scholarly journals Synthesis of Acid Polyols As a Feedstock to Produce Flexible Polyurethanes and Their Effect on the Income Level of Furniture Craftsmen

2019 ◽  
Vol 2 (1) ◽  
pp. 39
Author(s):  
Andi Budirohmi
Keyword(s):  
Fourier Transform ◽  
Fatty Acid ◽  
Raw Materials ◽  
Raw Material ◽  
Polymerization Process ◽  
Hydroxyl Group ◽  
Infra Red ◽  
Renewable Raw Material ◽  
Shoe Soles ◽  
Alternative Feedstock

Polyuretanes are widely used as elastomers, coatings, adhesivesand binders,interior and exterior cars, furniture,shoe soles, carpets, rigit and flexible foams, membrane materials as well as constuction materials .The production of polyurethanes is largely derived  from  polyols derived from petroleum . Howover, petroleum  is a non- renewable raw material . Thus it is necessary to look alternative feedstock  for the manufacture of polyol  as a polyurethane raw material. Synnthesis polyurethane by polymerization process  using  polyol volume based on polyol  oleat acid  polypropylenglycol ( PPG ) in order to know  whether fatty acid can be used  as raw materials  of polyurethane manufacture.From the result of the study. Based on Fourier Transform Infra  Red ( FTIR), showed,that the product  produced is polyol with obtained hydroxyl  group ( OH group )with hydroxylnumber is 129,81 mg KOH / g and 157,60 mg KOH / g sample of 70 

AlCl3·XNaCl Complex Compound as Catalyst Synthesis Dichlorophenylphosphine

2013 ◽  
Vol 641-642 ◽  
pp. 128-131 ◽  
Author(s):  
Tian Bo Fan ◽  
Gui Qi An ◽  
Tao Tang ◽  
Yun Yi Lui ◽  
Xiao Han ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Production Rate ◽  
Complex Compound ◽  
Industrial Production ◽  
Raw Materials ◽  
Reference Value ◽  
Raw Material ◽  
Catalyst Synthesis ◽  
Catalyst Amount

Dichlorophenylphosphine(DCPP) was prepared by the catalyst of AlCl3·XNaCl complex using C6H6, PCl3as raw materials. The influences of the catalyst amount, raw material ratio and the choice of extractant on the production rate were studied, as well as the recycling of the catalyst. Fourier transform infrared spectroscopy was employed to characterize the products. The results show that the products by experiments were dichlorophenylphosphine(DCPP). All above have some reference value for the industrial production.

scholarly journals Sintesis Merkaptoetil Karboksilat sebagai Bahan Baku Stabiliser Termal Polivinil Klorida: Variasi Sumber Asam Lemak

2020 ◽  
Vol 18 (2) ◽  
pp. 47
Author(s):  
I Dewa Gede Arsa Putrawan ◽  
Adli Azharuddin ◽  
Dendy Adityawarman ◽  
Dicka Ar Rahim
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Polyvinyl Chloride ◽  
Raw Materials ◽  
Batch Reactor ◽  
Strong Acid ◽  
Raw Material ◽  
Thermal Stabilizer ◽  
Palm Fatty Acid Distillate ◽  
Rigid Pvc

