scholarly journals Effect of Thermal Ageing on the Impact and Flexural Damage Behaviour of Carbon Fibre-Reinforced Epoxy Laminates

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 80 ◽  
Author(s):  
Irene García-Moreno ◽  
Miguel Caminero ◽  
Gloria Rodríguez ◽  
Juan López-Cela

Most of the composite materials that are used in aerospace structures have been manufactured using a thermostable matrix, as epoxy resin. The region of stability of these polymers is defined by the glass transition temperature (Tg). However, operating temperatures close and above the Tg can cause a variation in the properties of the polymer and consequently, modify the mechanical properties of the composite material. Therefore, it is necessary to understand the failure mechanisms that occur in the material in order to ensure stability and durability. The effect of temperature and time of exposure on the impact and flexural mechanical responses of carbon/epoxy composites are studied in this work. For that purpose, ageing treatments at temperatures below and above the Tg have been considered and then, impact and flexural tests have been performed. It was observed that thermal ageing cause two different effects: at temperatures below the Tg, there is an increase of the maximum strength because of a post-curing effect; however, the mechanical properties decrease at higher temperatures of thermal ageing due to the thermo-oxidation of the epoxy resin and the loss of adhesion in the matrix/fibre interface.


2021 ◽  
pp. 002199832199945
Author(s):  
Jong H Eun ◽  
Bo K Choi ◽  
Sun M Sung ◽  
Min S Kim ◽  
Joon S Lee

In this study, carbon/epoxy composites were manufactured by coating with a polyamide at different weight percentages (5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%) to improve their impact resistance and fracture toughness. The chemical reaction between the polyamide and epoxy resin were examined by fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray photoelectron spectroscopy. The mechanical properties and fracture toughness of the carbon/epoxy composites were analyzed. The mechanical properties of the carbon/epoxy composites, such as transverse flexural tests, longitudinal flexural tests, and impact tests, were investigated. After the impact tests, an ultrasonic C-scan was performed to reveal the internal damage area. The interlaminar fracture toughness of the carbon/epoxy composites was measured using a mode I test. The critical energy release rates were increased by 77% compared to the virgin carbon/epoxy composites. The surface morphology of the fractured surface was observed. The toughening mechanism of the carbon/epoxy composites was suggested based on the confirmed experimental data.



2020 ◽  
Vol 10 (3) ◽  
pp. 1159 ◽  
Author(s):  
Yingmei Xie ◽  
Hiroki Kurita ◽  
Ryugo Ishigami ◽  
Fumio Narita

Epoxy resins are a widely used common polymer due to their excellent mechanical properties. On the other hand, cellulose nanofiber (CNF) is one of the new generation of fibers, and recent test results show that CNF reinforced polymers have high mechanical properties. It has also been reported that an extremely low CNF addition increases the mechanical properties of the matrix resin. In this study, we prepared extremely-low CNF (~1 wt.%) reinforced epoxy resin matrix (epoxy-CNF) composites, and tried to understand the strengthening mechanism of the epoxy-CNF composite through the three-point flexural test, finite element analysis (FEA), and discussion based on organic chemistry. The flexural modulus and strength were significantly increased by the extremely low CNF addition (less than 0.2 wt.%), although the theories for short-fiber-reinforced composites cannot explain the strengthening mechanism of the epoxy-CNF composite. Hence, we propose the possibility that CNF behaves as an auxiliary agent to enhance the structure of the epoxy molecule, and not as a reinforcing fiber in the epoxy resin matrix.



2014 ◽  
Vol 775-776 ◽  
pp. 588-592
Author(s):  
Camila Rodrigues Amaral ◽  
Ruben Jesus Sanchez Rodriguez ◽  
Magno Luiz Tavares Bessa ◽  
Verônica Scarpini Cândido ◽  
Sergio Neves Monteiro

The correlation between the structural network of a diglycidyl ether of the bisphenol-A (DGEBA) epoxy resin, modified by two distinct aliphatic amines (tetraethylenepentamine TEPA and jeffamine D230), and its mechanical properties, was investigated as possible matrix for abrasive composites applications. Both flexural tests, to determine the yield stress and the elastic modulus, as well as impact tests to determine the notch toughness, were performed. The DGEBA/D230 presented the highest stiffness and toughness but lowest yield stress. This epoxy network also displayed a greater plastic deformation during fracture.



Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4169
Author(s):  
Marcel Zambrzycki ◽  
Krystian Sokolowski ◽  
Maciej Gubernat ◽  
Aneta Fraczek-Szczypta

In this work, we present a comparative study of the impact of secondary carbon nanofillers on the electrical and thermal conductivity, thermal stability, and mechanical properties of hybrid conductive polymer composites (CPC) based on high loadings of synthetic graphite and epoxy resin. Two different carbon nanofillers were chosen for the investigation—low-cost multi-layered graphene nanoplatelets (GN) and carbon black (CB), which were aimed at improving the overall performance of composites. The samples were obtained by a simple, inexpensive, and effective compression molding technique, and were investigated by the means of, i.a., scanning electron microscopy, Raman spectroscopy, electrical conductivity measurements, laser flash analysis, and thermogravimetry. The tests performed revealed that, due to the exceptional electronic transport properties of GN, its relatively low specific surface area, good aspect ratio, and nanometric sizes of particles, a notable improvement in the overall characteristics of the composites (best results for 4 wt % of GN; σ = 266.7 S cm−1; λ = 40.6 W mK−1; fl. strength = 40.1 MPa). In turn, the addition of CB resulted in a limited improvement in mechanical properties, and a deterioration in electrical and thermal properties, mainly due to the too high specific surface area of this nanofiller. The results obtained were compared with US Department of Energy recommendations regarding properties of materials for bipolar plates in fuel cells. As shown, the materials developed significantly exceed the recommended values of the majority of the most important parameters, indicating high potential application of the composites obtained.



2019 ◽  
Vol 38 (2019) ◽  
pp. 404-410 ◽  
Author(s):  
Weijuan Li ◽  
Haijian Xu ◽  
Xiaochun Sha ◽  
Jingsong Meng ◽  
Zhaodong Wang

AbstractIn this study, oxide dispersion strengthened (ODS) ferritic steels with nominal composition of Fe–14Cr–2W–0.35Y2O3 (14Cr non Zr-ODS) and Fe–14Cr–2W–0.3Zr–0.35Y2O3 (14Cr–Zr-ODS) were fabricated by mechanical alloying (MA) and hot isostatic pressing (HIP) technique to explore the impact of Zr addition on the microstructure and mechanical properties of 14Cr-ODS steels. Microstructure characterization revealed that Zr addition led to the formation of finer oxides, which was identified as Y4Zr3O12, with denser dispersion in the matrix. The ultimate tensile strength (UTS) of the non Zr-ODS steel is about 1201 MPa, but UTS of the Zr-ODS steel increases to1372 MPa, indicating the enhancement of mechanical properties by Zr addition.



Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3137 ◽  
Author(s):  
Monika Duda ◽  
Joanna Pach ◽  
Grzegorz Lesiuk

This paper contains experimental results of mechanical testing of the AISI 304 steel with composite coatings. The main goal was to investigate the impact of the applied polyurea composite coating on selected mechanical properties: Adhesion, impact resistance, static behavior, and, finally, fatigue lifetime of notched specimens. In the paper the following configurations of coatings were tested: EP (epoxy resin), EP_GF (epoxy resin + glass fabric), EP_GF_HF (epoxy resin + glass fabric hemp fiber), EP_PUA (epoxy resin + polyurea) resin, EP_GF_PUA (epoxy resin + glass fabric + polyurea) resin, and EP_GF_HF_PUA (epoxy resin + glass fabric + hemp fiber + polyurea) resin. The highest value of force required to break adhesive bonds was observed for the EP_PUA coating, the smallest for the single EP coating. A tendency of polyurea to increase the adhesion of the coating to the base was noticed. The largest area of delamination during the impact test was observed for the EP_GF_HF coating and the smallest for the EP-coated sample. In all tested samples, observed delamination damage during the pull-off test was located between the coating and the metallic base of the sample.



