scholarly journals Impact of Elevated Temperatures on Strength Properties and Microstructure of Calcium Sulfoaluminate Paste

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6751
Author(s):  
Konrad A. Sodol ◽  
Łukasz Kaczmarek ◽  
Jacek Szer ◽  
Sebastian Miszczak ◽  
Mariusz Stegliński

This article is motivated by civil fire safety. Fire-prevention engineering demands a wide range of information about building materials including alternative cements, for instance CSA-cement. Because of exposure of the cement-base material to a high temperature, its strength properties deteriorate due to dehydration connected with phase and microstructure changes. Previous research indicated that the main endothermic reaction of CSA-based composite, dehydration of ettringite, might be used as a cooling system for a metal structure during fire-load. This article examines visual assessment, microstructure, density, as well as flexural and compressive strength parameters of CSA-based composite after isothermal heating at temperatures from 23 °C to 800 °C. The results of SEM/EDS investigations showed that the calcium sulfoaluminate paste may start partially re-sintering above 600 °C. Mechanical tests revealed significant reduction of strength parameters but residual compressive strength was maintained in the whole temperature range e.g., 8 MPa at 800 °C. Additionally, visual assessment of the specimens indicated that it might be possible to predict the material temperature heating based on the specific surface color. These findings add to the evidence of general knowledge about CSA hydrates.

Buildings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 82
Author(s):  
Salmabanu Luhar ◽  
Demetris Nicolaides ◽  
Ismail Luhar

Even though, an innovative inorganic family of geopolymer concretes are eye-catching potential building materials, it is quite essential to comprehend the fire and thermal resistance of these structural materials at a very high temperature and also when experiencing fire with a view to make certain not only the safety and security of lives and properties but also to establish them as more sustainable edifice materials for future. The experimental and field observations of degree of cracking, spalling and loss of strength within the geopolymer concretes subsequent to exposure at elevated temperature and incidences of occurrences of disastrous fires extend an indication of their resistance against such severely catastrophic conditions. The impact of heat and fire on mechanical attributes viz., mechanical-compressive strength, flexural behavior, elastic modulus; durability—thermal shrinkage; chemical stability; the impact of thermal creep on compressive strength; and microstructure properties—XRD, FTIR, NMR, SEM as well as physico-chemical modifications of geopolymer composites subsequent to their exposures at elevated temperatures is reviewed in depth. The present scientific state-of-the-art review manuscript aimed to assess the fire and thermal resistance of geopolymer concrete along with its thermo-chemistry at a towering temperature in order to introduce this novel, most modern, user and eco-benign construction materials as potentially promising, sustainable, durable, thermal and fire-resistant building materials promoting their optimal and apposite applications for construction and infrastructure industries.


2010 ◽  
Vol 168-170 ◽  
pp. 709-715
Author(s):  
Dongsik Oh ◽  
Doheom Song ◽  
Seongseok Go

Hwangtoh (loess) has pozzolanic properties that mean it can be used as a cement admixture when activated at high temperatures, and that it can be used in combination with building materials such as fly ash or blast furnace slag. This study aimed to analyze the relationship between the compressive strength and the brick bond strength of various mortars containing hwangtoh, and also to find the optimum mixing conditions for the use of hwangtoh. It was found that the mortars’ strength properties are significantly influenced by the water/cement ratio W/C and the activated hwangtoh substitution ratio. We recommend the following materials and mixing conditions: W/C 60%, a cement substitution ratio of activated hwangtoh of 20 ~ 25%, and the addition of 10% blast furnace slag to improve the compressive strength of such mortars.


2020 ◽  
Vol 992 ◽  
pp. 253-258
Author(s):  
M.P. Lebedev ◽  
V.N. Tagrov ◽  
E.S. Lukin

The article deals with the manufacture of modern structural ceramic materials from clay and loam deposits of the Republic of Sakha (Yakutia). The importance and relevance of the development of the production of building materials from local raw materials is emphasized, since this will certainly affect the effectiveness of the construction complex as a whole. The successful development of the construction complex is capable of not only stimulating growth in all sectors of the economy, but also contributes to solving the most pressing social problems. Today, Yakutia has huge reserves of mineral raw materials for the production of a wide range of building materials and products. Of practical interest are wall materials made from clay soils. Given the features of the region’s raw material base, this work focuses on additional processing of traditional material. Controlling the complex physicochemical and structural-mechanical transformations that occur during heat treatment, a methodology has been developed for creating a composite material that will allow competitive innovative materials with enhanced strength properties to be produced with a reinforcing element with a glassy phase matrix of mullite crystals. The fabricated samples have a wide range of physical and mechanical properties and allow using it as a high-quality structural building ceramics, as well as industrial floor technical tile.