Abstrak. Merkaptoetil karboksilat merupakan bahan baku stabiliser termal polivinil klorida atau polyvinyl chloride (PVC) berbasis timah organik. Stabiliser termal perlu ditambahkan ke dalam resin PVC sebelum diekstrusi untuk mencegah kerusakan karena pengerjaan panas. Stabiliser termal PVC dari timah organik dikenal sangat efektif, khususnya untuk aplikasi PVC kaku seperti pipa dan bingkai jendela. Penelitian ini bertujuan mengevaluasi sintesis merkaptoetil karboksilat dari asam lemak dan merkapto etanol dengan variasi sumber asam lemak yang meliputi asam lemak sawit, dedak padi dan biji kapuk. Percobaan dilakukan dalam sebuah reaktor partaian (batch) dengan asam kuat sebagai katalis. Percobaan dilakukan pada temperatur 60-80°C dan ekses merkapto etanol 10%. Kinerja sintesis dievaluasi melalui pengukuran kadar gugus merkaptan dan angka asam dalam produk serta perolehan produk. Pada rentang temperatur 60-80°C, ketiga asam lemak memberikan produk dengan kadar merkaptan pada rentang 6,4-7,8%.  Temperatur 70°C merupakan temperatur terbaik karena menghasilkan produk dengan kadar merkaptan tertinggi tanpa memadat selama penyimpanan. Pada temperatur ini, produk memiliki angka asam pada rentang 11-41 mg KOH/g dan perolehan pada rentang 70-81%. Ketiga sumber asam lemak memberikan produk dengan kadar merkaptan yang mencukupi untuk dapat digunakan sebagai bahan baku stabiliser PVC. Mempertimbangkan kualitas produk dan ketersediaan di pasaran, distilat asam lemak sawit dipandang sebagai bahan baku yang paling baik. Kata kunci: asam lemak, merkaptoetil karboksilat, polivinil klorida, stabiliser termal. Abstract. Synthesis of Mercaptoethyl Carboxylate as Raw Materials for Polyvinyl Chloride Thermal Stabilizer: Variation in Fatty Acid Source. Mercaptoethyl carboxylate is a raw material for organotin-based polyvinyl chloride (PVC) thermal stabilizer. Thermal stabilizers need to be added to the PVC resin before extruded to prevent degradation due to heat treatment. Organotin PVC stabilizers are known to be very effective, especially for rigid PVC applications such as pipes and frames. This study was aimed to evaluate the synthesis of mercaptoethyl carboxylate from fatty acids and mercaptoethanol with various sources of fatty acids including palm, rice bran and kapok seed fatty acids. The experiment was carried out in a batch reactor with a strong acid as a catalyst. The experiments were conducted at 60-80°C and 10% mercapto ethanol excess. The performance of synthesis was evaluated by measuring mercaptan and acid contents and yield. In the range of 60-80°C, all three fatty acids provided products with mercaptan levels in the range of 6.4-7.8%. A temperature of 70°C is the best temperature as it gave a product with the highest mercaptan content without solidification during storage. At this temperature, the product had acid values in the range 11-41 mg KOH/g and yields in the range of 70-81%. Considering product quality and availability in the market, palm fatty acid distillate was seen as the best raw material. Keywords: fatty acid, mercaptoethyl carboxylate, polyvinyl chloride, thermal stabilizer. Graphical Abstract

scholarly journals Sustainable products in the leather industry

2020 ◽  
Author(s):  
Olga Ballus ◽  
Anna Bacardit
Keyword(s):  
Carbon Footprint ◽  
Raw Materials ◽  
Raw Material ◽  
Low Carbon ◽  
Leather Industry ◽  
Material Content ◽  
Sustainable Products ◽  
Short Lifespan ◽  
Renewable Raw Material ◽  
Lower Carbon

Protecting the environment is one of the three objectives of sustainability. One way to achieve this is to preserve natural resources by using renewable or residual raw materials. These products have a shorter lifespan and a lower carbon footprint, are highly biodegradable, and are therefore considered to be sustainable products. In this paper, three retanning agents and two oils classified as sustainable products were studied. First, biobased carbon content (an indicator of renewable raw material content) was determined. Then, the physical and organoleptic properties of the leathers treated with each product (degree of softness, firmness and fullness) were evaluated. The COD of residual baths was also determined in oils. The products presented in this paper meet the sustainability requirements, i.e., high renewable raw material content, short lifespan, and low carbon footprint. In addition, these products show high fixation and therefore have a low COD in residual baths, thus also contributing to their sustainability.

scholarly journals Miscanthus plants processing in fuel, energy, chemical and microbiological industries

2019 ◽  
pp. 403-411
Author(s):  
Olga Babich ◽  
Olga Krieger ◽  
Evgeny Chupakhin ◽  
Oksana Kozlova
Keyword(s):  
Alternative Energy ◽  
Plant Biomass ◽  
Raw Materials ◽  
Hydrocarbon Fuel ◽  
Raw Material ◽  
Biomass Combustion ◽  
Alternative Energy Sources ◽  
Miscanthus Giganteus ◽  
Renewable Raw Material ◽  
Physical And Chemical

