scholarly journals RESEARCH OF PROPERTIES, STRUCTURAL FEATURES AND TECHNOLOGICAL POSSIBILITIES OF NEW POLYMERIC MATERIALS FOR FILLING-RETANNING OF LEATHER

2021 ◽  
Vol 297 (3) ◽  
pp. 162-167
Author(s):  
OLGA ANDREYEVA ◽  
NATALIIA PERVAIA ◽  
INNA LOSHKAREVA ◽  
NATALIA CHUMAKOVA ◽  
Keyword(s):  
Raw Materials ◽  
Inorganic Compounds ◽  
Polymeric Materials ◽  
Structural Features ◽  
Polymer Materials ◽  
Melamine Formaldehyde ◽  
Sulfur Silicon ◽  
Oh Groups ◽  
Positive Effect

The paper presents the results of research of two new industrial polymer materials in the form of the Syntan RS3L product and the Syntan F187 product. It has been experimentally established that these materials differ in appearance, structure, and physicochemical properties. So, the first product is a solution of polyacrylates and is well compatible with water, while the second product is a synthetic composition of melamine-formaldehyde resins and inorganic compounds based on aluminium, iron, potassium, sulfur, silicon in the form of a powder, which is partially soluble in water. Using the method of infrared spectroscopy, the features of the structure of polymeric materials are determined – the presence of various groups and bonds, which indicates the polyfunctional nature of both reagents. It was found that after treatment of a chrome tanned collagen preparation with Syntan LF187, the optical density in the IR spectrum of collagen changes to the greatest extent at a frequency of 876-873 cm-1, which corresponds to stretching vibrations of O-O groups of peroxides in the protein structure. When exposed to the Syntan RS3 product, significant changes are observed in the frequency range 1240-1235 cm-1, which corresponds to the stretching and deformation vibrations of the nitrogen-containing Amide II groups, amines and OH groups of alcohols. When studying the technological capabilities of polymeric materials as reagents for filling and retanning chrome tanned leather for shoe uppers from cattle raw materials, it was found that, according to the organoleptic assessment and the indicator of the generalized objective function, the best were leather samples processed with 2.0 % of the Syntan RS3 product. The results obtained can be explained by the peculiarities of the distribution and interaction of materials in the structure of the dermis, the essence of which is the formation of strong and at the same time flexible bonds, which has a positive effect on the formation of the structure and quality indicators of leather. To confirm the obtained data, it is planned to conduct semi-production tests. It is expected that the quality of the finished product will improve, and the existing vegetable and synthetic tanning agents will be replaced with a modern, more efficient and environmentally friendly polymer material.

Mechanical Properties of Irradiated Polyamide under Thermal Stress

2016 ◽  
Vol 368 ◽  
pp. 178-181 ◽  
Author(s):  
Martin Bednarik ◽  
David Manas ◽  
Miroslav Maňas ◽  
Ales Mizera ◽  
Vojtech Šenkeřík
Keyword(s):  
Mechanical Properties ◽  
Raw Materials ◽  
Glass Fibers ◽  
Chemical Properties ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
Beam Radiation ◽  
Manufactured Products ◽  
Radiation Crosslinking ◽  
Positive Effect

It was found in this study, that radiation crosslinking has a positive effect on the mechanical properties of selected type polyamide. In recent years, there have been increasing requirements for quality and cost effectiveness of manufactured products in all areas of industrial production. These requirements are best met with the polymeric materials, which have many advantages in comparison to traditional materials. The main advantages of polymer materials are especially in their ease of processability, availability, and price of the raw materials. Radiation crosslinking is one of the ways to give the conventional plastics mechanical, thermal, and chemical properties of expensive and highly resistant construction polymers. The main purpose of this paper has been to determine the effect of radiation crosslinking on the tensile strength and elongation of PA 66 (filled with 30 % glass fibers). These properties were examined in dependence on the dosage of the ionizing electron beam radiation (non-irradiated samples and those irradiated by dosage 66 and 132 kGy were compared) and on the test temperature (23, 50, 80, and 110 oC). Radiation cross-linking of PA 66 results in increased mechanical strength, and decreased of elongation. As an addition, the increased surface microhardness of polyamide was found.

scholarly journals Recent Advances in Fabrication of Non-Isocyanate Polyurethane-Based Composite Materials

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3497
Author(s):  
Piotr Stachak ◽  
Izabela Łukaszewska ◽  
Edyta Hebda ◽  
Krzysztof Pielichowski
Keyword(s):  
Raw Materials ◽  
Synthesis Method ◽  
Polymeric Materials ◽  
Original Research ◽  
Significant Group ◽  
Oh Groups ◽  
New Class ◽  
Hazardous Chemical ◽  
Wide Range

