scholarly journals Accelerated aging studies of the selected commercial films

Polimery ◽  
2021 ◽  
Vol 66 (6) ◽  
pp. 350-356
Author(s):  
Magdalena Cichecka ◽  
Beata Pałys ◽  
Bożena Wilbik-Hałgas ◽  
Marcin H. Struszczyk

The Arrhenius method was used to investigate the effect of accelerated aging conditions on the physical and mechanical properties of polymer films for technical, medical, food and office applications. Temperature and UV radiation were taken into account as environmental factors. It was shown that the tested films are more sensitive to thermal degradation than UV radiation. The reduction in tensile strength after thermal aging does not exceed 40%, and in the case of UV radiation, 14%. The estimated lifetime of the tested films is over 5 years.

Author(s):  
Galina S. Bozhenkova ◽  
Alexandra N. Tarakanovskaya ◽  
Oksana D. Tarnovskaya ◽  
Roman V. Ashirov

The article is devoted to the production of polymer by metathesis ring-opening polymerization under the influence of ruthenium initiator of type of Hoveyda-Grubbs II generation. The monomer used the mixture of dimethyl ether norbornene-2;3-dicarboxylic acid. The monomer was prepared by the Diels-Alder reaction of dicyclopentadiene and dimethyl maleate. The polymer was prepared in bulk of the monomer mixture. In this paper we have studied the physical and mechanical properties polydimethyl ether of norbornene-2;3-dicarboxylic acid; and assessed the impact of environmental factors on the change in properties of the polymer. As environmental factors; light; UV radiation; water; 0.1 M hydrochloric acid were applied; and accelerated aging conditions; which were held in a climate chamber. During performance we found that maintaining the polymer samples in the UV light chamber led to the slight increase in flexural modulus. In contrast; the polymer storage in water and in a hydrochloric acid solution for two months resulted in a slight decrease in the modulus of elasticity in bending index. These factors did not affect the change in the glass transition temperature of the polymer. Under the conditions of accelerated aging conducted for 1; 2 and 6 days after two cycles we observed the drop in modulus for bending of 8.5%; after 6 cycles of 13%. The glass transition temperature of polydimethyl ether of norbornene-2;3-dicarboxylic acid after 6 cycles decreased by only 3.4% in the climatic chamber. Studies have shown that the resulting polymer is resistant to water; hydrochloric acid; light and UV radiation; as well as it saves properties at a sufficient level for operation at conditions of accelerated aging. It should be noted that the tested polymer was prepared without additives; stabilizers and antioxidants. The proposed polymer can be used as a structural material for machine parts; including bulky.For citation:Bozhenkova G.S.; Tarakanovskaya A.N.; Tarnovskaya O.D.; Ashirov R.V. Influence of environmental factors on physical-mechanical properties of polydimethyl ether of norborene -2;3-dicarboxylic acid. Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2017. V. 60. N 5. P. 68-73


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2359
Author(s):  
Harmaen Ahmad Saffian ◽  
Masayuki Yamaguchi ◽  
Hidayah Ariffin ◽  
Khalina Abdan ◽  
Nur Kartinee Kassim ◽  
...  

In this study, Kraft lignin was esterified with phthalic anhydride and was served as reinforcing filler for poly(butylene succinate) (PBS). Composites with different ratios of PBS, lignin (L), modified lignin (ML) and kenaf core fibers (KCF) were fabricated using a compounding method. The fabricated PBS composites and its counterparts were tested for thermal, physical and mechanical properties. Weight percent gain of 4.5% after lignin modification and the FTIR spectra has confirmed the occurrence of an esterification reaction. Better thermo-mechanical properties were observed in the PBS composites reinforced with modified lignin and KCF, as higher storage modulus and loss modulus were recorded using dynamic mechanical analysis. The density of the composites fabricated ranged from 1.26 to 1.43 g/cm3. Water absorption of the composites with the addition of modified lignin is higher than that of composites with unmodified lignin. Pure PBS exhibited the highest tensile strength of 18.62 MPa. Incorporation of lignin and KCF into PBS resulted in different extents of reduction in tensile strength (15.78 to 18.60 MPa). However, PBS composite reinforced with modified lignin exhibited better tensile and flexural strength compared to its unmodified lignin counterpart. PBS composite reinforced with 30 wt% ML and 20 wt% KCF had the highest Izod impact, as fibers could diverge the cracking propagation of the matrix. The thermal conductivity value of the composites ranged from 0.0903 to 0.0983 W/mK, showing great potential as a heat insulator.


2012 ◽  
Vol 3 (1) ◽  
pp. 13-26
Author(s):  
Myrtha Karina ◽  
Lucia Indrarti ◽  
Rike Yudianti ◽  
Indriyati

The effect of castor oil on the physical and mechanical properties of bacterial cellulose is described. Bacterial cellulose (BC) was impregnated with 0.5–2% (w/v) castor oil (CO) in acetone–water, providing BCCO films. Scanning electron micrographs revealed that the castor oil penetrated the pores of the bacterial cellulose, resulting in a smoother morphology and enhanced hydrophilicity. Castor oil caused a slight change in crystallinity indices and resulted in reduced tensile strength and Young's modulus but increased elongation at break. A significant reduction in tensile strength and Young's modulus was achieved in BCCO films with 2% castor oil, and there was an improvement in elongation at break and hydrophilicity. Impregnation with castor oil, a biodegradable and safe plasticiser, resulted in less rigid and more ductile composites.


Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2865
Author(s):  
Md Jihad Miah ◽  
Md. Munir Hossain Patoary ◽  
Suvash Chandra Paul ◽  
Adewumi John Babafemi ◽  
Biranchi Panda

This paper investigates the possibility of utilizing steel slags produced in the steelmaking industry as an alternative to burnt clay brick aggregate (BA) in concrete. Within this context, physical, mechanical (i.e., compressive and splitting tensile strength), length change, and durability (porosity) tests were conducted on concrete made with nine different percentage replacements (0%, 10%, 20%, 30%, 40%, 50%, 60%, 80%, and 100% by volume of BA) of BA by induction of furnace steel slag aggregate (SSA). In addition, the chemical composition of aggregate through X-ray fluorescence (XRF) analysis and microstructural analysis through scanning electron microscopy (SEM) of aggregates and concrete were performed. The experimental results show that the physical and mechanical properties of concrete made with SSA were significantly higher than that of concrete made with BA. The compressive and tensile strength increased by 73% when SSA fully replaced BA. The expansion of concrete made with SSA was a bit higher than the concrete made with BA. Furthermore, a significant lower porosity was observed for concrete made with SSA than BA, which decreased by 40% for 100% SSA concrete than 100% BA concrete. The relation between compressive and tensile strength with the porosity of concrete mixes are in agreement with the relationships presented in the literature. This study demonstrates that SSA can be used as a full replacement of BA, which is economical, conserves the natural aggregate, and is sustainable building material since burning brick produces a lot of CO2.


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Chatree Homkhiew ◽  
Surasit Rawangwong ◽  
Worapong Boonchouytan ◽  
Wiriya Thongruang ◽  
Thanate Ratanawilai

The aim of this work is to investigate the effects of rubberwood sawdust (RWS) size and content as well as the ratio of natural rubber (NR)/high-density polyethylene (HDPE) blend on properties of RWS reinforced thermoplastic natural rubber (TPNR) composites. The addition of RWS about 30–50 wt% improved the modulus of the rupture and tensile strength of TPNR composites blending with NR/HDPE ratios of 60/40 and 50/50. TPNR composites reinforced with RWS 80 mesh yielded better tensile strength and modulus of rupture than the composites with RWS 40 mesh. The TPNR/RWS composites with larger HDPE content gave higher tensile, flexural, and Shore hardness properties and thermal stability as well as lower water absorption. The TPNR/RWS composites with larger plastic content were therefore suggested for applications requiring high performance of thermal, physical, and mechanical properties.


2021 ◽  
Vol 887 ◽  
pp. 110-115
Author(s):  
G.A. Sabirova ◽  
R.R. Safin ◽  
N.R. Galyavetdinov

This paper presents the findings of experimental studies of the physical and mechanical properties of wood-filled composites based on polylactide (PLA) and vegetable filler in the form of wood flour (WF) thermally modified at 200-240 °C. It also reveals the dependence of the tensile strength, impact strength, bending elastic modulus, and density of composites on the amount of wood filler and the temperature of its thermal pre-modification. We established that an increase in the concentration of the introduced filler and the degree of its heat treatment results in a decrease of the tensile strength, impact strength and density of composite materials, while with a lower binder content, thermal modification at 200 °C has a positive effect on bending elastic modulus. We also found that 40 % content of a wood filler heated to 200 °C is sufficient to maintain relatively high physical and mechanical properties of composite materials. With a higher content of a wood filler, the cost can be reduced but the quality of products made of this material may significantly deteriorate. However, depending on the application and the life cycle of this product, it is possible to develop a formulation that includes a high concentration of filler.


2020 ◽  
Author(s):  
Jackie E. Kendrick ◽  
Lauren N. Schaefer ◽  
Jenny Schauroth ◽  
Andrew F. Bell ◽  
Oliver D. Lamb ◽  
...  