The increasing shortage of fossil hydrocarbon fuel dictates the need to search for and develop alternative energy sources, including plant biomass. This paper is devoted to the study of the Miscanthus plants biomass potential and the analysis of technologies of its processing into products targeted at bioenergy, chemistry, and microbiology. Miscanthus is a promising renewable raw material to replace wood raw materials for the production of chemical, fuel, energy, and microbiological industries. Miscanthus is characterised by highly productive (up to 40 tons per one hectare of dry matter) C4-photosynthesis. Dry Miscanthus contains 47.1–49.7% carbon, 5.38–5.92% hydrogen, and 41.4–44.6% oxygen. The mineral composition includes K, Cl, N and S, which influence the processes occurring during biomass combustion. The total amount of extractives per dry substance lies in the range of 0.3–2.2 % for different extraction reagents. Miscanthus has optimal properties as an energy source. Miscanthus × giganteus pellets showed the energy value of about 29 kJ/g. For the bioconversion of plants into bioethanol, it is advisable to carry out simultaneous saccharification and fermentation, thus reducing the duration of process steps and energy costs. Miscanthus cellulose is of high quality and can be used for the synthesis of new products. Further research will focus on the selection of rational parameters for processing miscanthus biomass into products with improved physical and chemical characteristics: bioethanol, pellets, industrial cellulose, bacterial cellulose, carbohydrate substrate.

The Development of Composite Building Product and its Fire Technical Characteristics

2014 ◽  
Vol 1001 ◽  
pp. 368-372
Author(s):  
Miroslava Netopilová ◽  
Jan Mikulenka ◽  
Anna Benešová
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Industrial Waste ◽  
Raw Materials ◽  
Raw Material ◽  
Waste Materials ◽  
Building Industry ◽  
Building Product ◽  
Material Resources ◽  
Renewable Raw Material

The article focuses on the research and development of a new composite material applicable in building industry, renewable raw material resources and industrial waste materials. The aim of the research is not only the application of concrete secondary raw materials but also the gaining of required safety aspects of these composite materials, i.e. certain fire technical characteristics.

scholarly journals Development of Innovative Polyol Systems From Recycled Polyethylene Terephthalate and Renewable Raw Materials for Rigid Polyurethane Foams

2020 ◽  
Author(s):  
◽  
Aiga Ivdre
Keyword(s):  
Raw Materials ◽  
Polyurethane Foams ◽  
Raw Material ◽  
Insulation Material ◽  
Recycled Pet ◽  
Renewable Raw Materials ◽  
Material Resources ◽  
Pu Foam ◽  
Renewable Raw Material ◽  
Pu Foams

The Thesis aims to develop innovative polyols suitable for the production of rigid PU foam from recycled PET flakes and renewable raw material resources (rapeseed oil and tall oil) and to evaluate the effect of polyols on the most important properties of rigid PU foams as a thermal insulation material.

scholarly journals Calcium soap from palm fatty acid distillate for ruminant feed: Ca(OH)2 as calcium source

2018 ◽  
Vol 159 ◽  
pp. 02062
Author(s):  
Lienda A. Handojo ◽  
Antonius Indarto ◽  
Dian Shofinita ◽  
Anggina Meitha ◽  
Rakhmawati Nabila ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Water Temperature ◽  
Raw Materials ◽  
Acid Value ◽  
Raw Material ◽  
Calcium Soap ◽  
Calcium Source ◽  
Soap Production ◽  
Ruminant Feed

PFAD can be utilized as raw material for producing calcium soap, a kind of ruminant feed supplement. It gives benefits to the ruminants’ health and increases the quantity and quality of cattle’s milk. This research evaluated the effect of stoichiometric mole ratio of Ca(OH)2 to PFAD and water temperature on calcium soap production using PFAD and calcium hydroxide as raw materials by applying modified fusion method. The result showed that the acid value of products decreased as the mole ratio of Ca(OH)2 to PFAD increased and the low water temperature lowered the acid value of products. The highest fatty acid conversion (98%) was achieved at the stoichiometric mole ratio of 3. However, the use of such high mole ratio is not preferable because the product will have excessive calcium, which may disturb the absorption of other minerals in ruminant’s digestion. Thus, further research related to operating condition and the use of other calcium sources in the calcium soap production is still required.

scholarly journals The use of bio-efficient plant materials to optimize the fatty acid composition of poultry terrins

