Comparative Study of Metakaolin and Zeolite Tuff Influence on Properties of High-Strength Concrete

Author(s):  
Leonid I. Dvorkin ◽  
Vadim Zhitkovsky ◽  
Nataliya Lushnikova ◽  
Mohammed Sonebi

Composite admixtures which include active pozzolanic components and high-range water reducers, allows to obtain high-strength, particularly dense and durable concrete to achieve a reduction in resources and energy consumption of manufacturing.Zeolite, containing a significant amount of active silica, can serve as one of the alternative substances to resources and energy consuming mineral admixtures like metakaolin and silica fume. The deposits of zeolites are developed in Transcarpathia (Ukraine), USA, Japan, New Zealand, Iceland and other countries. It is known that zeolite tuffs exhibit pozzolanic properties and are capable to substitution reactions with calcium hydroxide.However, the high dispersion of zeolite rocks leads to a significant increase in the water consumption of concrete. Simultaneous introduction of zeolite tuffs with superplasticizers, which significantly reduce the water content, creates the preconditions for their effective use in high-strength concrete.Along with dehydrated (calcined) zeolite, natural (non-calcined) zeolite expresses itself as an effective mineral admixture of concrete. When using non-calcined zeolite, the effect of increasing in compressive strength at the age of 3 and 7 days is close to the effect obtained when using dehydrated zeolite: 8-10% and 10- 12%, respectively, and 28 days the strength growth is 13-22%. The use of non-calcined zeolite has a significant economic feasibility, so it certainly deserves attention. There were compared the effect of zeolite to metakaolinThe results of the research indicate that the use of composite admixtures, consisted of calcined (non-calcined) zeolite tuff of high dispersity and superplasticizer of naphthalene formaldehyde type, allows to obtain concretes classes C50…C65.

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Sadaqat Ullah Khan ◽  
Muhammad Fadhil Nuruddin ◽  
Tehmina Ayub ◽  
Nasir Shafiq

This paper presents a review of the properties of fresh concrete including workability, heat of hydration, setting time, bleeding, and reactivity by using mineral admixtures fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), metakaolin (MK), and rice husk ash (RHA). Comparison of normal and high-strength concrete in which cement has been partially supplemented by mineral admixture has been considered. It has been concluded that mineral admixtures may be categorized into two groups: chemically active mineral admixtures and microfiller mineral admixtures. Chemically active mineral admixtures decrease workability and setting time of concrete but increase the heat of hydration and reactivity. On the other hand, microfiller mineral admixtures increase workability and setting time of concrete but decrease the heat of hydration and reactivity. In general, small particle size and higher specific surface area of mineral admixture are favourable to produce highly dense and impermeable concrete; however, they cause low workability and demand more water which may be offset by adding effective superplasticizer.


2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Cong Ma ◽  
Yuehu Tan ◽  
Erbing Li ◽  
Yinsuo Dai ◽  
Meng Yang

A study on high-performance grouting mortar is reported. The common mortar was modified by mineral admixtures such as gypsum, bauxite, and alunite. The effects of mineral admixtures on the fluidity, setting time, expansion, strength, and other properties of mortar were evaluated experimentally. The microstructure of the modified mortar was characterized by X-ray diffraction, scanning electron microscopy, and mercury intrusion porosimetry. Moreover, the expansive performance and strength of the grouting mortar were verified by anchor pullout test. The results show that the best conditions for gypsum-bauxite grouting mortar are as follows: a water-to-binder ratio of 0.3, a mineral admixture content of ~15%, and a molar ratioKof 2. The ultimate bearing capacity of the gypsum-bauxite grouting mortar anchor increased by 39.6% compared to the common mortar anchor. The gypsum-bauxite grouting mortar has good fluidity, quick-setting, microexpansion, early strength, and high strength performances.