2013 ◽  
Vol 824 ◽  
pp. 86-90 ◽  
Author(s):  
B. Adebayo ◽  
A.E. Aladejare

The effect of rock properties on excavation-loading operation in quarries was investigated by conducting test on the mechanical properties of selected rocks. These rock samples were tested in the laboratory for specific gravity, point load strength, uniaxial compressive strength and mineral composition using weigh balance, point load tester, 1100kN compression machine and petrological microscope respectively. The filling rates of the front end loaders bucket were determined. The result obtained show that value of uniaxial compressive strength varied from 29.22 MPa-30.87 MPa. The bucket filling rate varied from 0.180-0.250 m3/s and 0.145-0.170 m3/s for porphyritic biotite granite and coarse biotite granite respectively. There is strong relationship between bucket filling rate and strength properties with values of R2 ranging from 0.9737 to 0.9981.Therefore strength parameters of the rock have effect on excavation loading operation in quarries.


Author(s):  
Shakir Hussain

Abstract: Polymer waste volumes have surged in recent years as a result of growing industrialization and fast improvements in living standards. In Malaysia, the majority of polymer waste is discarded rather than recycled. This circumstance results in major issues such as waste of natural resources and pollution of the environment. Polymer products, such as synthetic fibres, plastics, and rubber, are petrochemical compounds that disintegrate slowly in nature. Even after a long amount of time, plastic materials are not easily biodegradable. In reality, a wide range of waste materials can be used as a cement matrix inert. For the manufacture of the polymer concrete, trash bag plastics were employed as polymer wastes HDPE in this study (PC). The purpose of this research is to investigate the characteristics and characterisation of polymer HDPE as a coarse aggregate replacement in concrete. Temperatures of 160°C, 170°C, 180°C, 190°C, and 200°C were used in the heating procedure. By volumetric approach, five compositions of coarse aggregate with varied crushed stone: HDPE waste ratios of 0:100, 15:85, 30:70, 45:55, and 60:40 were utilised. The use of polymerwaste as coarse aggregate in traditional concrete was examined. With fresh and hardened concrete tests, the effects of polymer wastes on the workability and strength of the concrete were investigated. After 28 days, the compressive strength of the PCwas determined to be suitable for nonstructural use. The findings of the cost research revealed that the PC is more cost effective than traditional concrete. Keywords: Polymer Wastes HDPE; Coarse Aggregate; Compressive Strength; Properties


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6890
Author(s):  
Muhammad Ibraheem ◽  
Faheem Butt ◽  
Rana Muhammad Waqas ◽  
Khadim Hussain ◽  
Rana Faisal Tufail ◽  
...  

The purpose of this research is to study the effects of quarry rock dust (QRD) and steel fibers (SF) inclusion on the fresh, mechanical, and microstructural properties of fly ash (FA) and ground granulated blast furnace slag (SG)-based geopolymer concrete (GPC) exposed to elevated temperatures. Such types of ternary mixes were prepared by blending waste materials from different industries, including QRD, SG, and FA, with alkaline activator solutions. The multiphysical models show that the inclusion of steel fibers and binders can enhance the mechanical properties of GPC. In this study, a total of 18 different mix proportions were designed with different proportions of QRD (0%, 5%, 10%, 15%, and 20%) and steel fibers (0.75% and 1.5%). The slag was replaced by different proportions of QRD in fly ash, and SG-based GPC mixes to study the effect of QRD incorporation. The mechanical properties of specimens, i.e., compressive strength, splitting tensile strength, and flexural strength, were determined by testing cubes, cylinders, and prisms, respectively, at different ages (7, 28, and 56 days). The specimens were also heated up to 800 °C to evaluate the resistance of specimens to elevated temperature in terms of residual compressive strength and weight loss. The test results showed that the mechanical strength of GPC mixes (without steel fibers) increased by 6–11%, with an increase in QRD content up to 15% at the age of 28 days. In contrast, more than 15% of QRD contents resulted in decreasing the mechanical strength properties. Incorporating steel fibers in a fraction of 0.75% by volume increased the compressive, tensile, and flexural strength of GPC mixes by 15%, 23%, and 34%, respectively. However, further addition of steel fibers at 1.5% by volume lowered the mechanical strength properties. The optimal mixture of QRD incorporated FA-SG-based GPC (QFS-GPC) was observed with 15% QRD and 0.75% steel fibers contents considering the performance in workability and mechanical properties. The results also showed that under elevated temperatures up to 800 °C, the weight loss of QFS-GPC specimens persistently increased with a consistent decrease in the residual compressive strength for increasing QRD content and temperature. Furthermore, the microstructure characterization of QRD blended GPC mixes were also carried out by performing scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS).