Polyurethanes (PUs) are a significant group of polymeric materials that, due to their outstanding mechanical, chemical, and physical properties, are used in a wide range of applications. Conventionally, PUs are obtained in polyaddition reactions between diisocyanates and polyols. Due to the toxicity of isocyanate raw materials and their synthesis method utilizing phosgene, new cleaner synthetic routes for polyurethanes without using isocyanates have attracted increasing attention in recent years. Among different attempts to replace the conventional process, polyaddition of cyclic carbonates (CCs) and polyfunctional amines seems to be the most promising way to obtain non-isocyanate polyurethanes (NIPUs) or, more precisely, polyhydroxyurethanes (PHUs), while primary and secondary –OH groups are being formed alongside urethane linkages. Such an approach eliminates hazardous chemical compounds from the synthesis and leads to the fabrication of polymeric materials with unique and tunable properties. The main advantages include better chemical, mechanical, and thermal resistance, and the process itself is invulnerable to moisture, which is an essential technological feature. NIPUs can be modified via copolymerization or used as matrices to fabricate polymer composites with different additives, similar to their conventional counterparts. Hence, non-isocyanate polyurethanes are a new class of environmentally friendly polymeric materials. Many papers on the matter above have been published, including both original research and extensive reviews. However, they do not provide collected information on NIPU composites fabrication and processing. Hence, this review describes the latest progress in non-isocyanate polyurethane synthesis, modification, and finally processing. While focusing primarily on the carbonate/amine route, methods of obtaining NIPU are described, and their properties are presented. Ways of incorporating various compounds into NIPU matrices are characterized by the role of PHU materials in copolymeric materials or as an additive. Finally, diverse processing methods of non-isocyanate polyurethanes are presented, including electrospinning or 3D printing.

scholarly journals Use of by-products of millet, amaranth and sorghum grains in bakery production

2020 ◽  
Vol 17 ◽  
pp. 00047
Author(s):  
A.V. Volkova ◽  
A. V. Kazarina ◽  
O. N. Antimonova ◽  
Yu. Yu. Nikonorova ◽  
E. A. Atakova
Keyword(s):  
Wheat Flour ◽  
Raw Materials ◽  
Bakery Products ◽  
Systematic Analysis ◽  
Composite Mixture ◽  
Biotechnological Processes ◽  
Processed Products ◽  
Cereal Industry ◽  
Positive Effect

The use of additional gluten-free grain raw materials in the form of flour or secondary raw materials of cereal industry in the recipes of bakery products allows regulating the biotechnological processes of dough maturing and proofing, obtaining a finished product with new functional properties and high nutritional value. The purpose of the research is to justify experimentally the use of processed products of amaranth grain and sorghum for the production of bread of high quality and functionality. The methodological basis of the study is presented by a systematic analysis of the technology for the production of bakery products enriched with promising phyto-fortifiers. In accordance with the chosen methodology, the chemical composition is analyzed and the positive effect of the use of flour from millet grain, sorghum and amaranth seeds in the mixture with premium wheat flour on the quality of bread is experimentally justified. It was found that the introduction of these types of additional raw materials had a positive effect on the activation of baking yeast and the maturation of dough. In the production of bread from wheat flour of the highest grade, it is optimal to use these phyto-fortifiers in the amount of 3% by weight of the composite mixture.

scholarly journals Synthesis and Characterization of a Lignin-Styrene-Butyl Acrylate Based Composite

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1080
Author(s):  
Daniel López Serna ◽  
Perla Elizondo Martínez ◽  
Miguel Ángel Reyes González ◽  
Antonio Alberto Zaldívar Cadena ◽  
Erasto Armando Zaragoza Contreras ◽  
...  
Keyword(s):  
Contact Angle ◽  
Butyl Acrylate ◽  
Raw Materials ◽  
Positive Influence ◽  
Polymer Chains ◽  
Polymer Materials ◽  
Polymerization Process ◽  
Oh Groups ◽  
Water Measurement

In recent years, the pursuit of new polymer materials based on renewable raw materials has been intensified with the aim of reusing waste materials in sustainable processes. The synthesis of a lignin, styrene, and butyl acrylate based composite was carried out by a mass polymerization process. A series of four composites were prepared by varying the amount of lignin in 5, 10, 15, and 20 wt.% keeping the content of butyl acrylate constant (14 wt.%). FTIR and SEM revealed that the –OH functional groups of lignin reacted with styrene, which was observed by the incorporation of lignin in the copolymer. Additionally, DSC analysis showed that the increment in lignin loading in the composite had a positive influence on thermal stability. Likewise, Shore D hardness assays exhibited an increase from 25 to 69 when 5 and 20 wt.% lignin was used respectively. In this same sense, the contact angle (water) measurement showed that the LEBA15 and LEBA20 composites presented hydrophobic properties (whit contact angle above 90°) despite having the highest amount of lignin, demonstrating that the interaction of the polymer chains with the –OH groups of lignin was the main mechanism in the composites interaction.