2014 ◽  
Vol 584-586 ◽  
pp. 1541-1544
Author(s):  
Xin Li ◽  
Qiang Wang ◽  
Shu Hua Liu

The activity index of steel slag-GGBS composite mineral admixture with different steel slag contents at the W/B of 0.3, 0.4, and 0.5 was investigated. The results show that the activity index of the composite mineral admixture with higher GGBS content is larger, and this phenomenon is more obvious at later ages. At lower W/B, the gap of activity index of different composite mineral admixtures is smaller. The activity index of each composite mineral admixture is higher at lower W/B and at later age. The steel slag-GGBS composite mineral admixture is more suitable to be used in high strength concrete than in low strength concrete. As far as the long-term properties of concrete are concerned, the activity index of the composite mineral admixture at the late age should be adopted.


In the manufacturing industry among the primary producers of carbon dioxide, cement industry plays one o f the important role. Hence if we reduce the amount of usage of cement in concrete preparation, it will be helpful for a healthy environment. Upon consider the environmental pollution, in the concrete preparation mineral admixtures are used as a partial substitute for cement. Here in this paper, ultra-fine ceramic powder is using as a mineral admixture which are procured from used or broken tiles in 5%, 10% and 15% as level of replacement and also carbon black powder from rubber industry in 1% both by weight of water to made a high strength concrete of M50 grade Concrete. In severe environments like industrial and marine environments, a concrete with high strength may not perform because they are characterized by high chloride content, sulphate content or combination of both. Hence in order to provide such an environment in the laboratory, the specimens are subjected for curing in H2SO4 acid (industrial) and NaCl base (marine). To find the performance of the use of ceramic powder, black carbon powder, compressibility strength and split tensile strength, flexural strength, porosity, corrosion resistance tests are performed.


2014 ◽  
Vol 629-630 ◽  
pp. 371-375
Author(s):  
Ji Wei Cai ◽  
Si Jia Yan ◽  
Gong Lei Wei ◽  
Lu Wang ◽  
Jin Jin Zhou

Fly ash (FA) and granular blast-furnace slag (GBFS) are usual mineral admixtures to conventional concrete, and their contents substituted for Portland cement definitely affect development rate of strength of concrete. C30 and C60 concrete samples with FA and/or GBFS were prepared to study the influence of substitution content of the mineral admixtures on 3 d, 7 d and 28 d strength. The results reveal that the development rate of strength in period from 3 d to 7 d gets slow with increasing content of mineral admixtures except for concrete with only GBFS less than 20%. In the case of substituting FA as the only mineral admixture for part of cement, the development rate of strength of C30 concrete in period from 7 d to 28 d keeps roughly constant even that of C60 concrete increases. When substituting mineral admixtures in the presence of GBFS for cement within experimental range, the development rate of strength in period from 7 d to 28 d gets fast with increasing substitution content. The enhancing effect of combining FA and GBFS occurs in period from 7 d to 28 d for both C30 and C60 concretes (FA+GBFS≤40%), even occurs in period from 3 d to 7 d for C60 concrete. Based on 7 d strength and the development rate, 28 d strength of concrete can be predicted accurately.


2013 ◽  
Vol 857 ◽  
pp. 105-109
Author(s):  
Xiu Hua Zheng ◽  
Shu Jie Song ◽  
Yong Quan Zhang

This paper presents an experimental study on the permeability and the pore structure of lightweight concrete with fly ash, zeolite powder, or silica fume, in comparison to that of normal weight aggregate concrete. The results showed that the mineral admixtures can improve the anti-permeability performance of lightweight aggregate concrete, and mixed with compound mineral admixtures further more. The resistance to chloride-ion permeability of light weight concrete was higher than that of At the same strength grade, the anti-permeability performance of lightweight aggregate concrete is better than that of normal weight aggregate concrete. The anti-permeability performance of LC40 was similar to that of C60. Mineral admixtures can obviously improve the pore structure of lightweight aggregate concrete, the total porosity reduced while the pore size decreased.


