Microstructure and Dynamic Ultra-Micro Hardness of the As-Cast and Extruded Mg-Al-Ca-Sm Alloys

2007 ◽  
Vol 26-28 ◽  
pp. 153-156 ◽  
Author(s):  
Hyeon Taek Son ◽  
Jae Seol Lee ◽  
Ji Min Hong ◽  
Dae Guen Kim ◽  
Kyosuke Yoshimi ◽  
...  
Keyword(s):  
Grain Size ◽  
Elevated Temperatures ◽  
Extrusion Direction ◽  
Hot Extrusion ◽  
Hardness Test ◽  
Eutectic Phase ◽  
Micro Hardness ◽  
Maximum Hardness ◽  
Average Grain Size ◽  
Cast Alloys

The as-cast microstructure of Mg-5Al-3Ca-2Sm alloy consists of equiaxed α-Mg matrix, (Mg, Al)2Ca eutectic phase and Al-Sm rich intermetallic compounds. This eutectic phase of the extruded alloys was elongated to extrusion direction and size of this phase was finered compare to that of as-cast alloys because of severe deformation during hot extrusion. After hot extrusion, the average grain size of Mg-5Al-3Ca and Mg-5Al-3Ca-2Sm alloys was 4.8 *m and 3.8 *m, respectively. In load-unload hardness test, penetration depth was decreased with added Sm and after extrusion procedure because of grain size refining by addition Sm and large deformation. Hardness value of the alloys containing Sm was higher than that of Mg-5Al-3Ca alloy due to grain refining and formation Al-Sm rich intermetallic compound at gain boundary and α-Mg matrix. Maximum hardness value was obtained at the extruded Mg-5Al-3Ca-2Sm alloy at elevated temperatures.

Hot-Extruded Microstructure and Mechanical Properties of Mg-Al-Sn Alloys

2010 ◽  
Vol 297-301 ◽  
pp. 1037-1041
Author(s):  
Young Mo Kim ◽  
Soon Sub Park ◽  
Seul Ki Park ◽  
Hyeon Taek Son ◽  
Jae Seol Lee
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Tensile Strength ◽  
Fine Particles ◽  
Extrusion Direction ◽  
Hot Extrusion ◽  
Eutectic Phase ◽  
Al Content ◽  
Cast Alloys ◽  
Mg2sn Phase

The microstructure of as-cast Mg-xAl-2Sn alloys consists of an α-Mg matrix, a Mg17Al12 eutectic phase and a Mg2Sn phase. In as-cast alloys, the Mg17Al12 eutectic phase was located at along grain boundaries. The eutectic phase of the extruded alloys was elongated in the extrusion direction and crushed into fine particles because of deformation during hot extrusion, and the grain size was refined with an increased Al content. The maximum values of the yield strength and tensile strength were 240 MPa and 300 MPa at 9 wt.% containing Al element, respectively.

Effect of Warm Rolling on Microstructure and High Temperature Mechanical Behavior of a Nano-Structured Al-8Fe-2Mo-2V-1Zr Alloy

2005 ◽  
Vol 486-487 ◽  
pp. 411-414 ◽  
Author(s):  
Won Yong Kim ◽  
Jae Sung Park ◽  
Mok Soon Kim
Keyword(s):  
Particle Size ◽  
Grain Size ◽  
Elevated Temperatures ◽  
Hot Extrusion ◽  
Warm Rolling ◽  
Spray Forming ◽  
Grain Structure ◽  
Average Grain Size ◽  
Two Samples ◽  
Additional Process

Mechanical properties of a nano-structured Al-8Fe-2Mo-2V-1Zr alloy produced by spray forming and subsequent hot-extrusion at 420°C were investigated in terms of tensile test as a function of temperature. Warm rolling was adapted as an additional process to expect further refinement in microstructure. Well-defined equiaxed grain structure and finely distributed dispersoids with nano-scale in particle size were observed in the spray formed and hot extruded sample (as-received sample). The average grain size and particle size were measured to 500 nm and 50 nm, respectively. While it was found that warm rolling gives rise to precipitate fine dispersoids less than 10 nm without influencing the grain size of matrix phase, in the temperature range of RT∼150°C, distinguishable changes in ultimate tensile strength were not found between the as-received and warm-rolled samples. At elevated temperatures ranging from 350 to 550°C, warm-rolled sample showed a higher value of elongation than as-received one although similar values of elongation were observed between two samples at temperatures lower than 350°C.