scholarly journals Development of technology for macaroni products based on flour of grain crops and ion-zoned water

2021 ◽  
Vol 1 (11 (109)) ◽  
pp. 51-60
Author(s):  
Meruyet Baiysbayeva ◽  
Galiya Iskakova ◽  
Assel Izembayeva ◽  
Nurgul Batyrbayeva ◽  
Fatima Dikhanbayeva ◽  
...  
Keyword(s):  
Nutritional Value ◽  
Raw Materials ◽  
Food Additives ◽  
Ion Concentration ◽  
Corn Flour ◽  
Biological Value ◽  
Concentration Of Ions ◽  
Amaranth Flour ◽  
Positive Effect

The nutritional value of food is one of the most important factors that determine the health of the population. In the macaroni market, dietary and functional products, fortified macaroni products and products of high nutritional value occupy a small segment that does not exceed 1 %. In this regard, the development of an assortment of pasta with increased nutritional value, with a directionally changed chemical composition, is relevant. In the pasta industry, an increase in the nutritional and biological value of products is achieved through the introduction of non-traditional types of raw materials and special food additives into the recipe. To reduce the deteriorating effect of corn and amaranth flour on the pasta properties of flour from durum wheat, ionized water was used with a concentration of ions of 1,000, 2,000, 3,000, 4,000 units/cm3 and ozone of 2 mg/l. It was found that ionized water has a positive effect on the properties of gluten and the quality of pasta with the addition of corn and amaranth flour. It was determined that the best quality of pasta is achieved when using ionized water with an ion concentration of 3,000 units/cm3 and ozone 2 mg/l and at dosages of amaranth flour 17.5 %, corn flour – 20 % to pasta flour. Summing up the results of the experimental study, the amount of prescription components for the production of pasta with high nutritional and biological value was optimized

scholarly journals An Overview of the Main Trends in the Creation of Biodegradable Polymer Materials

2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Irina N. Vikhareva ◽  
Evgeniya A. Buylova ◽  
Gulnara U. Yarmuhametova ◽  
Guliya K. Aminova ◽  
Aliya K. Mazitova
Keyword(s):  
Raw Materials ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
New Approach ◽  
Renewable Raw Materials ◽  
Biodegradable Composite ◽  
Operational Characteristics ◽  
Technical Solutions ◽  
Further Development ◽  
Degradation Time

Plastic is one of the most demanded materials on the planet, and the increasing consumption of which contributes to the accumulation of significant amounts of waste based on it. For this reason, a new approach to the development of these materials has been formed: the production of polymers with constant operational characteristics during the period of consumption and capable of then being destroyed under the influence of environmental factors and being involved in the metabolic processes of natural biosystems. The paper outlines the prerequisites for the development of the field of creating biodegradable composite materials, as well as the main technical solutions for obtaining such polymeric materials. The main current solutions for reducing and regulating the degradation time of polymer materials are presented. The most promising ways of further development of the field of bioplastics production are described. Common types of polymers based on renewable raw materials, composites with their use, and modified materials from natural and synthetic polymers are considered.

scholarly journals Statistical prediction of biogas and methane yields during anaerobic digestion based on the composition of lignocellulosic biomass

BioResources ◽  
2021 ◽  
Vol 16 (4) ◽  
pp. 7086-7100
Author(s):  
Agata Stachowiak–Wencek ◽  
Jan Bocianowski ◽  
Hanna Waliszewska ◽  
Sławomir Borysiak ◽  
Bogusława Waliszewska ◽  
...  
Keyword(s):  
Anaerobic Digestion ◽  
Crystalline Structure ◽  
Raw Materials ◽  
Statistical Prediction ◽  
Degree Of Crystallinity ◽  
Oh Groups ◽  
X Ray Scattering ◽  
Independent Features ◽  
The Degree Of Crystallinity

In the described study, the relationships between the percentage and structure of selected lignocellulosic components and the efficiency of their anaerobic digestion and the quality of the produced biogas were analyzed. This research included various lignocellulosic raw materials. The biogas efficiency and quality tests were carried out according to DIN standard 38 414-8 (1985) and VDI standard 4630 (2016). Multiple TAPPI standards and the Seifert method were used to determine the chemical composition of the lignocellulose materials. Lignin structure analysis was performed using Fourier transform infrared spectroscopy. Wide-angle X-Ray scattering analysis was used to determine the degree of crystallinity of cellulose. The biogas was positively correlated with C=O and the syringyl to guaiacyl ratio, and negatively correlated with the crystalline structure of cellulose, lignin, cellulose, and extractives. In addition, methane was positively correlated with holocellulose and extractives and negatively correlated with the crystalline structure of cellulose, cellulose, substances soluble in NaOH, and the OH groups. The found independent features accounted for 86.0% of the biogas variability and 68.0% of the methane variability.

