Research on Synthesis and Performance of Solvent-Free Aluminum-Plastic Composite Polyurethane Adhesive

2012 ◽  
Vol 583 ◽  
pp. 9-13 ◽  
Author(s):  
Qing Wang ◽  
Guang Xue Chen ◽  
Shuang Lian Chen ◽  
Jing Lei Tai ◽  
Qi Feng Chen
Keyword(s):  
Water Resistance ◽  
Raw Materials ◽  
Peel Strength ◽  
Solvent Free ◽  
Polyurethane Adhesive ◽  
Low Viscosity ◽  
Plastic Composite ◽  
Comprehensive Properties ◽  
Polyurethane Adhesives ◽  
And Performance

A low-viscosity and solvent-free polyurethane adhesive was prepared with mixed polyester, polyether and IPDI as main raw materials. The influences of different moral ratios of polyester and polyether on reaction time, viscosity and water resistance, adhesive strength were researched. The effects of catalysts to adhesive were well discussed. The experimental results showed that polyurethane adhesives composed by mixed polyester and polyether had low viscosity and had better waterproof quality. The adhesives showed the best comprehensive properties when the mole ratio of OHs of polyether to OHs of polyester was 0.3/0.7. Catalysts added to this adhesive could speed the curing reaction, but it reduced the peel strength of the adhesives.

The Preparation of Solvent-Free Polyurethane Laminating Adhesive with Mixed-Polyols

2012 ◽  
Vol 549 ◽  
pp. 177-182 ◽  
Author(s):  
Shuang Lian Chen ◽  
Guang Xue Chen ◽  
Qi Feng Chen ◽  
Chun Jiang Jia ◽  
Qin Wang
Keyword(s):  
Heat Resistance ◽  
Adhesion Strength ◽  
Vegetable Oil ◽  
Water Resistance ◽  
Raw Materials ◽  
Solvent Free ◽  
Polyurethane Adhesive ◽  
Oh Groups ◽  
Two Component ◽  
Peeling Strength

A two-component polyurethane adhesive based on solvent-free was prepared with PBA, vegetable oil polyols, IPDI and several different small molecular polyols as main raw materials. The influences of different mole ratios of NCO groups (from prepolymer )and OH groups (from the mixed polyols) on water absorbing capacity and T-style peeling strength were studied, as well as the effects of small molecular polyols on curing speed, heat resistance, water absorbing capacity and T-style peeling strength. The results showed that PU adhesive performed the best when mole ratio of NCO/OH was 1.3 in this experiment. And small molecular polyols added to the adhesives can not increase the curing speed and the ability of heat resistance. However, it could significantly improve the adhesion strength of PU adhesive, and adding appropriate amount of small molecular polyols selectively could improve its water resistance.

Synthesis and characterisation of heatproof polyester polyols used in polyurethane adhesive

2016 ◽  
Vol 45 (6) ◽  
pp. 439-443 ◽  
Author(s):  
Tingting Xu ◽  
Cuifeng Zhang ◽  
Lijun Chen
Keyword(s):  
Heat Resistance ◽  
Benzene Ring ◽  
Design Methodology ◽  
Raw Materials ◽  
Sebacic Acid ◽  
Vacuum Melting ◽  
Polyurethane Adhesive ◽  
Content Type ◽  
Wide Range ◽  
Polyurethane Adhesives

Purpose Presently, a wide range of polyurethane adhesives can be obtained using different kinds of polyols and isocyanates. However, the applied temperature of the polyurethane adhesive is not more than 80°C. The film of polyurethane adhesive will be softened and deformed when its applied temperature is more than 100°C. Thus, the mechanical property of the polyurethane adhesive is decreased clearly, which limits its further application. The purpose of the study is to improve the heat resistance of polyols, especially polyester polyols and its resultant polyurethane adhesives. Design/methodology/approach The more rigid benzene ring is introduced into the polyester polyols to improve the heat resistance of its resultant polyurethane adhesive. Findings The more rigid benzene ring has ben introduced into the polyester polyols and the heat resistance of its resultant polyurethane adhesive is improved. Originality/value The polyester polyols with more rigid benzene ring have been prepared successfully by the vacuum melting method when diethylene glycol, neopentyl glycol, 1,6-hexanediol, ethanediol, isophthalic acid, terephthalic acid, sebacic acid and adipic acid are used as raw materials and tetra-isopropyl titanate is adopted as the catalyst.