2014 ◽  
Vol 879 ◽  
pp. 90-95 ◽  
Author(s):  
Abdul Rahman Noor Leha ◽  
Nor Amalina Nordin

Biocomposite from bamboo powder was fabricated by compression molding technique. The objective of this study was to investigate the mechanical properties of bamboo compounded with epoxy with different ratio. Tensile and flexural tests were done to characterize its mechanical properties. It was observed that the strength of bamboo-polyester was increased with increasing amount of bamboo powder. The tensile and flexural strength shows the highest value at 25 wt.% bamboo. However, the impact test shows the maximum value at 20 wt.% bamboo powder. These results exhibit the bamboo-polyester can be a good candidate to be used in many engineering applications



2021 ◽  
Vol 67 (1-2) ◽  
pp. 27-35
Author(s):  
Idawu Yakubu Suleiman ◽  
Auwal Kasim ◽  
Abdullahi Tanko Mohammed ◽  
Munir Zubairu Sirajo

This paper aims to investigate the mechanical (tensile, hardness, impact, elongation), microstructure and wear behaviours of aluminium alloy reinforced with mussel shell powder (MSP) at different weight percentages (0 wt. % to 15 wt. %) at 3 wt. % interval. The mussel shell powder was characterized by X-ray fluorescence (XRF). The matrix and the composites’ morphology were studied using a scanning electron microscope attached with energy dispersive spectroscopy for the distribution of mussel shell powder particles within the matrix. The wear behaviour of the alloy and composites produced at various reinforcements were carried out using a Taber abrasion wear-testing machine. The XRF showed the compositions of MSP to contain calcium oxide (95.70 %), silica (0.83 %) and others. Mechanical properties showed that tensile values increase with increases in MSP, hardness value increases from 6 wt. % to 15 wt. % of MSP. The impact energy decreased from 42.6 J at 3 wt. % to 22.6 J at 15 wt. %; the percentage elongation also decreased from 37.4 % at 3 wt. % to 20.5 % at 15 wt. % MSP, respectively. The bending stress results increase with increases in the percentage of reinforcement. The morphologies revealed that uniform distribution of MSP within the matrix resulted to improvement in mechanical properties. The wear resistance of the composites increases with increase in the applied load and decreases with increases in the weight percentage of MSP and can be used in the production of brake pads and insulators in the automobile industry.



2009 ◽  
Vol 79-82 ◽  
pp. 553-556 ◽  
Author(s):  
Ling Fei Shi ◽  
Gang Li ◽  
Gang Sui ◽  
Xiao Ping Yang

The increasing proliferation and application of advanced polymer composites requires higher and broader performance resin matrices. Poly(oxypropylene) with –NH2 end-groups has been widely used to toughen epoxy resins, but the strength of resin matrix may be reduced due to the addition of flexible segments in the crosslinking network. Carbon nanotubes (CNTs) have been paid more and more attention in recent years because of their superior thermal and mechanical properties. In this paper, CNTs grafted with Jeffamines T403 were used to simultaneously improve the reinforcement and toughening of an epoxy resin. The untreated multi-walled carbon nanotubes (u-MWNTs) were functionalized with amine groups according to three steps: carboxylation, acylation, and amidation. The f-MWNTs were characterized by Fourier transform infra-red (FTIR) and X-ray photoelectron spectroscopy (XPS). The experimental results indicated that the T403 was grafted to the surface of MWCNTs. The mechanical and thermal properties of epoxy with f-MWNTs were investigated. The tensile and flexural strength increased by 7.77 % and 7.03 % after adding 0.5wt% f-MWCNTs without sacrificing the impact toughness. At the same time, dynamic mechanical thermal analysis (DMTA) showed that the glass transition temperature (Tg) of epoxy with f-MWNTs were increased. The fracture surface of epoxy with f-MWNTs was observed by scanning electron microscopy (SEM) to understand the dispersion of f-MWNTs in epoxy matrix and interfacial adhesion between f-MWNTs and epoxy matrix, which can be attributed to the strong interfacial bonding between f-MWNTs and epoxy resin.



2011 ◽  
Vol 197-198 ◽  
pp. 1100-1103
Author(s):  
Jian Li

A polyurethane/clay (PU/clay) composite was synthesized. The microstructure of the composite was examined by scanning electron microscopy. The impact properties of the composite were characterized by impact testing. The study on the structure of the composite showed that clays could be dispersed in the polymer matrix well apart from a few of clusters. The results from mechanical analysis indicated that the impact properties of the composite were increased greatly in comparison with pure polyurethane. The investigation on the mechanical properties showed that the impact strength could be obviously increased by adding 20 wt% (by weight) clay to the matrix.



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