scholarly journals Transition to biodegradable composites as a method for solving environmental problems

2020 ◽  
Vol 221 ◽  
pp. 01004
Author(s):  
Gulnaz Sabirova ◽  
Ruslan Safin ◽  
Shamil Mukhametzyanov ◽  
Nour Galyavetdinov
Keyword(s):  
Composite Materials ◽  
Impact Strength ◽  
Negative Impact ◽  
Positive Impact ◽  
Raw Materials ◽  
Polymeric Materials ◽  
Thermal Modification ◽  
Polymer Materials ◽  
Necessary Condition ◽  
Plant Raw Materials

In environmental matters, one of the most pressing problems is the efficient disposal of polymeric materials that have a negative impact on the ecology of soils and oceans. A necessary condition for the sustainable development of industrial production and processing of polymer products is the transition to polymer materials based on renewable plant raw materials, in particular polylactides, polyhydroalkanates, etc. However, the technology for the production of these types of polymers is seriously inferior to synthetic polymers in the field of energy engineering. In this regard, research in the field of creating composite materials by introducing wood filler is currently particularly relevant. This research covers the results of stress-strain behavior of wood filled polylactic wood powder composite materials thermally modified by high temperatures ranged from 200 to 240 °С. Wood impact strength dependence is defined and static bending and composite density dependence on wood filler quantity and the temperature of its thermal modification is also established. It was specified that with the increasing of filler densification and its thermal treatment, the wood impact strength and composite density is decreasing, while with the reduced content of binding, the thermal modification of 200 °С has a positive impact on bending elastic coefficient. The conducted research allows identifying rational areas of use of composite materials as an effective factor in managing natural resources.

scholarly journals Biodegradable polymer materials and modifying additives: state of the art. Part I

2020 ◽  
Vol 12 (6) ◽  
pp. 320-325
Author(s):  
I.N. Vikhareva ◽  
I.I. Zaripov ◽  
D.F. Kinzyabulatova ◽  
N.S. Minigazimov ◽  
G.K. Aminova
Keyword(s):  
Biodegradable Polymers ◽  
Raw Materials ◽  
Optimal Solution ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
New Approach ◽  
Factors Analysis ◽  
Current State ◽  
Production Capacities ◽  
Further Development

One of the most demanded materials on the planet is plastic, the excellent performance of which contributes to the accumulation of a significant amount of waste on its basis. In this regard, a new approach to the development of these materials has been formed in scientific circles: the production of polymer composites with constant performance characteristics for a certain period and then capable of destruction under the influence of environmental factors. Analysis of the current state of the industry of polymeric materials shows that the most urgent is the use of such classical polymers as polyolefins and polyvinyl chloride. First of all, the optimal solution to this problem due to the lack of a suitable replacement for traditional polymers is the development of composites based on them with the use of biodegradable additives. In this case, a set of problems associated with waste disposal is solved: the decomposition period of the recycled waste is significantly reduced, the territories required for plastic waste are reduced. The paper outlines the preconditions for the emergence and further development of the field of biodegradable polymers. The main quantitative characteristics of the production capacities of manufactured bioplastics by types, regions and industries of application are given. Modern methods of reducing and regulating the degradation time of polymer materials are presented. The main global and domestic manufacturers of biodegradable polymers and their products are listed, as well as a list of the main manufacturers of biodegradable additives for polymeric materials. Modern types of bioplastics based on renewable raw materials, composites with their use, as well as modified materials from natural and synthetic polymers are listed. The main methods for determining the biodegradability of existing bioplastics are described

scholarly journals Effective chemical methods of fire control: new threats and new solutions

2019 ◽  
Vol 89 (5) ◽  
pp. 442-448
Author(s):  
S. D. Varfoloveev ◽  
S. M. Lomakin ◽  
P. A. Sakharov ◽  
A. V. Khvatov
Keyword(s):  
Flame Retardant ◽  
Flame Retardants ◽  
Raw Materials ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
The Novel ◽  
Fire Control ◽  
Renewable Raw Materials ◽  
New Type ◽  
Intumescent Flame Retardants

This paper discusses the prospective flame retardant systems for polymeric materials, while considering the environmental issues they create. Polymer nanocomposites with carbon nano-additives and layered silicates are presented as a new type of flame retardant system which exhibits a synergistic effect flame retardancy for traditional polymer thermoplasts. Particular attention is paid to the novel intumescent flame retardants based on the oxidized renewable raw materials, which can be successfully used in the manufacture of multi-purpose timber construction and polymer materials.

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