Microstructure, Electrical and Thermal Conductivity of the As-Extruded Al-xMM (Mischmetal) Based Alloys

2021 ◽  
Vol 21 (3) ◽  
pp. 1984-1989
Author(s):  
Yong-Ho Kim ◽  
Hyo-Sang Yoo ◽  
Seong-Ho Lee ◽  
Gyu-Seok Lee ◽  
Hyeon-Taek Son
Keyword(s):  
Thermal Conductivity ◽  
Intermetallic Compounds ◽  
Fine Particles ◽  
Hot Extrusion ◽  
Wide Band ◽  
Extrusion Process ◽  
Eutectic Phase ◽  
Extrusion Ratio ◽  
Average Grain Size ◽  
Cast Alloys

The effect of addition of Mischmetal (MM) on the microstructure, electrical and thermal conductivity, and mechanical properties of the as-extruded Al-MM based alloys were investigated. The studied AlxMM alloys (where x = 0.2, 0.5, 1.0, 1.5, 2.0 and 5.0 wt.%) were cast and homogenized at 550 °C for 4 h. The cast billets were extruded into 12 mm bars with an extrusion ratio of 39 at 550 °C. The addition of MM resulted in the formation of Al11(Ce, La)3 intermetallic compounds and the area fraction of these intermetallic compounds increased with an increase in the MM content. The Al11(Ce, La)3 phase, which was distributed in the as-cast alloys, was crushed into fine particles and arrayed along the extruded direction during the extrusion process. In particular, these intermetallic compounds in the extruded Al-5.0MM alloy were distributed with a wide-band structure due to the fragmentation of the eutectic phase with a lamellar structure. As the MM content increased from 1.0 wt.% to 5.0 wt.%, the average grain size decreased remarkably from 740 to 73 μm. This was due to formation of Al11(Ce, La)3 particles during the hot extrusion process, which promoted dynamic recrystallization and suppression of grain growth. The electrical and thermal conductivity of the extruded alloys containing up to 2.0 wt.% MM were around 60.5% IACS and 230 W/m · K, respectively. However, the electrical and thermal conductivity of the extruded alloy with 5.0 wt.% MM decreased to 55.4% IACS and 206 W/m · K, respectively. As the MM content increased from 1.0 wt.% to 5.0 wt.%, the ultimate tensile strength (UTS) was improved remarkably from 74 to 119 MPa which was attributed to the grain refinement and formation of Al11(Ce, La)3 intermetallic compounds by the addition of MM.

scholarly journals Effect of Grain Size and Structure, Solid Solution Elements, Precipitates and Twinning on Nanohardness of Mg-RE Alloys

2013 ◽  
Vol 765 ◽  
pp. 491-495 ◽  
Author(s):  
Petra Maier ◽  
Asta Richter ◽  
Gerhard Tober ◽  
Norbert Hort
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Cold Work ◽  
Extrusion Direction ◽  
Hot Extrusion ◽  
Recrystallization Process ◽  
Average Grain Size ◽  
Second Phases ◽  
Inhomogeneous Microstructure ◽  
Isothermal Ageing

In this study Mg10GdxNd alloys are investigated by nanoindentation hardness measurements in several material conditions. Mg10GdxNd alloys with an average coarse grain size of 500 µm were cast by permanent mold direct chill casting. Hardness values vary due to the inhomogeneous microstructure formed during the solidification process consisting of dendrite arms with preferred orientation direction. The effect of dissolving particles during solution heat treatment (T4) and isothermal ageing (T6) was observed to a different extent depending on Nd content. Isothermal ageing promotes a duplex microstructure of coarse β1phase precipitates and regions containing much finer precipitates. Post processing by direct extrusion changes the microstructure dramatically to an average grain size of 15 µm. The microstructure after hot extrusion shows segregation of precipitates in the extrusion direction. Near this alignment of second phases hardness and plastic deformation differ from precipitates enriched in RE elements due to depleted regions of solid solution around them. This phenomenon is known from alloying element segregation to grain boundaries. Depending on the amount and location of second phases in the as-cast microstructure and degree of cold work, recrystallization leads to an inhomogeneous microstructure, consisting of fine grains (15 µm) and very fine grains, where second phases act as nuclei during the recrystallization process. Furthermore, mechanical testing (fatigue) causes an increase in dislocation density by work hardening and extensive twinning near the fractured surface. Here the hardening effect interferes with grain size strengthening.

