work we address the HF problem from these aspects. A cellular automaton model is used to analyze percolation and transport of a distributed-fibrosis inflicted heart-like tissue. Although based on a rather simple mathematical model, it leads to several important outcomes: (1) It is shown that, for a single wave front (as the one emanated by the heart's sinus node), the percolation of heart-like matrices is exactly similar to the forest fire case. (2) It is shown that, on the average, the shape of the transport (a question not dealt with in relation to forest fire, and deals with the delay of action potential when passing a fibrotic tissue) behaves like a Gaussian. (3) Moreover, it is shown that close to the percolation threshold the parameters of this Gaussian behave in a critical way. From the physical point of view, these three results are an important contribution to the general percolation investigation. The relevance of our results to cardiological issues, specifically to the question of reentry initiation, are discussed and it is shown that: (A) Without an ectopic source and under a mere sinus node operation, no arrhythmia is generated, and (B) A sufficiently high refractory period could prevent some reentry mechanisms, even in partially fibrotic heart tissue.

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