scholarly journals Influence of biobased polyol type on the properties of polyurethane hotmelt adhesives for footwear joints

2021 ◽  
Vol 9 (1) ◽  
Author(s):  
M. P. Carbonell-Blasco ◽  
M. A. Pérez-Limiñana ◽  
C. Ruzafa-Silvestre ◽  
F. Arán-Ais ◽  
E. Orgilés-Calpena
Keyword(s):  
Raw Materials ◽  
Peel Test ◽  
Softening Temperature ◽  
Peel Strength ◽  
Adhesion Test ◽  
Scanning Calorimetry ◽  
Final Performance ◽  
Footwear Industry ◽  
Polyurethane Adhesives ◽  
Useful Life

AbstractPolyurethanes, one of the most used polymers worldwide, are strongly dependent of non-renewable fossil resources. Thus, boosting the production of new polyurethanes based on more sustainable raw materials is crucial to move towards the footwear industry decarbonisation. The aim of this study is to synthesise and characterise reactive hotmelt polyurethanes from biomass and CO2-based polyols as bioadhesives for the footwear industry. The influence of biobased polyols on the polyurethane structure, and therefore, on their final properties was analysed by different experimental techniques such us Fourier transform infrared spectroscopy (FTIR), Differential scanning calorimetry (DSC), Thermogravimetric analysis (TGA), Melting viscosity, Softening temperature and T-peel strength test, in order to assess their viability for the upper to sole bonding process. The results obtained indicated that the incorporation of different amounts of the biobased polyols produces changes in the structure and final performance of the polyurethanes. Therefore, adhesion test carried out by the T-peel test 72 h after the upper -to- sole bonding of the sustainable adhesives show high final adhesion values. These sustainable raw materials provide polyurethane adhesives with additional beneficial non-toxicity and sustainable characteristics, without harming their properties during their useful life.

Study on Synthesis and Paper-Plastic Composite Property of Maleic Rosin Modified Acrylic Resin

2010 ◽  
Vol 174 ◽  
pp. 462-465
Author(s):  
Jin Yan ◽  
Guang Xue Chen ◽  
Shuang Shuang Wen ◽  
Xiao Meng Cui ◽  
Zhen Cai Qu
Keyword(s):  
Ir Spectra ◽  
Raw Materials ◽  
Low Cost ◽  
Acrylic Resin ◽  
Acid Value ◽  
Peel Strength ◽  
Adhesive Properties ◽  
Adsorption Effect ◽  
Plastic Composite ◽  
Rosin Ester

In this paper, allyl maleated rosin ester was synthesized by the esterification of maleic rosin and allyl alcohol with catalyst. And then a new waterborne paper-plastic composite adhesive was prepared through the semi-continuous emulsion polymerization method with allyl maleated rosin ester, butyl acrylate, vinyl acetate and acrylic acid as raw materials. The product of esterification was analyzed by IR spectra, and its acid value was determined too. Polymer was analyzed by DSC and IR spectra and its T-style peel strength was determined. The adsorption effect of adhesives to ink was also tested. The results showed that this paper-plastic composite adhesive had good adhesive properties: excellent compatibility with the ink, longer stability period, and low cost.

scholarly journals A Brief Review on Solvent-Free Synthesis of Zeolites

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 788
Author(s):  
Jinlin Mei ◽  
Aijun Duan ◽  
Xilong Wang
Keyword(s):  
High Efficiency ◽  
Raw Materials ◽  
Solvent Free ◽  
High Yield ◽  
Control Synthesis ◽  
Mechanical Mixing ◽  
Synthesis Mechanism ◽  
Wastewater Pollution ◽  
Low Efficiency ◽  
Solvent Free Synthesis