Microstructure and Mechanical Property of Mg-Sn-Al Wrought Magnesium Alloys

2017 ◽  
Vol 898 ◽  
pp. 97-103 ◽  
Author(s):  
Zheng Hua Huang ◽  
Nan Zhou ◽  
Jing Xu ◽  
Yang De Li ◽  
Wei Rong Li
Keyword(s):  
Mechanical Properties ◽  
Mechanical Property ◽  
Tensile Strength ◽  
Yield Strength ◽  
Ambient Temperature ◽  
Hot Extrusion ◽  
Average Grain Size ◽  
Zk60 Alloy ◽  
Cast Alloys ◽  
Az31b Alloy

The microstructures, phase constitutions and mechanical properties of as-cast samples, extruded rods and plates of Mg-3.52Sn-3.32Al and Mg-6.54Sn-4.78Al alloys were investigated by optical microscopy, scanning electron microscopy, X-ray diffraction and mechanical testing. The results show that as-cast microstructure consists of α-Mg matrix, Mg2Sn and a few dispersed β-Mg17Al12 phases. The two as-cast alloys exhibit good tensile mechanical properties. After hot extrusion, dynamic recrystallization occurs. Average grain size reaches 6 μm ~ 8 μm for rods, and a lot of fine micro-scaled particles exist, resulting in significant enhancement of tensile mechanical properties. The extruded Mg-3.52Sn-3.32Al rod exhibits better comprehensive tensile mechanical property than AZ31B alloy, with tensile strength σb of 295 MPa, yield strength of 200 MPa and elongation of 21.5% at ambient temperature. The extruded Mg-6.54Sn-4.78Al rod exhibits equivalent comprehensive tensile mechanical properties with ZK60 alloy, achieving tensile strength of 355 MPa, yield strength of 275 MPa and elongation of 11% at ambient temperature. The extruded plates at ambient temperature performed a tensile strength of 270 MPa.

scholarly journals Crystallography of grain refinement in cast zinc–copper alloys

2015 ◽  
Vol 48 (3) ◽  
pp. 890-900 ◽  
Author(s):  
Zhilin Liu ◽  
Dong Qiu ◽  
Feng Wang ◽  
John A. Taylor ◽  
Mingxing Zhang
Keyword(s):  
Grain Size ◽  
Grain Refinement ◽  
Copper Alloys ◽  
Diffraction Method ◽  
Electron Backscattered Diffraction ◽  
Grain Coarsening ◽  
Cu Content ◽  
Edge Matching ◽  
Average Grain Size ◽  
Cast Alloys

Adding the peritectic forming element Cu effectively reduced the average grain size of cast Zn by over 85%. At a specified cast condition, the smallest grain size was obtained at 2 wt% Cu addition. A further increase in Cu content led to grain coarsening in the cast Zn–Cu alloys. Although the solute effect of Cu was predominately responsible for the grain refinement through restriction of the grain growth, it was found that the variation of grain size is also closely related to the formation of the pro-peritectic phase, ∊-CuZn4. Crystallographic calculations using the edge-to-edge matching model showed low interatomic misfit and interplanar mismatch between Zn and the ∊-CuZn4phase. In addition, a reproducible h.c.p.–h.c.p. (h.c.p. denotes hexagonal close-packed) orientation relationship between Zn and the ∊-CuZn4particles (located within the Zn grain centres) was also experimentally determined using the electron backscattered diffraction method. This indicated the high potency of the pro-peritectic ∊-CuZn4particles as effective heterogeneous nucleation sites for η-Zn, which further refined the Zn grains. However, when the Cu content was over 2.0 wt%, formation of large ∊-CuZn4particles resulted in grain coarsening of the cast alloys.

Investigating the Relationships Between Structures and Properties of Al Alloys Incorporated With Ti and Mg Inclusions

2016 ◽  
Vol 138 (3) ◽  
Author(s):  
Halil Ibrahim Kurt ◽  
Ibrahim H. Guzelbey ◽  
Serdar Salman ◽  
Razamzan Asmatulu ◽  
Mustafa Dere
Keyword(s):  
Solid Solution ◽  
Grain Size ◽  
Elevated Temperatures ◽  
Solidification Process ◽  
Optical Microscope ◽  
Industrial Applications ◽  
Al Alloys ◽  
Average Grain Size ◽  
Solidification Processes ◽  
Grain Size And Shape

This study investigates the influence of titanium (Ti) and magnesium (Mg) additions on aluminum (Al) alloys in order to evaluate the relationship between the structure and properties of the new alloys. The alloys obtained at elevated temperatures mainly consist of Al–2Mg–1Ti, Al–2Mg–3Ti, Al–4Mg–2Ti, and Al–6Mg–2Ti alloys, as well as α and τ solid solution phases of intermetallic structures. Microstructural analyses were performed using X-ray diffraction (XRD), optical microscope, and energy dispersive spectrometry (EDS) techniques. Test results show that the average grain size of the alloys decreased with the addition of Ti inclusions during the casting and solidification processes, and the smallest grain size was found to be 90 μm for the Al–6Mg–3Ti alloy. In addition, tensile properties of the Al–Mg–Ti alloys were initially improved and then worsened after the addition of higher concentrations of Ti. The highest tensile and hardness values of the alloys were Al–4Mg–2Ti (205 MPa) and Al–6Mg–3Ti (80 BHN). The primary reasons for having higher mechanical properties may be attributed to strengthening of the solid solution and refinement of the grain size and shape during the solidification process. For this study, the optimum concentrations of Ti and Mg added to the Al alloys were 4 and 2 wt.%, respectively. This study may be useful for field researchers to develop new classes of Al alloys for various industrial applications.