2022 ◽  
Vol 1048 ◽  
pp. 359-365
Author(s):  
Ihtesham Hussain Mohammed ◽  
Ahmed Majid Salim Al Aamri ◽  
Shakila Javed ◽  
Yahya Ubaid Al Shamsi

In this study, an experimental investigation was done to study the behaviour of Normal Strength Concrete (NSC) and High Strength Concrete (HSC) Plain beams under torsion with the concrete mix of M40 and M100. No mineral admixtures are used to obtain the required strength of concrete. Eight NSC beams and eight HSC beams whose width was varying with 75 mm, 100 mm, and 150 mm; depth varying as 75 mm, 100 mm, 150 mm and 200 mm; and span of the beams varying 600 mm, 800 mm and 1200 mm were casted and cured to stud the effect of torsion. The principle aim of this study was to understand the torsional behaviour of the NSC and HSC beams for rotation, cracking, size effect and torsional strength. A standard torsional loading method was used for conducting the testing of beams. The results obtained were compared with different theories and code equations. It was observed that the torsional strength of the beam increases with the increase in strength of concrete. HSC beams have higher torsional strength than the NSC beams which has the same amount of reinforcement.


2018 ◽  
Vol 2018 ◽  
pp. 1-12
Author(s):  
Fatih Özcan ◽  
Halil Kaymak

In this work, utilization of metakaolin (MK) and calcite (C), working reversely in workability aspect, as mineral admixture in self-compacting concrete (SCC), was investigated. MK and C replaced cement in mass basis at various replacement ratios, separately and together. In total, 19 different SCCs were produced. Binder content and water to binder ratio were selected as 500 kg/m3 and 0.4, respectively. Workability tests including slump flow, T50, L-box, and V-funnel tests were performed. Consistency and setting times of binder paste were measured. While replacement of MK with cement increased the amount of plasticiser requirement, calcite worked reversely and decreased it. Reverse influence of MK and C on plasticiser requirement of SCC made possible to produce SCC at total 45% replacement ratio of MK and C together. Samples of SCC were cured in water at 20°C temperature. Compressive strengths of SCC samples were measured up to six months to evaluate the influence of MK and C, separately and together. Ultrasonic pulse velocity, abrasion, and capillary water absorption values of samples were determined at specified age. MK inclusion in concrete reduces workability, while C inclusion increases it. C and MK inclusion together remedied workability of concrete and enabled to produce SCC with high volume of admixtures. Furthermore, C incorporation increased one-day compressive strength, while MK incorporation reduced it in comparison with control concrete. In long term, C inclusion reduced compressive strength; however, MK inclusion increased it. C inclusion remedied one-day strength of concrete when it was used together with MK. MK inclusion remedied long-term compressive strength when it was used together with C and enabled to produce high-strength SCC with high volume of admixtures. SCC containing MK and C together showed better durability-related property.


Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3500
Author(s):  
Yanyan Hu ◽  
Linlin Ma ◽  
Tingshu He

Pre-stressed high-strength concrete piles (PHCP) are widely used in the building industry in China. The main aim of our research was to investigate the utilization of quartz powder, fly ash, and blast furnace slag as mineral additives to prepare PHCP mortar. The samples were prepared using steam and autoclaving steaming. The influence of minerals on the sulfate resistance of mortar was analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) tests. The results showed that when compared to single doped quartz powder samples, samples prepared using fly ash or blast furnace slag improved the sulfate resistance of the PHCP mortar. Furthermore, the resistance to sulfate attack of samples with dual doped quartz powder, fly ash, and blast furnace slag also improved. MIP tests showed that mineral additives can change the pore size distribution after autoclave curing. However, the number of aching holes increased after mixing with 20% quartz powder and caused a decrease in the sulfate resistance.


2018 ◽  
Vol 940 ◽  
pp. 123-127
Author(s):  
Il Sun Kim ◽  
Yoon Suk Choi ◽  
Chan Kyu Lee ◽  
Eun Ik Yang

Calcium leaching degradation could be happened in reinforcement concrete member due to the contact with pure water in underground condition. Thus, it is needed to evaluate the resistance of calcium leaching for concrete mixed with mineral admixtures. So, in this paper, to evaluate the flexural behavior in RC member with mineral admixture under calcium leaching degradation, we investigated the effect of calcium leaching using the non-linear finite-element program. From the results, the load capacity and flexible rigidity of a degraded RC member decrease when the degradation level increases with leaching period. And, regardless of the type of mineral admixtures, finite-element-method analysis effectively showed the characteristics of calcium leaching damaged RC beam.


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