The traditional hydrothermal method to prepare zeolite will inevitably use a large amount of water as a solvent, which will lead to higher autogenous pressure, low efficiency, and wastewater pollution. The solvent-free method can be used to synthesize various types of zeolites by mechanical mixing, grinding, and heating of solid raw materials, which exhibits the apparent advantages of high yield, low pollution, and high efficiency. This review mainly introduces the development process of solvent-free synthesis, preparation of hierarchical zeolite, morphology control, synthesis mechanism and applications of solvent-free methods. It can be believed that solvent-free methods will become a research focus and have enormous industrial application potential.

scholarly journals Rheological and Microbiological Characteristics of Hops and Hot Trub Particles Formed during Beer Production

Molecules ◽  
2021 ◽  
Vol 26 (3) ◽  
pp. 681
Author(s):  
Monika Sterczyńska ◽  
Marek Zdaniewicz ◽  
Katarzyna Wolny-Koładka
Keyword(s):  
Rheological Properties ◽  
Raw Materials ◽  
Raw Material ◽  
Microbiological Analysis ◽  
Waste Products ◽  
Low Viscosity ◽  
Post Process ◽  
High Shear Rates ◽  
Different Temperatures ◽  
Beer Production

During the production of beer, and especially beer wort, the main wastes are spent grain and hot trub, i.e., the so-called “hot break.” Combined with yeast after fermentation, they represent the most valuable wastes. Hot trub is also one of the most valuable by-products. Studies on the chemical composition of these sediments and their rheological properties as waste products will contribute to their effective disposal and even further use as valuable pharmaceutical and cosmetic raw materials. So far, hot trub has been studied for morphology and particle distribution depending on the raw material composition and beer wort extract. However, there are no preliminary studies on the rheological properties of hot trub and hops. In particular, no attention has yet been paid to the dependence of these properties on the hop variety or different protein sources used. The aim of this study was to examine the effect of different hopping methods on hot trub viscosity and beer wort physicochemical parameters. Additionally, the hop solutions were measured at different temperatures. A microbiological analysis of hop sediments was also performed to determine the post-process survival of selected microorganisms in these wastes. For manufacturers of pumps used in the brewing industry, the most convenient material is that of the lowest viscosity. Low viscosity hot trub can be removed at lower velocities, which reduces costs and simplifies washing and transport. The sediments also had similar equilibrium viscosity values at high shear rates.

scholarly journals Preparation and Performance Evaluation of Antibacterial Melt-Spun Polyurethane Fiber Loaded with Berberine Hydrochloride

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2336
Author(s):  
Ruifang Zhao ◽  
Pengfei Tan ◽  
Yanting Han ◽  
Feng Yang ◽  
Yidong Shi ◽  
...  
Keyword(s):  
Antibacterial Agent ◽  
Bacterial Infections ◽  
Antibacterial Properties ◽  
Coating Technology ◽  
Daily Lives ◽  
Berberine Hydrochloride ◽  
Comprehensive Properties ◽  
Melt Spun ◽  
And Performance ◽  
Application Prospects

(1) Background: Bacterial infections have long threatened global public safety; hence, it is significant to continuously develop antibacterial fibers that are closely related to people’s daily lives. Berberine hydrochloride is a natural antibacterial agent that has application prospects in the preparation of antibacterial fibers. (2) Methods: This study firstly verified the antibacterial properties of berberine hydrochloride and its possible antibacterial mechanism. Thereafter, berberine hydrochloride was introduced into the self-made melt-spun polyurethane fiber through optimized coating technology. The performance of coating modified polyurethane fiber has been systematically evaluated, including its antibacterial properties, mechanical properties, and surface wettability. (3) Results: Results show that the antibacterial polyurethane fiber with desirable comprehensive properties is expected to be used in the biomedical fields. (4) Conclusions: The research also provides a reference for the development and application of other natural antibacterial ingredients in fiber fields.