2021 ◽  
Vol 30 ◽  
pp. 01014
Author(s):  
Nadezhda Popova ◽  
Yuliya Pisklyukova ◽  
Viktoriya Orlova
Keyword(s):  
Fatty Acid ◽  
Raw Materials ◽  
Raw Material ◽  
Poultry Meat ◽  
Biological Efficiency ◽  
Omega 3 ◽  
Plant Materials ◽  
Poultry Products ◽  
Wide Range ◽  
Omega 6

The development of functional products characterized by high biological efficiency is an urgent task. The article presents the results of the development of balanced-fatty acid terrins from poultry meat. To increase the biological effectiveness of chopped products, raw materials containing omega-3 and omega-6 polyunsaturated fatty acids (PUFAs) were selected. Based on the analysis of the chemical composition of the raw material kit, the intervals for the Introduction of ingredients containing biologically effective components are calculated. Their optimum amount has been experimentally established. The resulting innovative products are characterized by a balanced composition in terms of content and ratio of omega-3 and omega-6 PUFAs. In addition, the value of the indicator of biological value has increased. Developed poultry terrins can be recommended both for a wide range of consumers, and for use in diet (including low-carb diets), baby food. The developed terrines will expand the range of chopped poultry products of functional orientation.

scholarly journals Chemical and bioactive properties of the oils from Brazilian nuts

2020 ◽  
Vol 19 (2) ◽  
pp. 180-186
Author(s):  
Tainara Costa ◽  
Carolina Médici Veronezi ◽  
Neuza Jorge
Keyword(s):  
Fatty Acid Composition ◽  
Fatty Acid ◽  
Acid Composition ◽  
Raw Materials ◽  
Raw Material ◽  
Total Carbohydrate ◽  
Total Carotenoids ◽  
Bioactive Substances ◽  
Lipid Fractions

This paper aims to determine the content of bioactive substances of lipid fractions extracted from Bertholletia excelsa, Lecythis pisonis and Dipteryx lacunifera, in by the interest of better identifying the quality of these raw materials. Proximate composition of nuts was determined by official methods and total carbohydrate was calculated by difference. The oils were extracted from the nuts by cold pressing and analyzed for fatty acid composition, tocopherols, phytosterols and total carotenoids and phenolics compounds. The fatty acid composition of oil extracted from L. pisonis was more unsaturated compared with others oils. L. pisonis oil showed to be richer in total tocopherol and γ-tocopherol, moreover showed considerable total phytosterol and carotenoid amounts, thus representing an important source of vitamins A and E. The oils showed significant content of phenolic compounds, with the exception of the oil extracted from D. lacunifera. The study revealed that the oils from Brazilian nuts contain bioactive compounds in relevant quantities, L. pisonis oil standing out. This fact favors their use for food and, as raw material in chemical, pharmaceutical and cosmetic industries, adding value to products derived from these oils, increasing the viable sources of raw materials.

scholarly journals Thread Rolling: An Efficient Mechanical Pretreatment for Corn Stover Saccharification

Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 542
Author(s):  
Likang Deng ◽  
Jun Li
Keyword(s):  
Fourier Transform ◽  
Enzymatic Hydrolysis ◽  
Raw Materials ◽  
Sugar Cane Bagasse ◽  
Raw Material ◽  
X Rays ◽  
Mechanical Pretreatment ◽  
Thread Rolling ◽  
Ft Ir ◽  
Scanning Electron

Sugar cane bagasse and corn stalks are rich in lignocellulose, which can be degraded into monosaccharides through enzymatic hydrolysis. Appropriate pretreatment methods can effectively improve the efficiency of lignocellulose enzymatic hydrolysis. To enhance the efficiency of enzymatic hydrolysis, thread rolling pretreatment as a physical pretreatment was applied in this study. The influence of raw material meshes size after pretreatment was also taken as the research target. Specific surface area analysis, Scanning electron microscope (SEM), X-rays diffraction (XRD), and Fourier transform infrared (FT-IR) were used for characterizations. The results showed that, the total monosaccharide recovery rates of the raw materials, 20–40 mesh, 40–60 mesh, and 60–80 mesh enzymolysis substrates were 17.6%, 34.58%, 37.94%, and 50.69%, respectively. The sample after pretreatment showed a better recovery of monosaccharide than that of the raw material. Moreover, the enzymolysis substrates with a larger mesh exhibited a higher recovery of monosaccharide than that of the enzymolysis substrates with smaller meshes. This indicated that thread rolling pretreatment can effectively improve the efficiency of enzymatic hydrolysis.

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