Abstract. Volcanoes represent one of the most critical geological settings for hazard modelling due to their propensity to both unpredictably erupt and collapse, even in times of quiescence. Volcanoes are heterogeneous at multiple scales, from porosity which is variably distributed and frequently anisotropic to strata that are laterally discontinuous and commonly pierced by fractures and faults. Due to variable and, at times, intense stress and strain conditions during and post-emplacement, volcanic rocks span an exceptionally wide range of physical and mechanical properties. Understanding the constituent materials' attributes is key to improving the interpretation of hazards posed by the diverse array of volcanic complexes. Here, we examine the spectrum of physical and mechanical properties presented by a single dome-forming eruption at a dacitic volcano, Mount Unzen (Japan) by testing a number of isotropic and anisotropic lavas in tension and compression and using monitored acoustic emission (AE) analysis. The lava dome was erupted as a series of 13 lobes between 1991–1995, and its ongoing instability means much of the volcano and its surroundings remain within an exclusion zone today. During a field campaign in 2015, we selected 4 representative blocks as the focus of this study. The core samples from each block span range in porosity from 9.14 to 42.81 %, and permeability ranges from 1.54 × 10−14 to 2.67 × 10−10 m2 (from 1065 measurements). For a given porosity, sample permeability varies by > 2 orders of magnitude is lower for macroscopically anisotropic samples than isotropic samples of similar porosity. An additional 379 permeability measurements on planar block surfaces ranged from 1.90 × 10−15 to 2.58 × 10−12 m2, with a single block having higher standard deviation and coefficient of variation than a single core. Permeability under confined conditions showed that the lowest permeability samples, whose porosity largely comprises microfractures, are most sensitive to effective pressure. The permeability measurements highlight the importance of both scale and confinement conditions in the description of permeability. The uniaxial compressive strength (UCS) ranges from 13.48 to 47.80 MPa, and tensile strength (UTS) using the Brazilian disc method ranges from 1.30 to 3.70 MPa, with crack-dominated lavas being weaker than vesicle-dominated materials of equivalent porosity. UCS is lower in saturated conditions, whilst the impact of saturation on UTS is variable. UCS is between 6.8 and 17.3 times higher than UTS, with anisotropic samples forming each end member. The Young's modulus of dry samples ranges from 4.49 to 21.59 GPa and is systematically reduced in water-saturated tests. The interrelation of porosity, UCS, UTS and Young's modulus was modelled with good replication of the data. Acceleration of monitored acoustic emission (AE) rates during deformation was assessed by fitting Poisson point process models in a Bayesian framework. An exponential acceleration model closely replicated the tensile strength tests, whilst compressive tests tended to have relatively high early rates of AEs, suggesting failure forecast may be more accurate in tensile regimes, though with shorter warning times. The Gutenberg-Richter b-value has a negative correlation with connected porosity for both UCS and UTS tests which we attribute to different stress intensities caused by differing pore networks. b-value is higher for UTS than UCS, and typically decreases (positive Δb) during tests, with the exception of cataclastic samples in compression. Δb correlates positively with connected porosity in compression, and negatively in tension. Δb using a fixed sampling length may be a more useful metric for monitoring changes in activity at volcanoes than b-value with an arbitrary starting point. Using coda wave interferometry (CWI) we identify velocity reductions during mechanical testing in compression and tension, the magnitude of which is greater in more porous samples in UTS but independent of porosity in UCS, and which scales to both b-value and Δb. Yet, saturation obscures velocity changes caused by evolving material properties, which could mask damage accrual or source migration in water-rich environments such as volcanoes. The results of this study highlight that heterogeneity and anisotropy within a single system not only add uncertainty but also have a defining role in the channelling of fluid flow and localisation of strain that dictate a volcano's hazards and the geophysical indicators we use to interpret them.


2021 ◽  
Vol 16 (3) ◽  
pp. 124-135
Author(s):  
Nilüfer Yıldız Varan

Antimicrobials are substances or mixtures of substances used to destroy or suppress the growth of harmful microorganisms such as bacteria, viruses, or fungi on inanimate objects and surfaces. In this study, an alternative method is presented using triclosan agents that can kill bacteria and viruses to help keep patient, operating, and emergency rooms free of germs. Samples were treated with triclosan to achieve antimicrobial/antiviral/antifungal properties for further designs to help comfort and bacteria, virus, fungi (BVF) resistantance during use. The physical, and mechanical properties of triclosan treated cotton and cotton/elastane fabrics in comparison with untreated control samples was investigated. The results showed that a small significant decrease was observed for tensile strength (strip and grab methods), tear strength and seam strength. Besides, statistically a small significant decrease was observed with the increase in triclosan concentration for all samples. The panama weaves showed the lowest tensile strength and the highest tear strength and statistically small significant decrease was observed for all treated samples. The antimicrobial tests showed that all treated samples have a very good antimicrobial activity which can also lead to antivirus protection by providing hygienic environment for the users during future designs.


2020 ◽  
Vol 990 ◽  
pp. 262-266
Author(s):  
Prathumrat Nu-Yang ◽  
Atiwat Wiriya-Amornchai ◽  
Jaehoon Yoon ◽  
Chainat Saechau ◽  
Poom Rattanamusik

Thermoplastic vulcanizates or TPVs is a type of materials exhibiting excellent properties between thermoplastic and elastomer by combining the characteristics of vulcanized rubber with the processing properties of thermoplastics. This research aims to study the effect of thermal aging on the morphology and mechanical properties of thermoplastic vulcanizates (TPVs) based on a mixture of natural rubber (NR) and polystyrene (PS). TPVs samples were prepared using the internal mixer at a mass ratio of NR/PS 70/30, 50/50, 30/70 and 0/100. Tensile properties and impact strength showed that when the amount of NR increased tends of impact strength and elongation at break increased but tends of tensile strength decreased. On the other hand, tends of tensile strength for thermal aging at 70°C for 3 days increased when the amount of PS increase. The blending ratio of NR / PS at 70/30 is the best. It gave a worthy increase from 19.94 MPa to be 25.56 MPa (28.18%).


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