Synthesis of Low Viscosity Polydimethylsiloxane Using Low Grade of Octamethylcyclotetrasiloxane

2021 ◽  
Vol 1028 ◽  
pp. 365-370
Author(s):  
Diba G Auliya ◽  
Soni Setiadji ◽  
Zulfi Mofa Agasa ◽  
Fitrilawati ◽  
Norman Syakir ◽  
...  
Keyword(s):  
Ring Opening ◽  
Raw Materials ◽  
Vitreoretinal Surgery ◽  
Production Costs ◽  
Low Grade ◽  
High Grade ◽  
High Quality ◽  
Low Viscosity ◽  
Polymerization Method

Polydimethylsiloxane (PDMS) has been widely used as a vitreous humour substitution in vitreoretinal surgery. Due to its limited availability and increasing domestic needs, the price of PDMS in Indonesia became very expensive. Previously, we reported the synthesized of PDMS from a high grade of monomer of 98% of Octamethylcyclotetrasiloxane (D4) and found that all PDMS samples produced high quality samples similar to that of commercial one. However, by considering the ease of obtaining raw materials and also the production costs, the synthesis of PDMS using monomer which easy to be found in Indonesia and low production costs is needed to be developed. Here, we reported the synthesis of PDMS using low grade of 96% of D4 in order to produce high quality of PDMS with low viscosity that can be used for vitreous humous substitution in vitreoretinal surgery. PDMS samples with low viscosity value of 0.94-1.35 Pa.s have been successfully synthesized from low grade of D4 and MM using ring-opening polymerization method. The yields of PDMS resulted in this research were in the range between 67.27% and 76.26%. From FTIR spectroscopy, it is found that all synthesized samples have structure and functional groups similar to PDMS using high grade of monomer of 98% Octamethylcyclotetrasiloxane (D4). From refractometer and surfgauge measurements, all samples have refractive index in the range of 1,4034-1,4040 and the value surface tension was 21 m.N/m.

A New Aluminium Silicon-Boron Nitride Abradable for Compressor Components

1998 ◽  
Author(s):  
K. Boddenberg ◽  
B. Kock ◽  
M. Dorfman ◽  
L. Russo ◽  
M. Nestler
Keyword(s):  
Boron Nitride ◽  
Raw Materials ◽  
Electrical Energy ◽  
Air Separation ◽  
Energy Costs ◽  
Performance Improvements ◽  
And Performance ◽  
Materials Used ◽  
Abradable Coatings ◽  
Optimization And Performance

Abstract Air separation plants use centrifugal compressors where air and electrical energy are the only raw materials used in the production process. So energy costs play a crucial role and the compressors are heavily penalized when guaranteed performance levels are not achieved. In order to better generate performance, abradable coatings, previously used in the gas turbine industry, have been designed into turbocompressors. This paper will show the optimization and performance improvements of a new aluminium silicon-boron nitride material.

Serpentinite Magnesium Binders, Based on Technogenic Raw Materials

2021 ◽  
Vol 316 ◽  
pp. 1050-1054
Author(s):  
V.N. Zyryanova ◽  
E.V. Lytkina ◽  
A.P. Ochur-Ool
Keyword(s):  
Mechanical Strength ◽  
Water Resistance ◽  
Raw Materials ◽  
Raw Material ◽  
Material Base ◽  
Hardening Process ◽  
Dispersed System ◽  
Technogenic Raw Materials

Increasing water resistance and mechanical strength of hardening magnesian binders’ products can be achieved by introducing microfillings into a hardening dispersed system. It is shown that serpentine provides an increase strength and water resistance in hydration and hardening process, being as a structure-forming component, it intensifies this process. It allows expanding the raw material base for the production of magnesia binders for construction purposes.

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