2013 ◽  
Vol 2013 ◽  
pp. 1-5
Author(s):  
Ping Wang ◽  
Dong-yan Liu

The increasing amount of waste residue produced during the electrolytic preparation process of manganese has nowadays brought about serious environmental problems. The research on utilization of manganese slag has been a hot spot around the world. The utilization of manganese slag is not only environment friendly, but also economically feasible. In the current work, a summarization of the main methods to produced building materials from manganese slag materials was given. Baking-free brick, a promising building material, was produced from manganese slag with the addition of quicklime and cement. The physical properties, chemical composition, and mechanical performances of the obtained samples were measured by several analyses and characterization methods. Then the influence of adding materials and molding pressure during the preparation of baking-free brick samples on their compressive strength properties was researched. It is concluded that the baking-free brick prepared from manganese residue could have excellent compressive strength performance under certain formula.


2021 ◽  
Vol 11 (21) ◽  
pp. 10443
Author(s):  
Michał Łach ◽  
Bartłomiej Kluska ◽  
Damian Janus ◽  
Dawid Kabat ◽  
Kinga Pławecka ◽  
...  

This work aimed to determine the effect of the addition of different types of reinforcing fibers on the strength properties of geopolymers such as flexural and compressive strength. Geopolymers are an attractive alternative to conventional binders and building materials; however, one of the main problems of their widespread use is their low resistance to brittle fracture. To improve the mechanical properties, reinforcement in the form of glass, carbon, and basalt fibers (as grids) was applied to geopolymers in the following work. Additionally, composites with these fibers were produced not only in the matrix of pure geopolymer but also as a hybrid variant with the addition of cement. Furthermore, basalt grids were used as reinforcement for geopolymers not only based on ash but also metakaolin. An additional variable used in the study was the molar concentration of the alkali solution (5 M and 10 M) for the different types of geopolymer samples. The mechanical properties of geopolymer materials and geopolymer–cement hybrids are the highest when reinforcement in the form of carbon fiber is used. Strength values for geopolymers reinforced with basalt mats depend on the number of reinforcement layers and the concentration of the alkaline solution used. All produced composites were tested for compressive strength and bending strength. When using basalt mesh, it was possible to achieve a bending strength of 12 MPa. The highest compressive strength that was achieved was the value of 66 MPa, while for samples not reinforced with fibers, only about 40 MPa was achieved.


2018 ◽  
Vol 188 (2) ◽  
pp. 187-196
Author(s):  
Pawel Ogrodnik ◽  
Bartosz Zegardlo

Modern dynamically developing building industry poses more and more complex challenges to building materials. Elevated constructions must satisfy a number of requirements including safety, durability and being environmentally friendly. The unfavorable impact of increased temperatures on the work of a construction structure is manifested by the change in the properties of the heated material and the occurrence of deformation, stresses and thermal scratches. These are particularly dangerous phenomena when they occur in elements with limited freedom of linear deformation. The purpose of the research presented in this article was to find a solution for concrete that is both resistant to spalling and characterized by high strength properties after heating. The main thesis put forward by the authors of the article is the assumption that deliberate concrete aeration will allow the introduction of evenly distributed micro air bubbles into its volume, which will constitute a reservoir for increasing the volume of water converting into water vapor as a result of a sudden increase in temperature. The presented schema enabled the assumption that the strength parameters of aerated concrete would decrease slightly in relation to non-aerated concrete, however it would be still possible to use in reinforced concrete constructions. As can be seen from the aforementioned analyzes, aeration modification can be an effective means of designing high temperature resistant concrete.


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