Effect of rate controlled sintering on microstructure and electrical properties of ZnO doped with bismuth and antimony oxides

1997 ◽  
Vol 12 (9) ◽  
pp. 2447-2454 ◽  
Author(s):  
Gaurav Agarwal ◽  
Robert F. Speyer
Keyword(s):  
Grain Size ◽  
Liquid Phase ◽  
Grain Growth ◽  
Elevated Temperatures ◽  
Antimony Oxide ◽  
Second Phase ◽  
Dopant Content ◽  
Average Grain Size ◽  
Rate Controlled ◽  
Grain Boundary Pinning

Various rate controlled sintering (RCS) schedules were used on isostatically pressed particulate compacts of ZnO with Bi2O3 and Sb2O3 additives. For low additive content, smaller average grain sizes with more rapid RCS schedules were attributable to thermal schedules which minimized the time at elevated temperatures where grain growth could occur. β–Bi2O3, Zn7Sb2O12, and Zn2Sb3Bi3O14 phases formed during/after sintering. Elevated heat-treatment temperatures favored the formation of Zn7Sb2O12 and additional β–Bi2O3, while Zn2Sb3Bi3O14 was dominant in sintered samples where the RCS schedule did not result in temperatures in excess of 1100 °C. Zn2Sb3Bi3O14 precipitated during sintering, functioning as grain boundary pinning sites which impeded ZnO grain growth. Bismuth and antimony oxide-based liquid facilitated sintering at lower temperatures, which in turn resulted in decreased average grain size. Rapid RCS schedules for samples with low dopant content resulted in lower sintering temperatures, since time was not allowed for Zn2Sb3Bi3O14 precipitation to deplete the liquid phase. For higher dopant contents, liquid phase was adequately plentiful, wherein longer RCS schedules resulted in lower sintering temperatures. Increasing concentration of second phase generally fostered decreased grain size and attenuated the effect of thermal schedule on the microstructure. Electrical resistance and breakdown voltage increased consistent with decreasing ZnO average grain size.

Effects of Specimen Diameter on Microstructure and Microhardness of Hot Extruded AZ31B Magnesium Alloy

2014 ◽  
Vol 1004-1005 ◽  
pp. 158-162 ◽  
Author(s):  
Xiang Ting Hong ◽  
Fu Chen ◽  
Fei Chen ◽  
Wang Yu ◽  
Bo Rong Sang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Size Effects ◽  
Strain Distribution ◽  
Elevated Temperatures ◽  
Az31b Magnesium Alloy ◽  
Specimen Diameter ◽  
Average Grain Size ◽  
Micro Parts

Microstructures of metal micro parts after microforming at elevated temperatures must be evaluated due to mechanical properties depend on average grain size. In this work, the effects of specimen diameter on the microstructure and microhardness of a hot-extruded AZ31B magnesium alloy were studied. Obvious size effect on microstructure and microhardness of the alloy could be observed. The size effects could be explained by strain distribution and dislocation density differences between the two kinds of specimens.

Effect of CO2 Laser Surface Melting on the Microstructure of AZ91D Magnesium Alloy

2011 ◽  
Vol 464 ◽  
pp. 461-464
Author(s):  
Ju Fang Chen ◽  
Xing Cheng Li ◽  
Jiang Tao Wang ◽  
Wei Ning Lei
Keyword(s):  
Grain Size ◽  
Magnesium Alloy ◽  
Continuous Wave ◽  
Surface Melting ◽  
Laser Surface ◽  
Laser Surface Melting ◽  
Micro Hardness ◽  
Az91d Magnesium Alloy ◽  
Average Grain Size ◽  
Melted Layer

In the present study, the effect of laser surface melting (LSM) on microstructure of AZ91D magnesium alloy was investigated with a 2kW continuous wave CO2 laser. The results indicate that both the substrate and laser melted layer mainly consisted of α-Mg and β-Mg17Al12, the amount of β-phase in laser melted layer was decreased as compared to that of the substrate. The microstructure of the laser surface melted zone consists of fine dendrites with an average grain size of less than 10m, the grain size was reduced by a factor of more than 10 times as compared to that of the substrate. The micro-hardness of the melted layer was increased to 70–85HV as compared to that of the substrate (about 53HV). Because of the grain refinement, the enhancement of the hard phase β-Mg17Al12, and the solid solution hardening of alloy elements, the micro-hardness and strength of the laser melted layer was increased significantly.

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